Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation

Laminating adhesives used in multilayer films present strong, irreversible adhesion that limits the produced packaging systems to single-use applications. From a sustainability point of view, the recovery of individual polymers after use is imperative and a pivotal step is to make this adhesion reve...
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Gespeichert in:

Autor*in:	Seyler, H. [verfasserIn] Quiles-Díaz, S. [verfasserIn] Ellis, G.J. [verfasserIn] Shuttleworth, P.S. [verfasserIn] Flores, A. [verfasserIn] Gómez-Fatou, M.A. [verfasserIn] Salavagione, H.J. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Graphene and other 2D-materials Layered structures Recycling Photothermal effect Creep

Übergeordnetes Werk:	Enthalten in: Composites science and technology - Amsterdam [u.a.] : Elsevier, 1985, 243
Übergeordnetes Werk:	volume:243

DOI / URN:	10.1016/j.compscitech.2023.110271

Katalog-ID:	ELV064981827

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520			\|a Laminating adhesives used in multilayer films present strong, irreversible adhesion that limits the produced packaging systems to single-use applications. From a sustainability point of view, the recovery of individual polymers after use is imperative and a pivotal step is to make this adhesion reversible via breakdown of the adhesive structure. This work describes a promising strategy based on the incorporation of graphene into thermoreversible adhesive resin formulations to trigger the rupture of the adhesive network by exposure to IR radiation. Graphene is a thermal absorber that abruptly heats up under irradiation and efficiently dissipates this heat to the surrounding environment causing the adhesive network to collapse, resulting in remarkable changes in its mechanical properties. In this study, graphene was incorporated at low concentrations (0.25–1 wt %) into solvent-free polyurethane adhesives containing thermoreversible moieties. The photothermal effect at different loadings was evaluated and the formulation displaying the best balance between photothermal effect and optical properties was selected. Furthermore, the effect of irradiation on cyclability, fluidity and mechanical properties of the graphene-containing adhesives is evaluated. Good cyclability was observed and samples with a graphene loading of 0.25 wt % and 11.5 wt % of thermoreversible bonds (TRB) showed the largest difference in elongation under IR irradiation with respect to the neat adhesive. Creep testing demonstrated that the strain of this sample increases by almost 200% after irradiation due to the breakdown of the three-dimensional adhesive network triggered by the photothermal effect of graphene.
650		4	\|a Graphene and other 2D-materials
650		4	\|a Layered structures
650		4	\|a Recycling
650		4	\|a Photothermal effect
650		4	\|a Creep
700	1		\|a Quiles-Díaz, S. \|e verfasserin \|4 aut
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700	1		\|a Flores, A. \|e verfasserin \|4 aut
700	1		\|a Gómez-Fatou, M.A. \|e verfasserin \|4 aut
700	1		\|a Salavagione, H.J. \|e verfasserin \|0 (orcid)0000-0001-9588-7879 \|4 aut
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allfields	10.1016/j.compscitech.2023.110271 doi (DE-627)ELV064981827 (ELSEVIER)S0266-3538(23)00365-2 DE-627 ger DE-627 rda eng 660 670 VZ 51.75 bkl Seyler, H. verfasserin aut Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Laminating adhesives used in multilayer films present strong, irreversible adhesion that limits the produced packaging systems to single-use applications. From a sustainability point of view, the recovery of individual polymers after use is imperative and a pivotal step is to make this adhesion reversible via breakdown of the adhesive structure. This work describes a promising strategy based on the incorporation of graphene into thermoreversible adhesive resin formulations to trigger the rupture of the adhesive network by exposure to IR radiation. Graphene is a thermal absorber that abruptly heats up under irradiation and efficiently dissipates this heat to the surrounding environment causing the adhesive network to collapse, resulting in remarkable changes in its mechanical properties. In this study, graphene was incorporated at low concentrations (0.25–1 wt %) into solvent-free polyurethane adhesives containing thermoreversible moieties. The photothermal effect at different loadings was evaluated and the formulation displaying the best balance between photothermal effect and optical properties was selected. Furthermore, the effect of irradiation on cyclability, fluidity and mechanical properties of the graphene-containing adhesives is evaluated. Good cyclability was observed and samples with a graphene loading of 0.25 wt % and 11.5 wt % of thermoreversible bonds (TRB) showed the largest difference in elongation under IR irradiation with respect to the neat adhesive. Creep testing demonstrated that the strain of this sample increases by almost 200% after irradiation due to the breakdown of the three-dimensional adhesive network triggered by the photothermal effect of graphene. Graphene and other 2D-materials Layered structures Recycling Photothermal effect Creep Quiles-Díaz, S. verfasserin aut Ellis, G.J. verfasserin aut Shuttleworth, P.S. verfasserin aut Flores, A. verfasserin aut Gómez-Fatou, M.A. verfasserin aut Salavagione, H.J. verfasserin (orcid)0000-0001-9588-7879 aut Enthalten in Composites science and technology Amsterdam [u.a.] : Elsevier, 1985 243 Online-Ressource (DE-627)320509095 (DE-600)2013182-3 (DE-576)098330314 1879-1050 nnns volume:243 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.75 Verbundwerkstoffe Schichtstoffe VZ AR 243
spelling	10.1016/j.compscitech.2023.110271 doi (DE-627)ELV064981827 (ELSEVIER)S0266-3538(23)00365-2 DE-627 ger DE-627 rda eng 660 670 VZ 51.75 bkl Seyler, H. verfasserin aut Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Laminating adhesives used in multilayer films present strong, irreversible adhesion that limits the produced packaging systems to single-use applications. From a sustainability point of view, the recovery of individual polymers after use is imperative and a pivotal step is to make this adhesion reversible via breakdown of the adhesive structure. This work describes a promising strategy based on the incorporation of graphene into thermoreversible adhesive resin formulations to trigger the rupture of the adhesive network by exposure to IR radiation. Graphene is a thermal absorber that abruptly heats up under irradiation and efficiently dissipates this heat to the surrounding environment causing the adhesive network to collapse, resulting in remarkable changes in its mechanical properties. In this study, graphene was incorporated at low concentrations (0.25–1 wt %) into solvent-free polyurethane adhesives containing thermoreversible moieties. The photothermal effect at different loadings was evaluated and the formulation displaying the best balance between photothermal effect and optical properties was selected. Furthermore, the effect of irradiation on cyclability, fluidity and mechanical properties of the graphene-containing adhesives is evaluated. Good cyclability was observed and samples with a graphene loading of 0.25 wt % and 11.5 wt % of thermoreversible bonds (TRB) showed the largest difference in elongation under IR irradiation with respect to the neat adhesive. Creep testing demonstrated that the strain of this sample increases by almost 200% after irradiation due to the breakdown of the three-dimensional adhesive network triggered by the photothermal effect of graphene. Graphene and other 2D-materials Layered structures Recycling Photothermal effect Creep Quiles-Díaz, S. verfasserin aut Ellis, G.J. verfasserin aut Shuttleworth, P.S. verfasserin aut Flores, A. verfasserin aut Gómez-Fatou, M.A. verfasserin aut Salavagione, H.J. verfasserin (orcid)0000-0001-9588-7879 aut Enthalten in Composites science and technology Amsterdam [u.a.] : Elsevier, 1985 243 Online-Ressource (DE-627)320509095 (DE-600)2013182-3 (DE-576)098330314 1879-1050 nnns volume:243 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.75 Verbundwerkstoffe Schichtstoffe VZ AR 243
allfields_unstemmed	10.1016/j.compscitech.2023.110271 doi (DE-627)ELV064981827 (ELSEVIER)S0266-3538(23)00365-2 DE-627 ger DE-627 rda eng 660 670 VZ 51.75 bkl Seyler, H. verfasserin aut Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Laminating adhesives used in multilayer films present strong, irreversible adhesion that limits the produced packaging systems to single-use applications. From a sustainability point of view, the recovery of individual polymers after use is imperative and a pivotal step is to make this adhesion reversible via breakdown of the adhesive structure. This work describes a promising strategy based on the incorporation of graphene into thermoreversible adhesive resin formulations to trigger the rupture of the adhesive network by exposure to IR radiation. Graphene is a thermal absorber that abruptly heats up under irradiation and efficiently dissipates this heat to the surrounding environment causing the adhesive network to collapse, resulting in remarkable changes in its mechanical properties. In this study, graphene was incorporated at low concentrations (0.25–1 wt %) into solvent-free polyurethane adhesives containing thermoreversible moieties. The photothermal effect at different loadings was evaluated and the formulation displaying the best balance between photothermal effect and optical properties was selected. Furthermore, the effect of irradiation on cyclability, fluidity and mechanical properties of the graphene-containing adhesives is evaluated. Good cyclability was observed and samples with a graphene loading of 0.25 wt % and 11.5 wt % of thermoreversible bonds (TRB) showed the largest difference in elongation under IR irradiation with respect to the neat adhesive. Creep testing demonstrated that the strain of this sample increases by almost 200% after irradiation due to the breakdown of the three-dimensional adhesive network triggered by the photothermal effect of graphene. Graphene and other 2D-materials Layered structures Recycling Photothermal effect Creep Quiles-Díaz, S. verfasserin aut Ellis, G.J. verfasserin aut Shuttleworth, P.S. verfasserin aut Flores, A. verfasserin aut Gómez-Fatou, M.A. verfasserin aut Salavagione, H.J. verfasserin (orcid)0000-0001-9588-7879 aut Enthalten in Composites science and technology Amsterdam [u.a.] : Elsevier, 1985 243 Online-Ressource (DE-627)320509095 (DE-600)2013182-3 (DE-576)098330314 1879-1050 nnns volume:243 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.75 Verbundwerkstoffe Schichtstoffe VZ AR 243
allfieldsGer	10.1016/j.compscitech.2023.110271 doi (DE-627)ELV064981827 (ELSEVIER)S0266-3538(23)00365-2 DE-627 ger DE-627 rda eng 660 670 VZ 51.75 bkl Seyler, H. verfasserin aut Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Laminating adhesives used in multilayer films present strong, irreversible adhesion that limits the produced packaging systems to single-use applications. From a sustainability point of view, the recovery of individual polymers after use is imperative and a pivotal step is to make this adhesion reversible via breakdown of the adhesive structure. This work describes a promising strategy based on the incorporation of graphene into thermoreversible adhesive resin formulations to trigger the rupture of the adhesive network by exposure to IR radiation. Graphene is a thermal absorber that abruptly heats up under irradiation and efficiently dissipates this heat to the surrounding environment causing the adhesive network to collapse, resulting in remarkable changes in its mechanical properties. In this study, graphene was incorporated at low concentrations (0.25–1 wt %) into solvent-free polyurethane adhesives containing thermoreversible moieties. The photothermal effect at different loadings was evaluated and the formulation displaying the best balance between photothermal effect and optical properties was selected. Furthermore, the effect of irradiation on cyclability, fluidity and mechanical properties of the graphene-containing adhesives is evaluated. Good cyclability was observed and samples with a graphene loading of 0.25 wt % and 11.5 wt % of thermoreversible bonds (TRB) showed the largest difference in elongation under IR irradiation with respect to the neat adhesive. Creep testing demonstrated that the strain of this sample increases by almost 200% after irradiation due to the breakdown of the three-dimensional adhesive network triggered by the photothermal effect of graphene. Graphene and other 2D-materials Layered structures Recycling Photothermal effect Creep Quiles-Díaz, S. verfasserin aut Ellis, G.J. verfasserin aut Shuttleworth, P.S. verfasserin aut Flores, A. verfasserin aut Gómez-Fatou, M.A. verfasserin aut Salavagione, H.J. verfasserin (orcid)0000-0001-9588-7879 aut Enthalten in Composites science and technology Amsterdam [u.a.] : Elsevier, 1985 243 Online-Ressource (DE-627)320509095 (DE-600)2013182-3 (DE-576)098330314 1879-1050 nnns volume:243 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.75 Verbundwerkstoffe Schichtstoffe VZ AR 243
allfieldsSound	10.1016/j.compscitech.2023.110271 doi (DE-627)ELV064981827 (ELSEVIER)S0266-3538(23)00365-2 DE-627 ger DE-627 rda eng 660 670 VZ 51.75 bkl Seyler, H. verfasserin aut Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Laminating adhesives used in multilayer films present strong, irreversible adhesion that limits the produced packaging systems to single-use applications. From a sustainability point of view, the recovery of individual polymers after use is imperative and a pivotal step is to make this adhesion reversible via breakdown of the adhesive structure. This work describes a promising strategy based on the incorporation of graphene into thermoreversible adhesive resin formulations to trigger the rupture of the adhesive network by exposure to IR radiation. Graphene is a thermal absorber that abruptly heats up under irradiation and efficiently dissipates this heat to the surrounding environment causing the adhesive network to collapse, resulting in remarkable changes in its mechanical properties. In this study, graphene was incorporated at low concentrations (0.25–1 wt %) into solvent-free polyurethane adhesives containing thermoreversible moieties. The photothermal effect at different loadings was evaluated and the formulation displaying the best balance between photothermal effect and optical properties was selected. Furthermore, the effect of irradiation on cyclability, fluidity and mechanical properties of the graphene-containing adhesives is evaluated. Good cyclability was observed and samples with a graphene loading of 0.25 wt % and 11.5 wt % of thermoreversible bonds (TRB) showed the largest difference in elongation under IR irradiation with respect to the neat adhesive. Creep testing demonstrated that the strain of this sample increases by almost 200% after irradiation due to the breakdown of the three-dimensional adhesive network triggered by the photothermal effect of graphene. Graphene and other 2D-materials Layered structures Recycling Photothermal effect Creep Quiles-Díaz, S. verfasserin aut Ellis, G.J. verfasserin aut Shuttleworth, P.S. verfasserin aut Flores, A. verfasserin aut Gómez-Fatou, M.A. verfasserin aut Salavagione, H.J. verfasserin (orcid)0000-0001-9588-7879 aut Enthalten in Composites science and technology Amsterdam [u.a.] : Elsevier, 1985 243 Online-Ressource (DE-627)320509095 (DE-600)2013182-3 (DE-576)098330314 1879-1050 nnns volume:243 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.75 Verbundwerkstoffe Schichtstoffe VZ AR 243
language	English
source	Enthalten in Composites science and technology 243 volume:243
sourceStr	Enthalten in Composites science and technology 243 volume:243
format_phy_str_mv	Article
bklname	Verbundwerkstoffe Schichtstoffe
institution	findex.gbv.de
topic_facet	Graphene and other 2D-materials Layered structures Recycling Photothermal effect Creep
dewey-raw	660
isfreeaccess_bool	false
container_title	Composites science and technology
authorswithroles_txt_mv	Seyler, H. @@aut@@ Quiles-Díaz, S. @@aut@@ Ellis, G.J. @@aut@@ Shuttleworth, P.S. @@aut@@ Flores, A. @@aut@@ Gómez-Fatou, M.A. @@aut@@ Salavagione, H.J. @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	320509095
dewey-sort	3660
id	ELV064981827
language_de	englisch
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author	Seyler, H.
spellingShingle	Seyler, H. ddc 660 bkl 51.75 misc Graphene and other 2D-materials misc Layered structures misc Recycling misc Photothermal effect misc Creep Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation
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title	Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation
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title_full	Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation
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title_sort	polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation
title_auth	Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation
abstract	Laminating adhesives used in multilayer films present strong, irreversible adhesion that limits the produced packaging systems to single-use applications. From a sustainability point of view, the recovery of individual polymers after use is imperative and a pivotal step is to make this adhesion reversible via breakdown of the adhesive structure. This work describes a promising strategy based on the incorporation of graphene into thermoreversible adhesive resin formulations to trigger the rupture of the adhesive network by exposure to IR radiation. Graphene is a thermal absorber that abruptly heats up under irradiation and efficiently dissipates this heat to the surrounding environment causing the adhesive network to collapse, resulting in remarkable changes in its mechanical properties. In this study, graphene was incorporated at low concentrations (0.25–1 wt %) into solvent-free polyurethane adhesives containing thermoreversible moieties. The photothermal effect at different loadings was evaluated and the formulation displaying the best balance between photothermal effect and optical properties was selected. Furthermore, the effect of irradiation on cyclability, fluidity and mechanical properties of the graphene-containing adhesives is evaluated. Good cyclability was observed and samples with a graphene loading of 0.25 wt % and 11.5 wt % of thermoreversible bonds (TRB) showed the largest difference in elongation under IR irradiation with respect to the neat adhesive. Creep testing demonstrated that the strain of this sample increases by almost 200% after irradiation due to the breakdown of the three-dimensional adhesive network triggered by the photothermal effect of graphene.
abstractGer	Laminating adhesives used in multilayer films present strong, irreversible adhesion that limits the produced packaging systems to single-use applications. From a sustainability point of view, the recovery of individual polymers after use is imperative and a pivotal step is to make this adhesion reversible via breakdown of the adhesive structure. This work describes a promising strategy based on the incorporation of graphene into thermoreversible adhesive resin formulations to trigger the rupture of the adhesive network by exposure to IR radiation. Graphene is a thermal absorber that abruptly heats up under irradiation and efficiently dissipates this heat to the surrounding environment causing the adhesive network to collapse, resulting in remarkable changes in its mechanical properties. In this study, graphene was incorporated at low concentrations (0.25–1 wt %) into solvent-free polyurethane adhesives containing thermoreversible moieties. The photothermal effect at different loadings was evaluated and the formulation displaying the best balance between photothermal effect and optical properties was selected. Furthermore, the effect of irradiation on cyclability, fluidity and mechanical properties of the graphene-containing adhesives is evaluated. Good cyclability was observed and samples with a graphene loading of 0.25 wt % and 11.5 wt % of thermoreversible bonds (TRB) showed the largest difference in elongation under IR irradiation with respect to the neat adhesive. Creep testing demonstrated that the strain of this sample increases by almost 200% after irradiation due to the breakdown of the three-dimensional adhesive network triggered by the photothermal effect of graphene.
abstract_unstemmed	Laminating adhesives used in multilayer films present strong, irreversible adhesion that limits the produced packaging systems to single-use applications. From a sustainability point of view, the recovery of individual polymers after use is imperative and a pivotal step is to make this adhesion reversible via breakdown of the adhesive structure. This work describes a promising strategy based on the incorporation of graphene into thermoreversible adhesive resin formulations to trigger the rupture of the adhesive network by exposure to IR radiation. Graphene is a thermal absorber that abruptly heats up under irradiation and efficiently dissipates this heat to the surrounding environment causing the adhesive network to collapse, resulting in remarkable changes in its mechanical properties. In this study, graphene was incorporated at low concentrations (0.25–1 wt %) into solvent-free polyurethane adhesives containing thermoreversible moieties. The photothermal effect at different loadings was evaluated and the formulation displaying the best balance between photothermal effect and optical properties was selected. Furthermore, the effect of irradiation on cyclability, fluidity and mechanical properties of the graphene-containing adhesives is evaluated. Good cyclability was observed and samples with a graphene loading of 0.25 wt % and 11.5 wt % of thermoreversible bonds (TRB) showed the largest difference in elongation under IR irradiation with respect to the neat adhesive. Creep testing demonstrated that the strain of this sample increases by almost 200% after irradiation due to the breakdown of the three-dimensional adhesive network triggered by the photothermal effect of graphene.
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title_short	Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation
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author2	Quiles-Díaz, S. Ellis, G.J. Shuttleworth, P.S. Flores, A. Gómez-Fatou, M.A. Salavagione, H.J.
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doi_str	10.1016/j.compscitech.2023.110271
up_date	2024-07-06T21:24:34.835Z
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Furthermore, the effect of irradiation on cyclability, fluidity and mechanical properties of the graphene-containing adhesives is evaluated. Good cyclability was observed and samples with a graphene loading of 0.25 wt % and 11.5 wt % of thermoreversible bonds (TRB) showed the largest difference in elongation under IR irradiation with respect to the neat adhesive. 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Polymer nanocomposite adhesives with internal nano-heaters to facilitate multilayer laminate separation

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