Thioether-functionalized covalent organic framework for mercury removal

Post-synthetic modification of COFs via pendant groups or secondary functional groups of the skeleton structure is an important strategy to introduce new properties or enhance existing properties of COFs. Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional...
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Autor*in:	Liu, Yuyang [verfasserIn] Chen, Ying [verfasserIn] Li, Yarong [verfasserIn] Li, Yongqiang [verfasserIn] He, Chiyang [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Covalent organic frameworks Thioether Post-synthetic modification Mercury removal

Übergeordnetes Werk:	Enthalten in: Colloids and surfaces / A - Amsterdam [u.a.] : Elsevier Science, 1993, 681
Übergeordnetes Werk:	volume:681

DOI / URN:	10.1016/j.colsurfa.2023.132807

Katalog-ID:	ELV06601722X

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520			\|a Post-synthetic modification of COFs via pendant groups or secondary functional groups of the skeleton structure is an important strategy to introduce new properties or enhance existing properties of COFs. Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional groups into a reasonably designed novel COF (TAPA-TFPD) through a post-synthetic modification strategy to create a promising thioether functionalized adsorbent for mercury removal. The thioether functionalized COF material, TAPA-TFPD-S-S, exhibited high mercury removal efficiency from aqueous solution, and the adsorption capacity of Hg2+ was up to 593 mg/g. This efficient mercury removal performance can be attributed its well-defined pore channel sufficient to facilitate Hg2+ diffusion together with high concentration of sulfide chelating sites distributed uniformly throughout the pore wall. The strong interaction between Hg2+ and the thioether groups of TAPA-TFPD-S-S was confirmed by XPS. In addition, TAPA-TFPD-S-S also has the ability to capture Hg0 from the air. The efficient capture of mercury species from aqueous solution and air and the excellent reusability make the prepared thioether-functionalized COFs have great development potential in practical applications. Our work not only demonstrates the utilization of thioether-functionalized COFs in the removal of heavy metal contaminants, but also highlights the exceptional potential of post-synthetic modification strategies in the development of environmental remediation materials.
650		4	\|a Covalent organic frameworks
650		4	\|a Thioether
650		4	\|a Post-synthetic modification
650		4	\|a Mercury removal
700	1		\|a Chen, Ying \|e verfasserin \|4 aut
700	1		\|a Li, Yarong \|e verfasserin \|4 aut
700	1		\|a Li, Yongqiang \|e verfasserin \|0 (orcid)0000-0002-5517-9349 \|4 aut
700	1		\|a He, Chiyang \|e verfasserin \|4 aut
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publishDate	2023
allfields	10.1016/j.colsurfa.2023.132807 doi (DE-627)ELV06601722X (ELSEVIER)S0927-7757(23)01891-5 DE-627 ger DE-627 rda eng 540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Liu, Yuyang verfasserin aut Thioether-functionalized covalent organic framework for mercury removal 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Post-synthetic modification of COFs via pendant groups or secondary functional groups of the skeleton structure is an important strategy to introduce new properties or enhance existing properties of COFs. Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional groups into a reasonably designed novel COF (TAPA-TFPD) through a post-synthetic modification strategy to create a promising thioether functionalized adsorbent for mercury removal. The thioether functionalized COF material, TAPA-TFPD-S-S, exhibited high mercury removal efficiency from aqueous solution, and the adsorption capacity of Hg2+ was up to 593 mg/g. This efficient mercury removal performance can be attributed its well-defined pore channel sufficient to facilitate Hg2+ diffusion together with high concentration of sulfide chelating sites distributed uniformly throughout the pore wall. The strong interaction between Hg2+ and the thioether groups of TAPA-TFPD-S-S was confirmed by XPS. In addition, TAPA-TFPD-S-S also has the ability to capture Hg0 from the air. The efficient capture of mercury species from aqueous solution and air and the excellent reusability make the prepared thioether-functionalized COFs have great development potential in practical applications. Our work not only demonstrates the utilization of thioether-functionalized COFs in the removal of heavy metal contaminants, but also highlights the exceptional potential of post-synthetic modification strategies in the development of environmental remediation materials. Covalent organic frameworks Thioether Post-synthetic modification Mercury removal Chen, Ying verfasserin aut Li, Yarong verfasserin aut Li, Yongqiang verfasserin (orcid)0000-0002-5517-9349 aut He, Chiyang verfasserin aut Enthalten in Colloids and surfaces / A Amsterdam [u.a.] : Elsevier Science, 1993 681 Online-Ressource (DE-627)306659956 (DE-600)1500517-3 (DE-576)098614843 1873-4359 nnns volume:681 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 Kolloidchemie Grenzflächenchemie VZ 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 52.78 Oberflächentechnik Wärmebehandlung VZ 58.20 Chemische Technologien: Allgemeines VZ AR 681
spelling	10.1016/j.colsurfa.2023.132807 doi (DE-627)ELV06601722X (ELSEVIER)S0927-7757(23)01891-5 DE-627 ger DE-627 rda eng 540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Liu, Yuyang verfasserin aut Thioether-functionalized covalent organic framework for mercury removal 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Post-synthetic modification of COFs via pendant groups or secondary functional groups of the skeleton structure is an important strategy to introduce new properties or enhance existing properties of COFs. Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional groups into a reasonably designed novel COF (TAPA-TFPD) through a post-synthetic modification strategy to create a promising thioether functionalized adsorbent for mercury removal. The thioether functionalized COF material, TAPA-TFPD-S-S, exhibited high mercury removal efficiency from aqueous solution, and the adsorption capacity of Hg2+ was up to 593 mg/g. This efficient mercury removal performance can be attributed its well-defined pore channel sufficient to facilitate Hg2+ diffusion together with high concentration of sulfide chelating sites distributed uniformly throughout the pore wall. The strong interaction between Hg2+ and the thioether groups of TAPA-TFPD-S-S was confirmed by XPS. In addition, TAPA-TFPD-S-S also has the ability to capture Hg0 from the air. The efficient capture of mercury species from aqueous solution and air and the excellent reusability make the prepared thioether-functionalized COFs have great development potential in practical applications. Our work not only demonstrates the utilization of thioether-functionalized COFs in the removal of heavy metal contaminants, but also highlights the exceptional potential of post-synthetic modification strategies in the development of environmental remediation materials. Covalent organic frameworks Thioether Post-synthetic modification Mercury removal Chen, Ying verfasserin aut Li, Yarong verfasserin aut Li, Yongqiang verfasserin (orcid)0000-0002-5517-9349 aut He, Chiyang verfasserin aut Enthalten in Colloids and surfaces / A Amsterdam [u.a.] : Elsevier Science, 1993 681 Online-Ressource (DE-627)306659956 (DE-600)1500517-3 (DE-576)098614843 1873-4359 nnns volume:681 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 Kolloidchemie Grenzflächenchemie VZ 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 52.78 Oberflächentechnik Wärmebehandlung VZ 58.20 Chemische Technologien: Allgemeines VZ AR 681
allfields_unstemmed	10.1016/j.colsurfa.2023.132807 doi (DE-627)ELV06601722X (ELSEVIER)S0927-7757(23)01891-5 DE-627 ger DE-627 rda eng 540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Liu, Yuyang verfasserin aut Thioether-functionalized covalent organic framework for mercury removal 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Post-synthetic modification of COFs via pendant groups or secondary functional groups of the skeleton structure is an important strategy to introduce new properties or enhance existing properties of COFs. Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional groups into a reasonably designed novel COF (TAPA-TFPD) through a post-synthetic modification strategy to create a promising thioether functionalized adsorbent for mercury removal. The thioether functionalized COF material, TAPA-TFPD-S-S, exhibited high mercury removal efficiency from aqueous solution, and the adsorption capacity of Hg2+ was up to 593 mg/g. This efficient mercury removal performance can be attributed its well-defined pore channel sufficient to facilitate Hg2+ diffusion together with high concentration of sulfide chelating sites distributed uniformly throughout the pore wall. The strong interaction between Hg2+ and the thioether groups of TAPA-TFPD-S-S was confirmed by XPS. In addition, TAPA-TFPD-S-S also has the ability to capture Hg0 from the air. The efficient capture of mercury species from aqueous solution and air and the excellent reusability make the prepared thioether-functionalized COFs have great development potential in practical applications. Our work not only demonstrates the utilization of thioether-functionalized COFs in the removal of heavy metal contaminants, but also highlights the exceptional potential of post-synthetic modification strategies in the development of environmental remediation materials. Covalent organic frameworks Thioether Post-synthetic modification Mercury removal Chen, Ying verfasserin aut Li, Yarong verfasserin aut Li, Yongqiang verfasserin (orcid)0000-0002-5517-9349 aut He, Chiyang verfasserin aut Enthalten in Colloids and surfaces / A Amsterdam [u.a.] : Elsevier Science, 1993 681 Online-Ressource (DE-627)306659956 (DE-600)1500517-3 (DE-576)098614843 1873-4359 nnns volume:681 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 Kolloidchemie Grenzflächenchemie VZ 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 52.78 Oberflächentechnik Wärmebehandlung VZ 58.20 Chemische Technologien: Allgemeines VZ AR 681
allfieldsGer	10.1016/j.colsurfa.2023.132807 doi (DE-627)ELV06601722X (ELSEVIER)S0927-7757(23)01891-5 DE-627 ger DE-627 rda eng 540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Liu, Yuyang verfasserin aut Thioether-functionalized covalent organic framework for mercury removal 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Post-synthetic modification of COFs via pendant groups or secondary functional groups of the skeleton structure is an important strategy to introduce new properties or enhance existing properties of COFs. Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional groups into a reasonably designed novel COF (TAPA-TFPD) through a post-synthetic modification strategy to create a promising thioether functionalized adsorbent for mercury removal. The thioether functionalized COF material, TAPA-TFPD-S-S, exhibited high mercury removal efficiency from aqueous solution, and the adsorption capacity of Hg2+ was up to 593 mg/g. This efficient mercury removal performance can be attributed its well-defined pore channel sufficient to facilitate Hg2+ diffusion together with high concentration of sulfide chelating sites distributed uniformly throughout the pore wall. The strong interaction between Hg2+ and the thioether groups of TAPA-TFPD-S-S was confirmed by XPS. In addition, TAPA-TFPD-S-S also has the ability to capture Hg0 from the air. The efficient capture of mercury species from aqueous solution and air and the excellent reusability make the prepared thioether-functionalized COFs have great development potential in practical applications. Our work not only demonstrates the utilization of thioether-functionalized COFs in the removal of heavy metal contaminants, but also highlights the exceptional potential of post-synthetic modification strategies in the development of environmental remediation materials. Covalent organic frameworks Thioether Post-synthetic modification Mercury removal Chen, Ying verfasserin aut Li, Yarong verfasserin aut Li, Yongqiang verfasserin (orcid)0000-0002-5517-9349 aut He, Chiyang verfasserin aut Enthalten in Colloids and surfaces / A Amsterdam [u.a.] : Elsevier Science, 1993 681 Online-Ressource (DE-627)306659956 (DE-600)1500517-3 (DE-576)098614843 1873-4359 nnns volume:681 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 Kolloidchemie Grenzflächenchemie VZ 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 52.78 Oberflächentechnik Wärmebehandlung VZ 58.20 Chemische Technologien: Allgemeines VZ AR 681
allfieldsSound	10.1016/j.colsurfa.2023.132807 doi (DE-627)ELV06601722X (ELSEVIER)S0927-7757(23)01891-5 DE-627 ger DE-627 rda eng 540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Liu, Yuyang verfasserin aut Thioether-functionalized covalent organic framework for mercury removal 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Post-synthetic modification of COFs via pendant groups or secondary functional groups of the skeleton structure is an important strategy to introduce new properties or enhance existing properties of COFs. Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional groups into a reasonably designed novel COF (TAPA-TFPD) through a post-synthetic modification strategy to create a promising thioether functionalized adsorbent for mercury removal. The thioether functionalized COF material, TAPA-TFPD-S-S, exhibited high mercury removal efficiency from aqueous solution, and the adsorption capacity of Hg2+ was up to 593 mg/g. This efficient mercury removal performance can be attributed its well-defined pore channel sufficient to facilitate Hg2+ diffusion together with high concentration of sulfide chelating sites distributed uniformly throughout the pore wall. The strong interaction between Hg2+ and the thioether groups of TAPA-TFPD-S-S was confirmed by XPS. In addition, TAPA-TFPD-S-S also has the ability to capture Hg0 from the air. The efficient capture of mercury species from aqueous solution and air and the excellent reusability make the prepared thioether-functionalized COFs have great development potential in practical applications. Our work not only demonstrates the utilization of thioether-functionalized COFs in the removal of heavy metal contaminants, but also highlights the exceptional potential of post-synthetic modification strategies in the development of environmental remediation materials. Covalent organic frameworks Thioether Post-synthetic modification Mercury removal Chen, Ying verfasserin aut Li, Yarong verfasserin aut Li, Yongqiang verfasserin (orcid)0000-0002-5517-9349 aut He, Chiyang verfasserin aut Enthalten in Colloids and surfaces / A Amsterdam [u.a.] : Elsevier Science, 1993 681 Online-Ressource (DE-627)306659956 (DE-600)1500517-3 (DE-576)098614843 1873-4359 nnns volume:681 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2411 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 35.18 Kolloidchemie Grenzflächenchemie VZ 33.68 Oberflächen Dünne Schichten Grenzflächen Physik VZ 52.78 Oberflächentechnik Wärmebehandlung VZ 58.20 Chemische Technologien: Allgemeines VZ AR 681
language	English
source	Enthalten in Colloids and surfaces / A 681 volume:681
sourceStr	Enthalten in Colloids and surfaces / A 681 volume:681
format_phy_str_mv	Article
bklname	Kolloidchemie Grenzflächenchemie Oberflächen Dünne Schichten Grenzflächen Oberflächentechnik Wärmebehandlung Chemische Technologien: Allgemeines
institution	findex.gbv.de
topic_facet	Covalent organic frameworks Thioether Post-synthetic modification Mercury removal
dewey-raw	540
isfreeaccess_bool	false
container_title	Colloids and surfaces / A
authorswithroles_txt_mv	Liu, Yuyang @@aut@@ Chen, Ying @@aut@@ Li, Yarong @@aut@@ Li, Yongqiang @@aut@@ He, Chiyang @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	306659956
dewey-sort	3540
id	ELV06601722X
language_de	englisch
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author	Liu, Yuyang
spellingShingle	Liu, Yuyang ddc 540 bkl 35.18 bkl 33.68 bkl 52.78 bkl 58.20 misc Covalent organic frameworks misc Thioether misc Post-synthetic modification misc Mercury removal Thioether-functionalized covalent organic framework for mercury removal
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topic_title	540 VZ 35.18 bkl 33.68 bkl 52.78 bkl 58.20 bkl Thioether-functionalized covalent organic framework for mercury removal Covalent organic frameworks Thioether Post-synthetic modification Mercury removal
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title	Thioether-functionalized covalent organic framework for mercury removal
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title_full	Thioether-functionalized covalent organic framework for mercury removal
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title_sort	thioether-functionalized covalent organic framework for mercury removal
title_auth	Thioether-functionalized covalent organic framework for mercury removal
abstract	Post-synthetic modification of COFs via pendant groups or secondary functional groups of the skeleton structure is an important strategy to introduce new properties or enhance existing properties of COFs. Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional groups into a reasonably designed novel COF (TAPA-TFPD) through a post-synthetic modification strategy to create a promising thioether functionalized adsorbent for mercury removal. The thioether functionalized COF material, TAPA-TFPD-S-S, exhibited high mercury removal efficiency from aqueous solution, and the adsorption capacity of Hg2+ was up to 593 mg/g. This efficient mercury removal performance can be attributed its well-defined pore channel sufficient to facilitate Hg2+ diffusion together with high concentration of sulfide chelating sites distributed uniformly throughout the pore wall. The strong interaction between Hg2+ and the thioether groups of TAPA-TFPD-S-S was confirmed by XPS. In addition, TAPA-TFPD-S-S also has the ability to capture Hg0 from the air. The efficient capture of mercury species from aqueous solution and air and the excellent reusability make the prepared thioether-functionalized COFs have great development potential in practical applications. Our work not only demonstrates the utilization of thioether-functionalized COFs in the removal of heavy metal contaminants, but also highlights the exceptional potential of post-synthetic modification strategies in the development of environmental remediation materials.
abstractGer	Post-synthetic modification of COFs via pendant groups or secondary functional groups of the skeleton structure is an important strategy to introduce new properties or enhance existing properties of COFs. Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional groups into a reasonably designed novel COF (TAPA-TFPD) through a post-synthetic modification strategy to create a promising thioether functionalized adsorbent for mercury removal. The thioether functionalized COF material, TAPA-TFPD-S-S, exhibited high mercury removal efficiency from aqueous solution, and the adsorption capacity of Hg2+ was up to 593 mg/g. This efficient mercury removal performance can be attributed its well-defined pore channel sufficient to facilitate Hg2+ diffusion together with high concentration of sulfide chelating sites distributed uniformly throughout the pore wall. The strong interaction between Hg2+ and the thioether groups of TAPA-TFPD-S-S was confirmed by XPS. In addition, TAPA-TFPD-S-S also has the ability to capture Hg0 from the air. The efficient capture of mercury species from aqueous solution and air and the excellent reusability make the prepared thioether-functionalized COFs have great development potential in practical applications. Our work not only demonstrates the utilization of thioether-functionalized COFs in the removal of heavy metal contaminants, but also highlights the exceptional potential of post-synthetic modification strategies in the development of environmental remediation materials.
abstract_unstemmed	Post-synthetic modification of COFs via pendant groups or secondary functional groups of the skeleton structure is an important strategy to introduce new properties or enhance existing properties of COFs. Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional groups into a reasonably designed novel COF (TAPA-TFPD) through a post-synthetic modification strategy to create a promising thioether functionalized adsorbent for mercury removal. The thioether functionalized COF material, TAPA-TFPD-S-S, exhibited high mercury removal efficiency from aqueous solution, and the adsorption capacity of Hg2+ was up to 593 mg/g. This efficient mercury removal performance can be attributed its well-defined pore channel sufficient to facilitate Hg2+ diffusion together with high concentration of sulfide chelating sites distributed uniformly throughout the pore wall. The strong interaction between Hg2+ and the thioether groups of TAPA-TFPD-S-S was confirmed by XPS. In addition, TAPA-TFPD-S-S also has the ability to capture Hg0 from the air. The efficient capture of mercury species from aqueous solution and air and the excellent reusability make the prepared thioether-functionalized COFs have great development potential in practical applications. Our work not only demonstrates the utilization of thioether-functionalized COFs in the removal of heavy metal contaminants, but also highlights the exceptional potential of post-synthetic modification strategies in the development of environmental remediation materials.
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title_short	Thioether-functionalized covalent organic framework for mercury removal
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author2	Chen, Ying Li, Yarong Li, Yongqiang He, Chiyang
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up_date	2024-07-07T01:02:43.693Z
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Herein, we take advantage of the inherent advantages of COFs and introduce thioether functional groups into a reasonably designed novel COF (TAPA-TFPD) through a post-synthetic modification strategy to create a promising thioether functionalized adsorbent for mercury removal. The thioether functionalized COF material, TAPA-TFPD-S-S, exhibited high mercury removal efficiency from aqueous solution, and the adsorption capacity of Hg2+ was up to 593 mg/g. This efficient mercury removal performance can be attributed its well-defined pore channel sufficient to facilitate Hg2+ diffusion together with high concentration of sulfide chelating sites distributed uniformly throughout the pore wall. The strong interaction between Hg2+ and the thioether groups of TAPA-TFPD-S-S was confirmed by XPS. In addition, TAPA-TFPD-S-S also has the ability to capture Hg0 from the air. The efficient capture of mercury species from aqueous solution and air and the excellent reusability make the prepared thioether-functionalized COFs have great development potential in practical applications. Our work not only demonstrates the utilization of thioether-functionalized COFs in the removal of heavy metal contaminants, but also highlights the exceptional potential of post-synthetic modification strategies in the development of environmental remediation materials.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Covalent organic frameworks</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thioether</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Post-synthetic modification</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mercury removal</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chen, Ying</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Yarong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Yongqiang</subfield><subfield code="e">verfasserin</subfield><subfield code="0">(orcid)0000-0002-5517-9349</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">He, Chiyang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Colloids and surfaces / A</subfield><subfield code="d">Amsterdam [u.a.] : Elsevier Science, 1993</subfield><subfield code="g">681</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)306659956</subfield><subfield code="w">(DE-600)1500517-3</subfield><subfield code="w">(DE-576)098614843</subfield><subfield code="x">1873-4359</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield 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Thioether-functionalized covalent organic framework for mercury removal

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