A novel broadband near-infrared phosphor Ca

Near-infrared spectroscopy (NIRS) is a rapid, non-destructive analytical characterization tool. In this study, we report near-infrared (NIR) phosphor Ca3MgTiGe3O12:Cr3+ in garnet system, achieving ultra-broadband NIR emission. The emission spectrum of the phosphor ranges from 690 nm–1100 nm with a f...
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Gespeichert in:

Autor*in:	He, Mianmian [verfasserIn] Yi, Shuangping [verfasserIn] Hu, Zhengfa [verfasserIn] Zhao, Weiren [verfasserIn] Wang, Yinhai [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2023

Schlagwörter:	Near infrared photoluminescence Ca Broadband Phosphor

Übergeordnetes Werk:	Enthalten in: Journal of luminescence - New York, NY [u.a.] : Elsevier, 1970, 266
Übergeordnetes Werk:	volume:266

DOI / URN:	10.1016/j.jlumin.2023.120304

Katalog-ID:	ELV066058309

Internformat


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520			\|a Near-infrared spectroscopy (NIRS) is a rapid, non-destructive analytical characterization tool. In this study, we report near-infrared (NIR) phosphor Ca3MgTiGe3O12:Cr3+ in garnet system, achieving ultra-broadband NIR emission. The emission spectrum of the phosphor ranges from 690 nm–1100 nm with a full width of half maximum (FWHM) value of ∼127 nm. The emission peak is observed at 786 nm when the excitation wavelength is 463 nm. The broadband emission seen in this study was identified as a result of 4T2 → 4A2 transition of Cr3+ in host lattice. The internal quantum efficiency (IQE) of the material was found to be as high as 66.5 %. The energy transfer mechanism, quantum yield, thermal stability and preparation conditions of the material were further investigated. These studies show that these materials with highly-efficient ultra-brosd near-infrared emissions are promising candidates for high-quality near-infrared light sources.
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matchkey_str	article:00222313:2023----::nvlrabnnaifae
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bklnumber	33.00
publishDate	2023
allfields	10.1016/j.jlumin.2023.120304 doi (DE-627)ELV066058309 (ELSEVIER)S0022-2313(23)00637-3 DE-627 ger DE-627 rda eng 530 VZ 33.00 bkl He, Mianmian verfasserin aut A novel broadband near-infrared phosphor Ca 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Near-infrared spectroscopy (NIRS) is a rapid, non-destructive analytical characterization tool. In this study, we report near-infrared (NIR) phosphor Ca3MgTiGe3O12:Cr3+ in garnet system, achieving ultra-broadband NIR emission. The emission spectrum of the phosphor ranges from 690 nm–1100 nm with a full width of half maximum (FWHM) value of ∼127 nm. The emission peak is observed at 786 nm when the excitation wavelength is 463 nm. The broadband emission seen in this study was identified as a result of 4T2 → 4A2 transition of Cr3+ in host lattice. The internal quantum efficiency (IQE) of the material was found to be as high as 66.5 %. The energy transfer mechanism, quantum yield, thermal stability and preparation conditions of the material were further investigated. These studies show that these materials with highly-efficient ultra-brosd near-infrared emissions are promising candidates for high-quality near-infrared light sources. Near infrared photoluminescence Ca Broadband Phosphor Yi, Shuangping verfasserin aut Hu, Zhengfa verfasserin aut Zhao, Weiren verfasserin aut Wang, Yinhai verfasserin aut Enthalten in Journal of luminescence New York, NY [u.a.] : Elsevier, 1970 266 Online-Ressource (DE-627)302468749 (DE-600)1491401-3 (DE-576)120883473 0022-2313 nnns volume:266 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 Physik: Allgemeines VZ AR 266
spelling	10.1016/j.jlumin.2023.120304 doi (DE-627)ELV066058309 (ELSEVIER)S0022-2313(23)00637-3 DE-627 ger DE-627 rda eng 530 VZ 33.00 bkl He, Mianmian verfasserin aut A novel broadband near-infrared phosphor Ca 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Near-infrared spectroscopy (NIRS) is a rapid, non-destructive analytical characterization tool. In this study, we report near-infrared (NIR) phosphor Ca3MgTiGe3O12:Cr3+ in garnet system, achieving ultra-broadband NIR emission. The emission spectrum of the phosphor ranges from 690 nm–1100 nm with a full width of half maximum (FWHM) value of ∼127 nm. The emission peak is observed at 786 nm when the excitation wavelength is 463 nm. The broadband emission seen in this study was identified as a result of 4T2 → 4A2 transition of Cr3+ in host lattice. The internal quantum efficiency (IQE) of the material was found to be as high as 66.5 %. The energy transfer mechanism, quantum yield, thermal stability and preparation conditions of the material were further investigated. These studies show that these materials with highly-efficient ultra-brosd near-infrared emissions are promising candidates for high-quality near-infrared light sources. Near infrared photoluminescence Ca Broadband Phosphor Yi, Shuangping verfasserin aut Hu, Zhengfa verfasserin aut Zhao, Weiren verfasserin aut Wang, Yinhai verfasserin aut Enthalten in Journal of luminescence New York, NY [u.a.] : Elsevier, 1970 266 Online-Ressource (DE-627)302468749 (DE-600)1491401-3 (DE-576)120883473 0022-2313 nnns volume:266 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 Physik: Allgemeines VZ AR 266
allfields_unstemmed	10.1016/j.jlumin.2023.120304 doi (DE-627)ELV066058309 (ELSEVIER)S0022-2313(23)00637-3 DE-627 ger DE-627 rda eng 530 VZ 33.00 bkl He, Mianmian verfasserin aut A novel broadband near-infrared phosphor Ca 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Near-infrared spectroscopy (NIRS) is a rapid, non-destructive analytical characterization tool. In this study, we report near-infrared (NIR) phosphor Ca3MgTiGe3O12:Cr3+ in garnet system, achieving ultra-broadband NIR emission. The emission spectrum of the phosphor ranges from 690 nm–1100 nm with a full width of half maximum (FWHM) value of ∼127 nm. The emission peak is observed at 786 nm when the excitation wavelength is 463 nm. The broadband emission seen in this study was identified as a result of 4T2 → 4A2 transition of Cr3+ in host lattice. The internal quantum efficiency (IQE) of the material was found to be as high as 66.5 %. The energy transfer mechanism, quantum yield, thermal stability and preparation conditions of the material were further investigated. These studies show that these materials with highly-efficient ultra-brosd near-infrared emissions are promising candidates for high-quality near-infrared light sources. Near infrared photoluminescence Ca Broadband Phosphor Yi, Shuangping verfasserin aut Hu, Zhengfa verfasserin aut Zhao, Weiren verfasserin aut Wang, Yinhai verfasserin aut Enthalten in Journal of luminescence New York, NY [u.a.] : Elsevier, 1970 266 Online-Ressource (DE-627)302468749 (DE-600)1491401-3 (DE-576)120883473 0022-2313 nnns volume:266 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 Physik: Allgemeines VZ AR 266
allfieldsGer	10.1016/j.jlumin.2023.120304 doi (DE-627)ELV066058309 (ELSEVIER)S0022-2313(23)00637-3 DE-627 ger DE-627 rda eng 530 VZ 33.00 bkl He, Mianmian verfasserin aut A novel broadband near-infrared phosphor Ca 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Near-infrared spectroscopy (NIRS) is a rapid, non-destructive analytical characterization tool. In this study, we report near-infrared (NIR) phosphor Ca3MgTiGe3O12:Cr3+ in garnet system, achieving ultra-broadband NIR emission. The emission spectrum of the phosphor ranges from 690 nm–1100 nm with a full width of half maximum (FWHM) value of ∼127 nm. The emission peak is observed at 786 nm when the excitation wavelength is 463 nm. The broadband emission seen in this study was identified as a result of 4T2 → 4A2 transition of Cr3+ in host lattice. The internal quantum efficiency (IQE) of the material was found to be as high as 66.5 %. The energy transfer mechanism, quantum yield, thermal stability and preparation conditions of the material were further investigated. These studies show that these materials with highly-efficient ultra-brosd near-infrared emissions are promising candidates for high-quality near-infrared light sources. Near infrared photoluminescence Ca Broadband Phosphor Yi, Shuangping verfasserin aut Hu, Zhengfa verfasserin aut Zhao, Weiren verfasserin aut Wang, Yinhai verfasserin aut Enthalten in Journal of luminescence New York, NY [u.a.] : Elsevier, 1970 266 Online-Ressource (DE-627)302468749 (DE-600)1491401-3 (DE-576)120883473 0022-2313 nnns volume:266 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 Physik: Allgemeines VZ AR 266
allfieldsSound	10.1016/j.jlumin.2023.120304 doi (DE-627)ELV066058309 (ELSEVIER)S0022-2313(23)00637-3 DE-627 ger DE-627 rda eng 530 VZ 33.00 bkl He, Mianmian verfasserin aut A novel broadband near-infrared phosphor Ca 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Near-infrared spectroscopy (NIRS) is a rapid, non-destructive analytical characterization tool. In this study, we report near-infrared (NIR) phosphor Ca3MgTiGe3O12:Cr3+ in garnet system, achieving ultra-broadband NIR emission. The emission spectrum of the phosphor ranges from 690 nm–1100 nm with a full width of half maximum (FWHM) value of ∼127 nm. The emission peak is observed at 786 nm when the excitation wavelength is 463 nm. The broadband emission seen in this study was identified as a result of 4T2 → 4A2 transition of Cr3+ in host lattice. The internal quantum efficiency (IQE) of the material was found to be as high as 66.5 %. The energy transfer mechanism, quantum yield, thermal stability and preparation conditions of the material were further investigated. These studies show that these materials with highly-efficient ultra-brosd near-infrared emissions are promising candidates for high-quality near-infrared light sources. Near infrared photoluminescence Ca Broadband Phosphor Yi, Shuangping verfasserin aut Hu, Zhengfa verfasserin aut Zhao, Weiren verfasserin aut Wang, Yinhai verfasserin aut Enthalten in Journal of luminescence New York, NY [u.a.] : Elsevier, 1970 266 Online-Ressource (DE-627)302468749 (DE-600)1491401-3 (DE-576)120883473 0022-2313 nnns volume:266 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.00 Physik: Allgemeines VZ AR 266
language	English
source	Enthalten in Journal of luminescence 266 volume:266
sourceStr	Enthalten in Journal of luminescence 266 volume:266
format_phy_str_mv	Article
bklname	Physik: Allgemeines
institution	findex.gbv.de
topic_facet	Near infrared photoluminescence Ca Broadband Phosphor
dewey-raw	530
isfreeaccess_bool	false
container_title	Journal of luminescence
authorswithroles_txt_mv	He, Mianmian @@aut@@ Yi, Shuangping @@aut@@ Hu, Zhengfa @@aut@@ Zhao, Weiren @@aut@@ Wang, Yinhai @@aut@@
publishDateDaySort_date	2023-01-01T00:00:00Z
hierarchy_top_id	302468749
dewey-sort	3530
id	ELV066058309
language_de	englisch
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author	He, Mianmian
spellingShingle	He, Mianmian ddc 530 bkl 33.00 misc Near infrared photoluminescence misc Ca misc Broadband misc Phosphor A novel broadband near-infrared phosphor Ca
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topic_title	530 VZ 33.00 bkl A novel broadband near-infrared phosphor Ca Near infrared photoluminescence Ca Broadband Phosphor
topic	ddc 530 bkl 33.00 misc Near infrared photoluminescence misc Ca misc Broadband misc Phosphor
topic_unstemmed	ddc 530 bkl 33.00 misc Near infrared photoluminescence misc Ca misc Broadband misc Phosphor
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title	A novel broadband near-infrared phosphor Ca
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title_full	A novel broadband near-infrared phosphor Ca
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author_browse	He, Mianmian Yi, Shuangping Hu, Zhengfa Zhao, Weiren Wang, Yinhai
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title_sort	a novel broadband near-infrared phosphor ca
title_auth	A novel broadband near-infrared phosphor Ca
abstract	Near-infrared spectroscopy (NIRS) is a rapid, non-destructive analytical characterization tool. In this study, we report near-infrared (NIR) phosphor Ca3MgTiGe3O12:Cr3+ in garnet system, achieving ultra-broadband NIR emission. The emission spectrum of the phosphor ranges from 690 nm–1100 nm with a full width of half maximum (FWHM) value of ∼127 nm. The emission peak is observed at 786 nm when the excitation wavelength is 463 nm. The broadband emission seen in this study was identified as a result of 4T2 → 4A2 transition of Cr3+ in host lattice. The internal quantum efficiency (IQE) of the material was found to be as high as 66.5 %. The energy transfer mechanism, quantum yield, thermal stability and preparation conditions of the material were further investigated. These studies show that these materials with highly-efficient ultra-brosd near-infrared emissions are promising candidates for high-quality near-infrared light sources.
abstractGer	Near-infrared spectroscopy (NIRS) is a rapid, non-destructive analytical characterization tool. In this study, we report near-infrared (NIR) phosphor Ca3MgTiGe3O12:Cr3+ in garnet system, achieving ultra-broadband NIR emission. The emission spectrum of the phosphor ranges from 690 nm–1100 nm with a full width of half maximum (FWHM) value of ∼127 nm. The emission peak is observed at 786 nm when the excitation wavelength is 463 nm. The broadband emission seen in this study was identified as a result of 4T2 → 4A2 transition of Cr3+ in host lattice. The internal quantum efficiency (IQE) of the material was found to be as high as 66.5 %. The energy transfer mechanism, quantum yield, thermal stability and preparation conditions of the material were further investigated. These studies show that these materials with highly-efficient ultra-brosd near-infrared emissions are promising candidates for high-quality near-infrared light sources.
abstract_unstemmed	Near-infrared spectroscopy (NIRS) is a rapid, non-destructive analytical characterization tool. In this study, we report near-infrared (NIR) phosphor Ca3MgTiGe3O12:Cr3+ in garnet system, achieving ultra-broadband NIR emission. The emission spectrum of the phosphor ranges from 690 nm–1100 nm with a full width of half maximum (FWHM) value of ∼127 nm. The emission peak is observed at 786 nm when the excitation wavelength is 463 nm. The broadband emission seen in this study was identified as a result of 4T2 → 4A2 transition of Cr3+ in host lattice. The internal quantum efficiency (IQE) of the material was found to be as high as 66.5 %. The energy transfer mechanism, quantum yield, thermal stability and preparation conditions of the material were further investigated. These studies show that these materials with highly-efficient ultra-brosd near-infrared emissions are promising candidates for high-quality near-infrared light sources.
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title_short	A novel broadband near-infrared phosphor Ca
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author2	Yi, Shuangping Hu, Zhengfa Zhao, Weiren Wang, Yinhai
author2Str	Yi, Shuangping Hu, Zhengfa Zhao, Weiren Wang, Yinhai
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doi_str	10.1016/j.jlumin.2023.120304
up_date	2024-07-07T01:11:22.317Z
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