Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition

The removal of organic pollutants especially the antibiotics from wastewater discharge is now becoming very important to mankind. To remove these antibiotics from water in safe and sustainable manner, photocatalytic degradation can be a feasible strategy. Amongst different photocatalysts, coordinati...
Ausführliche Beschreibung

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Autor*in:	Wu, Yu [verfasserIn] Xia, Fangfang [verfasserIn] Li, Congzhu [verfasserIn] Jayswal, Madhav Raj [verfasserIn] Prakash, Om [verfasserIn] Muddassir, Mohd. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Coordination polymer Photocatalytic degradation Pathway Antibiotics

Übergeordnetes Werk:	Enthalten in: Inorganica chimica acta - New York, NY [u.a.] : Elsevier, 1967, 558
Übergeordnetes Werk:	volume:558

DOI / URN:	10.1016/j.ica.2023.121723

Katalog-ID:	ELV064831507

Internformat


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520			\|a The removal of organic pollutants especially the antibiotics from wastewater discharge is now becoming very important to mankind. To remove these antibiotics from water in safe and sustainable manner, photocatalytic degradation can be a feasible strategy. Amongst different photocatalysts, coordination polymers (CPs) are now-a-days gaining attention as a new photocatalytic material. Herein, two coordination polymers derived from Ni(II) and Co(II) having compositions [Ni(HL)(4,4′-bipy)0.5·0.75H2O] (1) and [Co(HL)(phen)·H2O] (2) (H3L = 3-(3,5-dicarboxylphenyl) picolinic acid, 4,4′-bipy = 4, 4′-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized. Both 1 and 2 have been used as photocatalysts to photodegrade varied antibiotics viz. nitrofurazone (NFZ), oxytetracycline (OXY), chloroamphenicol (CAP), metronidazole (MDZ) and sulfamethoxazole (SMT), amongst which it exhibits best photodegradation of the metronidazole (MDZ) antibiotic. Experiments revealed that in comparison to 1, the CP 2 exhibited better photocatalytic activity for the photodegradation of MDZ. A plausible photocatalytic degradation pathway has been proposed by radical tapping experiments and theoretical calculations.
650		4	\|a Coordination polymer
650		4	\|a Photocatalytic degradation
650		4	\|a Pathway
650		4	\|a Antibiotics
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700	1		\|a Prakash, Om \|e verfasserin \|4 aut
700	1		\|a Muddassir, Mohd. \|e verfasserin \|4 aut
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publishDate	2023
allfields	10.1016/j.ica.2023.121723 doi (DE-627)ELV064831507 (ELSEVIER)S0020-1693(23)00348-1 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Wu, Yu verfasserin aut Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The removal of organic pollutants especially the antibiotics from wastewater discharge is now becoming very important to mankind. To remove these antibiotics from water in safe and sustainable manner, photocatalytic degradation can be a feasible strategy. Amongst different photocatalysts, coordination polymers (CPs) are now-a-days gaining attention as a new photocatalytic material. Herein, two coordination polymers derived from Ni(II) and Co(II) having compositions [Ni(HL)(4,4′-bipy)0.5·0.75H2O] (1) and [Co(HL)(phen)·H2O] (2) (H3L = 3-(3,5-dicarboxylphenyl) picolinic acid, 4,4′-bipy = 4, 4′-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized. Both 1 and 2 have been used as photocatalysts to photodegrade varied antibiotics viz. nitrofurazone (NFZ), oxytetracycline (OXY), chloroamphenicol (CAP), metronidazole (MDZ) and sulfamethoxazole (SMT), amongst which it exhibits best photodegradation of the metronidazole (MDZ) antibiotic. Experiments revealed that in comparison to 1, the CP 2 exhibited better photocatalytic activity for the photodegradation of MDZ. A plausible photocatalytic degradation pathway has been proposed by radical tapping experiments and theoretical calculations. Coordination polymer Photocatalytic degradation Pathway Antibiotics Xia, Fangfang verfasserin aut Li, Congzhu verfasserin aut Jayswal, Madhav Raj verfasserin aut Prakash, Om verfasserin aut Muddassir, Mohd. verfasserin aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 558 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:558 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 558
spelling	10.1016/j.ica.2023.121723 doi (DE-627)ELV064831507 (ELSEVIER)S0020-1693(23)00348-1 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Wu, Yu verfasserin aut Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The removal of organic pollutants especially the antibiotics from wastewater discharge is now becoming very important to mankind. To remove these antibiotics from water in safe and sustainable manner, photocatalytic degradation can be a feasible strategy. Amongst different photocatalysts, coordination polymers (CPs) are now-a-days gaining attention as a new photocatalytic material. Herein, two coordination polymers derived from Ni(II) and Co(II) having compositions [Ni(HL)(4,4′-bipy)0.5·0.75H2O] (1) and [Co(HL)(phen)·H2O] (2) (H3L = 3-(3,5-dicarboxylphenyl) picolinic acid, 4,4′-bipy = 4, 4′-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized. Both 1 and 2 have been used as photocatalysts to photodegrade varied antibiotics viz. nitrofurazone (NFZ), oxytetracycline (OXY), chloroamphenicol (CAP), metronidazole (MDZ) and sulfamethoxazole (SMT), amongst which it exhibits best photodegradation of the metronidazole (MDZ) antibiotic. Experiments revealed that in comparison to 1, the CP 2 exhibited better photocatalytic activity for the photodegradation of MDZ. A plausible photocatalytic degradation pathway has been proposed by radical tapping experiments and theoretical calculations. Coordination polymer Photocatalytic degradation Pathway Antibiotics Xia, Fangfang verfasserin aut Li, Congzhu verfasserin aut Jayswal, Madhav Raj verfasserin aut Prakash, Om verfasserin aut Muddassir, Mohd. verfasserin aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 558 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:558 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 558
allfields_unstemmed	10.1016/j.ica.2023.121723 doi (DE-627)ELV064831507 (ELSEVIER)S0020-1693(23)00348-1 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Wu, Yu verfasserin aut Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The removal of organic pollutants especially the antibiotics from wastewater discharge is now becoming very important to mankind. To remove these antibiotics from water in safe and sustainable manner, photocatalytic degradation can be a feasible strategy. Amongst different photocatalysts, coordination polymers (CPs) are now-a-days gaining attention as a new photocatalytic material. Herein, two coordination polymers derived from Ni(II) and Co(II) having compositions [Ni(HL)(4,4′-bipy)0.5·0.75H2O] (1) and [Co(HL)(phen)·H2O] (2) (H3L = 3-(3,5-dicarboxylphenyl) picolinic acid, 4,4′-bipy = 4, 4′-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized. Both 1 and 2 have been used as photocatalysts to photodegrade varied antibiotics viz. nitrofurazone (NFZ), oxytetracycline (OXY), chloroamphenicol (CAP), metronidazole (MDZ) and sulfamethoxazole (SMT), amongst which it exhibits best photodegradation of the metronidazole (MDZ) antibiotic. Experiments revealed that in comparison to 1, the CP 2 exhibited better photocatalytic activity for the photodegradation of MDZ. A plausible photocatalytic degradation pathway has been proposed by radical tapping experiments and theoretical calculations. Coordination polymer Photocatalytic degradation Pathway Antibiotics Xia, Fangfang verfasserin aut Li, Congzhu verfasserin aut Jayswal, Madhav Raj verfasserin aut Prakash, Om verfasserin aut Muddassir, Mohd. verfasserin aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 558 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:558 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 558
allfieldsGer	10.1016/j.ica.2023.121723 doi (DE-627)ELV064831507 (ELSEVIER)S0020-1693(23)00348-1 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Wu, Yu verfasserin aut Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The removal of organic pollutants especially the antibiotics from wastewater discharge is now becoming very important to mankind. To remove these antibiotics from water in safe and sustainable manner, photocatalytic degradation can be a feasible strategy. Amongst different photocatalysts, coordination polymers (CPs) are now-a-days gaining attention as a new photocatalytic material. Herein, two coordination polymers derived from Ni(II) and Co(II) having compositions [Ni(HL)(4,4′-bipy)0.5·0.75H2O] (1) and [Co(HL)(phen)·H2O] (2) (H3L = 3-(3,5-dicarboxylphenyl) picolinic acid, 4,4′-bipy = 4, 4′-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized. Both 1 and 2 have been used as photocatalysts to photodegrade varied antibiotics viz. nitrofurazone (NFZ), oxytetracycline (OXY), chloroamphenicol (CAP), metronidazole (MDZ) and sulfamethoxazole (SMT), amongst which it exhibits best photodegradation of the metronidazole (MDZ) antibiotic. Experiments revealed that in comparison to 1, the CP 2 exhibited better photocatalytic activity for the photodegradation of MDZ. A plausible photocatalytic degradation pathway has been proposed by radical tapping experiments and theoretical calculations. Coordination polymer Photocatalytic degradation Pathway Antibiotics Xia, Fangfang verfasserin aut Li, Congzhu verfasserin aut Jayswal, Madhav Raj verfasserin aut Prakash, Om verfasserin aut Muddassir, Mohd. verfasserin aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 558 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:558 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 558
allfieldsSound	10.1016/j.ica.2023.121723 doi (DE-627)ELV064831507 (ELSEVIER)S0020-1693(23)00348-1 DE-627 ger DE-627 rda eng 540 VZ 35.00 bkl Wu, Yu verfasserin aut Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The removal of organic pollutants especially the antibiotics from wastewater discharge is now becoming very important to mankind. To remove these antibiotics from water in safe and sustainable manner, photocatalytic degradation can be a feasible strategy. Amongst different photocatalysts, coordination polymers (CPs) are now-a-days gaining attention as a new photocatalytic material. Herein, two coordination polymers derived from Ni(II) and Co(II) having compositions [Ni(HL)(4,4′-bipy)0.5·0.75H2O] (1) and [Co(HL)(phen)·H2O] (2) (H3L = 3-(3,5-dicarboxylphenyl) picolinic acid, 4,4′-bipy = 4, 4′-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized. Both 1 and 2 have been used as photocatalysts to photodegrade varied antibiotics viz. nitrofurazone (NFZ), oxytetracycline (OXY), chloroamphenicol (CAP), metronidazole (MDZ) and sulfamethoxazole (SMT), amongst which it exhibits best photodegradation of the metronidazole (MDZ) antibiotic. Experiments revealed that in comparison to 1, the CP 2 exhibited better photocatalytic activity for the photodegradation of MDZ. A plausible photocatalytic degradation pathway has been proposed by radical tapping experiments and theoretical calculations. Coordination polymer Photocatalytic degradation Pathway Antibiotics Xia, Fangfang verfasserin aut Li, Congzhu verfasserin aut Jayswal, Madhav Raj verfasserin aut Prakash, Om verfasserin aut Muddassir, Mohd. verfasserin aut Enthalten in Inorganica chimica acta New York, NY [u.a.] : Elsevier, 1967 558 Online-Ressource (DE-627)301510946 (DE-600)1484441-2 (DE-576)081952694 0020-1693 nnns volume:558 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 558
language	English
source	Enthalten in Inorganica chimica acta 558 volume:558
sourceStr	Enthalten in Inorganica chimica acta 558 volume:558
format_phy_str_mv	Article
bklname	Chemie: Allgemeines
institution	findex.gbv.de
topic_facet	Coordination polymer Photocatalytic degradation Pathway Antibiotics
dewey-raw	540
isfreeaccess_bool	false
container_title	Inorganica chimica acta
authorswithroles_txt_mv	Wu, Yu @@aut@@ Xia, Fangfang @@aut@@ Li, Congzhu @@aut@@ Jayswal, Madhav Raj @@aut@@ Prakash, Om @@aut@@ Muddassir, Mohd. @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	301510946
dewey-sort	3540
id	ELV064831507
language_de	englisch
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author	Wu, Yu
spellingShingle	Wu, Yu ddc 540 bkl 35.00 misc Coordination polymer misc Photocatalytic degradation misc Pathway misc Antibiotics Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition
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topic_title	540 VZ 35.00 bkl Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition Coordination polymer Photocatalytic degradation Pathway Antibiotics
topic	ddc 540 bkl 35.00 misc Coordination polymer misc Photocatalytic degradation misc Pathway misc Antibiotics
topic_unstemmed	ddc 540 bkl 35.00 misc Coordination polymer misc Photocatalytic degradation misc Pathway misc Antibiotics
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title	Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition
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title_full	Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition
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author_browse	Wu, Yu Xia, Fangfang Li, Congzhu Jayswal, Madhav Raj Prakash, Om Muddassir, Mohd.
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doi_str_mv	10.1016/j.ica.2023.121723
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title_sort	two new ni(ii) and co(ii)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition
title_auth	Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition
abstract	The removal of organic pollutants especially the antibiotics from wastewater discharge is now becoming very important to mankind. To remove these antibiotics from water in safe and sustainable manner, photocatalytic degradation can be a feasible strategy. Amongst different photocatalysts, coordination polymers (CPs) are now-a-days gaining attention as a new photocatalytic material. Herein, two coordination polymers derived from Ni(II) and Co(II) having compositions [Ni(HL)(4,4′-bipy)0.5·0.75H2O] (1) and [Co(HL)(phen)·H2O] (2) (H3L = 3-(3,5-dicarboxylphenyl) picolinic acid, 4,4′-bipy = 4, 4′-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized. Both 1 and 2 have been used as photocatalysts to photodegrade varied antibiotics viz. nitrofurazone (NFZ), oxytetracycline (OXY), chloroamphenicol (CAP), metronidazole (MDZ) and sulfamethoxazole (SMT), amongst which it exhibits best photodegradation of the metronidazole (MDZ) antibiotic. Experiments revealed that in comparison to 1, the CP 2 exhibited better photocatalytic activity for the photodegradation of MDZ. A plausible photocatalytic degradation pathway has been proposed by radical tapping experiments and theoretical calculations.
abstractGer	The removal of organic pollutants especially the antibiotics from wastewater discharge is now becoming very important to mankind. To remove these antibiotics from water in safe and sustainable manner, photocatalytic degradation can be a feasible strategy. Amongst different photocatalysts, coordination polymers (CPs) are now-a-days gaining attention as a new photocatalytic material. Herein, two coordination polymers derived from Ni(II) and Co(II) having compositions [Ni(HL)(4,4′-bipy)0.5·0.75H2O] (1) and [Co(HL)(phen)·H2O] (2) (H3L = 3-(3,5-dicarboxylphenyl) picolinic acid, 4,4′-bipy = 4, 4′-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized. Both 1 and 2 have been used as photocatalysts to photodegrade varied antibiotics viz. nitrofurazone (NFZ), oxytetracycline (OXY), chloroamphenicol (CAP), metronidazole (MDZ) and sulfamethoxazole (SMT), amongst which it exhibits best photodegradation of the metronidazole (MDZ) antibiotic. Experiments revealed that in comparison to 1, the CP 2 exhibited better photocatalytic activity for the photodegradation of MDZ. A plausible photocatalytic degradation pathway has been proposed by radical tapping experiments and theoretical calculations.
abstract_unstemmed	The removal of organic pollutants especially the antibiotics from wastewater discharge is now becoming very important to mankind. To remove these antibiotics from water in safe and sustainable manner, photocatalytic degradation can be a feasible strategy. Amongst different photocatalysts, coordination polymers (CPs) are now-a-days gaining attention as a new photocatalytic material. Herein, two coordination polymers derived from Ni(II) and Co(II) having compositions [Ni(HL)(4,4′-bipy)0.5·0.75H2O] (1) and [Co(HL)(phen)·H2O] (2) (H3L = 3-(3,5-dicarboxylphenyl) picolinic acid, 4,4′-bipy = 4, 4′-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized. Both 1 and 2 have been used as photocatalysts to photodegrade varied antibiotics viz. nitrofurazone (NFZ), oxytetracycline (OXY), chloroamphenicol (CAP), metronidazole (MDZ) and sulfamethoxazole (SMT), amongst which it exhibits best photodegradation of the metronidazole (MDZ) antibiotic. Experiments revealed that in comparison to 1, the CP 2 exhibited better photocatalytic activity for the photodegradation of MDZ. A plausible photocatalytic degradation pathway has been proposed by radical tapping experiments and theoretical calculations.
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title_short	Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition
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author2	Xia, Fangfang Li, Congzhu Jayswal, Madhav Raj Prakash, Om Muddassir, Mohd
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doi_str	10.1016/j.ica.2023.121723
up_date	2024-07-06T20:54:27.222Z
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Two new Ni(II) and Co(II)-based coordination polymers based on mixed linkers as photocatalysts for antibiotics decomposition

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