Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity
In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsor...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Yan, Shanshan [verfasserIn] Chen, Haoran [verfasserIn] Zhu, Haonan [verfasserIn] Lin, Zixiang [verfasserIn] Wu, Gang [verfasserIn] Gao, Wenran [verfasserIn] Zhang, Hong [verfasserIn] Hu, Xun [verfasserIn] Zhang, Junjie [verfasserIn] Zhang, Shu [verfasserIn] Zhang, Shoujun [verfasserIn] Wu, Yinlong [verfasserIn] |
|---|
| Format: |
E-Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2022 |
|---|
| Schlagwörter: |
|---|
| Übergeordnetes Werk: |
Enthalten in: Fuel - New York, NY [u.a.] : Elsevier, 1970, 338 |
|---|---|
| Übergeordnetes Werk: |
volume:338 |
| DOI / URN: |
10.1016/j.fuel.2022.127224 |
|---|
| Katalog-ID: |
ELV066244803 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | ELV066244803 | ||
| 003 | DE-627 | ||
| 005 | 20231224093016.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231224s2022 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.fuel.2022.127224 |2 doi | |
| 035 | |a (DE-627)ELV066244803 | ||
| 035 | |a (ELSEVIER)S0016-2361(22)04048-0 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 660 |q VZ |
| 084 | |a 58.21 |2 bkl | ||
| 100 | 1 | |a Yan, Shanshan |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity |
| 264 | 1 | |c 2022 | |
| 336 | |a nicht spezifiziert |b zzz |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 520 | |a In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption. | ||
| 650 | 4 | |a Bio-oil | |
| 650 | 4 | |a Biochar | |
| 650 | 4 | |a Slurry | |
| 650 | 4 | |a Selective adsorption | |
| 650 | 4 | |a Aromatic compounds | |
| 700 | 1 | |a Chen, Haoran |e verfasserin |4 aut | |
| 700 | 1 | |a Zhu, Haonan |e verfasserin |4 aut | |
| 700 | 1 | |a Lin, Zixiang |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Gang |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Wenran |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Hong |e verfasserin |4 aut | |
| 700 | 1 | |a Hu, Xun |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Junjie |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Shu |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Shoujun |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Yinlong |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Fuel |d New York, NY [u.a.] : Elsevier, 1970 |g 338 |h Online-Ressource |w (DE-627)300898584 |w (DE-600)1483656-7 |w (DE-576)09555176X |x 0016-2361 |7 nnns |
| 773 | 1 | 8 | |g volume:338 |
| 912 | |a GBV_USEFLAG_U | ||
| 912 | |a GBV_ELV | ||
| 912 | |a SYSFLAG_U | ||
| 912 | |a SSG-OLC-PHA | ||
| 912 | |a GBV_ILN_20 | ||
| 912 | |a GBV_ILN_22 | ||
| 912 | |a GBV_ILN_23 | ||
| 912 | |a GBV_ILN_24 | ||
| 912 | |a GBV_ILN_31 | ||
| 912 | |a GBV_ILN_32 | ||
| 912 | |a GBV_ILN_40 | ||
| 912 | |a GBV_ILN_60 | ||
| 912 | |a GBV_ILN_62 | ||
| 912 | |a GBV_ILN_63 | ||
| 912 | |a GBV_ILN_65 | ||
| 912 | |a GBV_ILN_69 | ||
| 912 | |a GBV_ILN_70 | ||
| 912 | |a GBV_ILN_73 | ||
| 912 | |a GBV_ILN_74 | ||
| 912 | |a GBV_ILN_90 | ||
| 912 | |a GBV_ILN_95 | ||
| 912 | |a GBV_ILN_100 | ||
| 912 | |a GBV_ILN_105 | ||
| 912 | |a GBV_ILN_110 | ||
| 912 | |a GBV_ILN_150 | ||
| 912 | |a GBV_ILN_151 | ||
| 912 | |a GBV_ILN_224 | ||
| 912 | |a GBV_ILN_370 | ||
| 912 | |a GBV_ILN_602 | ||
| 912 | |a GBV_ILN_702 | ||
| 912 | |a GBV_ILN_2003 | ||
| 912 | |a GBV_ILN_2004 | ||
| 912 | |a GBV_ILN_2005 | ||
| 912 | |a GBV_ILN_2006 | ||
| 912 | |a GBV_ILN_2008 | ||
| 912 | |a GBV_ILN_2010 | ||
| 912 | |a GBV_ILN_2011 | ||
| 912 | |a GBV_ILN_2014 | ||
| 912 | |a GBV_ILN_2015 | ||
| 912 | |a GBV_ILN_2020 | ||
| 912 | |a GBV_ILN_2021 | ||
| 912 | |a GBV_ILN_2025 | ||
| 912 | |a GBV_ILN_2027 | ||
| 912 | |a GBV_ILN_2034 | ||
| 912 | |a GBV_ILN_2038 | ||
| 912 | |a GBV_ILN_2044 | ||
| 912 | |a GBV_ILN_2048 | ||
| 912 | |a GBV_ILN_2049 | ||
| 912 | |a GBV_ILN_2050 | ||
| 912 | |a GBV_ILN_2056 | ||
| 912 | |a GBV_ILN_2059 | ||
| 912 | |a GBV_ILN_2061 | ||
| 912 | |a GBV_ILN_2064 | ||
| 912 | |a GBV_ILN_2065 | ||
| 912 | |a GBV_ILN_2068 | ||
| 912 | |a GBV_ILN_2088 | ||
| 912 | |a GBV_ILN_2111 | ||
| 912 | |a GBV_ILN_2112 | ||
| 912 | |a GBV_ILN_2113 | ||
| 912 | |a GBV_ILN_2118 | ||
| 912 | |a GBV_ILN_2122 | ||
| 912 | |a GBV_ILN_2129 | ||
| 912 | |a GBV_ILN_2143 | ||
| 912 | |a GBV_ILN_2147 | ||
| 912 | |a GBV_ILN_2148 | ||
| 912 | |a GBV_ILN_2152 | ||
| 912 | |a GBV_ILN_2153 | ||
| 912 | |a GBV_ILN_2190 | ||
| 912 | |a GBV_ILN_2336 | ||
| 912 | |a GBV_ILN_2470 | ||
| 912 | |a GBV_ILN_2507 | ||
| 912 | |a GBV_ILN_2522 | ||
| 912 | |a GBV_ILN_4035 | ||
| 912 | |a GBV_ILN_4037 | ||
| 912 | |a GBV_ILN_4046 | ||
| 912 | |a GBV_ILN_4112 | ||
| 912 | |a GBV_ILN_4125 | ||
| 912 | |a GBV_ILN_4126 | ||
| 912 | |a GBV_ILN_4242 | ||
| 912 | |a GBV_ILN_4251 | ||
| 912 | |a GBV_ILN_4305 | ||
| 912 | |a GBV_ILN_4313 | ||
| 912 | |a GBV_ILN_4322 | ||
| 912 | |a GBV_ILN_4323 | ||
| 912 | |a GBV_ILN_4324 | ||
| 912 | |a GBV_ILN_4326 | ||
| 912 | |a GBV_ILN_4333 | ||
| 912 | |a GBV_ILN_4334 | ||
| 912 | |a GBV_ILN_4335 | ||
| 912 | |a GBV_ILN_4338 | ||
| 912 | |a GBV_ILN_4393 | ||
| 936 | b | k | |a 58.21 |j Brennstoffe |j Kraftstoffe |j Explosivstoffe |q VZ |
| 951 | |a AR | ||
| 952 | |d 338 | ||
| author_variant |
s y sy h c hc h z hz z l zl g w gw w g wg h z hz x h xh j z jz s z sz s z sz y w yw |
|---|---|
| matchkey_str |
article:00162361:2022----::nacddopinfiolnciaebohrnlryuladh |
| hierarchy_sort_str |
2022 |
| bklnumber |
58.21 |
| publishDate |
2022 |
| allfields |
10.1016/j.fuel.2022.127224 doi (DE-627)ELV066244803 (ELSEVIER)S0016-2361(22)04048-0 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Yan, Shanshan verfasserin aut Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption. Bio-oil Biochar Slurry Selective adsorption Aromatic compounds Chen, Haoran verfasserin aut Zhu, Haonan verfasserin aut Lin, Zixiang verfasserin aut Wu, Gang verfasserin aut Gao, Wenran verfasserin aut Zhang, Hong verfasserin aut Hu, Xun verfasserin aut Zhang, Junjie verfasserin aut Zhang, Shu verfasserin aut Zhang, Shoujun verfasserin aut Wu, Yinlong verfasserin aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 338 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:338 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 338 |
| spelling |
10.1016/j.fuel.2022.127224 doi (DE-627)ELV066244803 (ELSEVIER)S0016-2361(22)04048-0 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Yan, Shanshan verfasserin aut Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption. Bio-oil Biochar Slurry Selective adsorption Aromatic compounds Chen, Haoran verfasserin aut Zhu, Haonan verfasserin aut Lin, Zixiang verfasserin aut Wu, Gang verfasserin aut Gao, Wenran verfasserin aut Zhang, Hong verfasserin aut Hu, Xun verfasserin aut Zhang, Junjie verfasserin aut Zhang, Shu verfasserin aut Zhang, Shoujun verfasserin aut Wu, Yinlong verfasserin aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 338 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:338 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 338 |
| allfields_unstemmed |
10.1016/j.fuel.2022.127224 doi (DE-627)ELV066244803 (ELSEVIER)S0016-2361(22)04048-0 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Yan, Shanshan verfasserin aut Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption. Bio-oil Biochar Slurry Selective adsorption Aromatic compounds Chen, Haoran verfasserin aut Zhu, Haonan verfasserin aut Lin, Zixiang verfasserin aut Wu, Gang verfasserin aut Gao, Wenran verfasserin aut Zhang, Hong verfasserin aut Hu, Xun verfasserin aut Zhang, Junjie verfasserin aut Zhang, Shu verfasserin aut Zhang, Shoujun verfasserin aut Wu, Yinlong verfasserin aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 338 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:338 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 338 |
| allfieldsGer |
10.1016/j.fuel.2022.127224 doi (DE-627)ELV066244803 (ELSEVIER)S0016-2361(22)04048-0 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Yan, Shanshan verfasserin aut Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption. Bio-oil Biochar Slurry Selective adsorption Aromatic compounds Chen, Haoran verfasserin aut Zhu, Haonan verfasserin aut Lin, Zixiang verfasserin aut Wu, Gang verfasserin aut Gao, Wenran verfasserin aut Zhang, Hong verfasserin aut Hu, Xun verfasserin aut Zhang, Junjie verfasserin aut Zhang, Shu verfasserin aut Zhang, Shoujun verfasserin aut Wu, Yinlong verfasserin aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 338 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:338 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 338 |
| allfieldsSound |
10.1016/j.fuel.2022.127224 doi (DE-627)ELV066244803 (ELSEVIER)S0016-2361(22)04048-0 DE-627 ger DE-627 rda eng 660 VZ 58.21 bkl Yan, Shanshan verfasserin aut Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity 2022 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption. Bio-oil Biochar Slurry Selective adsorption Aromatic compounds Chen, Haoran verfasserin aut Zhu, Haonan verfasserin aut Lin, Zixiang verfasserin aut Wu, Gang verfasserin aut Gao, Wenran verfasserin aut Zhang, Hong verfasserin aut Hu, Xun verfasserin aut Zhang, Junjie verfasserin aut Zhang, Shu verfasserin aut Zhang, Shoujun verfasserin aut Wu, Yinlong verfasserin aut Enthalten in Fuel New York, NY [u.a.] : Elsevier, 1970 338 Online-Ressource (DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X 0016-2361 nnns volume:338 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 58.21 Brennstoffe Kraftstoffe Explosivstoffe VZ AR 338 |
| language |
English |
| source |
Enthalten in Fuel 338 volume:338 |
| sourceStr |
Enthalten in Fuel 338 volume:338 |
| format_phy_str_mv |
Article |
| bklname |
Brennstoffe Kraftstoffe Explosivstoffe |
| institution |
findex.gbv.de |
| topic_facet |
Bio-oil Biochar Slurry Selective adsorption Aromatic compounds |
| dewey-raw |
660 |
| isfreeaccess_bool |
false |
| container_title |
Fuel |
| authorswithroles_txt_mv |
Yan, Shanshan @@aut@@ Chen, Haoran @@aut@@ Zhu, Haonan @@aut@@ Lin, Zixiang @@aut@@ Wu, Gang @@aut@@ Gao, Wenran @@aut@@ Zhang, Hong @@aut@@ Hu, Xun @@aut@@ Zhang, Junjie @@aut@@ Zhang, Shu @@aut@@ Zhang, Shoujun @@aut@@ Wu, Yinlong @@aut@@ |
| publishDateDaySort_date |
2022-01-01T00:00:00Z |
| hierarchy_top_id |
300898584 |
| dewey-sort |
3660 |
| id |
ELV066244803 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">ELV066244803</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231224093016.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">231224s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.fuel.2022.127224</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV066244803</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0016-2361(22)04048-0</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.21</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yan, Shanshan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Bio-oil</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Biochar</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Slurry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Selective adsorption</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Aromatic compounds</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chen, Haoran</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhu, Haonan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lin, Zixiang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wu, Gang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gao, Wenran</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Hong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Hu, Xun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Junjie</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Shu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Shoujun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wu, Yinlong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Fuel</subfield><subfield code="d">New York, NY [u.a.] : Elsevier, 1970</subfield><subfield code="g">338</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)300898584</subfield><subfield code="w">(DE-600)1483656-7</subfield><subfield code="w">(DE-576)09555176X</subfield><subfield code="x">0016-2361</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.21</subfield><subfield code="j">Brennstoffe</subfield><subfield code="j">Kraftstoffe</subfield><subfield code="j">Explosivstoffe</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">338</subfield></datafield></record></collection>
|
| author |
Yan, Shanshan |
| spellingShingle |
Yan, Shanshan ddc 660 bkl 58.21 misc Bio-oil misc Biochar misc Slurry misc Selective adsorption misc Aromatic compounds Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity |
| authorStr |
Yan, Shanshan |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)300898584 |
| format |
electronic Article |
| dewey-ones |
660 - Chemical engineering |
| delete_txt_mv |
keep |
| author_role |
aut aut aut aut aut aut aut aut aut aut aut aut |
| collection |
elsevier |
| remote_str |
true |
| illustrated |
Not Illustrated |
| issn |
0016-2361 |
| topic_title |
660 VZ 58.21 bkl Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity Bio-oil Biochar Slurry Selective adsorption Aromatic compounds |
| topic |
ddc 660 bkl 58.21 misc Bio-oil misc Biochar misc Slurry misc Selective adsorption misc Aromatic compounds |
| topic_unstemmed |
ddc 660 bkl 58.21 misc Bio-oil misc Biochar misc Slurry misc Selective adsorption misc Aromatic compounds |
| topic_browse |
ddc 660 bkl 58.21 misc Bio-oil misc Biochar misc Slurry misc Selective adsorption misc Aromatic compounds |
| format_facet |
Elektronische Aufsätze Aufsätze Elektronische Ressource |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
cr |
| hierarchy_parent_title |
Fuel |
| hierarchy_parent_id |
300898584 |
| dewey-tens |
660 - Chemical engineering |
| hierarchy_top_title |
Fuel |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)300898584 (DE-600)1483656-7 (DE-576)09555176X |
| title |
Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity |
| ctrlnum |
(DE-627)ELV066244803 (ELSEVIER)S0016-2361(22)04048-0 |
| title_full |
Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity |
| author_sort |
Yan, Shanshan |
| journal |
Fuel |
| journalStr |
Fuel |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
600 - Technology |
| recordtype |
marc |
| publishDateSort |
2022 |
| contenttype_str_mv |
zzz |
| author_browse |
Yan, Shanshan Chen, Haoran Zhu, Haonan Lin, Zixiang Wu, Gang Gao, Wenran Zhang, Hong Hu, Xun Zhang, Junjie Zhang, Shu Zhang, Shoujun Wu, Yinlong |
| container_volume |
338 |
| class |
660 VZ 58.21 bkl |
| format_se |
Elektronische Aufsätze |
| author-letter |
Yan, Shanshan |
| doi_str_mv |
10.1016/j.fuel.2022.127224 |
| dewey-full |
660 |
| author2-role |
verfasserin |
| title_sort |
enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity |
| title_auth |
Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity |
| abstract |
In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption. |
| abstractGer |
In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption. |
| abstract_unstemmed |
In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption. |
| collection_details |
GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_63 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_224 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2006 GBV_ILN_2008 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2038 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2065 GBV_ILN_2068 GBV_ILN_2088 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2113 GBV_ILN_2118 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2147 GBV_ILN_2148 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_2522 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4046 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4126 GBV_ILN_4242 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4335 GBV_ILN_4338 GBV_ILN_4393 |
| title_short |
Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity |
| remote_bool |
true |
| author2 |
Chen, Haoran Zhu, Haonan Lin, Zixiang Wu, Gang Gao, Wenran Zhang, Hong Hu, Xun Zhang, Junjie Zhang, Shu Zhang, Shoujun Wu, Yinlong |
| author2Str |
Chen, Haoran Zhu, Haonan Lin, Zixiang Wu, Gang Gao, Wenran Zhang, Hong Hu, Xun Zhang, Junjie Zhang, Shu Zhang, Shoujun Wu, Yinlong |
| ppnlink |
300898584 |
| mediatype_str_mv |
c |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| doi_str |
10.1016/j.fuel.2022.127224 |
| up_date |
2024-07-06T17:05:25.791Z |
| _version_ |
1803850115492872192 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">ELV066244803</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231224093016.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">231224s2022 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1016/j.fuel.2022.127224</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)ELV066244803</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(ELSEVIER)S0016-2361(22)04048-0</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.21</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Yan, Shanshan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Enhanced adsorption of bio-oil on activated biochar in slurry fuels and the adsorption selectivity</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2022</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">In this study, activated biochars were prepared by CO2 and KOH activations for enhanced bio-oil adsorption in the slurry system. The results showed that activated biochars show better adsorption capacities on bio-oil than unactivated biochars due to the improved pore structure, and the highest adsorption rate reached 5.49 g bio-oil/g biochar by CO2 activated biochar prepared at 900 °C. The biochars especially activated biochars showed the best selectivity over aromatic compounds in bio-oil, followed by the selectivity over acids and ketones, and relatively weak selectivity for alcohols, aldehydes and monosaccharides. The average molecular weights of adsorbed bio-oil samples were 476–578 g/mol, higher than the 436 g/mol of bio-oil, implying the selective adsorption over heavy components. Biochar with large specific surface area, high O content or highly aromatized structure can facilitate the adsorption of monophenols and fused rings through pore filling, hydrogen bonding, π-π interactions and hydrophobic effect. Biochars with high O content can also have better adsorption selectivity on the acids and ketones in bio-oil via hydrogen bonding and electrostatic force. In summary, the developed pore structure, abundant O-containing functional groups, and high graphitization degree of biochar are beneficial for bio-oil adsorption.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Bio-oil</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Biochar</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Slurry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Selective adsorption</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Aromatic compounds</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chen, Haoran</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhu, Haonan</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lin, Zixiang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wu, Gang</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gao, Wenran</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Hong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Hu, Xun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Junjie</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Shu</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zhang, Shoujun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wu, Yinlong</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Fuel</subfield><subfield code="d">New York, NY [u.a.] : Elsevier, 1970</subfield><subfield code="g">338</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)300898584</subfield><subfield code="w">(DE-600)1483656-7</subfield><subfield code="w">(DE-576)09555176X</subfield><subfield code="x">0016-2361</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ELV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_20</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_23</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_24</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_31</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_32</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_40</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_60</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_62</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_63</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_65</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_69</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_73</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_74</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_90</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_95</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_100</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_105</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_110</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_150</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_151</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_224</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_370</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_602</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_702</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2003</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2005</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2008</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2010</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2011</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2015</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2020</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2021</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2025</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2034</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2038</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2044</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2048</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2049</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2050</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2056</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2059</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2061</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2064</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2065</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2068</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2088</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2111</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2113</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2118</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2122</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2129</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2143</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2147</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2148</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2152</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2153</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2190</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2336</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2470</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2507</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2522</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4035</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4037</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4046</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4112</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4125</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4126</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4242</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4251</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4305</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4313</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4322</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4323</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4324</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4326</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4333</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4334</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4335</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4338</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4393</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.21</subfield><subfield code="j">Brennstoffe</subfield><subfield code="j">Kraftstoffe</subfield><subfield code="j">Explosivstoffe</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">338</subfield></datafield></record></collection>
|
| score |
7.4020147 |