Superlong supercooling solvents (SSSs): Alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling
Water, supercritical fluids, ionic liquids and deep eutectic solvents (DESs) have been considered as green solvents for many years. The demand of green and sustainable development requires the search of novel green solvents. Some of the reported DESs might be not be the real DESs because we observe...
Ausführliche Beschreibung
Autor*in: |
Chen, Yu [verfasserIn] Zhang, Fuguang [verfasserIn] Sun, Haiyang [verfasserIn] Chang, Yi [verfasserIn] Zhang, Ziyang [verfasserIn] Liu, Zhenghui [verfasserIn] Yang, Mingshuai [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2023 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Journal of molecular liquids - New York, NY [u.a.] : Elsevier, 1983, 391 |
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Übergeordnetes Werk: |
volume:391 |
DOI / URN: |
10.1016/j.molliq.2023.123410 |
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Katalog-ID: |
ELV065458524 |
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520 | |a Water, supercritical fluids, ionic liquids and deep eutectic solvents (DESs) have been considered as green solvents for many years. The demand of green and sustainable development requires the search of novel green solvents. Some of the reported DESs might be not be the real DESs because we observe that these so-called reported liquid DESs become solid after exposure to the room temperature for many hours or days. Here, we for the first time propose a new concept of green solvents, superlong supercooling solvents (SSSs), as the green alternatives to water, supercritical fluids, ionic liquids and DESs. SSSs are the metastable liquid solvents either single component or multiple components due to the superlong supercooling effect at the temperature around or a little higher than room temperature. SSSs should condense after a superlong time; however, SSSs could be used as the green solvents before the condensation due to the superlong supercooling. Typical application example of SSSs is that SSSs could leach nearly 100% valuable metals from lithium-ion batteries cathode at low temperature, which is much higher than that by reported DESs and ILs at the same conditions. The new concept of SSSs would be very helpful for expanding the area of green solvents and green chemistry for building a greener world. | ||
650 | 4 | |a Deep eutectic solvents | |
650 | 4 | |a Physical properties | |
650 | 4 | |a Chemical thermodynamics | |
650 | 4 | |a Green chemistry | |
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700 | 1 | |a Zhang, Fuguang |e verfasserin |4 aut | |
700 | 1 | |a Sun, Haiyang |e verfasserin |4 aut | |
700 | 1 | |a Chang, Yi |e verfasserin |4 aut | |
700 | 1 | |a Zhang, Ziyang |e verfasserin |4 aut | |
700 | 1 | |a Liu, Zhenghui |e verfasserin |4 aut | |
700 | 1 | |a Yang, Mingshuai |e verfasserin |4 aut | |
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allfields |
10.1016/j.molliq.2023.123410 doi (DE-627)ELV065458524 (ELSEVIER)S0167-7322(23)02216-X DE-627 ger DE-627 rda eng 540 VZ 35.21 bkl Chen, Yu verfasserin (orcid)0000-0003-3420-7694 aut Superlong supercooling solvents (SSSs): Alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Water, supercritical fluids, ionic liquids and deep eutectic solvents (DESs) have been considered as green solvents for many years. The demand of green and sustainable development requires the search of novel green solvents. Some of the reported DESs might be not be the real DESs because we observe that these so-called reported liquid DESs become solid after exposure to the room temperature for many hours or days. Here, we for the first time propose a new concept of green solvents, superlong supercooling solvents (SSSs), as the green alternatives to water, supercritical fluids, ionic liquids and DESs. SSSs are the metastable liquid solvents either single component or multiple components due to the superlong supercooling effect at the temperature around or a little higher than room temperature. SSSs should condense after a superlong time; however, SSSs could be used as the green solvents before the condensation due to the superlong supercooling. Typical application example of SSSs is that SSSs could leach nearly 100% valuable metals from lithium-ion batteries cathode at low temperature, which is much higher than that by reported DESs and ILs at the same conditions. The new concept of SSSs would be very helpful for expanding the area of green solvents and green chemistry for building a greener world. Deep eutectic solvents Physical properties Chemical thermodynamics Green chemistry Green solvents Zhang, Fuguang verfasserin aut Sun, Haiyang verfasserin aut Chang, Yi verfasserin aut Zhang, Ziyang verfasserin aut Liu, Zhenghui verfasserin aut Yang, Mingshuai verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 391 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:391 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.21 Lösungen Flüssigkeiten Physikalische Chemie VZ AR 391 |
spelling |
10.1016/j.molliq.2023.123410 doi (DE-627)ELV065458524 (ELSEVIER)S0167-7322(23)02216-X DE-627 ger DE-627 rda eng 540 VZ 35.21 bkl Chen, Yu verfasserin (orcid)0000-0003-3420-7694 aut Superlong supercooling solvents (SSSs): Alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Water, supercritical fluids, ionic liquids and deep eutectic solvents (DESs) have been considered as green solvents for many years. The demand of green and sustainable development requires the search of novel green solvents. Some of the reported DESs might be not be the real DESs because we observe that these so-called reported liquid DESs become solid after exposure to the room temperature for many hours or days. Here, we for the first time propose a new concept of green solvents, superlong supercooling solvents (SSSs), as the green alternatives to water, supercritical fluids, ionic liquids and DESs. SSSs are the metastable liquid solvents either single component or multiple components due to the superlong supercooling effect at the temperature around or a little higher than room temperature. SSSs should condense after a superlong time; however, SSSs could be used as the green solvents before the condensation due to the superlong supercooling. Typical application example of SSSs is that SSSs could leach nearly 100% valuable metals from lithium-ion batteries cathode at low temperature, which is much higher than that by reported DESs and ILs at the same conditions. The new concept of SSSs would be very helpful for expanding the area of green solvents and green chemistry for building a greener world. Deep eutectic solvents Physical properties Chemical thermodynamics Green chemistry Green solvents Zhang, Fuguang verfasserin aut Sun, Haiyang verfasserin aut Chang, Yi verfasserin aut Zhang, Ziyang verfasserin aut Liu, Zhenghui verfasserin aut Yang, Mingshuai verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 391 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:391 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.21 Lösungen Flüssigkeiten Physikalische Chemie VZ AR 391 |
allfields_unstemmed |
10.1016/j.molliq.2023.123410 doi (DE-627)ELV065458524 (ELSEVIER)S0167-7322(23)02216-X DE-627 ger DE-627 rda eng 540 VZ 35.21 bkl Chen, Yu verfasserin (orcid)0000-0003-3420-7694 aut Superlong supercooling solvents (SSSs): Alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Water, supercritical fluids, ionic liquids and deep eutectic solvents (DESs) have been considered as green solvents for many years. The demand of green and sustainable development requires the search of novel green solvents. Some of the reported DESs might be not be the real DESs because we observe that these so-called reported liquid DESs become solid after exposure to the room temperature for many hours or days. Here, we for the first time propose a new concept of green solvents, superlong supercooling solvents (SSSs), as the green alternatives to water, supercritical fluids, ionic liquids and DESs. SSSs are the metastable liquid solvents either single component or multiple components due to the superlong supercooling effect at the temperature around or a little higher than room temperature. SSSs should condense after a superlong time; however, SSSs could be used as the green solvents before the condensation due to the superlong supercooling. Typical application example of SSSs is that SSSs could leach nearly 100% valuable metals from lithium-ion batteries cathode at low temperature, which is much higher than that by reported DESs and ILs at the same conditions. The new concept of SSSs would be very helpful for expanding the area of green solvents and green chemistry for building a greener world. Deep eutectic solvents Physical properties Chemical thermodynamics Green chemistry Green solvents Zhang, Fuguang verfasserin aut Sun, Haiyang verfasserin aut Chang, Yi verfasserin aut Zhang, Ziyang verfasserin aut Liu, Zhenghui verfasserin aut Yang, Mingshuai verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 391 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:391 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.21 Lösungen Flüssigkeiten Physikalische Chemie VZ AR 391 |
allfieldsGer |
10.1016/j.molliq.2023.123410 doi (DE-627)ELV065458524 (ELSEVIER)S0167-7322(23)02216-X DE-627 ger DE-627 rda eng 540 VZ 35.21 bkl Chen, Yu verfasserin (orcid)0000-0003-3420-7694 aut Superlong supercooling solvents (SSSs): Alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Water, supercritical fluids, ionic liquids and deep eutectic solvents (DESs) have been considered as green solvents for many years. The demand of green and sustainable development requires the search of novel green solvents. Some of the reported DESs might be not be the real DESs because we observe that these so-called reported liquid DESs become solid after exposure to the room temperature for many hours or days. Here, we for the first time propose a new concept of green solvents, superlong supercooling solvents (SSSs), as the green alternatives to water, supercritical fluids, ionic liquids and DESs. SSSs are the metastable liquid solvents either single component or multiple components due to the superlong supercooling effect at the temperature around or a little higher than room temperature. SSSs should condense after a superlong time; however, SSSs could be used as the green solvents before the condensation due to the superlong supercooling. Typical application example of SSSs is that SSSs could leach nearly 100% valuable metals from lithium-ion batteries cathode at low temperature, which is much higher than that by reported DESs and ILs at the same conditions. The new concept of SSSs would be very helpful for expanding the area of green solvents and green chemistry for building a greener world. Deep eutectic solvents Physical properties Chemical thermodynamics Green chemistry Green solvents Zhang, Fuguang verfasserin aut Sun, Haiyang verfasserin aut Chang, Yi verfasserin aut Zhang, Ziyang verfasserin aut Liu, Zhenghui verfasserin aut Yang, Mingshuai verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 391 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:391 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.21 Lösungen Flüssigkeiten Physikalische Chemie VZ AR 391 |
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10.1016/j.molliq.2023.123410 doi (DE-627)ELV065458524 (ELSEVIER)S0167-7322(23)02216-X DE-627 ger DE-627 rda eng 540 VZ 35.21 bkl Chen, Yu verfasserin (orcid)0000-0003-3420-7694 aut Superlong supercooling solvents (SSSs): Alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Water, supercritical fluids, ionic liquids and deep eutectic solvents (DESs) have been considered as green solvents for many years. The demand of green and sustainable development requires the search of novel green solvents. Some of the reported DESs might be not be the real DESs because we observe that these so-called reported liquid DESs become solid after exposure to the room temperature for many hours or days. Here, we for the first time propose a new concept of green solvents, superlong supercooling solvents (SSSs), as the green alternatives to water, supercritical fluids, ionic liquids and DESs. SSSs are the metastable liquid solvents either single component or multiple components due to the superlong supercooling effect at the temperature around or a little higher than room temperature. SSSs should condense after a superlong time; however, SSSs could be used as the green solvents before the condensation due to the superlong supercooling. Typical application example of SSSs is that SSSs could leach nearly 100% valuable metals from lithium-ion batteries cathode at low temperature, which is much higher than that by reported DESs and ILs at the same conditions. The new concept of SSSs would be very helpful for expanding the area of green solvents and green chemistry for building a greener world. Deep eutectic solvents Physical properties Chemical thermodynamics Green chemistry Green solvents Zhang, Fuguang verfasserin aut Sun, Haiyang verfasserin aut Chang, Yi verfasserin aut Zhang, Ziyang verfasserin aut Liu, Zhenghui verfasserin aut Yang, Mingshuai verfasserin aut Enthalten in Journal of molecular liquids New York, NY [u.a.] : Elsevier, 1983 391 Online-Ressource (DE-627)302469664 (DE-600)1491496-7 (DE-576)259483915 1873-3166 nnns volume:391 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_374 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2807 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.21 Lösungen Flüssigkeiten Physikalische Chemie VZ AR 391 |
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Chen, Yu @@aut@@ Zhang, Fuguang @@aut@@ Sun, Haiyang @@aut@@ Chang, Yi @@aut@@ Zhang, Ziyang @@aut@@ Liu, Zhenghui @@aut@@ Yang, Mingshuai @@aut@@ |
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Chen, Yu ddc 540 bkl 35.21 misc Deep eutectic solvents misc Physical properties misc Chemical thermodynamics misc Green chemistry misc Green solvents Superlong supercooling solvents (SSSs): Alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling |
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540 VZ 35.21 bkl Superlong supercooling solvents (SSSs): Alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling Deep eutectic solvents Physical properties Chemical thermodynamics Green chemistry Green solvents |
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superlong supercooling solvents (ssss): alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling |
title_auth |
Superlong supercooling solvents (SSSs): Alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling |
abstract |
Water, supercritical fluids, ionic liquids and deep eutectic solvents (DESs) have been considered as green solvents for many years. The demand of green and sustainable development requires the search of novel green solvents. Some of the reported DESs might be not be the real DESs because we observe that these so-called reported liquid DESs become solid after exposure to the room temperature for many hours or days. Here, we for the first time propose a new concept of green solvents, superlong supercooling solvents (SSSs), as the green alternatives to water, supercritical fluids, ionic liquids and DESs. SSSs are the metastable liquid solvents either single component or multiple components due to the superlong supercooling effect at the temperature around or a little higher than room temperature. SSSs should condense after a superlong time; however, SSSs could be used as the green solvents before the condensation due to the superlong supercooling. Typical application example of SSSs is that SSSs could leach nearly 100% valuable metals from lithium-ion batteries cathode at low temperature, which is much higher than that by reported DESs and ILs at the same conditions. The new concept of SSSs would be very helpful for expanding the area of green solvents and green chemistry for building a greener world. |
abstractGer |
Water, supercritical fluids, ionic liquids and deep eutectic solvents (DESs) have been considered as green solvents for many years. The demand of green and sustainable development requires the search of novel green solvents. Some of the reported DESs might be not be the real DESs because we observe that these so-called reported liquid DESs become solid after exposure to the room temperature for many hours or days. Here, we for the first time propose a new concept of green solvents, superlong supercooling solvents (SSSs), as the green alternatives to water, supercritical fluids, ionic liquids and DESs. SSSs are the metastable liquid solvents either single component or multiple components due to the superlong supercooling effect at the temperature around or a little higher than room temperature. SSSs should condense after a superlong time; however, SSSs could be used as the green solvents before the condensation due to the superlong supercooling. Typical application example of SSSs is that SSSs could leach nearly 100% valuable metals from lithium-ion batteries cathode at low temperature, which is much higher than that by reported DESs and ILs at the same conditions. The new concept of SSSs would be very helpful for expanding the area of green solvents and green chemistry for building a greener world. |
abstract_unstemmed |
Water, supercritical fluids, ionic liquids and deep eutectic solvents (DESs) have been considered as green solvents for many years. The demand of green and sustainable development requires the search of novel green solvents. Some of the reported DESs might be not be the real DESs because we observe that these so-called reported liquid DESs become solid after exposure to the room temperature for many hours or days. Here, we for the first time propose a new concept of green solvents, superlong supercooling solvents (SSSs), as the green alternatives to water, supercritical fluids, ionic liquids and DESs. SSSs are the metastable liquid solvents either single component or multiple components due to the superlong supercooling effect at the temperature around or a little higher than room temperature. SSSs should condense after a superlong time; however, SSSs could be used as the green solvents before the condensation due to the superlong supercooling. Typical application example of SSSs is that SSSs could leach nearly 100% valuable metals from lithium-ion batteries cathode at low temperature, which is much higher than that by reported DESs and ILs at the same conditions. The new concept of SSSs would be very helpful for expanding the area of green solvents and green chemistry for building a greener world. |
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title_short |
Superlong supercooling solvents (SSSs): Alternative green solvents to ionic liquids and deep eutectic solvents for lithium-ion batteries recycling |
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|
score |
7.40063 |