Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling
Volatile organic compounds (VOCs) in vehicle cabins pose some health concerns, especially in new cars where interior plastics contribute substantially to VOCs emissions. We investigated the reasons for enhanced VOCs emissions from surface-coated thermoplastic polyester elastomer (TPEE), an automotiv...
Ausführliche Beschreibung
Autor*in: |
Kim, Hyo Jeong [verfasserIn] Jeong, Chanul [verfasserIn] Oh, Arom [verfasserIn] Seo, Yong-Soo [verfasserIn] Jeon, Hotak [verfasserIn] Eom, Youngho [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2023 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Journal of hazardous materials - New York, NY [u.a.] : Science Direct, 1976, 461 |
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Übergeordnetes Werk: |
volume:461 |
DOI / URN: |
10.1016/j.jhazmat.2023.132614 |
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Katalog-ID: |
ELV065169670 |
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245 | 1 | 0 | |a Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling |
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520 | |a Volatile organic compounds (VOCs) in vehicle cabins pose some health concerns, especially in new cars where interior plastics contribute substantially to VOCs emissions. We investigated the reasons for enhanced VOCs emissions from surface-coated thermoplastic polyester elastomer (TPEE), an automotive interior plastic. After applying solvent-based primer and clearcoat coatings, total VOCs (TVOC) level increased by 12.1 times (2066-24,983 μg m−3). Among the 15 emitted VOCs, seven VOCs (esters and ketones) originating from the coating solutions accounted for 77.4 % of TVOC. The remaining solvents resulted from TPEE swelling during coating owing to high chemical affinity with the solvents as evidenced by a low contact angle (14.3°) and high degree swelling (68.9%). Further baking at 80C reduced VOCs levels over time, but some major compounds (methyl isobutyl ketone and butyl acetate) persisted until 6 h. Primer and clearcoat films reduced solvent volatilization by approximately 70 %, creating a blocking effect. Apart from solvents, neat TPEE contained 4.2 % of its weight as potential VOCs. Therefore, enhanced VOCs emissions stem from three factors: (1) excessive TPEE swelling caused by coating solvents and residual solvents released as VOCs, (2) restricted volatilization caused by the coating, and (3) emission of inherent VOCs from neat TPEE. | ||
650 | 4 | |a Automotive interior plastic | |
650 | 4 | |a Surface coating | |
650 | 4 | |a Swelling | |
650 | 4 | |a Thermoplastic polyester elastomer | |
650 | 4 | |a Volatile organic compound | |
700 | 1 | |a Jeong, Chanul |e verfasserin |4 aut | |
700 | 1 | |a Oh, Arom |e verfasserin |4 aut | |
700 | 1 | |a Seo, Yong-Soo |e verfasserin |4 aut | |
700 | 1 | |a Jeon, Hotak |e verfasserin |4 aut | |
700 | 1 | |a Eom, Youngho |e verfasserin |0 (orcid)0000-0002-0922-1155 |4 aut | |
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allfields |
10.1016/j.jhazmat.2023.132614 doi (DE-627)ELV065169670 (ELSEVIER)S0304-3894(23)01897-6 DE-627 ger DE-627 rda eng 530 VZ 43.13 bkl 50.17 bkl 58.53 bkl Kim, Hyo Jeong verfasserin aut Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Volatile organic compounds (VOCs) in vehicle cabins pose some health concerns, especially in new cars where interior plastics contribute substantially to VOCs emissions. We investigated the reasons for enhanced VOCs emissions from surface-coated thermoplastic polyester elastomer (TPEE), an automotive interior plastic. After applying solvent-based primer and clearcoat coatings, total VOCs (TVOC) level increased by 12.1 times (2066-24,983 μg m−3). Among the 15 emitted VOCs, seven VOCs (esters and ketones) originating from the coating solutions accounted for 77.4 % of TVOC. The remaining solvents resulted from TPEE swelling during coating owing to high chemical affinity with the solvents as evidenced by a low contact angle (14.3°) and high degree swelling (68.9%). Further baking at 80C reduced VOCs levels over time, but some major compounds (methyl isobutyl ketone and butyl acetate) persisted until 6 h. Primer and clearcoat films reduced solvent volatilization by approximately 70 %, creating a blocking effect. Apart from solvents, neat TPEE contained 4.2 % of its weight as potential VOCs. Therefore, enhanced VOCs emissions stem from three factors: (1) excessive TPEE swelling caused by coating solvents and residual solvents released as VOCs, (2) restricted volatilization caused by the coating, and (3) emission of inherent VOCs from neat TPEE. Automotive interior plastic Surface coating Swelling Thermoplastic polyester elastomer Volatile organic compound Jeong, Chanul verfasserin aut Oh, Arom verfasserin aut Seo, Yong-Soo verfasserin aut Jeon, Hotak verfasserin aut Eom, Youngho verfasserin (orcid)0000-0002-0922-1155 aut Enthalten in Journal of hazardous materials New York, NY [u.a.] : Science Direct, 1976 461 Online-Ressource (DE-627)302467904 (DE-600)1491302-1 (DE-576)259483893 1873-3336 nnns volume:461 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.13 Umwelttoxikologie VZ 50.17 Sicherheitstechnik VZ 58.53 Abfallwirtschaft VZ AR 461 |
spelling |
10.1016/j.jhazmat.2023.132614 doi (DE-627)ELV065169670 (ELSEVIER)S0304-3894(23)01897-6 DE-627 ger DE-627 rda eng 530 VZ 43.13 bkl 50.17 bkl 58.53 bkl Kim, Hyo Jeong verfasserin aut Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Volatile organic compounds (VOCs) in vehicle cabins pose some health concerns, especially in new cars where interior plastics contribute substantially to VOCs emissions. We investigated the reasons for enhanced VOCs emissions from surface-coated thermoplastic polyester elastomer (TPEE), an automotive interior plastic. After applying solvent-based primer and clearcoat coatings, total VOCs (TVOC) level increased by 12.1 times (2066-24,983 μg m−3). Among the 15 emitted VOCs, seven VOCs (esters and ketones) originating from the coating solutions accounted for 77.4 % of TVOC. The remaining solvents resulted from TPEE swelling during coating owing to high chemical affinity with the solvents as evidenced by a low contact angle (14.3°) and high degree swelling (68.9%). Further baking at 80C reduced VOCs levels over time, but some major compounds (methyl isobutyl ketone and butyl acetate) persisted until 6 h. Primer and clearcoat films reduced solvent volatilization by approximately 70 %, creating a blocking effect. Apart from solvents, neat TPEE contained 4.2 % of its weight as potential VOCs. Therefore, enhanced VOCs emissions stem from three factors: (1) excessive TPEE swelling caused by coating solvents and residual solvents released as VOCs, (2) restricted volatilization caused by the coating, and (3) emission of inherent VOCs from neat TPEE. Automotive interior plastic Surface coating Swelling Thermoplastic polyester elastomer Volatile organic compound Jeong, Chanul verfasserin aut Oh, Arom verfasserin aut Seo, Yong-Soo verfasserin aut Jeon, Hotak verfasserin aut Eom, Youngho verfasserin (orcid)0000-0002-0922-1155 aut Enthalten in Journal of hazardous materials New York, NY [u.a.] : Science Direct, 1976 461 Online-Ressource (DE-627)302467904 (DE-600)1491302-1 (DE-576)259483893 1873-3336 nnns volume:461 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.13 Umwelttoxikologie VZ 50.17 Sicherheitstechnik VZ 58.53 Abfallwirtschaft VZ AR 461 |
allfields_unstemmed |
10.1016/j.jhazmat.2023.132614 doi (DE-627)ELV065169670 (ELSEVIER)S0304-3894(23)01897-6 DE-627 ger DE-627 rda eng 530 VZ 43.13 bkl 50.17 bkl 58.53 bkl Kim, Hyo Jeong verfasserin aut Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Volatile organic compounds (VOCs) in vehicle cabins pose some health concerns, especially in new cars where interior plastics contribute substantially to VOCs emissions. We investigated the reasons for enhanced VOCs emissions from surface-coated thermoplastic polyester elastomer (TPEE), an automotive interior plastic. After applying solvent-based primer and clearcoat coatings, total VOCs (TVOC) level increased by 12.1 times (2066-24,983 μg m−3). Among the 15 emitted VOCs, seven VOCs (esters and ketones) originating from the coating solutions accounted for 77.4 % of TVOC. The remaining solvents resulted from TPEE swelling during coating owing to high chemical affinity with the solvents as evidenced by a low contact angle (14.3°) and high degree swelling (68.9%). Further baking at 80C reduced VOCs levels over time, but some major compounds (methyl isobutyl ketone and butyl acetate) persisted until 6 h. Primer and clearcoat films reduced solvent volatilization by approximately 70 %, creating a blocking effect. Apart from solvents, neat TPEE contained 4.2 % of its weight as potential VOCs. Therefore, enhanced VOCs emissions stem from three factors: (1) excessive TPEE swelling caused by coating solvents and residual solvents released as VOCs, (2) restricted volatilization caused by the coating, and (3) emission of inherent VOCs from neat TPEE. Automotive interior plastic Surface coating Swelling Thermoplastic polyester elastomer Volatile organic compound Jeong, Chanul verfasserin aut Oh, Arom verfasserin aut Seo, Yong-Soo verfasserin aut Jeon, Hotak verfasserin aut Eom, Youngho verfasserin (orcid)0000-0002-0922-1155 aut Enthalten in Journal of hazardous materials New York, NY [u.a.] : Science Direct, 1976 461 Online-Ressource (DE-627)302467904 (DE-600)1491302-1 (DE-576)259483893 1873-3336 nnns volume:461 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.13 Umwelttoxikologie VZ 50.17 Sicherheitstechnik VZ 58.53 Abfallwirtschaft VZ AR 461 |
allfieldsGer |
10.1016/j.jhazmat.2023.132614 doi (DE-627)ELV065169670 (ELSEVIER)S0304-3894(23)01897-6 DE-627 ger DE-627 rda eng 530 VZ 43.13 bkl 50.17 bkl 58.53 bkl Kim, Hyo Jeong verfasserin aut Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Volatile organic compounds (VOCs) in vehicle cabins pose some health concerns, especially in new cars where interior plastics contribute substantially to VOCs emissions. We investigated the reasons for enhanced VOCs emissions from surface-coated thermoplastic polyester elastomer (TPEE), an automotive interior plastic. After applying solvent-based primer and clearcoat coatings, total VOCs (TVOC) level increased by 12.1 times (2066-24,983 μg m−3). Among the 15 emitted VOCs, seven VOCs (esters and ketones) originating from the coating solutions accounted for 77.4 % of TVOC. The remaining solvents resulted from TPEE swelling during coating owing to high chemical affinity with the solvents as evidenced by a low contact angle (14.3°) and high degree swelling (68.9%). Further baking at 80C reduced VOCs levels over time, but some major compounds (methyl isobutyl ketone and butyl acetate) persisted until 6 h. Primer and clearcoat films reduced solvent volatilization by approximately 70 %, creating a blocking effect. Apart from solvents, neat TPEE contained 4.2 % of its weight as potential VOCs. Therefore, enhanced VOCs emissions stem from three factors: (1) excessive TPEE swelling caused by coating solvents and residual solvents released as VOCs, (2) restricted volatilization caused by the coating, and (3) emission of inherent VOCs from neat TPEE. Automotive interior plastic Surface coating Swelling Thermoplastic polyester elastomer Volatile organic compound Jeong, Chanul verfasserin aut Oh, Arom verfasserin aut Seo, Yong-Soo verfasserin aut Jeon, Hotak verfasserin aut Eom, Youngho verfasserin (orcid)0000-0002-0922-1155 aut Enthalten in Journal of hazardous materials New York, NY [u.a.] : Science Direct, 1976 461 Online-Ressource (DE-627)302467904 (DE-600)1491302-1 (DE-576)259483893 1873-3336 nnns volume:461 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.13 Umwelttoxikologie VZ 50.17 Sicherheitstechnik VZ 58.53 Abfallwirtschaft VZ AR 461 |
allfieldsSound |
10.1016/j.jhazmat.2023.132614 doi (DE-627)ELV065169670 (ELSEVIER)S0304-3894(23)01897-6 DE-627 ger DE-627 rda eng 530 VZ 43.13 bkl 50.17 bkl 58.53 bkl Kim, Hyo Jeong verfasserin aut Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Volatile organic compounds (VOCs) in vehicle cabins pose some health concerns, especially in new cars where interior plastics contribute substantially to VOCs emissions. We investigated the reasons for enhanced VOCs emissions from surface-coated thermoplastic polyester elastomer (TPEE), an automotive interior plastic. After applying solvent-based primer and clearcoat coatings, total VOCs (TVOC) level increased by 12.1 times (2066-24,983 μg m−3). Among the 15 emitted VOCs, seven VOCs (esters and ketones) originating from the coating solutions accounted for 77.4 % of TVOC. The remaining solvents resulted from TPEE swelling during coating owing to high chemical affinity with the solvents as evidenced by a low contact angle (14.3°) and high degree swelling (68.9%). Further baking at 80C reduced VOCs levels over time, but some major compounds (methyl isobutyl ketone and butyl acetate) persisted until 6 h. Primer and clearcoat films reduced solvent volatilization by approximately 70 %, creating a blocking effect. Apart from solvents, neat TPEE contained 4.2 % of its weight as potential VOCs. Therefore, enhanced VOCs emissions stem from three factors: (1) excessive TPEE swelling caused by coating solvents and residual solvents released as VOCs, (2) restricted volatilization caused by the coating, and (3) emission of inherent VOCs from neat TPEE. Automotive interior plastic Surface coating Swelling Thermoplastic polyester elastomer Volatile organic compound Jeong, Chanul verfasserin aut Oh, Arom verfasserin aut Seo, Yong-Soo verfasserin aut Jeon, Hotak verfasserin aut Eom, Youngho verfasserin (orcid)0000-0002-0922-1155 aut Enthalten in Journal of hazardous materials New York, NY [u.a.] : Science Direct, 1976 461 Online-Ressource (DE-627)302467904 (DE-600)1491302-1 (DE-576)259483893 1873-3336 nnns volume:461 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.13 Umwelttoxikologie VZ 50.17 Sicherheitstechnik VZ 58.53 Abfallwirtschaft VZ AR 461 |
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Enthalten in Journal of hazardous materials 461 volume:461 |
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Enthalten in Journal of hazardous materials 461 volume:461 |
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Umwelttoxikologie Sicherheitstechnik Abfallwirtschaft |
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topic_facet |
Automotive interior plastic Surface coating Swelling Thermoplastic polyester elastomer Volatile organic compound |
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Journal of hazardous materials |
authorswithroles_txt_mv |
Kim, Hyo Jeong @@aut@@ Jeong, Chanul @@aut@@ Oh, Arom @@aut@@ Seo, Yong-Soo @@aut@@ Jeon, Hotak @@aut@@ Eom, Youngho @@aut@@ |
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2023-01-01T00:00:00Z |
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Kim, Hyo Jeong |
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Kim, Hyo Jeong ddc 530 bkl 43.13 bkl 50.17 bkl 58.53 misc Automotive interior plastic misc Surface coating misc Swelling misc Thermoplastic polyester elastomer misc Volatile organic compound Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling |
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530 VZ 43.13 bkl 50.17 bkl 58.53 bkl Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling Automotive interior plastic Surface coating Swelling Thermoplastic polyester elastomer Volatile organic compound |
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elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: importance of plastic swelling |
title_auth |
Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling |
abstract |
Volatile organic compounds (VOCs) in vehicle cabins pose some health concerns, especially in new cars where interior plastics contribute substantially to VOCs emissions. We investigated the reasons for enhanced VOCs emissions from surface-coated thermoplastic polyester elastomer (TPEE), an automotive interior plastic. After applying solvent-based primer and clearcoat coatings, total VOCs (TVOC) level increased by 12.1 times (2066-24,983 μg m−3). Among the 15 emitted VOCs, seven VOCs (esters and ketones) originating from the coating solutions accounted for 77.4 % of TVOC. The remaining solvents resulted from TPEE swelling during coating owing to high chemical affinity with the solvents as evidenced by a low contact angle (14.3°) and high degree swelling (68.9%). Further baking at 80C reduced VOCs levels over time, but some major compounds (methyl isobutyl ketone and butyl acetate) persisted until 6 h. Primer and clearcoat films reduced solvent volatilization by approximately 70 %, creating a blocking effect. Apart from solvents, neat TPEE contained 4.2 % of its weight as potential VOCs. Therefore, enhanced VOCs emissions stem from three factors: (1) excessive TPEE swelling caused by coating solvents and residual solvents released as VOCs, (2) restricted volatilization caused by the coating, and (3) emission of inherent VOCs from neat TPEE. |
abstractGer |
Volatile organic compounds (VOCs) in vehicle cabins pose some health concerns, especially in new cars where interior plastics contribute substantially to VOCs emissions. We investigated the reasons for enhanced VOCs emissions from surface-coated thermoplastic polyester elastomer (TPEE), an automotive interior plastic. After applying solvent-based primer and clearcoat coatings, total VOCs (TVOC) level increased by 12.1 times (2066-24,983 μg m−3). Among the 15 emitted VOCs, seven VOCs (esters and ketones) originating from the coating solutions accounted for 77.4 % of TVOC. The remaining solvents resulted from TPEE swelling during coating owing to high chemical affinity with the solvents as evidenced by a low contact angle (14.3°) and high degree swelling (68.9%). Further baking at 80C reduced VOCs levels over time, but some major compounds (methyl isobutyl ketone and butyl acetate) persisted until 6 h. Primer and clearcoat films reduced solvent volatilization by approximately 70 %, creating a blocking effect. Apart from solvents, neat TPEE contained 4.2 % of its weight as potential VOCs. Therefore, enhanced VOCs emissions stem from three factors: (1) excessive TPEE swelling caused by coating solvents and residual solvents released as VOCs, (2) restricted volatilization caused by the coating, and (3) emission of inherent VOCs from neat TPEE. |
abstract_unstemmed |
Volatile organic compounds (VOCs) in vehicle cabins pose some health concerns, especially in new cars where interior plastics contribute substantially to VOCs emissions. We investigated the reasons for enhanced VOCs emissions from surface-coated thermoplastic polyester elastomer (TPEE), an automotive interior plastic. After applying solvent-based primer and clearcoat coatings, total VOCs (TVOC) level increased by 12.1 times (2066-24,983 μg m−3). Among the 15 emitted VOCs, seven VOCs (esters and ketones) originating from the coating solutions accounted for 77.4 % of TVOC. The remaining solvents resulted from TPEE swelling during coating owing to high chemical affinity with the solvents as evidenced by a low contact angle (14.3°) and high degree swelling (68.9%). Further baking at 80C reduced VOCs levels over time, but some major compounds (methyl isobutyl ketone and butyl acetate) persisted until 6 h. Primer and clearcoat films reduced solvent volatilization by approximately 70 %, creating a blocking effect. Apart from solvents, neat TPEE contained 4.2 % of its weight as potential VOCs. Therefore, enhanced VOCs emissions stem from three factors: (1) excessive TPEE swelling caused by coating solvents and residual solvents released as VOCs, (2) restricted volatilization caused by the coating, and (3) emission of inherent VOCs from neat TPEE. |
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Elevated volatile organic compound emissions from coated thermoplastic polyester elastomer in automotive interior parts: Importance of plastic swelling |
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|
score |
7.399131 |