The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO

In this study, crystallization of anatase type-TiO2 was achieved in the traditional borosilicate glasses (Na2O.B2O3.SiO2) for the first time. The effect of the TiO2 /Na2O ratio was studied to optimize the selected glass composition, also the effect of adding a definite amount of different transition...
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Gespeichert in:

Autor*in:	Abdel-Hameed, S.A.M. [verfasserIn] Marzouk, M.A. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Borosilicate glasses Transition metals Glass ceramic Photoluminescence Anatase

Übergeordnetes Werk:	Enthalten in: Spectrochimica acta / A - Amsterdam [u.a.] : Elsevier Science, 1967, 304
Übergeordnetes Werk:	volume:304

DOI / URN:	10.1016/j.saa.2023.123393

Katalog-ID:	ELV065102290

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245	1	0	\|a The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO
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520			\|a In this study, crystallization of anatase type-TiO2 was achieved in the traditional borosilicate glasses (Na2O.B2O3.SiO2) for the first time. The effect of the TiO2 /Na2O ratio was studied to optimize the selected glass composition, also the effect of adding a definite amount of different transition metal oxides (TMO) was studied. The glasses were prepared via the conventional melt-quenching method. According to DSC results, heat treatment at 650 °C /10hrs was applied to convert the glasses into glass ceramics. XRD detected the crystallization of anatase, rutile, and cristobalite. A sample with a lower value of TiO2 /Na2O revealed a higher degree of crystallization of anatase than that with a higher value. Both Cr2O3 and NiO additions enhanced the crystallization of cristobalite; while additions of CoO, Fe2O3, V2O5, MnO, CuO or ZnO significantly enhanced the crystallization of anatase in the same order. The morphology of glass ceramic was observed by TEM and SEM, which revealed crystal size < 50 nm. The optical band gap was estimated from UV-Visible absorption spectra, it depicted a wide range of values (4.4–2.1 eV). PL spectra revealed emission colors varied from purple to blue color according to TMO and TiO2 /Na2O ratio. The obtained materials can be utilized as electron transport layers for perovskite solar cells.
650		4	\|a Borosilicate glasses
650		4	\|a Transition metals
650		4	\|a Glass ceramic
650		4	\|a Photoluminescence
650		4	\|a Anatase
700	1		\|a Marzouk, M.A. \|e verfasserin \|4 aut
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publishDate	2023
allfields	10.1016/j.saa.2023.123393 doi (DE-627)ELV065102290 (ELSEVIER)S1386-1425(23)01078-8 DE-627 ger DE-627 rda eng 540 530 VZ 35.00 bkl Abdel-Hameed, S.A.M. verfasserin aut The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, crystallization of anatase type-TiO2 was achieved in the traditional borosilicate glasses (Na2O.B2O3.SiO2) for the first time. The effect of the TiO2 /Na2O ratio was studied to optimize the selected glass composition, also the effect of adding a definite amount of different transition metal oxides (TMO) was studied. The glasses were prepared via the conventional melt-quenching method. According to DSC results, heat treatment at 650 °C /10hrs was applied to convert the glasses into glass ceramics. XRD detected the crystallization of anatase, rutile, and cristobalite. A sample with a lower value of TiO2 /Na2O revealed a higher degree of crystallization of anatase than that with a higher value. Both Cr2O3 and NiO additions enhanced the crystallization of cristobalite; while additions of CoO, Fe2O3, V2O5, MnO, CuO or ZnO significantly enhanced the crystallization of anatase in the same order. The morphology of glass ceramic was observed by TEM and SEM, which revealed crystal size < 50 nm. The optical band gap was estimated from UV-Visible absorption spectra, it depicted a wide range of values (4.4–2.1 eV). PL spectra revealed emission colors varied from purple to blue color according to TMO and TiO2 /Na2O ratio. The obtained materials can be utilized as electron transport layers for perovskite solar cells. Borosilicate glasses Transition metals Glass ceramic Photoluminescence Anatase Marzouk, M.A. verfasserin aut Enthalten in Spectrochimica acta / A Amsterdam [u.a.] : Elsevier Science, 1967 304 Online-Ressource (DE-627)320570983 (DE-600)2016492-0 (DE-576)090956206 1873-3557 nnns volume:304 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 304
spelling	10.1016/j.saa.2023.123393 doi (DE-627)ELV065102290 (ELSEVIER)S1386-1425(23)01078-8 DE-627 ger DE-627 rda eng 540 530 VZ 35.00 bkl Abdel-Hameed, S.A.M. verfasserin aut The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, crystallization of anatase type-TiO2 was achieved in the traditional borosilicate glasses (Na2O.B2O3.SiO2) for the first time. The effect of the TiO2 /Na2O ratio was studied to optimize the selected glass composition, also the effect of adding a definite amount of different transition metal oxides (TMO) was studied. The glasses were prepared via the conventional melt-quenching method. According to DSC results, heat treatment at 650 °C /10hrs was applied to convert the glasses into glass ceramics. XRD detected the crystallization of anatase, rutile, and cristobalite. A sample with a lower value of TiO2 /Na2O revealed a higher degree of crystallization of anatase than that with a higher value. Both Cr2O3 and NiO additions enhanced the crystallization of cristobalite; while additions of CoO, Fe2O3, V2O5, MnO, CuO or ZnO significantly enhanced the crystallization of anatase in the same order. The morphology of glass ceramic was observed by TEM and SEM, which revealed crystal size < 50 nm. The optical band gap was estimated from UV-Visible absorption spectra, it depicted a wide range of values (4.4–2.1 eV). PL spectra revealed emission colors varied from purple to blue color according to TMO and TiO2 /Na2O ratio. The obtained materials can be utilized as electron transport layers for perovskite solar cells. Borosilicate glasses Transition metals Glass ceramic Photoluminescence Anatase Marzouk, M.A. verfasserin aut Enthalten in Spectrochimica acta / A Amsterdam [u.a.] : Elsevier Science, 1967 304 Online-Ressource (DE-627)320570983 (DE-600)2016492-0 (DE-576)090956206 1873-3557 nnns volume:304 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 304
allfields_unstemmed	10.1016/j.saa.2023.123393 doi (DE-627)ELV065102290 (ELSEVIER)S1386-1425(23)01078-8 DE-627 ger DE-627 rda eng 540 530 VZ 35.00 bkl Abdel-Hameed, S.A.M. verfasserin aut The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, crystallization of anatase type-TiO2 was achieved in the traditional borosilicate glasses (Na2O.B2O3.SiO2) for the first time. The effect of the TiO2 /Na2O ratio was studied to optimize the selected glass composition, also the effect of adding a definite amount of different transition metal oxides (TMO) was studied. The glasses were prepared via the conventional melt-quenching method. According to DSC results, heat treatment at 650 °C /10hrs was applied to convert the glasses into glass ceramics. XRD detected the crystallization of anatase, rutile, and cristobalite. A sample with a lower value of TiO2 /Na2O revealed a higher degree of crystallization of anatase than that with a higher value. Both Cr2O3 and NiO additions enhanced the crystallization of cristobalite; while additions of CoO, Fe2O3, V2O5, MnO, CuO or ZnO significantly enhanced the crystallization of anatase in the same order. The morphology of glass ceramic was observed by TEM and SEM, which revealed crystal size < 50 nm. The optical band gap was estimated from UV-Visible absorption spectra, it depicted a wide range of values (4.4–2.1 eV). PL spectra revealed emission colors varied from purple to blue color according to TMO and TiO2 /Na2O ratio. The obtained materials can be utilized as electron transport layers for perovskite solar cells. Borosilicate glasses Transition metals Glass ceramic Photoluminescence Anatase Marzouk, M.A. verfasserin aut Enthalten in Spectrochimica acta / A Amsterdam [u.a.] : Elsevier Science, 1967 304 Online-Ressource (DE-627)320570983 (DE-600)2016492-0 (DE-576)090956206 1873-3557 nnns volume:304 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 304
allfieldsGer	10.1016/j.saa.2023.123393 doi (DE-627)ELV065102290 (ELSEVIER)S1386-1425(23)01078-8 DE-627 ger DE-627 rda eng 540 530 VZ 35.00 bkl Abdel-Hameed, S.A.M. verfasserin aut The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, crystallization of anatase type-TiO2 was achieved in the traditional borosilicate glasses (Na2O.B2O3.SiO2) for the first time. The effect of the TiO2 /Na2O ratio was studied to optimize the selected glass composition, also the effect of adding a definite amount of different transition metal oxides (TMO) was studied. The glasses were prepared via the conventional melt-quenching method. According to DSC results, heat treatment at 650 °C /10hrs was applied to convert the glasses into glass ceramics. XRD detected the crystallization of anatase, rutile, and cristobalite. A sample with a lower value of TiO2 /Na2O revealed a higher degree of crystallization of anatase than that with a higher value. Both Cr2O3 and NiO additions enhanced the crystallization of cristobalite; while additions of CoO, Fe2O3, V2O5, MnO, CuO or ZnO significantly enhanced the crystallization of anatase in the same order. The morphology of glass ceramic was observed by TEM and SEM, which revealed crystal size < 50 nm. The optical band gap was estimated from UV-Visible absorption spectra, it depicted a wide range of values (4.4–2.1 eV). PL spectra revealed emission colors varied from purple to blue color according to TMO and TiO2 /Na2O ratio. The obtained materials can be utilized as electron transport layers for perovskite solar cells. Borosilicate glasses Transition metals Glass ceramic Photoluminescence Anatase Marzouk, M.A. verfasserin aut Enthalten in Spectrochimica acta / A Amsterdam [u.a.] : Elsevier Science, 1967 304 Online-Ressource (DE-627)320570983 (DE-600)2016492-0 (DE-576)090956206 1873-3557 nnns volume:304 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 304
allfieldsSound	10.1016/j.saa.2023.123393 doi (DE-627)ELV065102290 (ELSEVIER)S1386-1425(23)01078-8 DE-627 ger DE-627 rda eng 540 530 VZ 35.00 bkl Abdel-Hameed, S.A.M. verfasserin aut The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, crystallization of anatase type-TiO2 was achieved in the traditional borosilicate glasses (Na2O.B2O3.SiO2) for the first time. The effect of the TiO2 /Na2O ratio was studied to optimize the selected glass composition, also the effect of adding a definite amount of different transition metal oxides (TMO) was studied. The glasses were prepared via the conventional melt-quenching method. According to DSC results, heat treatment at 650 °C /10hrs was applied to convert the glasses into glass ceramics. XRD detected the crystallization of anatase, rutile, and cristobalite. A sample with a lower value of TiO2 /Na2O revealed a higher degree of crystallization of anatase than that with a higher value. Both Cr2O3 and NiO additions enhanced the crystallization of cristobalite; while additions of CoO, Fe2O3, V2O5, MnO, CuO or ZnO significantly enhanced the crystallization of anatase in the same order. The morphology of glass ceramic was observed by TEM and SEM, which revealed crystal size < 50 nm. The optical band gap was estimated from UV-Visible absorption spectra, it depicted a wide range of values (4.4–2.1 eV). PL spectra revealed emission colors varied from purple to blue color according to TMO and TiO2 /Na2O ratio. The obtained materials can be utilized as electron transport layers for perovskite solar cells. Borosilicate glasses Transition metals Glass ceramic Photoluminescence Anatase Marzouk, M.A. verfasserin aut Enthalten in Spectrochimica acta / A Amsterdam [u.a.] : Elsevier Science, 1967 304 Online-Ressource (DE-627)320570983 (DE-600)2016492-0 (DE-576)090956206 1873-3557 nnns volume:304 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.00 Chemie: Allgemeines VZ AR 304
language	English
source	Enthalten in Spectrochimica acta / A 304 volume:304
sourceStr	Enthalten in Spectrochimica acta / A 304 volume:304
format_phy_str_mv	Article
bklname	Chemie: Allgemeines
institution	findex.gbv.de
topic_facet	Borosilicate glasses Transition metals Glass ceramic Photoluminescence Anatase
dewey-raw	540
isfreeaccess_bool	false
container_title	Spectrochimica acta / A
authorswithroles_txt_mv	Abdel-Hameed, S.A.M. @@aut@@ Marzouk, M.A. @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	320570983
dewey-sort	3540
id	ELV065102290
language_de	englisch
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author	Abdel-Hameed, S.A.M.
spellingShingle	Abdel-Hameed, S.A.M. ddc 540 bkl 35.00 misc Borosilicate glasses misc Transition metals misc Glass ceramic misc Photoluminescence misc Anatase The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO
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topic_title	540 530 VZ 35.00 bkl The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO Borosilicate glasses Transition metals Glass ceramic Photoluminescence Anatase
topic	ddc 540 bkl 35.00 misc Borosilicate glasses misc Transition metals misc Glass ceramic misc Photoluminescence misc Anatase
topic_unstemmed	ddc 540 bkl 35.00 misc Borosilicate glasses misc Transition metals misc Glass ceramic misc Photoluminescence misc Anatase
topic_browse	ddc 540 bkl 35.00 misc Borosilicate glasses misc Transition metals misc Glass ceramic misc Photoluminescence misc Anatase
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title	The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO
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title_full	The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO
author_sort	Abdel-Hameed, S.A.M.
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title_sort	the effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-tio
title_auth	The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO
abstract	In this study, crystallization of anatase type-TiO2 was achieved in the traditional borosilicate glasses (Na2O.B2O3.SiO2) for the first time. The effect of the TiO2 /Na2O ratio was studied to optimize the selected glass composition, also the effect of adding a definite amount of different transition metal oxides (TMO) was studied. The glasses were prepared via the conventional melt-quenching method. According to DSC results, heat treatment at 650 °C /10hrs was applied to convert the glasses into glass ceramics. XRD detected the crystallization of anatase, rutile, and cristobalite. A sample with a lower value of TiO2 /Na2O revealed a higher degree of crystallization of anatase than that with a higher value. Both Cr2O3 and NiO additions enhanced the crystallization of cristobalite; while additions of CoO, Fe2O3, V2O5, MnO, CuO or ZnO significantly enhanced the crystallization of anatase in the same order. The morphology of glass ceramic was observed by TEM and SEM, which revealed crystal size < 50 nm. The optical band gap was estimated from UV-Visible absorption spectra, it depicted a wide range of values (4.4–2.1 eV). PL spectra revealed emission colors varied from purple to blue color according to TMO and TiO2 /Na2O ratio. The obtained materials can be utilized as electron transport layers for perovskite solar cells.
abstractGer	In this study, crystallization of anatase type-TiO2 was achieved in the traditional borosilicate glasses (Na2O.B2O3.SiO2) for the first time. The effect of the TiO2 /Na2O ratio was studied to optimize the selected glass composition, also the effect of adding a definite amount of different transition metal oxides (TMO) was studied. The glasses were prepared via the conventional melt-quenching method. According to DSC results, heat treatment at 650 °C /10hrs was applied to convert the glasses into glass ceramics. XRD detected the crystallization of anatase, rutile, and cristobalite. A sample with a lower value of TiO2 /Na2O revealed a higher degree of crystallization of anatase than that with a higher value. Both Cr2O3 and NiO additions enhanced the crystallization of cristobalite; while additions of CoO, Fe2O3, V2O5, MnO, CuO or ZnO significantly enhanced the crystallization of anatase in the same order. The morphology of glass ceramic was observed by TEM and SEM, which revealed crystal size < 50 nm. The optical band gap was estimated from UV-Visible absorption spectra, it depicted a wide range of values (4.4–2.1 eV). PL spectra revealed emission colors varied from purple to blue color according to TMO and TiO2 /Na2O ratio. The obtained materials can be utilized as electron transport layers for perovskite solar cells.
abstract_unstemmed	In this study, crystallization of anatase type-TiO2 was achieved in the traditional borosilicate glasses (Na2O.B2O3.SiO2) for the first time. The effect of the TiO2 /Na2O ratio was studied to optimize the selected glass composition, also the effect of adding a definite amount of different transition metal oxides (TMO) was studied. The glasses were prepared via the conventional melt-quenching method. According to DSC results, heat treatment at 650 °C /10hrs was applied to convert the glasses into glass ceramics. XRD detected the crystallization of anatase, rutile, and cristobalite. A sample with a lower value of TiO2 /Na2O revealed a higher degree of crystallization of anatase than that with a higher value. Both Cr2O3 and NiO additions enhanced the crystallization of cristobalite; while additions of CoO, Fe2O3, V2O5, MnO, CuO or ZnO significantly enhanced the crystallization of anatase in the same order. The morphology of glass ceramic was observed by TEM and SEM, which revealed crystal size < 50 nm. The optical band gap was estimated from UV-Visible absorption spectra, it depicted a wide range of values (4.4–2.1 eV). PL spectra revealed emission colors varied from purple to blue color according to TMO and TiO2 /Na2O ratio. The obtained materials can be utilized as electron transport layers for perovskite solar cells.
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title_short	The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO
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up_date	2024-07-06T21:50:15.688Z
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The effect of different transition metal oxides on the characterization and photoluminescence properties of borosilicate glass ceramics containing nanosized anatase type-TiO

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