Surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode
A large nucleation overpotential on most metal substrates can cause uneven nucleation of Li, causing inhomogeneous Li deposition, leading to tip effects and gradually evolve into dendrites and dead Li. Surface lithiophilicity modification is conducive to promoting Li nucleation, thus avoid the gener...
Ausführliche Beschreibung
Autor*in: |
Wang, Yujue [verfasserIn] Chu, Ziqi [verfasserIn] Wang, Yilin [verfasserIn] Liu, Xionghao [verfasserIn] Zhao, Qian [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2023 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Journal of alloys and compounds - Lausanne : Elsevier, 1991, 971 |
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Übergeordnetes Werk: |
volume:971 |
DOI / URN: |
10.1016/j.jallcom.2023.172780 |
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Katalog-ID: |
ELV065630289 |
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520 | |a A large nucleation overpotential on most metal substrates can cause uneven nucleation of Li, causing inhomogeneous Li deposition, leading to tip effects and gradually evolve into dendrites and dead Li. Surface lithiophilicity modification is conducive to promoting Li nucleation, thus avoid the generation of dendrites and form uniform Li deposition. Herein, 3-mercapto-1,2,4-triazole (MT) is used to modify the surface of Cu foil to form lithiophilic modification layer decorated Cu electrode (MT/Cu). Due to the lone pair of electrons on N and S in the MT molecules, Li+ can be easily absorbed, thus realizing uniform and dendrite-free deposition, and improving cycling stability. After plating/stripping cycles for asymmetric cell, an average Coulombic efficiency up to 99.76 % can be achieved. When the Li-loaded composite anode (Li/MT/Cu) is matched with LiFePO4 cathode, the full cell possesses a capacity retention rate of 98.3 % after 200 cycles at 1 C, and the Coulombic efficiency throughout the process maintains over 99 %. This method of surface lithiophilicity modification is simple and effective, which can provide new ideas for the composition and modification of Li metal anodes. | ||
650 | 4 | |a 3-Mercapto-1,2,4-triazole | |
650 | 4 | |a Lithiophilicity modification | |
650 | 4 | |a Dendrite-free | |
650 | 4 | |a Homogeneous Li deposition | |
650 | 4 | |a Li metal anode | |
700 | 1 | |a Chu, Ziqi |e verfasserin |4 aut | |
700 | 1 | |a Wang, Yilin |e verfasserin |4 aut | |
700 | 1 | |a Liu, Xionghao |e verfasserin |4 aut | |
700 | 1 | |a Zhao, Qian |e verfasserin |0 (orcid)0000-0002-1508-5831 |4 aut | |
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allfields |
10.1016/j.jallcom.2023.172780 doi (DE-627)ELV065630289 (ELSEVIER)S0925-8388(23)04083-5 DE-627 ger DE-627 rda eng 670 540 VZ 51.54 bkl 33.61 bkl 35.90 bkl Wang, Yujue verfasserin aut Surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A large nucleation overpotential on most metal substrates can cause uneven nucleation of Li, causing inhomogeneous Li deposition, leading to tip effects and gradually evolve into dendrites and dead Li. Surface lithiophilicity modification is conducive to promoting Li nucleation, thus avoid the generation of dendrites and form uniform Li deposition. Herein, 3-mercapto-1,2,4-triazole (MT) is used to modify the surface of Cu foil to form lithiophilic modification layer decorated Cu electrode (MT/Cu). Due to the lone pair of electrons on N and S in the MT molecules, Li+ can be easily absorbed, thus realizing uniform and dendrite-free deposition, and improving cycling stability. After plating/stripping cycles for asymmetric cell, an average Coulombic efficiency up to 99.76 % can be achieved. When the Li-loaded composite anode (Li/MT/Cu) is matched with LiFePO4 cathode, the full cell possesses a capacity retention rate of 98.3 % after 200 cycles at 1 C, and the Coulombic efficiency throughout the process maintains over 99 %. This method of surface lithiophilicity modification is simple and effective, which can provide new ideas for the composition and modification of Li metal anodes. 3-Mercapto-1,2,4-triazole Lithiophilicity modification Dendrite-free Homogeneous Li deposition Li metal anode Chu, Ziqi verfasserin aut Wang, Yilin verfasserin aut Liu, Xionghao verfasserin aut Zhao, Qian verfasserin (orcid)0000-0002-1508-5831 aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 971 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:971 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.54 Nichteisenmetalle und ihre Legierungen VZ 33.61 Festkörperphysik VZ 35.90 Festkörperchemie VZ AR 971 |
spelling |
10.1016/j.jallcom.2023.172780 doi (DE-627)ELV065630289 (ELSEVIER)S0925-8388(23)04083-5 DE-627 ger DE-627 rda eng 670 540 VZ 51.54 bkl 33.61 bkl 35.90 bkl Wang, Yujue verfasserin aut Surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A large nucleation overpotential on most metal substrates can cause uneven nucleation of Li, causing inhomogeneous Li deposition, leading to tip effects and gradually evolve into dendrites and dead Li. Surface lithiophilicity modification is conducive to promoting Li nucleation, thus avoid the generation of dendrites and form uniform Li deposition. Herein, 3-mercapto-1,2,4-triazole (MT) is used to modify the surface of Cu foil to form lithiophilic modification layer decorated Cu electrode (MT/Cu). Due to the lone pair of electrons on N and S in the MT molecules, Li+ can be easily absorbed, thus realizing uniform and dendrite-free deposition, and improving cycling stability. After plating/stripping cycles for asymmetric cell, an average Coulombic efficiency up to 99.76 % can be achieved. When the Li-loaded composite anode (Li/MT/Cu) is matched with LiFePO4 cathode, the full cell possesses a capacity retention rate of 98.3 % after 200 cycles at 1 C, and the Coulombic efficiency throughout the process maintains over 99 %. This method of surface lithiophilicity modification is simple and effective, which can provide new ideas for the composition and modification of Li metal anodes. 3-Mercapto-1,2,4-triazole Lithiophilicity modification Dendrite-free Homogeneous Li deposition Li metal anode Chu, Ziqi verfasserin aut Wang, Yilin verfasserin aut Liu, Xionghao verfasserin aut Zhao, Qian verfasserin (orcid)0000-0002-1508-5831 aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 971 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:971 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.54 Nichteisenmetalle und ihre Legierungen VZ 33.61 Festkörperphysik VZ 35.90 Festkörperchemie VZ AR 971 |
allfields_unstemmed |
10.1016/j.jallcom.2023.172780 doi (DE-627)ELV065630289 (ELSEVIER)S0925-8388(23)04083-5 DE-627 ger DE-627 rda eng 670 540 VZ 51.54 bkl 33.61 bkl 35.90 bkl Wang, Yujue verfasserin aut Surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A large nucleation overpotential on most metal substrates can cause uneven nucleation of Li, causing inhomogeneous Li deposition, leading to tip effects and gradually evolve into dendrites and dead Li. Surface lithiophilicity modification is conducive to promoting Li nucleation, thus avoid the generation of dendrites and form uniform Li deposition. Herein, 3-mercapto-1,2,4-triazole (MT) is used to modify the surface of Cu foil to form lithiophilic modification layer decorated Cu electrode (MT/Cu). Due to the lone pair of electrons on N and S in the MT molecules, Li+ can be easily absorbed, thus realizing uniform and dendrite-free deposition, and improving cycling stability. After plating/stripping cycles for asymmetric cell, an average Coulombic efficiency up to 99.76 % can be achieved. When the Li-loaded composite anode (Li/MT/Cu) is matched with LiFePO4 cathode, the full cell possesses a capacity retention rate of 98.3 % after 200 cycles at 1 C, and the Coulombic efficiency throughout the process maintains over 99 %. This method of surface lithiophilicity modification is simple and effective, which can provide new ideas for the composition and modification of Li metal anodes. 3-Mercapto-1,2,4-triazole Lithiophilicity modification Dendrite-free Homogeneous Li deposition Li metal anode Chu, Ziqi verfasserin aut Wang, Yilin verfasserin aut Liu, Xionghao verfasserin aut Zhao, Qian verfasserin (orcid)0000-0002-1508-5831 aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 971 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:971 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.54 Nichteisenmetalle und ihre Legierungen VZ 33.61 Festkörperphysik VZ 35.90 Festkörperchemie VZ AR 971 |
allfieldsGer |
10.1016/j.jallcom.2023.172780 doi (DE-627)ELV065630289 (ELSEVIER)S0925-8388(23)04083-5 DE-627 ger DE-627 rda eng 670 540 VZ 51.54 bkl 33.61 bkl 35.90 bkl Wang, Yujue verfasserin aut Surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A large nucleation overpotential on most metal substrates can cause uneven nucleation of Li, causing inhomogeneous Li deposition, leading to tip effects and gradually evolve into dendrites and dead Li. Surface lithiophilicity modification is conducive to promoting Li nucleation, thus avoid the generation of dendrites and form uniform Li deposition. Herein, 3-mercapto-1,2,4-triazole (MT) is used to modify the surface of Cu foil to form lithiophilic modification layer decorated Cu electrode (MT/Cu). Due to the lone pair of electrons on N and S in the MT molecules, Li+ can be easily absorbed, thus realizing uniform and dendrite-free deposition, and improving cycling stability. After plating/stripping cycles for asymmetric cell, an average Coulombic efficiency up to 99.76 % can be achieved. When the Li-loaded composite anode (Li/MT/Cu) is matched with LiFePO4 cathode, the full cell possesses a capacity retention rate of 98.3 % after 200 cycles at 1 C, and the Coulombic efficiency throughout the process maintains over 99 %. This method of surface lithiophilicity modification is simple and effective, which can provide new ideas for the composition and modification of Li metal anodes. 3-Mercapto-1,2,4-triazole Lithiophilicity modification Dendrite-free Homogeneous Li deposition Li metal anode Chu, Ziqi verfasserin aut Wang, Yilin verfasserin aut Liu, Xionghao verfasserin aut Zhao, Qian verfasserin (orcid)0000-0002-1508-5831 aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 971 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:971 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.54 Nichteisenmetalle und ihre Legierungen VZ 33.61 Festkörperphysik VZ 35.90 Festkörperchemie VZ AR 971 |
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10.1016/j.jallcom.2023.172780 doi (DE-627)ELV065630289 (ELSEVIER)S0925-8388(23)04083-5 DE-627 ger DE-627 rda eng 670 540 VZ 51.54 bkl 33.61 bkl 35.90 bkl Wang, Yujue verfasserin aut Surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier A large nucleation overpotential on most metal substrates can cause uneven nucleation of Li, causing inhomogeneous Li deposition, leading to tip effects and gradually evolve into dendrites and dead Li. Surface lithiophilicity modification is conducive to promoting Li nucleation, thus avoid the generation of dendrites and form uniform Li deposition. Herein, 3-mercapto-1,2,4-triazole (MT) is used to modify the surface of Cu foil to form lithiophilic modification layer decorated Cu electrode (MT/Cu). Due to the lone pair of electrons on N and S in the MT molecules, Li+ can be easily absorbed, thus realizing uniform and dendrite-free deposition, and improving cycling stability. After plating/stripping cycles for asymmetric cell, an average Coulombic efficiency up to 99.76 % can be achieved. When the Li-loaded composite anode (Li/MT/Cu) is matched with LiFePO4 cathode, the full cell possesses a capacity retention rate of 98.3 % after 200 cycles at 1 C, and the Coulombic efficiency throughout the process maintains over 99 %. This method of surface lithiophilicity modification is simple and effective, which can provide new ideas for the composition and modification of Li metal anodes. 3-Mercapto-1,2,4-triazole Lithiophilicity modification Dendrite-free Homogeneous Li deposition Li metal anode Chu, Ziqi verfasserin aut Wang, Yilin verfasserin aut Liu, Xionghao verfasserin aut Zhao, Qian verfasserin (orcid)0000-0002-1508-5831 aut Enthalten in Journal of alloys and compounds Lausanne : Elsevier, 1991 971 Online-Ressource (DE-627)320504646 (DE-600)2012675-X (DE-576)098615009 nnns volume:971 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 51.54 Nichteisenmetalle und ihre Legierungen VZ 33.61 Festkörperphysik VZ 35.90 Festkörperchemie VZ AR 971 |
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Enthalten in Journal of alloys and compounds 971 volume:971 |
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Enthalten in Journal of alloys and compounds 971 volume:971 |
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Nichteisenmetalle und ihre Legierungen Festkörperphysik Festkörperchemie |
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3-Mercapto-1,2,4-triazole Lithiophilicity modification Dendrite-free Homogeneous Li deposition Li metal anode |
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Journal of alloys and compounds |
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Wang, Yujue @@aut@@ Chu, Ziqi @@aut@@ Wang, Yilin @@aut@@ Liu, Xionghao @@aut@@ Zhao, Qian @@aut@@ |
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2023-01-01T00:00:00Z |
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Wang, Yujue |
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Wang, Yujue ddc 670 bkl 51.54 bkl 33.61 bkl 35.90 misc 3-Mercapto-1,2,4-triazole misc Lithiophilicity modification misc Dendrite-free misc Homogeneous Li deposition misc Li metal anode Surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode |
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670 540 VZ 51.54 bkl 33.61 bkl 35.90 bkl Surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode 3-Mercapto-1,2,4-triazole Lithiophilicity modification Dendrite-free Homogeneous Li deposition Li metal anode |
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ddc 670 bkl 51.54 bkl 33.61 bkl 35.90 misc 3-Mercapto-1,2,4-triazole misc Lithiophilicity modification misc Dendrite-free misc Homogeneous Li deposition misc Li metal anode |
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ddc 670 bkl 51.54 bkl 33.61 bkl 35.90 misc 3-Mercapto-1,2,4-triazole misc Lithiophilicity modification misc Dendrite-free misc Homogeneous Li deposition misc Li metal anode |
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surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode |
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Surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode |
abstract |
A large nucleation overpotential on most metal substrates can cause uneven nucleation of Li, causing inhomogeneous Li deposition, leading to tip effects and gradually evolve into dendrites and dead Li. Surface lithiophilicity modification is conducive to promoting Li nucleation, thus avoid the generation of dendrites and form uniform Li deposition. Herein, 3-mercapto-1,2,4-triazole (MT) is used to modify the surface of Cu foil to form lithiophilic modification layer decorated Cu electrode (MT/Cu). Due to the lone pair of electrons on N and S in the MT molecules, Li+ can be easily absorbed, thus realizing uniform and dendrite-free deposition, and improving cycling stability. After plating/stripping cycles for asymmetric cell, an average Coulombic efficiency up to 99.76 % can be achieved. When the Li-loaded composite anode (Li/MT/Cu) is matched with LiFePO4 cathode, the full cell possesses a capacity retention rate of 98.3 % after 200 cycles at 1 C, and the Coulombic efficiency throughout the process maintains over 99 %. This method of surface lithiophilicity modification is simple and effective, which can provide new ideas for the composition and modification of Li metal anodes. |
abstractGer |
A large nucleation overpotential on most metal substrates can cause uneven nucleation of Li, causing inhomogeneous Li deposition, leading to tip effects and gradually evolve into dendrites and dead Li. Surface lithiophilicity modification is conducive to promoting Li nucleation, thus avoid the generation of dendrites and form uniform Li deposition. Herein, 3-mercapto-1,2,4-triazole (MT) is used to modify the surface of Cu foil to form lithiophilic modification layer decorated Cu electrode (MT/Cu). Due to the lone pair of electrons on N and S in the MT molecules, Li+ can be easily absorbed, thus realizing uniform and dendrite-free deposition, and improving cycling stability. After plating/stripping cycles for asymmetric cell, an average Coulombic efficiency up to 99.76 % can be achieved. When the Li-loaded composite anode (Li/MT/Cu) is matched with LiFePO4 cathode, the full cell possesses a capacity retention rate of 98.3 % after 200 cycles at 1 C, and the Coulombic efficiency throughout the process maintains over 99 %. This method of surface lithiophilicity modification is simple and effective, which can provide new ideas for the composition and modification of Li metal anodes. |
abstract_unstemmed |
A large nucleation overpotential on most metal substrates can cause uneven nucleation of Li, causing inhomogeneous Li deposition, leading to tip effects and gradually evolve into dendrites and dead Li. Surface lithiophilicity modification is conducive to promoting Li nucleation, thus avoid the generation of dendrites and form uniform Li deposition. Herein, 3-mercapto-1,2,4-triazole (MT) is used to modify the surface of Cu foil to form lithiophilic modification layer decorated Cu electrode (MT/Cu). Due to the lone pair of electrons on N and S in the MT molecules, Li+ can be easily absorbed, thus realizing uniform and dendrite-free deposition, and improving cycling stability. After plating/stripping cycles for asymmetric cell, an average Coulombic efficiency up to 99.76 % can be achieved. When the Li-loaded composite anode (Li/MT/Cu) is matched with LiFePO4 cathode, the full cell possesses a capacity retention rate of 98.3 % after 200 cycles at 1 C, and the Coulombic efficiency throughout the process maintains over 99 %. This method of surface lithiophilicity modification is simple and effective, which can provide new ideas for the composition and modification of Li metal anodes. |
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title_short |
Surface lithiophilicity modification with triazole to realize dendrite-free lithium metal anode |
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|
score |
7.399832 |