Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method
In this work, submicron powders of Co-substituted barium hexaferrites were obtained by hydrothermal synthesis (BaFe12-xCoxO19 with x = 0.1, 0.3, 0.5). According to XRD data, all samples were single-phase hexaferrites. From the dependence of the lattice volume on the cobalt concentration, it was conc...
Ausführliche Beschreibung
Autor*in: |
Mironovich, A. Yu. [verfasserIn] Kostishin, V.G. [verfasserIn] Al-Khafaji, H.I. [verfasserIn] Timofeev, A.V. [verfasserIn] Ril, A.I. [verfasserIn] Shakirzyanov, R.I. [verfasserIn] Savchenko, E.S. [verfasserIn] Yamilov, S.E. [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2023 |
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Übergeordnetes Werk: |
Enthalten in: Journal of magnetism and magnetic materials - Amsterdam : North-Holland Publ. Co., 1975, 588 |
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Übergeordnetes Werk: |
volume:588 |
DOI / URN: |
10.1016/j.jmmm.2023.171469 |
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Katalog-ID: |
ELV065637739 |
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245 | 1 | 0 | |a Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method |
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520 | |a In this work, submicron powders of Co-substituted barium hexaferrites were obtained by hydrothermal synthesis (BaFe12-xCoxO19 with x = 0.1, 0.3, 0.5). According to XRD data, all samples were single-phase hexaferrites. From the dependence of the lattice volume on the cobalt concentration, it was concluded that the charge balance is achieved mainly due to the formation of oxygen vacancies. With the help of Mössbauer spectroscopy, the distribution of cobalt over hexaferrite sublattices was established, namely, the absence of any site preferences was observed. The magnetometry results correlated with the data on the cationic distribution in BaFe12-xCoxO19: with an increase in the cobalt concentration, the saturation magnetization decreased. | ||
650 | 4 | |a Barium hexaferrite | |
650 | 4 | |a Hydrothermal synthesis | |
650 | 4 | |a Substituted hexaferrite | |
650 | 4 | |a Mössbauer spectroscopy | |
700 | 1 | |a Kostishin, V.G. |e verfasserin |4 aut | |
700 | 1 | |a Al-Khafaji, H.I. |e verfasserin |4 aut | |
700 | 1 | |a Timofeev, A.V. |e verfasserin |4 aut | |
700 | 1 | |a Ril, A.I. |e verfasserin |4 aut | |
700 | 1 | |a Shakirzyanov, R.I. |e verfasserin |4 aut | |
700 | 1 | |a Savchenko, E.S. |e verfasserin |4 aut | |
700 | 1 | |a Yamilov, S.E. |e verfasserin |4 aut | |
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10.1016/j.jmmm.2023.171469 doi (DE-627)ELV065637739 (ELSEVIER)S0304-8853(23)01119-8 DE-627 ger DE-627 rda eng 530 VZ 33.16 bkl Mironovich, A. Yu. verfasserin aut Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this work, submicron powders of Co-substituted barium hexaferrites were obtained by hydrothermal synthesis (BaFe12-xCoxO19 with x = 0.1, 0.3, 0.5). According to XRD data, all samples were single-phase hexaferrites. From the dependence of the lattice volume on the cobalt concentration, it was concluded that the charge balance is achieved mainly due to the formation of oxygen vacancies. With the help of Mössbauer spectroscopy, the distribution of cobalt over hexaferrite sublattices was established, namely, the absence of any site preferences was observed. The magnetometry results correlated with the data on the cationic distribution in BaFe12-xCoxO19: with an increase in the cobalt concentration, the saturation magnetization decreased. Barium hexaferrite Hydrothermal synthesis Substituted hexaferrite Mössbauer spectroscopy Kostishin, V.G. verfasserin aut Al-Khafaji, H.I. verfasserin aut Timofeev, A.V. verfasserin aut Ril, A.I. verfasserin aut Shakirzyanov, R.I. verfasserin aut Savchenko, E.S. verfasserin aut Yamilov, S.E. verfasserin aut Enthalten in Journal of magnetism and magnetic materials Amsterdam : North-Holland Publ. Co., 1975 588 Online-Ressource (DE-627)271175958 (DE-600)1479000-2 (DE-576)078412331 0304-8853 nnns volume:588 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.16 Elektrizität Magnetismus VZ AR 588 |
spelling |
10.1016/j.jmmm.2023.171469 doi (DE-627)ELV065637739 (ELSEVIER)S0304-8853(23)01119-8 DE-627 ger DE-627 rda eng 530 VZ 33.16 bkl Mironovich, A. Yu. verfasserin aut Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this work, submicron powders of Co-substituted barium hexaferrites were obtained by hydrothermal synthesis (BaFe12-xCoxO19 with x = 0.1, 0.3, 0.5). According to XRD data, all samples were single-phase hexaferrites. From the dependence of the lattice volume on the cobalt concentration, it was concluded that the charge balance is achieved mainly due to the formation of oxygen vacancies. With the help of Mössbauer spectroscopy, the distribution of cobalt over hexaferrite sublattices was established, namely, the absence of any site preferences was observed. The magnetometry results correlated with the data on the cationic distribution in BaFe12-xCoxO19: with an increase in the cobalt concentration, the saturation magnetization decreased. Barium hexaferrite Hydrothermal synthesis Substituted hexaferrite Mössbauer spectroscopy Kostishin, V.G. verfasserin aut Al-Khafaji, H.I. verfasserin aut Timofeev, A.V. verfasserin aut Ril, A.I. verfasserin aut Shakirzyanov, R.I. verfasserin aut Savchenko, E.S. verfasserin aut Yamilov, S.E. verfasserin aut Enthalten in Journal of magnetism and magnetic materials Amsterdam : North-Holland Publ. Co., 1975 588 Online-Ressource (DE-627)271175958 (DE-600)1479000-2 (DE-576)078412331 0304-8853 nnns volume:588 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.16 Elektrizität Magnetismus VZ AR 588 |
allfields_unstemmed |
10.1016/j.jmmm.2023.171469 doi (DE-627)ELV065637739 (ELSEVIER)S0304-8853(23)01119-8 DE-627 ger DE-627 rda eng 530 VZ 33.16 bkl Mironovich, A. Yu. verfasserin aut Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this work, submicron powders of Co-substituted barium hexaferrites were obtained by hydrothermal synthesis (BaFe12-xCoxO19 with x = 0.1, 0.3, 0.5). According to XRD data, all samples were single-phase hexaferrites. From the dependence of the lattice volume on the cobalt concentration, it was concluded that the charge balance is achieved mainly due to the formation of oxygen vacancies. With the help of Mössbauer spectroscopy, the distribution of cobalt over hexaferrite sublattices was established, namely, the absence of any site preferences was observed. The magnetometry results correlated with the data on the cationic distribution in BaFe12-xCoxO19: with an increase in the cobalt concentration, the saturation magnetization decreased. Barium hexaferrite Hydrothermal synthesis Substituted hexaferrite Mössbauer spectroscopy Kostishin, V.G. verfasserin aut Al-Khafaji, H.I. verfasserin aut Timofeev, A.V. verfasserin aut Ril, A.I. verfasserin aut Shakirzyanov, R.I. verfasserin aut Savchenko, E.S. verfasserin aut Yamilov, S.E. verfasserin aut Enthalten in Journal of magnetism and magnetic materials Amsterdam : North-Holland Publ. Co., 1975 588 Online-Ressource (DE-627)271175958 (DE-600)1479000-2 (DE-576)078412331 0304-8853 nnns volume:588 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.16 Elektrizität Magnetismus VZ AR 588 |
allfieldsGer |
10.1016/j.jmmm.2023.171469 doi (DE-627)ELV065637739 (ELSEVIER)S0304-8853(23)01119-8 DE-627 ger DE-627 rda eng 530 VZ 33.16 bkl Mironovich, A. Yu. verfasserin aut Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this work, submicron powders of Co-substituted barium hexaferrites were obtained by hydrothermal synthesis (BaFe12-xCoxO19 with x = 0.1, 0.3, 0.5). According to XRD data, all samples were single-phase hexaferrites. From the dependence of the lattice volume on the cobalt concentration, it was concluded that the charge balance is achieved mainly due to the formation of oxygen vacancies. With the help of Mössbauer spectroscopy, the distribution of cobalt over hexaferrite sublattices was established, namely, the absence of any site preferences was observed. The magnetometry results correlated with the data on the cationic distribution in BaFe12-xCoxO19: with an increase in the cobalt concentration, the saturation magnetization decreased. Barium hexaferrite Hydrothermal synthesis Substituted hexaferrite Mössbauer spectroscopy Kostishin, V.G. verfasserin aut Al-Khafaji, H.I. verfasserin aut Timofeev, A.V. verfasserin aut Ril, A.I. verfasserin aut Shakirzyanov, R.I. verfasserin aut Savchenko, E.S. verfasserin aut Yamilov, S.E. verfasserin aut Enthalten in Journal of magnetism and magnetic materials Amsterdam : North-Holland Publ. Co., 1975 588 Online-Ressource (DE-627)271175958 (DE-600)1479000-2 (DE-576)078412331 0304-8853 nnns volume:588 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.16 Elektrizität Magnetismus VZ AR 588 |
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10.1016/j.jmmm.2023.171469 doi (DE-627)ELV065637739 (ELSEVIER)S0304-8853(23)01119-8 DE-627 ger DE-627 rda eng 530 VZ 33.16 bkl Mironovich, A. Yu. verfasserin aut Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this work, submicron powders of Co-substituted barium hexaferrites were obtained by hydrothermal synthesis (BaFe12-xCoxO19 with x = 0.1, 0.3, 0.5). According to XRD data, all samples were single-phase hexaferrites. From the dependence of the lattice volume on the cobalt concentration, it was concluded that the charge balance is achieved mainly due to the formation of oxygen vacancies. With the help of Mössbauer spectroscopy, the distribution of cobalt over hexaferrite sublattices was established, namely, the absence of any site preferences was observed. The magnetometry results correlated with the data on the cationic distribution in BaFe12-xCoxO19: with an increase in the cobalt concentration, the saturation magnetization decreased. Barium hexaferrite Hydrothermal synthesis Substituted hexaferrite Mössbauer spectroscopy Kostishin, V.G. verfasserin aut Al-Khafaji, H.I. verfasserin aut Timofeev, A.V. verfasserin aut Ril, A.I. verfasserin aut Shakirzyanov, R.I. verfasserin aut Savchenko, E.S. verfasserin aut Yamilov, S.E. verfasserin aut Enthalten in Journal of magnetism and magnetic materials Amsterdam : North-Holland Publ. Co., 1975 588 Online-Ressource (DE-627)271175958 (DE-600)1479000-2 (DE-576)078412331 0304-8853 nnns volume:588 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.16 Elektrizität Magnetismus VZ AR 588 |
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530 VZ 33.16 bkl Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method Barium hexaferrite Hydrothermal synthesis Substituted hexaferrite Mössbauer spectroscopy |
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Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method |
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Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method |
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Mironovich, A. Yu. Kostishin, V.G. Al-Khafaji, H.I. Timofeev, A.V. Ril, A.I. Shakirzyanov, R.I. Savchenko, E.S. Yamilov, S.E. |
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magnetic and structural properties of co-substituted barium hexaferrite synthesized by hydrothermal method |
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Magnetic and structural properties of Co-substituted barium hexaferrite synthesized by hydrothermal method |
abstract |
In this work, submicron powders of Co-substituted barium hexaferrites were obtained by hydrothermal synthesis (BaFe12-xCoxO19 with x = 0.1, 0.3, 0.5). According to XRD data, all samples were single-phase hexaferrites. From the dependence of the lattice volume on the cobalt concentration, it was concluded that the charge balance is achieved mainly due to the formation of oxygen vacancies. With the help of Mössbauer spectroscopy, the distribution of cobalt over hexaferrite sublattices was established, namely, the absence of any site preferences was observed. The magnetometry results correlated with the data on the cationic distribution in BaFe12-xCoxO19: with an increase in the cobalt concentration, the saturation magnetization decreased. |
abstractGer |
In this work, submicron powders of Co-substituted barium hexaferrites were obtained by hydrothermal synthesis (BaFe12-xCoxO19 with x = 0.1, 0.3, 0.5). According to XRD data, all samples were single-phase hexaferrites. From the dependence of the lattice volume on the cobalt concentration, it was concluded that the charge balance is achieved mainly due to the formation of oxygen vacancies. With the help of Mössbauer spectroscopy, the distribution of cobalt over hexaferrite sublattices was established, namely, the absence of any site preferences was observed. The magnetometry results correlated with the data on the cationic distribution in BaFe12-xCoxO19: with an increase in the cobalt concentration, the saturation magnetization decreased. |
abstract_unstemmed |
In this work, submicron powders of Co-substituted barium hexaferrites were obtained by hydrothermal synthesis (BaFe12-xCoxO19 with x = 0.1, 0.3, 0.5). According to XRD data, all samples were single-phase hexaferrites. From the dependence of the lattice volume on the cobalt concentration, it was concluded that the charge balance is achieved mainly due to the formation of oxygen vacancies. With the help of Mössbauer spectroscopy, the distribution of cobalt over hexaferrite sublattices was established, namely, the absence of any site preferences was observed. The magnetometry results correlated with the data on the cationic distribution in BaFe12-xCoxO19: with an increase in the cobalt concentration, the saturation magnetization decreased. |
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Kostishin, V.G. Al-Khafaji, H.I. Timofeev, A.V. Ril, A.I. Shakirzyanov, R.I. Savchenko, E.S. Yamilov, S.E. |
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