Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites

Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	He, Yujie [verfasserIn] Zhao, Zhongjing [verfasserIn] Wang, Tao [verfasserIn] An, Lichao [verfasserIn] Zhang, Lu [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Carbon-based adsorbents Edge defects Antibiotics Adsorption NEXAFS measurements DFT calculations

Übergeordnetes Werk:	Enthalten in: Chemosphere - Amsterdam [u.a.] : Elsevier Science, 1972, 344
Übergeordnetes Werk:	volume:344

DOI / URN:	10.1016/j.chemosphere.2023.140341

Katalog-ID:	ELV065276876

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520			\|a Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption performance to antibiotics were explored. The experimental results suggested that the edge defects of DC-s samples were the active sites for the adsorption of tetracycline (TC) and norfloxacin (NOR). The adsorption capacity of the optimal sample DC-900 for TC and NOR was 155.8 and 168.0 mg g−1, respectively. Density functional theory (DFT) calculations further revealed that zigzag edge defects rather than armchair edge defects were crucial to the excellent adsorption performance of DC-s samples for antibiotics, and the natures for the difference in the adsorption performance of the two edge defects for antibiotics were their different electronic structures. In addition, DC-900 also showed stable adsorption efficiency for antibiotics in the interferences, dynamic adsorption, and cycle experiments, suggesting its good environmental application potential. This study provides new insight into clarifying the natures of edge defects with carbon-based adsorbents for high-efficiency removal of antibiotics, which may guide the exploration of cost-effective carbon-based adsorbents.
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650		4	\|a Adsorption
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allfields	10.1016/j.chemosphere.2023.140341 doi (DE-627)ELV065276876 (ELSEVIER)S0045-6535(23)02611-5 DE-627 ger DE-627 rda eng 333.7 VZ 43.00 bkl He, Yujie verfasserin aut Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption performance to antibiotics were explored. The experimental results suggested that the edge defects of DC-s samples were the active sites for the adsorption of tetracycline (TC) and norfloxacin (NOR). The adsorption capacity of the optimal sample DC-900 for TC and NOR was 155.8 and 168.0 mg g−1, respectively. Density functional theory (DFT) calculations further revealed that zigzag edge defects rather than armchair edge defects were crucial to the excellent adsorption performance of DC-s samples for antibiotics, and the natures for the difference in the adsorption performance of the two edge defects for antibiotics were their different electronic structures. In addition, DC-900 also showed stable adsorption efficiency for antibiotics in the interferences, dynamic adsorption, and cycle experiments, suggesting its good environmental application potential. This study provides new insight into clarifying the natures of edge defects with carbon-based adsorbents for high-efficiency removal of antibiotics, which may guide the exploration of cost-effective carbon-based adsorbents. Carbon-based adsorbents Edge defects Antibiotics Adsorption NEXAFS measurements DFT calculations Zhao, Zhongjing verfasserin aut Wang, Tao verfasserin aut An, Lichao verfasserin aut Zhang, Lu verfasserin aut Enthalten in Chemosphere Amsterdam [u.a.] : Elsevier Science, 1972 344 Online-Ressource (DE-627)306354217 (DE-600)1496851-4 (DE-576)081952961 1879-1298 nnns volume:344 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.00 Umweltforschung Umweltschutz: Allgemeines VZ AR 344
spelling	10.1016/j.chemosphere.2023.140341 doi (DE-627)ELV065276876 (ELSEVIER)S0045-6535(23)02611-5 DE-627 ger DE-627 rda eng 333.7 VZ 43.00 bkl He, Yujie verfasserin aut Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption performance to antibiotics were explored. The experimental results suggested that the edge defects of DC-s samples were the active sites for the adsorption of tetracycline (TC) and norfloxacin (NOR). The adsorption capacity of the optimal sample DC-900 for TC and NOR was 155.8 and 168.0 mg g−1, respectively. Density functional theory (DFT) calculations further revealed that zigzag edge defects rather than armchair edge defects were crucial to the excellent adsorption performance of DC-s samples for antibiotics, and the natures for the difference in the adsorption performance of the two edge defects for antibiotics were their different electronic structures. In addition, DC-900 also showed stable adsorption efficiency for antibiotics in the interferences, dynamic adsorption, and cycle experiments, suggesting its good environmental application potential. This study provides new insight into clarifying the natures of edge defects with carbon-based adsorbents for high-efficiency removal of antibiotics, which may guide the exploration of cost-effective carbon-based adsorbents. Carbon-based adsorbents Edge defects Antibiotics Adsorption NEXAFS measurements DFT calculations Zhao, Zhongjing verfasserin aut Wang, Tao verfasserin aut An, Lichao verfasserin aut Zhang, Lu verfasserin aut Enthalten in Chemosphere Amsterdam [u.a.] : Elsevier Science, 1972 344 Online-Ressource (DE-627)306354217 (DE-600)1496851-4 (DE-576)081952961 1879-1298 nnns volume:344 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.00 Umweltforschung Umweltschutz: Allgemeines VZ AR 344
allfields_unstemmed	10.1016/j.chemosphere.2023.140341 doi (DE-627)ELV065276876 (ELSEVIER)S0045-6535(23)02611-5 DE-627 ger DE-627 rda eng 333.7 VZ 43.00 bkl He, Yujie verfasserin aut Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption performance to antibiotics were explored. The experimental results suggested that the edge defects of DC-s samples were the active sites for the adsorption of tetracycline (TC) and norfloxacin (NOR). The adsorption capacity of the optimal sample DC-900 for TC and NOR was 155.8 and 168.0 mg g−1, respectively. Density functional theory (DFT) calculations further revealed that zigzag edge defects rather than armchair edge defects were crucial to the excellent adsorption performance of DC-s samples for antibiotics, and the natures for the difference in the adsorption performance of the two edge defects for antibiotics were their different electronic structures. In addition, DC-900 also showed stable adsorption efficiency for antibiotics in the interferences, dynamic adsorption, and cycle experiments, suggesting its good environmental application potential. This study provides new insight into clarifying the natures of edge defects with carbon-based adsorbents for high-efficiency removal of antibiotics, which may guide the exploration of cost-effective carbon-based adsorbents. Carbon-based adsorbents Edge defects Antibiotics Adsorption NEXAFS measurements DFT calculations Zhao, Zhongjing verfasserin aut Wang, Tao verfasserin aut An, Lichao verfasserin aut Zhang, Lu verfasserin aut Enthalten in Chemosphere Amsterdam [u.a.] : Elsevier Science, 1972 344 Online-Ressource (DE-627)306354217 (DE-600)1496851-4 (DE-576)081952961 1879-1298 nnns volume:344 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.00 Umweltforschung Umweltschutz: Allgemeines VZ AR 344
allfieldsGer	10.1016/j.chemosphere.2023.140341 doi (DE-627)ELV065276876 (ELSEVIER)S0045-6535(23)02611-5 DE-627 ger DE-627 rda eng 333.7 VZ 43.00 bkl He, Yujie verfasserin aut Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption performance to antibiotics were explored. The experimental results suggested that the edge defects of DC-s samples were the active sites for the adsorption of tetracycline (TC) and norfloxacin (NOR). The adsorption capacity of the optimal sample DC-900 for TC and NOR was 155.8 and 168.0 mg g−1, respectively. Density functional theory (DFT) calculations further revealed that zigzag edge defects rather than armchair edge defects were crucial to the excellent adsorption performance of DC-s samples for antibiotics, and the natures for the difference in the adsorption performance of the two edge defects for antibiotics were their different electronic structures. In addition, DC-900 also showed stable adsorption efficiency for antibiotics in the interferences, dynamic adsorption, and cycle experiments, suggesting its good environmental application potential. This study provides new insight into clarifying the natures of edge defects with carbon-based adsorbents for high-efficiency removal of antibiotics, which may guide the exploration of cost-effective carbon-based adsorbents. Carbon-based adsorbents Edge defects Antibiotics Adsorption NEXAFS measurements DFT calculations Zhao, Zhongjing verfasserin aut Wang, Tao verfasserin aut An, Lichao verfasserin aut Zhang, Lu verfasserin aut Enthalten in Chemosphere Amsterdam [u.a.] : Elsevier Science, 1972 344 Online-Ressource (DE-627)306354217 (DE-600)1496851-4 (DE-576)081952961 1879-1298 nnns volume:344 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.00 Umweltforschung Umweltschutz: Allgemeines VZ AR 344
allfieldsSound	10.1016/j.chemosphere.2023.140341 doi (DE-627)ELV065276876 (ELSEVIER)S0045-6535(23)02611-5 DE-627 ger DE-627 rda eng 333.7 VZ 43.00 bkl He, Yujie verfasserin aut Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption performance to antibiotics were explored. The experimental results suggested that the edge defects of DC-s samples were the active sites for the adsorption of tetracycline (TC) and norfloxacin (NOR). The adsorption capacity of the optimal sample DC-900 for TC and NOR was 155.8 and 168.0 mg g−1, respectively. Density functional theory (DFT) calculations further revealed that zigzag edge defects rather than armchair edge defects were crucial to the excellent adsorption performance of DC-s samples for antibiotics, and the natures for the difference in the adsorption performance of the two edge defects for antibiotics were their different electronic structures. In addition, DC-900 also showed stable adsorption efficiency for antibiotics in the interferences, dynamic adsorption, and cycle experiments, suggesting its good environmental application potential. This study provides new insight into clarifying the natures of edge defects with carbon-based adsorbents for high-efficiency removal of antibiotics, which may guide the exploration of cost-effective carbon-based adsorbents. Carbon-based adsorbents Edge defects Antibiotics Adsorption NEXAFS measurements DFT calculations Zhao, Zhongjing verfasserin aut Wang, Tao verfasserin aut An, Lichao verfasserin aut Zhang, Lu verfasserin aut Enthalten in Chemosphere Amsterdam [u.a.] : Elsevier Science, 1972 344 Online-Ressource (DE-627)306354217 (DE-600)1496851-4 (DE-576)081952961 1879-1298 nnns volume:344 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 43.00 Umweltforschung Umweltschutz: Allgemeines VZ AR 344
language	English
source	Enthalten in Chemosphere 344 volume:344
sourceStr	Enthalten in Chemosphere 344 volume:344
format_phy_str_mv	Article
bklname	Umweltforschung Umweltschutz: Allgemeines
institution	findex.gbv.de
topic_facet	Carbon-based adsorbents Edge defects Antibiotics Adsorption NEXAFS measurements DFT calculations
dewey-raw	333.7
isfreeaccess_bool	false
container_title	Chemosphere
authorswithroles_txt_mv	He, Yujie @@aut@@ Zhao, Zhongjing @@aut@@ Wang, Tao @@aut@@ An, Lichao @@aut@@ Zhang, Lu @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	306354217
dewey-sort	3333.7
id	ELV065276876
language_de	englisch
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author	He, Yujie
spellingShingle	He, Yujie ddc 333.7 bkl 43.00 misc Carbon-based adsorbents misc Edge defects misc Antibiotics misc Adsorption misc NEXAFS measurements misc DFT calculations Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites
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topic_title	333.7 VZ 43.00 bkl Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites Carbon-based adsorbents Edge defects Antibiotics Adsorption NEXAFS measurements DFT calculations
topic	ddc 333.7 bkl 43.00 misc Carbon-based adsorbents misc Edge defects misc Antibiotics misc Adsorption misc NEXAFS measurements misc DFT calculations
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title	Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites
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title_full	Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites
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title_sort	carbon-based materials as efficient adsorbents for the removal of antibiotics: the real contributions of carbon edge sites
title_auth	Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites
abstract	Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption performance to antibiotics were explored. The experimental results suggested that the edge defects of DC-s samples were the active sites for the adsorption of tetracycline (TC) and norfloxacin (NOR). The adsorption capacity of the optimal sample DC-900 for TC and NOR was 155.8 and 168.0 mg g−1, respectively. Density functional theory (DFT) calculations further revealed that zigzag edge defects rather than armchair edge defects were crucial to the excellent adsorption performance of DC-s samples for antibiotics, and the natures for the difference in the adsorption performance of the two edge defects for antibiotics were their different electronic structures. In addition, DC-900 also showed stable adsorption efficiency for antibiotics in the interferences, dynamic adsorption, and cycle experiments, suggesting its good environmental application potential. This study provides new insight into clarifying the natures of edge defects with carbon-based adsorbents for high-efficiency removal of antibiotics, which may guide the exploration of cost-effective carbon-based adsorbents.
abstractGer	Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption performance to antibiotics were explored. The experimental results suggested that the edge defects of DC-s samples were the active sites for the adsorption of tetracycline (TC) and norfloxacin (NOR). The adsorption capacity of the optimal sample DC-900 for TC and NOR was 155.8 and 168.0 mg g−1, respectively. Density functional theory (DFT) calculations further revealed that zigzag edge defects rather than armchair edge defects were crucial to the excellent adsorption performance of DC-s samples for antibiotics, and the natures for the difference in the adsorption performance of the two edge defects for antibiotics were their different electronic structures. In addition, DC-900 also showed stable adsorption efficiency for antibiotics in the interferences, dynamic adsorption, and cycle experiments, suggesting its good environmental application potential. This study provides new insight into clarifying the natures of edge defects with carbon-based adsorbents for high-efficiency removal of antibiotics, which may guide the exploration of cost-effective carbon-based adsorbents.
abstract_unstemmed	Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption performance to antibiotics were explored. The experimental results suggested that the edge defects of DC-s samples were the active sites for the adsorption of tetracycline (TC) and norfloxacin (NOR). The adsorption capacity of the optimal sample DC-900 for TC and NOR was 155.8 and 168.0 mg g−1, respectively. Density functional theory (DFT) calculations further revealed that zigzag edge defects rather than armchair edge defects were crucial to the excellent adsorption performance of DC-s samples for antibiotics, and the natures for the difference in the adsorption performance of the two edge defects for antibiotics were their different electronic structures. In addition, DC-900 also showed stable adsorption efficiency for antibiotics in the interferences, dynamic adsorption, and cycle experiments, suggesting its good environmental application potential. This study provides new insight into clarifying the natures of edge defects with carbon-based adsorbents for high-efficiency removal of antibiotics, which may guide the exploration of cost-effective carbon-based adsorbents.
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title_short	Carbon-based materials as efficient adsorbents for the removal of antibiotics: The real contributions of carbon edge sites
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author2	Zhao, Zhongjing Wang, Tao An, Lichao Zhang, Lu
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up_date	2024-07-06T22:27:51.953Z
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