Inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems
The inhibition effect of 8-hydroxyquinoline (8-HQ) on the corrosion of gray cast iron rotors for automotive applications was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 0.1 M HCl solution. The experimental results suggest that the 8-hydroxyquinoline...
Ausführliche Beschreibung
Autor*in: |
Motta, M. [verfasserIn] Zanocco, M. [verfasserIn] Rondinella, A. [verfasserIn] Iodice, V. [verfasserIn] Sin, A. [verfasserIn] Fedrizzi, L. [verfasserIn] Andreatta, F. [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2023 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Electrochimica acta - New York, NY [u.a.] : Elsevier, 1959, 449 |
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Übergeordnetes Werk: |
volume:449 |
DOI / URN: |
10.1016/j.electacta.2023.142221 |
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Katalog-ID: |
ELV064483258 |
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520 | |a The inhibition effect of 8-hydroxyquinoline (8-HQ) on the corrosion of gray cast iron rotors for automotive applications was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 0.1 M HCl solution. The experimental results suggest that the 8-hydroxyquinoline is a mixed inhibitor reducing both the anodic and the cathodic current densities. Besides, EIS results indicate that the inhibitor provides a stable protection over 9 days of exposure to the electrolyte due to the cooperative formation of an adsorbed layer of 8-HQ on the rotor and a top layer probably constituted by a complex between 8-HQ and iron. The presence of the adsorbed layer and the complex with 8-HQ was confirmed by means of Energy Dispersive X-ray analysis (EDX) and Fourier-transform spectroscopy (FT-IR). | ||
650 | 4 | |a Cast iron rotor | |
650 | 4 | |a 8-hydroxyquinoline | |
650 | 4 | |a Corrosion inhibitor | |
700 | 1 | |a Zanocco, M. |e verfasserin |4 aut | |
700 | 1 | |a Rondinella, A. |e verfasserin |4 aut | |
700 | 1 | |a Iodice, V. |e verfasserin |4 aut | |
700 | 1 | |a Sin, A. |e verfasserin |4 aut | |
700 | 1 | |a Fedrizzi, L. |e verfasserin |4 aut | |
700 | 1 | |a Andreatta, F. |e verfasserin |4 aut | |
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2023 |
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35.00 |
publishDate |
2023 |
allfields |
10.1016/j.electacta.2023.142221 doi (DE-627)ELV064483258 (ELSEVIER)S0013-4686(23)00402-4 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Motta, M. verfasserin (orcid)0000-0003-3433-4765 aut Inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The inhibition effect of 8-hydroxyquinoline (8-HQ) on the corrosion of gray cast iron rotors for automotive applications was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 0.1 M HCl solution. The experimental results suggest that the 8-hydroxyquinoline is a mixed inhibitor reducing both the anodic and the cathodic current densities. Besides, EIS results indicate that the inhibitor provides a stable protection over 9 days of exposure to the electrolyte due to the cooperative formation of an adsorbed layer of 8-HQ on the rotor and a top layer probably constituted by a complex between 8-HQ and iron. The presence of the adsorbed layer and the complex with 8-HQ was confirmed by means of Energy Dispersive X-ray analysis (EDX) and Fourier-transform spectroscopy (FT-IR). Cast iron rotor 8-hydroxyquinoline Corrosion inhibitor Zanocco, M. verfasserin aut Rondinella, A. verfasserin aut Iodice, V. verfasserin aut Sin, A. verfasserin aut Fedrizzi, L. verfasserin aut Andreatta, F. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 449 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:449 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 449 |
spelling |
10.1016/j.electacta.2023.142221 doi (DE-627)ELV064483258 (ELSEVIER)S0013-4686(23)00402-4 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Motta, M. verfasserin (orcid)0000-0003-3433-4765 aut Inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The inhibition effect of 8-hydroxyquinoline (8-HQ) on the corrosion of gray cast iron rotors for automotive applications was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 0.1 M HCl solution. The experimental results suggest that the 8-hydroxyquinoline is a mixed inhibitor reducing both the anodic and the cathodic current densities. Besides, EIS results indicate that the inhibitor provides a stable protection over 9 days of exposure to the electrolyte due to the cooperative formation of an adsorbed layer of 8-HQ on the rotor and a top layer probably constituted by a complex between 8-HQ and iron. The presence of the adsorbed layer and the complex with 8-HQ was confirmed by means of Energy Dispersive X-ray analysis (EDX) and Fourier-transform spectroscopy (FT-IR). Cast iron rotor 8-hydroxyquinoline Corrosion inhibitor Zanocco, M. verfasserin aut Rondinella, A. verfasserin aut Iodice, V. verfasserin aut Sin, A. verfasserin aut Fedrizzi, L. verfasserin aut Andreatta, F. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 449 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:449 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 449 |
allfields_unstemmed |
10.1016/j.electacta.2023.142221 doi (DE-627)ELV064483258 (ELSEVIER)S0013-4686(23)00402-4 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Motta, M. verfasserin (orcid)0000-0003-3433-4765 aut Inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The inhibition effect of 8-hydroxyquinoline (8-HQ) on the corrosion of gray cast iron rotors for automotive applications was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 0.1 M HCl solution. The experimental results suggest that the 8-hydroxyquinoline is a mixed inhibitor reducing both the anodic and the cathodic current densities. Besides, EIS results indicate that the inhibitor provides a stable protection over 9 days of exposure to the electrolyte due to the cooperative formation of an adsorbed layer of 8-HQ on the rotor and a top layer probably constituted by a complex between 8-HQ and iron. The presence of the adsorbed layer and the complex with 8-HQ was confirmed by means of Energy Dispersive X-ray analysis (EDX) and Fourier-transform spectroscopy (FT-IR). Cast iron rotor 8-hydroxyquinoline Corrosion inhibitor Zanocco, M. verfasserin aut Rondinella, A. verfasserin aut Iodice, V. verfasserin aut Sin, A. verfasserin aut Fedrizzi, L. verfasserin aut Andreatta, F. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 449 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:449 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 449 |
allfieldsGer |
10.1016/j.electacta.2023.142221 doi (DE-627)ELV064483258 (ELSEVIER)S0013-4686(23)00402-4 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Motta, M. verfasserin (orcid)0000-0003-3433-4765 aut Inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The inhibition effect of 8-hydroxyquinoline (8-HQ) on the corrosion of gray cast iron rotors for automotive applications was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 0.1 M HCl solution. The experimental results suggest that the 8-hydroxyquinoline is a mixed inhibitor reducing both the anodic and the cathodic current densities. Besides, EIS results indicate that the inhibitor provides a stable protection over 9 days of exposure to the electrolyte due to the cooperative formation of an adsorbed layer of 8-HQ on the rotor and a top layer probably constituted by a complex between 8-HQ and iron. The presence of the adsorbed layer and the complex with 8-HQ was confirmed by means of Energy Dispersive X-ray analysis (EDX) and Fourier-transform spectroscopy (FT-IR). Cast iron rotor 8-hydroxyquinoline Corrosion inhibitor Zanocco, M. verfasserin aut Rondinella, A. verfasserin aut Iodice, V. verfasserin aut Sin, A. verfasserin aut Fedrizzi, L. verfasserin aut Andreatta, F. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 449 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:449 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 449 |
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10.1016/j.electacta.2023.142221 doi (DE-627)ELV064483258 (ELSEVIER)S0013-4686(23)00402-4 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Motta, M. verfasserin (orcid)0000-0003-3433-4765 aut Inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The inhibition effect of 8-hydroxyquinoline (8-HQ) on the corrosion of gray cast iron rotors for automotive applications was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 0.1 M HCl solution. The experimental results suggest that the 8-hydroxyquinoline is a mixed inhibitor reducing both the anodic and the cathodic current densities. Besides, EIS results indicate that the inhibitor provides a stable protection over 9 days of exposure to the electrolyte due to the cooperative formation of an adsorbed layer of 8-HQ on the rotor and a top layer probably constituted by a complex between 8-HQ and iron. The presence of the adsorbed layer and the complex with 8-HQ was confirmed by means of Energy Dispersive X-ray analysis (EDX) and Fourier-transform spectroscopy (FT-IR). Cast iron rotor 8-hydroxyquinoline Corrosion inhibitor Zanocco, M. verfasserin aut Rondinella, A. verfasserin aut Iodice, V. verfasserin aut Sin, A. verfasserin aut Fedrizzi, L. verfasserin aut Andreatta, F. verfasserin aut Enthalten in Electrochimica acta New York, NY [u.a.] : Elsevier, 1959 449 Online-Ressource (DE-627)300897561 (DE-600)1483548-4 (DE-576)094752451 1873-3859 nnns volume:449 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 449 |
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Inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems |
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Inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems |
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Motta, M. |
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Motta, M. Zanocco, M. Rondinella, A. Iodice, V. Sin, A. Fedrizzi, L. Andreatta, F. |
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Elektronische Aufsätze |
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Motta, M. |
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10.1016/j.electacta.2023.142221 |
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inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems |
title_auth |
Inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems |
abstract |
The inhibition effect of 8-hydroxyquinoline (8-HQ) on the corrosion of gray cast iron rotors for automotive applications was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 0.1 M HCl solution. The experimental results suggest that the 8-hydroxyquinoline is a mixed inhibitor reducing both the anodic and the cathodic current densities. Besides, EIS results indicate that the inhibitor provides a stable protection over 9 days of exposure to the electrolyte due to the cooperative formation of an adsorbed layer of 8-HQ on the rotor and a top layer probably constituted by a complex between 8-HQ and iron. The presence of the adsorbed layer and the complex with 8-HQ was confirmed by means of Energy Dispersive X-ray analysis (EDX) and Fourier-transform spectroscopy (FT-IR). |
abstractGer |
The inhibition effect of 8-hydroxyquinoline (8-HQ) on the corrosion of gray cast iron rotors for automotive applications was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 0.1 M HCl solution. The experimental results suggest that the 8-hydroxyquinoline is a mixed inhibitor reducing both the anodic and the cathodic current densities. Besides, EIS results indicate that the inhibitor provides a stable protection over 9 days of exposure to the electrolyte due to the cooperative formation of an adsorbed layer of 8-HQ on the rotor and a top layer probably constituted by a complex between 8-HQ and iron. The presence of the adsorbed layer and the complex with 8-HQ was confirmed by means of Energy Dispersive X-ray analysis (EDX) and Fourier-transform spectroscopy (FT-IR). |
abstract_unstemmed |
The inhibition effect of 8-hydroxyquinoline (8-HQ) on the corrosion of gray cast iron rotors for automotive applications was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in a 0.1 M HCl solution. The experimental results suggest that the 8-hydroxyquinoline is a mixed inhibitor reducing both the anodic and the cathodic current densities. Besides, EIS results indicate that the inhibitor provides a stable protection over 9 days of exposure to the electrolyte due to the cooperative formation of an adsorbed layer of 8-HQ on the rotor and a top layer probably constituted by a complex between 8-HQ and iron. The presence of the adsorbed layer and the complex with 8-HQ was confirmed by means of Energy Dispersive X-ray analysis (EDX) and Fourier-transform spectroscopy (FT-IR). |
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title_short |
Inhibitive effect of 8-hydroxyquinoline on corrosion of gray cast iron in automotive braking systems |
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Zanocco, M. Rondinella, A. Iodice, V. Sin, A. Fedrizzi, L. Andreatta, F. |
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up_date |
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