Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders

The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	de Oro Calderon, R. [verfasserIn] Lunzer, M. [verfasserIn] Wodak, I. [verfasserIn] Steinlechner, R. [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	WC-based cemented carbides Alternative binders FeMn-based binders Phase formation Sintering conditions Thermodynamic calculations

Übergeordnetes Werk:	Enthalten in: International journal of refractory metals & hard materials - Amsterdam [u.a.] : Elsevier Science, 1995, 117
Übergeordnetes Werk:	volume:117

DOI / URN:	10.1016/j.ijrmhm.2023.106411

Katalog-ID:	ELV065314743

Internformat


LEADER	01000naa a22002652 4500
001	ELV065314743
003	DE-627
005	20231029093048.0
007	cr uuu---uuuuu
008	231029s2023 xx \|\|\|\|\|o 00\| \|\|eng c
024	7		\|a 10.1016/j.ijrmhm.2023.106411 \|2 doi
035			\|a (DE-627)ELV065314743
035			\|a (ELSEVIER)S0263-4368(23)00311-6
040			\|a DE-627 \|b ger \|c DE-627 \|e rda
041			\|a eng
082	0	4	\|a 670 \|q VZ
084			\|a 51.60 \|2 bkl
084			\|a 51.45 \|2 bkl
100	1		\|a de Oro Calderon, R. \|e verfasserin \|4 aut
245	1	0	\|a Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders
264		1	\|c 2023
336			\|a nicht spezifiziert \|b zzz \|2 rdacontent
337			\|a Computermedien \|b c \|2 rdamedia
338			\|a Online-Ressource \|b cr \|2 rdacarrier
520			\|a The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases.
650		4	\|a WC-based cemented carbides
650		4	\|a Alternative binders
650		4	\|a FeMn-based binders
650		4	\|a Phase formation
650		4	\|a Sintering conditions
650		4	\|a Thermodynamic calculations
700	1		\|a Lunzer, M. \|e verfasserin \|4 aut
700	1		\|a Wodak, I. \|e verfasserin \|4 aut
700	1		\|a Steinlechner, R. \|e verfasserin \|4 aut
773	0	8	\|i Enthalten in \|t International journal of refractory metals & hard materials \|d Amsterdam [u.a.] : Elsevier Science, 1995 \|g 117 \|h Online-Ressource \|w (DE-627)320526348 \|w (DE-600)2015219-X \|w (DE-576)120883600 \|x 0263-4368 \|7 nnns
773	1	8	\|g volume:117
912			\|a GBV_USEFLAG_U
912			\|a GBV_ELV
912			\|a SYSFLAG_U
912			\|a GBV_ILN_20
912			\|a GBV_ILN_22
912			\|a GBV_ILN_23
912			\|a GBV_ILN_24
912			\|a GBV_ILN_31
912			\|a GBV_ILN_32
912			\|a GBV_ILN_40
912			\|a GBV_ILN_60
912			\|a GBV_ILN_62
912			\|a GBV_ILN_65
912			\|a GBV_ILN_69
912			\|a GBV_ILN_70
912			\|a GBV_ILN_73
912			\|a GBV_ILN_74
912			\|a GBV_ILN_90
912			\|a GBV_ILN_95
912			\|a GBV_ILN_100
912			\|a GBV_ILN_105
912			\|a GBV_ILN_110
912			\|a GBV_ILN_150
912			\|a GBV_ILN_151
912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
912			\|a GBV_ILN_370
912			\|a GBV_ILN_602
912			\|a GBV_ILN_702
912			\|a GBV_ILN_2001
912			\|a GBV_ILN_2003
912			\|a GBV_ILN_2004
912			\|a GBV_ILN_2005
912			\|a GBV_ILN_2007
912			\|a GBV_ILN_2008
912			\|a GBV_ILN_2009
912			\|a GBV_ILN_2010
912			\|a GBV_ILN_2011
912			\|a GBV_ILN_2014
912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
912			\|a GBV_ILN_2143
912			\|a GBV_ILN_2152
912			\|a GBV_ILN_2153
912			\|a GBV_ILN_2190
912			\|a GBV_ILN_2232
912			\|a GBV_ILN_2336
912			\|a GBV_ILN_2470
912			\|a GBV_ILN_2507
912			\|a GBV_ILN_4035
912			\|a GBV_ILN_4037
912			\|a GBV_ILN_4112
912			\|a GBV_ILN_4125
912			\|a GBV_ILN_4242
912			\|a GBV_ILN_4249
912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4338
912			\|a GBV_ILN_4393
912			\|a GBV_ILN_4700
936	b	k	\|a 51.60 \|j Keramische Werkstoffe \|j Hartstoffe \|x Werkstoffkunde \|q VZ
936	b	k	\|a 51.45 \|j Werkstoffe mit besonderen Eigenschaften \|q VZ
951			\|a AR
952			\|d 117

Indexfelder

author_variant	o c r d ocr ocrd m l ml i w iw r s rs
matchkey_str	article:02634368:2023----::udmnaapcsfhsfrainncaecmnecriecn
hierarchy_sort_str	2023
bklnumber	51.60 51.45
publishDate	2023
allfields	10.1016/j.ijrmhm.2023.106411 doi (DE-627)ELV065314743 (ELSEVIER)S0263-4368(23)00311-6 DE-627 ger DE-627 rda eng 670 VZ 51.60 bkl 51.45 bkl de Oro Calderon, R. verfasserin aut Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases. WC-based cemented carbides Alternative binders FeMn-based binders Phase formation Sintering conditions Thermodynamic calculations Lunzer, M. verfasserin aut Wodak, I. verfasserin aut Steinlechner, R. verfasserin aut Enthalten in International journal of refractory metals & hard materials Amsterdam [u.a.] : Elsevier Science, 1995 117 Online-Ressource (DE-627)320526348 (DE-600)2015219-X (DE-576)120883600 0263-4368 nnns volume:117 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 51.45 Werkstoffe mit besonderen Eigenschaften VZ AR 117
spelling	10.1016/j.ijrmhm.2023.106411 doi (DE-627)ELV065314743 (ELSEVIER)S0263-4368(23)00311-6 DE-627 ger DE-627 rda eng 670 VZ 51.60 bkl 51.45 bkl de Oro Calderon, R. verfasserin aut Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases. WC-based cemented carbides Alternative binders FeMn-based binders Phase formation Sintering conditions Thermodynamic calculations Lunzer, M. verfasserin aut Wodak, I. verfasserin aut Steinlechner, R. verfasserin aut Enthalten in International journal of refractory metals & hard materials Amsterdam [u.a.] : Elsevier Science, 1995 117 Online-Ressource (DE-627)320526348 (DE-600)2015219-X (DE-576)120883600 0263-4368 nnns volume:117 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 51.45 Werkstoffe mit besonderen Eigenschaften VZ AR 117
allfields_unstemmed	10.1016/j.ijrmhm.2023.106411 doi (DE-627)ELV065314743 (ELSEVIER)S0263-4368(23)00311-6 DE-627 ger DE-627 rda eng 670 VZ 51.60 bkl 51.45 bkl de Oro Calderon, R. verfasserin aut Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases. WC-based cemented carbides Alternative binders FeMn-based binders Phase formation Sintering conditions Thermodynamic calculations Lunzer, M. verfasserin aut Wodak, I. verfasserin aut Steinlechner, R. verfasserin aut Enthalten in International journal of refractory metals & hard materials Amsterdam [u.a.] : Elsevier Science, 1995 117 Online-Ressource (DE-627)320526348 (DE-600)2015219-X (DE-576)120883600 0263-4368 nnns volume:117 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 51.45 Werkstoffe mit besonderen Eigenschaften VZ AR 117
allfieldsGer	10.1016/j.ijrmhm.2023.106411 doi (DE-627)ELV065314743 (ELSEVIER)S0263-4368(23)00311-6 DE-627 ger DE-627 rda eng 670 VZ 51.60 bkl 51.45 bkl de Oro Calderon, R. verfasserin aut Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases. WC-based cemented carbides Alternative binders FeMn-based binders Phase formation Sintering conditions Thermodynamic calculations Lunzer, M. verfasserin aut Wodak, I. verfasserin aut Steinlechner, R. verfasserin aut Enthalten in International journal of refractory metals & hard materials Amsterdam [u.a.] : Elsevier Science, 1995 117 Online-Ressource (DE-627)320526348 (DE-600)2015219-X (DE-576)120883600 0263-4368 nnns volume:117 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 51.45 Werkstoffe mit besonderen Eigenschaften VZ AR 117
allfieldsSound	10.1016/j.ijrmhm.2023.106411 doi (DE-627)ELV065314743 (ELSEVIER)S0263-4368(23)00311-6 DE-627 ger DE-627 rda eng 670 VZ 51.60 bkl 51.45 bkl de Oro Calderon, R. verfasserin aut Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases. WC-based cemented carbides Alternative binders FeMn-based binders Phase formation Sintering conditions Thermodynamic calculations Lunzer, M. verfasserin aut Wodak, I. verfasserin aut Steinlechner, R. verfasserin aut Enthalten in International journal of refractory metals & hard materials Amsterdam [u.a.] : Elsevier Science, 1995 117 Online-Ressource (DE-627)320526348 (DE-600)2015219-X (DE-576)120883600 0263-4368 nnns volume:117 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.60 Keramische Werkstoffe Hartstoffe Werkstoffkunde VZ 51.45 Werkstoffe mit besonderen Eigenschaften VZ AR 117
language	English
source	Enthalten in International journal of refractory metals & hard materials 117 volume:117
sourceStr	Enthalten in International journal of refractory metals & hard materials 117 volume:117
format_phy_str_mv	Article
bklname	Keramische Werkstoffe Hartstoffe Werkstoffe mit besonderen Eigenschaften
institution	findex.gbv.de
topic_facet	WC-based cemented carbides Alternative binders FeMn-based binders Phase formation Sintering conditions Thermodynamic calculations
dewey-raw	670
isfreeaccess_bool	false
container_title	International journal of refractory metals & hard materials
authorswithroles_txt_mv	de Oro Calderon, R. @@aut@@ Lunzer, M. @@aut@@ Wodak, I. @@aut@@ Steinlechner, R. @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	320526348
dewey-sort	3670
id	ELV065314743
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">ELV065314743</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231029093048.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">231029s2023 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.ijrmhm.2023.106411</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV065314743</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0263-4368(23)00311-6</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.60</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.45</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">de Oro Calderon, R.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">WC-based cemented carbides</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Alternative binders</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">FeMn-based binders</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Phase formation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sintering conditions</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thermodynamic calculations</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lunzer, M.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wodak, I.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Steinlechner, R.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">International journal of refractory metals & hard materials</subfield><subfield code="d">Amsterdam [u.a.] : Elsevier Science, 1995</subfield><subfield code="g">117</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)320526348</subfield><subfield code="w">(DE-600)2015219-X</subfield><subfield code="w">(DE-576)120883600</subfield><subfield code="x">0263-4368</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:117</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">51.60</subfield><subfield code="j">Keramische Werkstoffe</subfield><subfield code="j">Hartstoffe</subfield><subfield code="x">Werkstoffkunde</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">51.45</subfield><subfield code="j">Werkstoffe mit besonderen Eigenschaften</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">117</subfield></datafield></record></collection>
author	de Oro Calderon, R.
spellingShingle	de Oro Calderon, R. ddc 670 bkl 51.60 bkl 51.45 misc WC-based cemented carbides misc Alternative binders misc FeMn-based binders misc Phase formation misc Sintering conditions misc Thermodynamic calculations Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders
authorStr	de Oro Calderon, R.
ppnlink_with_tag_str_mv	@@773@@(DE-627)320526348
format	electronic Article
dewey-ones	670 - Manufacturing
delete_txt_mv	keep
author_role	aut aut aut aut
collection	elsevier
remote_str	true
illustrated	Not Illustrated
issn	0263-4368
topic_title	670 VZ 51.60 bkl 51.45 bkl Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders WC-based cemented carbides Alternative binders FeMn-based binders Phase formation Sintering conditions Thermodynamic calculations
topic	ddc 670 bkl 51.60 bkl 51.45 misc WC-based cemented carbides misc Alternative binders misc FeMn-based binders misc Phase formation misc Sintering conditions misc Thermodynamic calculations
topic_unstemmed	ddc 670 bkl 51.60 bkl 51.45 misc WC-based cemented carbides misc Alternative binders misc FeMn-based binders misc Phase formation misc Sintering conditions misc Thermodynamic calculations
topic_browse	ddc 670 bkl 51.60 bkl 51.45 misc WC-based cemented carbides misc Alternative binders misc FeMn-based binders misc Phase formation misc Sintering conditions misc Thermodynamic calculations
format_facet	Elektronische Aufsätze Aufsätze Elektronische Ressource
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	cr
hierarchy_parent_title	International journal of refractory metals & hard materials
hierarchy_parent_id	320526348
dewey-tens	670 - Manufacturing
hierarchy_top_title	International journal of refractory metals & hard materials
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)320526348 (DE-600)2015219-X (DE-576)120883600
title	Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders
ctrlnum	(DE-627)ELV065314743 (ELSEVIER)S0263-4368(23)00311-6
title_full	Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders
author_sort	de Oro Calderon, R.
journal	International journal of refractory metals & hard materials
journalStr	International journal of refractory metals & hard materials
lang_code	eng
isOA_bool	false
dewey-hundreds	600 - Technology
recordtype	marc
publishDateSort	2023
contenttype_str_mv	zzz
author_browse	de Oro Calderon, R. Lunzer, M. Wodak, I. Steinlechner, R.
container_volume	117
class	670 VZ 51.60 bkl 51.45 bkl
format_se	Elektronische Aufsätze
author-letter	de Oro Calderon, R.
doi_str_mv	10.1016/j.ijrmhm.2023.106411
dewey-full	670
author2-role	verfasserin
title_sort	fundamental aspects of phase formation in wc-based cemented carbides containing femn-based binders
title_auth	Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders
abstract	The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases.
abstractGer	The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases.
abstract_unstemmed	The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases.
collection_details	GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700
title_short	Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders
remote_bool	true
author2	Lunzer, M. Wodak, I. Steinlechner, R.
author2Str	Lunzer, M. Wodak, I. Steinlechner, R.
ppnlink	320526348
mediatype_str_mv	c
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1016/j.ijrmhm.2023.106411
up_date	2024-07-06T22:35:58.892Z
_version_	1803870912007634944
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">ELV065314743</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231029093048.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">231029s2023 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.ijrmhm.2023.106411</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV065314743</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0263-4368(23)00311-6</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">670</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.60</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.45</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">de Oro Calderon, R.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2023</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The hardmetal industry is continuously seeking for (Co, Ni)-free binder alternatives. Several attempts have been made to use FeMn binders, Mn being a very effective austenite stabilizer. Substitution of Co binders for FeMn based binders comes along with many challenges such as: narrow carbon windows, evaporation of Mn during sintering or the formation of stable Mn-oxides. This work presents an overview on the phase formation in hardmetals with different carbon contents prepared from FeMn, FeMnSi and FeMnNi binders. Due to the efficient role of Mn as cementite stabilizer, it was not possible to avoid the presence of eta-carbides and cementite under the conditions studied, and samples with intermediate carbon contents presented both eta-carbides and cementite in the microstructure. Only after the addition of 25 wt% of Ni to the binder it was possible to observe materials with two phase microstructures. The challenges related to Mn evaporation and formation of stable oxides can be overcome by a proper selection of the starting materials and the sintering conditions. It is thus proved that the main challenge posed by these materials is the difficulty to obtain microstructures without detrimental phases.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">WC-based cemented carbides</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Alternative binders</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">FeMn-based binders</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Phase formation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sintering conditions</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thermodynamic calculations</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lunzer, M.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wodak, I.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Steinlechner, R.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">International journal of refractory metals & hard materials</subfield><subfield code="d">Amsterdam [u.a.] : Elsevier Science, 1995</subfield><subfield code="g">117</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)320526348</subfield><subfield code="w">(DE-600)2015219-X</subfield><subfield code="w">(DE-576)120883600</subfield><subfield code="x">0263-4368</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:117</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_187</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_213</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_230</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2001</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2007</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2009</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2026</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2055</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2106</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2232</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4249</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4306</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4307</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4325</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4700</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">51.60</subfield><subfield code="j">Keramische Werkstoffe</subfield><subfield code="j">Hartstoffe</subfield><subfield code="x">Werkstoffkunde</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">51.45</subfield><subfield code="j">Werkstoffe mit besonderen Eigenschaften</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">117</subfield></datafield></record></collection>
score	7.4020653

Nicht das Richtige dabei?

Schreiben Sie uns!

Fundamental aspects of phase formation in WC-based cemented carbides containing FeMn-based binders

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?