Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries

The abundant sodium resources makes sodium ion batteries have the potential to be an alternative to lithium-ion batteries. Due to the large ionic radius of sodium ion, suitable cathode materials have a significant impact on the electrochemical performance of sodium ion batteries. Herein, Cu0.18V2O5•...
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Autor*in:	Huang, Lai [verfasserIn] Dong, Youzhong [verfasserIn] Jiang, Pan [verfasserIn] Zhao, Yanming [verfasserIn] Fan, Qinghua [verfasserIn] Kuan, Quan [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2024

Schlagwörter:	Sodium ion battery Cu High capacity In situ XRD Storage mechanism

Übergeordnetes Werk:	Enthalten in: Solid state ionics - Amsterdam [u.a.] : Elsevier Science, 1980, 405
Übergeordnetes Werk:	volume:405

DOI / URN:	10.1016/j.ssi.2024.116455

Katalog-ID:	ELV066667208

Internformat


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245	1	0	\|a Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries
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520			\|a The abundant sodium resources makes sodium ion batteries have the potential to be an alternative to lithium-ion batteries. Due to the large ionic radius of sodium ion, suitable cathode materials have a significant impact on the electrochemical performance of sodium ion batteries. Herein, Cu0.18V2O5•0.72H2O/ Ketjen black, a double modification strategy of groups (Cu2+/H2O) intercalation and Ketjen black composition materials was successfully synthesized. Copper ions and water molecules co-inserted into the V2O5 interlayer to increase its spacing, thus increasing the active sites of Na+ ions intercalation and deintercalation. Meanwhile, the interlayer groups serve as “pillars” to improve the structural stability of the material. Ketjen black not only reduces particle aggregation but also enhances electrical conductivity of the material. As the cathode of sodium-ion batteries, the combination of these factors allows the cathode to exhibit high reversible specific capacity (up to 155 mA h g−1 at 50 mA g−1) and superior cycle performance. The fast and highly reversible Na+-ion intercalation/deintercalation mechanism was revealed by in situ XRD.
650		4	\|a Sodium ion battery
650		4	\|a Cu
650		4	\|a High capacity
650		4	\|a In situ XRD
650		4	\|a Storage mechanism
700	1		\|a Dong, Youzhong \|e verfasserin \|4 aut
700	1		\|a Jiang, Pan \|e verfasserin \|4 aut
700	1		\|a Zhao, Yanming \|e verfasserin \|4 aut
700	1		\|a Fan, Qinghua \|e verfasserin \|4 aut
700	1		\|a Kuan, Quan \|e verfasserin \|4 aut
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912			\|a GBV_ILN_187
912			\|a GBV_ILN_213
912			\|a GBV_ILN_224
912			\|a GBV_ILN_230
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912			\|a GBV_ILN_702
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912			\|a GBV_ILN_2015
912			\|a GBV_ILN_2020
912			\|a GBV_ILN_2021
912			\|a GBV_ILN_2025
912			\|a GBV_ILN_2026
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_2034
912			\|a GBV_ILN_2044
912			\|a GBV_ILN_2048
912			\|a GBV_ILN_2049
912			\|a GBV_ILN_2050
912			\|a GBV_ILN_2055
912			\|a GBV_ILN_2056
912			\|a GBV_ILN_2059
912			\|a GBV_ILN_2061
912			\|a GBV_ILN_2064
912			\|a GBV_ILN_2088
912			\|a GBV_ILN_2106
912			\|a GBV_ILN_2110
912			\|a GBV_ILN_2111
912			\|a GBV_ILN_2112
912			\|a GBV_ILN_2122
912			\|a GBV_ILN_2129
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912			\|a GBV_ILN_4251
912			\|a GBV_ILN_4305
912			\|a GBV_ILN_4306
912			\|a GBV_ILN_4307
912			\|a GBV_ILN_4313
912			\|a GBV_ILN_4322
912			\|a GBV_ILN_4323
912			\|a GBV_ILN_4324
912			\|a GBV_ILN_4325
912			\|a GBV_ILN_4326
912			\|a GBV_ILN_4333
912			\|a GBV_ILN_4334
912			\|a GBV_ILN_4338
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Indexfelder

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publishDate	2024
allfields	10.1016/j.ssi.2024.116455 doi (DE-627)ELV066667208 (ELSEVIER)S0167-2738(24)00003-1 DE-627 ger DE-627 rda eng 530 VZ 33.61 bkl Huang, Lai verfasserin aut Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries 2024 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The abundant sodium resources makes sodium ion batteries have the potential to be an alternative to lithium-ion batteries. Due to the large ionic radius of sodium ion, suitable cathode materials have a significant impact on the electrochemical performance of sodium ion batteries. Herein, Cu0.18V2O5•0.72H2O/ Ketjen black, a double modification strategy of groups (Cu2+/H2O) intercalation and Ketjen black composition materials was successfully synthesized. Copper ions and water molecules co-inserted into the V2O5 interlayer to increase its spacing, thus increasing the active sites of Na+ ions intercalation and deintercalation. Meanwhile, the interlayer groups serve as “pillars” to improve the structural stability of the material. Ketjen black not only reduces particle aggregation but also enhances electrical conductivity of the material. As the cathode of sodium-ion batteries, the combination of these factors allows the cathode to exhibit high reversible specific capacity (up to 155 mA h g−1 at 50 mA g−1) and superior cycle performance. The fast and highly reversible Na+-ion intercalation/deintercalation mechanism was revealed by in situ XRD. Sodium ion battery Cu High capacity In situ XRD Storage mechanism Dong, Youzhong verfasserin aut Jiang, Pan verfasserin aut Zhao, Yanming verfasserin aut Fan, Qinghua verfasserin aut Kuan, Quan verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 405 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:405 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.61 Festkörperphysik VZ AR 405
spelling	10.1016/j.ssi.2024.116455 doi (DE-627)ELV066667208 (ELSEVIER)S0167-2738(24)00003-1 DE-627 ger DE-627 rda eng 530 VZ 33.61 bkl Huang, Lai verfasserin aut Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries 2024 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The abundant sodium resources makes sodium ion batteries have the potential to be an alternative to lithium-ion batteries. Due to the large ionic radius of sodium ion, suitable cathode materials have a significant impact on the electrochemical performance of sodium ion batteries. Herein, Cu0.18V2O5•0.72H2O/ Ketjen black, a double modification strategy of groups (Cu2+/H2O) intercalation and Ketjen black composition materials was successfully synthesized. Copper ions and water molecules co-inserted into the V2O5 interlayer to increase its spacing, thus increasing the active sites of Na+ ions intercalation and deintercalation. Meanwhile, the interlayer groups serve as “pillars” to improve the structural stability of the material. Ketjen black not only reduces particle aggregation but also enhances electrical conductivity of the material. As the cathode of sodium-ion batteries, the combination of these factors allows the cathode to exhibit high reversible specific capacity (up to 155 mA h g−1 at 50 mA g−1) and superior cycle performance. The fast and highly reversible Na+-ion intercalation/deintercalation mechanism was revealed by in situ XRD. Sodium ion battery Cu High capacity In situ XRD Storage mechanism Dong, Youzhong verfasserin aut Jiang, Pan verfasserin aut Zhao, Yanming verfasserin aut Fan, Qinghua verfasserin aut Kuan, Quan verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 405 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:405 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.61 Festkörperphysik VZ AR 405
allfields_unstemmed	10.1016/j.ssi.2024.116455 doi (DE-627)ELV066667208 (ELSEVIER)S0167-2738(24)00003-1 DE-627 ger DE-627 rda eng 530 VZ 33.61 bkl Huang, Lai verfasserin aut Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries 2024 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The abundant sodium resources makes sodium ion batteries have the potential to be an alternative to lithium-ion batteries. Due to the large ionic radius of sodium ion, suitable cathode materials have a significant impact on the electrochemical performance of sodium ion batteries. Herein, Cu0.18V2O5•0.72H2O/ Ketjen black, a double modification strategy of groups (Cu2+/H2O) intercalation and Ketjen black composition materials was successfully synthesized. Copper ions and water molecules co-inserted into the V2O5 interlayer to increase its spacing, thus increasing the active sites of Na+ ions intercalation and deintercalation. Meanwhile, the interlayer groups serve as “pillars” to improve the structural stability of the material. Ketjen black not only reduces particle aggregation but also enhances electrical conductivity of the material. As the cathode of sodium-ion batteries, the combination of these factors allows the cathode to exhibit high reversible specific capacity (up to 155 mA h g−1 at 50 mA g−1) and superior cycle performance. The fast and highly reversible Na+-ion intercalation/deintercalation mechanism was revealed by in situ XRD. Sodium ion battery Cu High capacity In situ XRD Storage mechanism Dong, Youzhong verfasserin aut Jiang, Pan verfasserin aut Zhao, Yanming verfasserin aut Fan, Qinghua verfasserin aut Kuan, Quan verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 405 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:405 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.61 Festkörperphysik VZ AR 405
allfieldsGer	10.1016/j.ssi.2024.116455 doi (DE-627)ELV066667208 (ELSEVIER)S0167-2738(24)00003-1 DE-627 ger DE-627 rda eng 530 VZ 33.61 bkl Huang, Lai verfasserin aut Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries 2024 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The abundant sodium resources makes sodium ion batteries have the potential to be an alternative to lithium-ion batteries. Due to the large ionic radius of sodium ion, suitable cathode materials have a significant impact on the electrochemical performance of sodium ion batteries. Herein, Cu0.18V2O5•0.72H2O/ Ketjen black, a double modification strategy of groups (Cu2+/H2O) intercalation and Ketjen black composition materials was successfully synthesized. Copper ions and water molecules co-inserted into the V2O5 interlayer to increase its spacing, thus increasing the active sites of Na+ ions intercalation and deintercalation. Meanwhile, the interlayer groups serve as “pillars” to improve the structural stability of the material. Ketjen black not only reduces particle aggregation but also enhances electrical conductivity of the material. As the cathode of sodium-ion batteries, the combination of these factors allows the cathode to exhibit high reversible specific capacity (up to 155 mA h g−1 at 50 mA g−1) and superior cycle performance. The fast and highly reversible Na+-ion intercalation/deintercalation mechanism was revealed by in situ XRD. Sodium ion battery Cu High capacity In situ XRD Storage mechanism Dong, Youzhong verfasserin aut Jiang, Pan verfasserin aut Zhao, Yanming verfasserin aut Fan, Qinghua verfasserin aut Kuan, Quan verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 405 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:405 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.61 Festkörperphysik VZ AR 405
allfieldsSound	10.1016/j.ssi.2024.116455 doi (DE-627)ELV066667208 (ELSEVIER)S0167-2738(24)00003-1 DE-627 ger DE-627 rda eng 530 VZ 33.61 bkl Huang, Lai verfasserin aut Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries 2024 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The abundant sodium resources makes sodium ion batteries have the potential to be an alternative to lithium-ion batteries. Due to the large ionic radius of sodium ion, suitable cathode materials have a significant impact on the electrochemical performance of sodium ion batteries. Herein, Cu0.18V2O5•0.72H2O/ Ketjen black, a double modification strategy of groups (Cu2+/H2O) intercalation and Ketjen black composition materials was successfully synthesized. Copper ions and water molecules co-inserted into the V2O5 interlayer to increase its spacing, thus increasing the active sites of Na+ ions intercalation and deintercalation. Meanwhile, the interlayer groups serve as “pillars” to improve the structural stability of the material. Ketjen black not only reduces particle aggregation but also enhances electrical conductivity of the material. As the cathode of sodium-ion batteries, the combination of these factors allows the cathode to exhibit high reversible specific capacity (up to 155 mA h g−1 at 50 mA g−1) and superior cycle performance. The fast and highly reversible Na+-ion intercalation/deintercalation mechanism was revealed by in situ XRD. Sodium ion battery Cu High capacity In situ XRD Storage mechanism Dong, Youzhong verfasserin aut Jiang, Pan verfasserin aut Zhao, Yanming verfasserin aut Fan, Qinghua verfasserin aut Kuan, Quan verfasserin aut Enthalten in Solid state ionics Amsterdam [u.a.] : Elsevier Science, 1980 405 Online-Ressource (DE-627)306710544 (DE-600)1500750-9 (DE-576)25193814X 0167-2738 nnns volume:405 GBV_USEFLAG_U GBV_ELV SYSFLAG_U GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2088 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 33.61 Festkörperphysik VZ AR 405
language	English
source	Enthalten in Solid state ionics 405 volume:405
sourceStr	Enthalten in Solid state ionics 405 volume:405
format_phy_str_mv	Article
bklname	Festkörperphysik
institution	findex.gbv.de
topic_facet	Sodium ion battery Cu High capacity In situ XRD Storage mechanism
dewey-raw	530
isfreeaccess_bool	false
container_title	Solid state ionics
authorswithroles_txt_mv	Huang, Lai @@aut@@ Dong, Youzhong @@aut@@ Jiang, Pan @@aut@@ Zhao, Yanming @@aut@@ Fan, Qinghua @@aut@@ Kuan, Quan @@aut@@
publishDateDaySort_date	2024-01-01T00:00:00Z
hierarchy_top_id	306710544
dewey-sort	3530
id	ELV066667208
language_de	englisch
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author	Huang, Lai
spellingShingle	Huang, Lai ddc 530 bkl 33.61 misc Sodium ion battery misc Cu misc High capacity misc In situ XRD misc Storage mechanism Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries
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topic_title	530 VZ 33.61 bkl Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries Sodium ion battery Cu High capacity In situ XRD Storage mechanism
topic	ddc 530 bkl 33.61 misc Sodium ion battery misc Cu misc High capacity misc In situ XRD misc Storage mechanism
topic_unstemmed	ddc 530 bkl 33.61 misc Sodium ion battery misc Cu misc High capacity misc In situ XRD misc Storage mechanism
topic_browse	ddc 530 bkl 33.61 misc Sodium ion battery misc Cu misc High capacity misc In situ XRD misc Storage mechanism
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title	Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries
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title_full	Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries
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journal	Solid state ionics
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title_sort	flower-like cu 0.18 v 2 o 5 ·0.72h 2 o/ketjen black composite as high performance cathode material for sodium-ion batteries
title_auth	Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries
abstract	The abundant sodium resources makes sodium ion batteries have the potential to be an alternative to lithium-ion batteries. Due to the large ionic radius of sodium ion, suitable cathode materials have a significant impact on the electrochemical performance of sodium ion batteries. Herein, Cu0.18V2O5•0.72H2O/ Ketjen black, a double modification strategy of groups (Cu2+/H2O) intercalation and Ketjen black composition materials was successfully synthesized. Copper ions and water molecules co-inserted into the V2O5 interlayer to increase its spacing, thus increasing the active sites of Na+ ions intercalation and deintercalation. Meanwhile, the interlayer groups serve as “pillars” to improve the structural stability of the material. Ketjen black not only reduces particle aggregation but also enhances electrical conductivity of the material. As the cathode of sodium-ion batteries, the combination of these factors allows the cathode to exhibit high reversible specific capacity (up to 155 mA h g−1 at 50 mA g−1) and superior cycle performance. The fast and highly reversible Na+-ion intercalation/deintercalation mechanism was revealed by in situ XRD.
abstractGer	The abundant sodium resources makes sodium ion batteries have the potential to be an alternative to lithium-ion batteries. Due to the large ionic radius of sodium ion, suitable cathode materials have a significant impact on the electrochemical performance of sodium ion batteries. Herein, Cu0.18V2O5•0.72H2O/ Ketjen black, a double modification strategy of groups (Cu2+/H2O) intercalation and Ketjen black composition materials was successfully synthesized. Copper ions and water molecules co-inserted into the V2O5 interlayer to increase its spacing, thus increasing the active sites of Na+ ions intercalation and deintercalation. Meanwhile, the interlayer groups serve as “pillars” to improve the structural stability of the material. Ketjen black not only reduces particle aggregation but also enhances electrical conductivity of the material. As the cathode of sodium-ion batteries, the combination of these factors allows the cathode to exhibit high reversible specific capacity (up to 155 mA h g−1 at 50 mA g−1) and superior cycle performance. The fast and highly reversible Na+-ion intercalation/deintercalation mechanism was revealed by in situ XRD.
abstract_unstemmed	The abundant sodium resources makes sodium ion batteries have the potential to be an alternative to lithium-ion batteries. Due to the large ionic radius of sodium ion, suitable cathode materials have a significant impact on the electrochemical performance of sodium ion batteries. Herein, Cu0.18V2O5•0.72H2O/ Ketjen black, a double modification strategy of groups (Cu2+/H2O) intercalation and Ketjen black composition materials was successfully synthesized. Copper ions and water molecules co-inserted into the V2O5 interlayer to increase its spacing, thus increasing the active sites of Na+ ions intercalation and deintercalation. Meanwhile, the interlayer groups serve as “pillars” to improve the structural stability of the material. Ketjen black not only reduces particle aggregation but also enhances electrical conductivity of the material. As the cathode of sodium-ion batteries, the combination of these factors allows the cathode to exhibit high reversible specific capacity (up to 155 mA h g−1 at 50 mA g−1) and superior cycle performance. The fast and highly reversible Na+-ion intercalation/deintercalation mechanism was revealed by in situ XRD.
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title_short	Flower-like Cu 0.18 V 2 O 5 ·0.72H 2 O/Ketjen black composite as high performance cathode material for sodium-ion batteries
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author2	Dong, Youzhong Jiang, Pan Zhao, Yanming Fan, Qinghua Kuan, Quan
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doi_str	10.1016/j.ssi.2024.116455
up_date	2024-07-06T18:33:51.679Z
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