Efficient removal of tetracycline by a novel bimetallic nickel/copper-loaded biochar: The crucial roles of π-π interaction and complexation
The development of a novel type of high-efficient biochar (BC) is important for the removal of tetracycline (TC). In this study, a bimetallic nickel/copper-loaded BC (Ni/Cu-BC) was synthesized, which had not been used for TC removal and lacked research on its safety and stability. The adsorption pro...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Zhang, Yu [verfasserIn] Ouyang, Zhuozhi [verfasserIn] Dong, Yankai [verfasserIn] Zhao, Jianhua [verfasserIn] Zhang, Hong [verfasserIn] Li, Xiaohan [verfasserIn] Zhang, Chi [verfasserIn] Tang, Xiwang [verfasserIn] Guo, Xuetao [verfasserIn] Zhu, Lingyan [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2023 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Applied surface science - Amsterdam : Elsevier, 1985, 640 |
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| Übergeordnetes Werk: |
volume:640 |
| DOI / URN: |
10.1016/j.apsusc.2023.158372 |
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| Katalog-ID: |
ELV064799557 |
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| 245 | 1 | 0 | |a Efficient removal of tetracycline by a novel bimetallic nickel/copper-loaded biochar: The crucial roles of π-π interaction and complexation |
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| 520 | |a The development of a novel type of high-efficient biochar (BC) is important for the removal of tetracycline (TC). In this study, a bimetallic nickel/copper-loaded BC (Ni/Cu-BC) was synthesized, which had not been used for TC removal and lacked research on its safety and stability. The adsorption process was more likely to be monolayer chemical adsorption from the experiment. The density functional theory (DFT) calculation revealed that the interaction energy (Eads), energy gap (Eg) and dipole moment (P(D)) confirmed that the bimetallic loading improved the adsorption strength of the BC to TC. Moreover, the distribution of Ni/Cu-BC surface charge was considerably different from BC after bimetallic loading, and local polarization occurred according to the analysis of molecular surface electrostatic potential (ESP). It was demonstrated that the π-π interaction and complexation played a crucial role in the removal of TC. Finally, the functional groups of Ni/Cu-BC in removal were in the following order: CO > CC > NH2 > MO > CO. This study proves that Ni/Cu-BC is a novel, high-efficient, safe and reusable adsorbent. Overall, this study provides a new perspective on the design of BC and develops its environmental applications. | ||
| 650 | 4 | |a Tetracycline | |
| 650 | 4 | |a Bimetallic nickel/copper-loaded biochar | |
| 650 | 4 | |a Removal mechanism | |
| 650 | 4 | |a Environmental application | |
| 700 | 1 | |a Ouyang, Zhuozhi |e verfasserin |0 (orcid)0000-0001-5098-4907 |4 aut | |
| 700 | 1 | |a Dong, Yankai |e verfasserin |0 (orcid)0009-0007-7052-8424 |4 aut | |
| 700 | 1 | |a Zhao, Jianhua |e verfasserin |0 (orcid)0000-0002-4298-4429 |4 aut | |
| 700 | 1 | |a Zhang, Hong |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Xiaohan |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Chi |e verfasserin |4 aut | |
| 700 | 1 | |a Tang, Xiwang |e verfasserin |4 aut | |
| 700 | 1 | |a Guo, Xuetao |e verfasserin |4 aut | |
| 700 | 1 | |a Zhu, Lingyan |e verfasserin |4 aut | |
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10.1016/j.apsusc.2023.158372 doi (DE-627)ELV064799557 (ELSEVIER)S0169-4332(23)02052-4 DE-627 ger DE-627 rda eng 670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Zhang, Yu verfasserin (orcid)0009-0008-0718-139X aut Efficient removal of tetracycline by a novel bimetallic nickel/copper-loaded biochar: The crucial roles of π-π interaction and complexation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The development of a novel type of high-efficient biochar (BC) is important for the removal of tetracycline (TC). In this study, a bimetallic nickel/copper-loaded BC (Ni/Cu-BC) was synthesized, which had not been used for TC removal and lacked research on its safety and stability. The adsorption process was more likely to be monolayer chemical adsorption from the experiment. The density functional theory (DFT) calculation revealed that the interaction energy (Eads), energy gap (Eg) and dipole moment (P(D)) confirmed that the bimetallic loading improved the adsorption strength of the BC to TC. Moreover, the distribution of Ni/Cu-BC surface charge was considerably different from BC after bimetallic loading, and local polarization occurred according to the analysis of molecular surface electrostatic potential (ESP). It was demonstrated that the π-π interaction and complexation played a crucial role in the removal of TC. Finally, the functional groups of Ni/Cu-BC in removal were in the following order: CO > CC > NH2 > MO > CO. This study proves that Ni/Cu-BC is a novel, high-efficient, safe and reusable adsorbent. Overall, this study provides a new perspective on the design of BC and develops its environmental applications. Tetracycline Bimetallic nickel/copper-loaded biochar Removal mechanism Environmental application Ouyang, Zhuozhi verfasserin (orcid)0000-0001-5098-4907 aut Dong, Yankai verfasserin (orcid)0009-0007-7052-8424 aut Zhao, Jianhua verfasserin (orcid)0000-0002-4298-4429 aut Zhang, Hong verfasserin aut Li, Xiaohan verfasserin aut Zhang, Chi verfasserin aut Tang, Xiwang verfasserin aut Guo, Xuetao verfasserin aut Zhu, Lingyan verfasserin aut Enthalten in Applied surface science Amsterdam : Elsevier, 1985 640 Online-Ressource (DE-627)312151128 (DE-600)2002520-8 (DE-576)094476985 nnns volume:640 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 35.18 Kolloidchemie Grenzflächenchemie VZ 52.78 Oberflächentechnik Wärmebehandlung VZ AR 640 |
| spelling |
10.1016/j.apsusc.2023.158372 doi (DE-627)ELV064799557 (ELSEVIER)S0169-4332(23)02052-4 DE-627 ger DE-627 rda eng 670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Zhang, Yu verfasserin (orcid)0009-0008-0718-139X aut Efficient removal of tetracycline by a novel bimetallic nickel/copper-loaded biochar: The crucial roles of π-π interaction and complexation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The development of a novel type of high-efficient biochar (BC) is important for the removal of tetracycline (TC). In this study, a bimetallic nickel/copper-loaded BC (Ni/Cu-BC) was synthesized, which had not been used for TC removal and lacked research on its safety and stability. The adsorption process was more likely to be monolayer chemical adsorption from the experiment. The density functional theory (DFT) calculation revealed that the interaction energy (Eads), energy gap (Eg) and dipole moment (P(D)) confirmed that the bimetallic loading improved the adsorption strength of the BC to TC. Moreover, the distribution of Ni/Cu-BC surface charge was considerably different from BC after bimetallic loading, and local polarization occurred according to the analysis of molecular surface electrostatic potential (ESP). It was demonstrated that the π-π interaction and complexation played a crucial role in the removal of TC. Finally, the functional groups of Ni/Cu-BC in removal were in the following order: CO > CC > NH2 > MO > CO. This study proves that Ni/Cu-BC is a novel, high-efficient, safe and reusable adsorbent. Overall, this study provides a new perspective on the design of BC and develops its environmental applications. Tetracycline Bimetallic nickel/copper-loaded biochar Removal mechanism Environmental application Ouyang, Zhuozhi verfasserin (orcid)0000-0001-5098-4907 aut Dong, Yankai verfasserin (orcid)0009-0007-7052-8424 aut Zhao, Jianhua verfasserin (orcid)0000-0002-4298-4429 aut Zhang, Hong verfasserin aut Li, Xiaohan verfasserin aut Zhang, Chi verfasserin aut Tang, Xiwang verfasserin aut Guo, Xuetao verfasserin aut Zhu, Lingyan verfasserin aut Enthalten in Applied surface science Amsterdam : Elsevier, 1985 640 Online-Ressource (DE-627)312151128 (DE-600)2002520-8 (DE-576)094476985 nnns volume:640 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 35.18 Kolloidchemie Grenzflächenchemie VZ 52.78 Oberflächentechnik Wärmebehandlung VZ AR 640 |
| allfields_unstemmed |
10.1016/j.apsusc.2023.158372 doi (DE-627)ELV064799557 (ELSEVIER)S0169-4332(23)02052-4 DE-627 ger DE-627 rda eng 670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Zhang, Yu verfasserin (orcid)0009-0008-0718-139X aut Efficient removal of tetracycline by a novel bimetallic nickel/copper-loaded biochar: The crucial roles of π-π interaction and complexation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The development of a novel type of high-efficient biochar (BC) is important for the removal of tetracycline (TC). In this study, a bimetallic nickel/copper-loaded BC (Ni/Cu-BC) was synthesized, which had not been used for TC removal and lacked research on its safety and stability. The adsorption process was more likely to be monolayer chemical adsorption from the experiment. The density functional theory (DFT) calculation revealed that the interaction energy (Eads), energy gap (Eg) and dipole moment (P(D)) confirmed that the bimetallic loading improved the adsorption strength of the BC to TC. Moreover, the distribution of Ni/Cu-BC surface charge was considerably different from BC after bimetallic loading, and local polarization occurred according to the analysis of molecular surface electrostatic potential (ESP). It was demonstrated that the π-π interaction and complexation played a crucial role in the removal of TC. Finally, the functional groups of Ni/Cu-BC in removal were in the following order: CO > CC > NH2 > MO > CO. This study proves that Ni/Cu-BC is a novel, high-efficient, safe and reusable adsorbent. Overall, this study provides a new perspective on the design of BC and develops its environmental applications. Tetracycline Bimetallic nickel/copper-loaded biochar Removal mechanism Environmental application Ouyang, Zhuozhi verfasserin (orcid)0000-0001-5098-4907 aut Dong, Yankai verfasserin (orcid)0009-0007-7052-8424 aut Zhao, Jianhua verfasserin (orcid)0000-0002-4298-4429 aut Zhang, Hong verfasserin aut Li, Xiaohan verfasserin aut Zhang, Chi verfasserin aut Tang, Xiwang verfasserin aut Guo, Xuetao verfasserin aut Zhu, Lingyan verfasserin aut Enthalten in Applied surface science Amsterdam : Elsevier, 1985 640 Online-Ressource (DE-627)312151128 (DE-600)2002520-8 (DE-576)094476985 nnns volume:640 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 35.18 Kolloidchemie Grenzflächenchemie VZ 52.78 Oberflächentechnik Wärmebehandlung VZ AR 640 |
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10.1016/j.apsusc.2023.158372 doi (DE-627)ELV064799557 (ELSEVIER)S0169-4332(23)02052-4 DE-627 ger DE-627 rda eng 670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Zhang, Yu verfasserin (orcid)0009-0008-0718-139X aut Efficient removal of tetracycline by a novel bimetallic nickel/copper-loaded biochar: The crucial roles of π-π interaction and complexation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The development of a novel type of high-efficient biochar (BC) is important for the removal of tetracycline (TC). In this study, a bimetallic nickel/copper-loaded BC (Ni/Cu-BC) was synthesized, which had not been used for TC removal and lacked research on its safety and stability. The adsorption process was more likely to be monolayer chemical adsorption from the experiment. The density functional theory (DFT) calculation revealed that the interaction energy (Eads), energy gap (Eg) and dipole moment (P(D)) confirmed that the bimetallic loading improved the adsorption strength of the BC to TC. Moreover, the distribution of Ni/Cu-BC surface charge was considerably different from BC after bimetallic loading, and local polarization occurred according to the analysis of molecular surface electrostatic potential (ESP). It was demonstrated that the π-π interaction and complexation played a crucial role in the removal of TC. Finally, the functional groups of Ni/Cu-BC in removal were in the following order: CO > CC > NH2 > MO > CO. This study proves that Ni/Cu-BC is a novel, high-efficient, safe and reusable adsorbent. Overall, this study provides a new perspective on the design of BC and develops its environmental applications. Tetracycline Bimetallic nickel/copper-loaded biochar Removal mechanism Environmental application Ouyang, Zhuozhi verfasserin (orcid)0000-0001-5098-4907 aut Dong, Yankai verfasserin (orcid)0009-0007-7052-8424 aut Zhao, Jianhua verfasserin (orcid)0000-0002-4298-4429 aut Zhang, Hong verfasserin aut Li, Xiaohan verfasserin aut Zhang, Chi verfasserin aut Tang, Xiwang verfasserin aut Guo, Xuetao verfasserin aut Zhu, Lingyan verfasserin aut Enthalten in Applied surface science Amsterdam : Elsevier, 1985 640 Online-Ressource (DE-627)312151128 (DE-600)2002520-8 (DE-576)094476985 nnns volume:640 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 35.18 Kolloidchemie Grenzflächenchemie VZ 52.78 Oberflächentechnik Wärmebehandlung VZ AR 640 |
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10.1016/j.apsusc.2023.158372 doi (DE-627)ELV064799557 (ELSEVIER)S0169-4332(23)02052-4 DE-627 ger DE-627 rda eng 670 530 660 VZ 33.68 bkl 35.18 bkl 52.78 bkl Zhang, Yu verfasserin (orcid)0009-0008-0718-139X aut Efficient removal of tetracycline by a novel bimetallic nickel/copper-loaded biochar: The crucial roles of π-π interaction and complexation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The development of a novel type of high-efficient biochar (BC) is important for the removal of tetracycline (TC). In this study, a bimetallic nickel/copper-loaded BC (Ni/Cu-BC) was synthesized, which had not been used for TC removal and lacked research on its safety and stability. The adsorption process was more likely to be monolayer chemical adsorption from the experiment. The density functional theory (DFT) calculation revealed that the interaction energy (Eads), energy gap (Eg) and dipole moment (P(D)) confirmed that the bimetallic loading improved the adsorption strength of the BC to TC. Moreover, the distribution of Ni/Cu-BC surface charge was considerably different from BC after bimetallic loading, and local polarization occurred according to the analysis of molecular surface electrostatic potential (ESP). It was demonstrated that the π-π interaction and complexation played a crucial role in the removal of TC. Finally, the functional groups of Ni/Cu-BC in removal were in the following order: CO > CC > NH2 > MO > CO. This study proves that Ni/Cu-BC is a novel, high-efficient, safe and reusable adsorbent. Overall, this study provides a new perspective on the design of BC and develops its environmental applications. Tetracycline Bimetallic nickel/copper-loaded biochar Removal mechanism Environmental application Ouyang, Zhuozhi verfasserin (orcid)0000-0001-5098-4907 aut Dong, Yankai verfasserin (orcid)0009-0007-7052-8424 aut Zhao, Jianhua verfasserin (orcid)0000-0002-4298-4429 aut Zhang, Hong verfasserin aut Li, Xiaohan verfasserin aut Zhang, Chi verfasserin aut Tang, Xiwang verfasserin aut Guo, Xuetao verfasserin aut Zhu, Lingyan verfasserin aut Enthalten in Applied surface science Amsterdam : Elsevier, 1985 640 Online-Ressource (DE-627)312151128 (DE-600)2002520-8 (DE-576)094476985 nnns volume:640 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 35.18 Kolloidchemie Grenzflächenchemie VZ 52.78 Oberflächentechnik Wärmebehandlung VZ AR 640 |
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Tetracycline Bimetallic nickel/copper-loaded biochar Removal mechanism Environmental application |
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Zhang, Yu @@aut@@ Ouyang, Zhuozhi @@aut@@ Dong, Yankai @@aut@@ Zhao, Jianhua @@aut@@ Zhang, Hong @@aut@@ Li, Xiaohan @@aut@@ Zhang, Chi @@aut@@ Tang, Xiwang @@aut@@ Guo, Xuetao @@aut@@ Zhu, Lingyan @@aut@@ |
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2023-01-01T00:00:00Z |
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efficient removal of tetracycline by a novel bimetallic nickel/copper-loaded biochar: the crucial roles of π-π interaction and complexation |
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Efficient removal of tetracycline by a novel bimetallic nickel/copper-loaded biochar: The crucial roles of π-π interaction and complexation |
| abstract |
The development of a novel type of high-efficient biochar (BC) is important for the removal of tetracycline (TC). In this study, a bimetallic nickel/copper-loaded BC (Ni/Cu-BC) was synthesized, which had not been used for TC removal and lacked research on its safety and stability. The adsorption process was more likely to be monolayer chemical adsorption from the experiment. The density functional theory (DFT) calculation revealed that the interaction energy (Eads), energy gap (Eg) and dipole moment (P(D)) confirmed that the bimetallic loading improved the adsorption strength of the BC to TC. Moreover, the distribution of Ni/Cu-BC surface charge was considerably different from BC after bimetallic loading, and local polarization occurred according to the analysis of molecular surface electrostatic potential (ESP). It was demonstrated that the π-π interaction and complexation played a crucial role in the removal of TC. Finally, the functional groups of Ni/Cu-BC in removal were in the following order: CO > CC > NH2 > MO > CO. This study proves that Ni/Cu-BC is a novel, high-efficient, safe and reusable adsorbent. Overall, this study provides a new perspective on the design of BC and develops its environmental applications. |
| abstractGer |
The development of a novel type of high-efficient biochar (BC) is important for the removal of tetracycline (TC). In this study, a bimetallic nickel/copper-loaded BC (Ni/Cu-BC) was synthesized, which had not been used for TC removal and lacked research on its safety and stability. The adsorption process was more likely to be monolayer chemical adsorption from the experiment. The density functional theory (DFT) calculation revealed that the interaction energy (Eads), energy gap (Eg) and dipole moment (P(D)) confirmed that the bimetallic loading improved the adsorption strength of the BC to TC. Moreover, the distribution of Ni/Cu-BC surface charge was considerably different from BC after bimetallic loading, and local polarization occurred according to the analysis of molecular surface electrostatic potential (ESP). It was demonstrated that the π-π interaction and complexation played a crucial role in the removal of TC. Finally, the functional groups of Ni/Cu-BC in removal were in the following order: CO > CC > NH2 > MO > CO. This study proves that Ni/Cu-BC is a novel, high-efficient, safe and reusable adsorbent. Overall, this study provides a new perspective on the design of BC and develops its environmental applications. |
| abstract_unstemmed |
The development of a novel type of high-efficient biochar (BC) is important for the removal of tetracycline (TC). In this study, a bimetallic nickel/copper-loaded BC (Ni/Cu-BC) was synthesized, which had not been used for TC removal and lacked research on its safety and stability. The adsorption process was more likely to be monolayer chemical adsorption from the experiment. The density functional theory (DFT) calculation revealed that the interaction energy (Eads), energy gap (Eg) and dipole moment (P(D)) confirmed that the bimetallic loading improved the adsorption strength of the BC to TC. Moreover, the distribution of Ni/Cu-BC surface charge was considerably different from BC after bimetallic loading, and local polarization occurred according to the analysis of molecular surface electrostatic potential (ESP). It was demonstrated that the π-π interaction and complexation played a crucial role in the removal of TC. Finally, the functional groups of Ni/Cu-BC in removal were in the following order: CO > CC > NH2 > MO > CO. This study proves that Ni/Cu-BC is a novel, high-efficient, safe and reusable adsorbent. Overall, this study provides a new perspective on the design of BC and develops its environmental applications. |
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| score |
7.400483 |