Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection
The nitrogen, sulfur codoped hierarchical porous carbon tubes were synthesized using oxidized asphaltene, melamine and trithiocyanuric acid, it showed excellent performance in the detection of trace amounts of Cd2+/Pb2+ thanks to its rich sulfur and nitrogen functional groups as well as hierarchical...
Ausführliche Beschreibung
Autor*in: |
Li, Huiyu [verfasserIn] Zuo, Pingping [verfasserIn] Qu, Shijie [verfasserIn] Qin, Fangfang [verfasserIn] Li, Na [verfasserIn] Shen, Wenzhong [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2023 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Applied surface science - Amsterdam : Elsevier, 1985, 615 |
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Übergeordnetes Werk: |
volume:615 |
DOI / URN: |
10.1016/j.apsusc.2023.156426 |
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Katalog-ID: |
ELV064167569 |
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245 | 1 | 0 | |a Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection |
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520 | |a The nitrogen, sulfur codoped hierarchical porous carbon tubes were synthesized using oxidized asphaltene, melamine and trithiocyanuric acid, it showed excellent performance in the detection of trace amounts of Cd2+/Pb2+ thanks to its rich sulfur and nitrogen functional groups as well as hierarchical porous tube structure. The introduction of oxidized asphaltene increased the conductivity of the resultant carbon material while retaining a high sulfur content (6.13 wt%). Under the optimum conditions, the resultant porous carbon tube was used as electrochemical detection sensor for heavy metal ions. The sensitivities and detection limits for individual Cd2+ and Pb2+ were 19.4802 and 33.2850 μA/μM, 2.80 and 1.38 nM; while the sensitivities and detection limits for simultaneous Cd2+ and Pb2+ were 14.5474 and 37.3337 μA/μM, 3.75 and 1.23 nM, respectively. This sensor also was utilized to detect actual water samples, and it was successful in measuring environmental heavy metal contaminants with acceptable recoveries of 97.34–102.83% for Cd2+ and 97.46–106.47% for Pb2+. | ||
650 | 4 | |a Nitrogen, sulfur codoped | |
650 | 4 | |a Heavy metal ion | |
650 | 4 | |a Oxidized asphaltene | |
650 | 4 | |a Nitrogen carbide | |
700 | 1 | |a Zuo, Pingping |e verfasserin |4 aut | |
700 | 1 | |a Qu, Shijie |e verfasserin |4 aut | |
700 | 1 | |a Qin, Fangfang |e verfasserin |4 aut | |
700 | 1 | |a Li, Na |e verfasserin |4 aut | |
700 | 1 | |a Shen, Wenzhong |e verfasserin |4 aut | |
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2023 |
allfields |
10.1016/j.apsusc.2023.156426 doi (DE-627)ELV064167569 (ELSEVIER)S0169-4332(23)00102-2 DE-627 ger DE-627 rda eng 670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Li, Huiyu verfasserin aut Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The nitrogen, sulfur codoped hierarchical porous carbon tubes were synthesized using oxidized asphaltene, melamine and trithiocyanuric acid, it showed excellent performance in the detection of trace amounts of Cd2+/Pb2+ thanks to its rich sulfur and nitrogen functional groups as well as hierarchical porous tube structure. The introduction of oxidized asphaltene increased the conductivity of the resultant carbon material while retaining a high sulfur content (6.13 wt%). Under the optimum conditions, the resultant porous carbon tube was used as electrochemical detection sensor for heavy metal ions. The sensitivities and detection limits for individual Cd2+ and Pb2+ were 19.4802 and 33.2850 μA/μM, 2.80 and 1.38 nM; while the sensitivities and detection limits for simultaneous Cd2+ and Pb2+ were 14.5474 and 37.3337 μA/μM, 3.75 and 1.23 nM, respectively. This sensor also was utilized to detect actual water samples, and it was successful in measuring environmental heavy metal contaminants with acceptable recoveries of 97.34–102.83% for Cd2+ and 97.46–106.47% for Pb2+. Nitrogen, sulfur codoped Heavy metal ion Oxidized asphaltene Nitrogen carbide Zuo, Pingping verfasserin aut Qu, Shijie verfasserin aut Qin, Fangfang verfasserin aut Li, Na verfasserin aut Shen, Wenzhong verfasserin aut Enthalten in Applied surface science Amsterdam : Elsevier, 1985 615 Online-Ressource (DE-627)312151128 (DE-600)2002520-8 (DE-576)094476985 nnns volume:615 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 35.18 Kolloidchemie Grenzflächenchemie VZ 52.78 Oberflächentechnik Wärmebehandlung VZ AR 615 |
spelling |
10.1016/j.apsusc.2023.156426 doi (DE-627)ELV064167569 (ELSEVIER)S0169-4332(23)00102-2 DE-627 ger DE-627 rda eng 670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Li, Huiyu verfasserin aut Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The nitrogen, sulfur codoped hierarchical porous carbon tubes were synthesized using oxidized asphaltene, melamine and trithiocyanuric acid, it showed excellent performance in the detection of trace amounts of Cd2+/Pb2+ thanks to its rich sulfur and nitrogen functional groups as well as hierarchical porous tube structure. The introduction of oxidized asphaltene increased the conductivity of the resultant carbon material while retaining a high sulfur content (6.13 wt%). Under the optimum conditions, the resultant porous carbon tube was used as electrochemical detection sensor for heavy metal ions. The sensitivities and detection limits for individual Cd2+ and Pb2+ were 19.4802 and 33.2850 μA/μM, 2.80 and 1.38 nM; while the sensitivities and detection limits for simultaneous Cd2+ and Pb2+ were 14.5474 and 37.3337 μA/μM, 3.75 and 1.23 nM, respectively. This sensor also was utilized to detect actual water samples, and it was successful in measuring environmental heavy metal contaminants with acceptable recoveries of 97.34–102.83% for Cd2+ and 97.46–106.47% for Pb2+. Nitrogen, sulfur codoped Heavy metal ion Oxidized asphaltene Nitrogen carbide Zuo, Pingping verfasserin aut Qu, Shijie verfasserin aut Qin, Fangfang verfasserin aut Li, Na verfasserin aut Shen, Wenzhong verfasserin aut Enthalten in Applied surface science Amsterdam : Elsevier, 1985 615 Online-Ressource (DE-627)312151128 (DE-600)2002520-8 (DE-576)094476985 nnns volume:615 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 35.18 Kolloidchemie Grenzflächenchemie VZ 52.78 Oberflächentechnik Wärmebehandlung VZ AR 615 |
allfields_unstemmed |
10.1016/j.apsusc.2023.156426 doi (DE-627)ELV064167569 (ELSEVIER)S0169-4332(23)00102-2 DE-627 ger DE-627 rda eng 670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Li, Huiyu verfasserin aut Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The nitrogen, sulfur codoped hierarchical porous carbon tubes were synthesized using oxidized asphaltene, melamine and trithiocyanuric acid, it showed excellent performance in the detection of trace amounts of Cd2+/Pb2+ thanks to its rich sulfur and nitrogen functional groups as well as hierarchical porous tube structure. The introduction of oxidized asphaltene increased the conductivity of the resultant carbon material while retaining a high sulfur content (6.13 wt%). Under the optimum conditions, the resultant porous carbon tube was used as electrochemical detection sensor for heavy metal ions. The sensitivities and detection limits for individual Cd2+ and Pb2+ were 19.4802 and 33.2850 μA/μM, 2.80 and 1.38 nM; while the sensitivities and detection limits for simultaneous Cd2+ and Pb2+ were 14.5474 and 37.3337 μA/μM, 3.75 and 1.23 nM, respectively. This sensor also was utilized to detect actual water samples, and it was successful in measuring environmental heavy metal contaminants with acceptable recoveries of 97.34–102.83% for Cd2+ and 97.46–106.47% for Pb2+. Nitrogen, sulfur codoped Heavy metal ion Oxidized asphaltene Nitrogen carbide Zuo, Pingping verfasserin aut Qu, Shijie verfasserin aut Qin, Fangfang verfasserin aut Li, Na verfasserin aut Shen, Wenzhong verfasserin aut Enthalten in Applied surface science Amsterdam : Elsevier, 1985 615 Online-Ressource (DE-627)312151128 (DE-600)2002520-8 (DE-576)094476985 nnns volume:615 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 35.18 Kolloidchemie Grenzflächenchemie VZ 52.78 Oberflächentechnik Wärmebehandlung VZ AR 615 |
allfieldsGer |
10.1016/j.apsusc.2023.156426 doi (DE-627)ELV064167569 (ELSEVIER)S0169-4332(23)00102-2 DE-627 ger DE-627 rda eng 670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Li, Huiyu verfasserin aut Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The nitrogen, sulfur codoped hierarchical porous carbon tubes were synthesized using oxidized asphaltene, melamine and trithiocyanuric acid, it showed excellent performance in the detection of trace amounts of Cd2+/Pb2+ thanks to its rich sulfur and nitrogen functional groups as well as hierarchical porous tube structure. The introduction of oxidized asphaltene increased the conductivity of the resultant carbon material while retaining a high sulfur content (6.13 wt%). Under the optimum conditions, the resultant porous carbon tube was used as electrochemical detection sensor for heavy metal ions. The sensitivities and detection limits for individual Cd2+ and Pb2+ were 19.4802 and 33.2850 μA/μM, 2.80 and 1.38 nM; while the sensitivities and detection limits for simultaneous Cd2+ and Pb2+ were 14.5474 and 37.3337 μA/μM, 3.75 and 1.23 nM, respectively. This sensor also was utilized to detect actual water samples, and it was successful in measuring environmental heavy metal contaminants with acceptable recoveries of 97.34–102.83% for Cd2+ and 97.46–106.47% for Pb2+. Nitrogen, sulfur codoped Heavy metal ion Oxidized asphaltene Nitrogen carbide Zuo, Pingping verfasserin aut Qu, Shijie verfasserin aut Qin, Fangfang verfasserin aut Li, Na verfasserin aut Shen, Wenzhong verfasserin aut Enthalten in Applied surface science Amsterdam : Elsevier, 1985 615 Online-Ressource (DE-627)312151128 (DE-600)2002520-8 (DE-576)094476985 nnns volume:615 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 35.18 Kolloidchemie Grenzflächenchemie VZ 52.78 Oberflächentechnik Wärmebehandlung VZ AR 615 |
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10.1016/j.apsusc.2023.156426 doi (DE-627)ELV064167569 (ELSEVIER)S0169-4332(23)00102-2 DE-627 ger DE-627 rda eng 670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Li, Huiyu verfasserin aut Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The nitrogen, sulfur codoped hierarchical porous carbon tubes were synthesized using oxidized asphaltene, melamine and trithiocyanuric acid, it showed excellent performance in the detection of trace amounts of Cd2+/Pb2+ thanks to its rich sulfur and nitrogen functional groups as well as hierarchical porous tube structure. The introduction of oxidized asphaltene increased the conductivity of the resultant carbon material while retaining a high sulfur content (6.13 wt%). Under the optimum conditions, the resultant porous carbon tube was used as electrochemical detection sensor for heavy metal ions. The sensitivities and detection limits for individual Cd2+ and Pb2+ were 19.4802 and 33.2850 μA/μM, 2.80 and 1.38 nM; while the sensitivities and detection limits for simultaneous Cd2+ and Pb2+ were 14.5474 and 37.3337 μA/μM, 3.75 and 1.23 nM, respectively. This sensor also was utilized to detect actual water samples, and it was successful in measuring environmental heavy metal contaminants with acceptable recoveries of 97.34–102.83% for Cd2+ and 97.46–106.47% for Pb2+. Nitrogen, sulfur codoped Heavy metal ion Oxidized asphaltene Nitrogen carbide Zuo, Pingping verfasserin aut Qu, Shijie verfasserin aut Qin, Fangfang verfasserin aut Li, Na verfasserin aut Shen, Wenzhong verfasserin aut Enthalten in Applied surface science Amsterdam : Elsevier, 1985 615 Online-Ressource (DE-627)312151128 (DE-600)2002520-8 (DE-576)094476985 nnns volume:615 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 35.18 Kolloidchemie Grenzflächenchemie VZ 52.78 Oberflächentechnik Wärmebehandlung VZ AR 615 |
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Nitrogen, sulfur codoped Heavy metal ion Oxidized asphaltene Nitrogen carbide |
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Li, Huiyu @@aut@@ Zuo, Pingping @@aut@@ Qu, Shijie @@aut@@ Qin, Fangfang @@aut@@ Li, Na @@aut@@ Shen, Wenzhong @@aut@@ |
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Li, Huiyu ddc 670 bkl 33.68 bkl 35.18 bkl 52.78 misc Nitrogen, sulfur codoped misc Heavy metal ion misc Oxidized asphaltene misc Nitrogen carbide Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection |
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670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection Nitrogen, sulfur codoped Heavy metal ion Oxidized asphaltene Nitrogen carbide |
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hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection |
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Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection |
abstract |
The nitrogen, sulfur codoped hierarchical porous carbon tubes were synthesized using oxidized asphaltene, melamine and trithiocyanuric acid, it showed excellent performance in the detection of trace amounts of Cd2+/Pb2+ thanks to its rich sulfur and nitrogen functional groups as well as hierarchical porous tube structure. The introduction of oxidized asphaltene increased the conductivity of the resultant carbon material while retaining a high sulfur content (6.13 wt%). Under the optimum conditions, the resultant porous carbon tube was used as electrochemical detection sensor for heavy metal ions. The sensitivities and detection limits for individual Cd2+ and Pb2+ were 19.4802 and 33.2850 μA/μM, 2.80 and 1.38 nM; while the sensitivities and detection limits for simultaneous Cd2+ and Pb2+ were 14.5474 and 37.3337 μA/μM, 3.75 and 1.23 nM, respectively. This sensor also was utilized to detect actual water samples, and it was successful in measuring environmental heavy metal contaminants with acceptable recoveries of 97.34–102.83% for Cd2+ and 97.46–106.47% for Pb2+. |
abstractGer |
The nitrogen, sulfur codoped hierarchical porous carbon tubes were synthesized using oxidized asphaltene, melamine and trithiocyanuric acid, it showed excellent performance in the detection of trace amounts of Cd2+/Pb2+ thanks to its rich sulfur and nitrogen functional groups as well as hierarchical porous tube structure. The introduction of oxidized asphaltene increased the conductivity of the resultant carbon material while retaining a high sulfur content (6.13 wt%). Under the optimum conditions, the resultant porous carbon tube was used as electrochemical detection sensor for heavy metal ions. The sensitivities and detection limits for individual Cd2+ and Pb2+ were 19.4802 and 33.2850 μA/μM, 2.80 and 1.38 nM; while the sensitivities and detection limits for simultaneous Cd2+ and Pb2+ were 14.5474 and 37.3337 μA/μM, 3.75 and 1.23 nM, respectively. This sensor also was utilized to detect actual water samples, and it was successful in measuring environmental heavy metal contaminants with acceptable recoveries of 97.34–102.83% for Cd2+ and 97.46–106.47% for Pb2+. |
abstract_unstemmed |
The nitrogen, sulfur codoped hierarchical porous carbon tubes were synthesized using oxidized asphaltene, melamine and trithiocyanuric acid, it showed excellent performance in the detection of trace amounts of Cd2+/Pb2+ thanks to its rich sulfur and nitrogen functional groups as well as hierarchical porous tube structure. The introduction of oxidized asphaltene increased the conductivity of the resultant carbon material while retaining a high sulfur content (6.13 wt%). Under the optimum conditions, the resultant porous carbon tube was used as electrochemical detection sensor for heavy metal ions. The sensitivities and detection limits for individual Cd2+ and Pb2+ were 19.4802 and 33.2850 μA/μM, 2.80 and 1.38 nM; while the sensitivities and detection limits for simultaneous Cd2+ and Pb2+ were 14.5474 and 37.3337 μA/μM, 3.75 and 1.23 nM, respectively. This sensor also was utilized to detect actual water samples, and it was successful in measuring environmental heavy metal contaminants with acceptable recoveries of 97.34–102.83% for Cd2+ and 97.46–106.47% for Pb2+. |
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title_short |
Hybrid hierarchically porous carbon micron tubes for trace cadmium and lead ions electrochemical detection |
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Zuo, Pingping Qu, Shijie Qin, Fangfang Li, Na Shen, Wenzhong |
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score |
7.4013596 |