Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite
The separation of fluorite and calcite during flotation is challenging due to the complex interfacial forces that cause capping of fine-grained calcite on coarse-grained fluorite. In this paper, the micro flotation test, Zeta potential test, contact Angle test, scanning electron microscope and E-DLV...
Ausführliche Beschreibung
Autor*in: |
Guo, Shihai [verfasserIn] Kuang, Jingzhong [verfasserIn] Zhang, Shaoyan [verfasserIn] Huang, Zheyu [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2023 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Separation and purification technology - Amsterdam [u.a.] : Elsevier Science, 1997, 336 |
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Übergeordnetes Werk: |
volume:336 |
DOI / URN: |
10.1016/j.seppur.2023.126172 |
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Katalog-ID: |
ELV067106935 |
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520 | |a The separation of fluorite and calcite during flotation is challenging due to the complex interfacial forces that cause capping of fine-grained calcite on coarse-grained fluorite. In this paper, the micro flotation test, Zeta potential test, contact Angle test, scanning electron microscope and E-DLVO theoretical calculation were used to investigate the combination of sodium hexametaphosphate (SHMP) and calcium lignosulphonate (CLS) to disperse calcite on fluorite surface. The test results show that SHMP and CLS alone cannot effectively remove the cover, but the combination of the two can achieve good dispersion effect. In addition, Zeta potential shows that SHMP can significantly enhance the electrical properties of mineral surface, while CLS has a negligible effect on it. The contact Angle test proved that CLS adsorbed on the surface of mineral enhanced the hydrophilicity and hydration force of mineral. E-DLVO theoretical calculation further proves that CLS can not only enhance the hydration force between minerals, but also generate steric hindrance effect. When the distance between minerals is less than 1.8 nm, the steric hindrance force is greater than the repulsion force of hydration, and the steric hindrance force plays a dominant role. | ||
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650 | 4 | |a Calcium lignosulphonate | |
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700 | 1 | |a Kuang, Jingzhong |e verfasserin |4 aut | |
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700 | 1 | |a Huang, Zheyu |e verfasserin |4 aut | |
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2023 |
allfields |
10.1016/j.seppur.2023.126172 doi (DE-627)ELV067106935 (ELSEVIER)S1383-5866(23)03080-0 DE-627 ger DE-627 rda eng 540 VZ 58.11 bkl 58.13 bkl Guo, Shihai verfasserin aut Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The separation of fluorite and calcite during flotation is challenging due to the complex interfacial forces that cause capping of fine-grained calcite on coarse-grained fluorite. In this paper, the micro flotation test, Zeta potential test, contact Angle test, scanning electron microscope and E-DLVO theoretical calculation were used to investigate the combination of sodium hexametaphosphate (SHMP) and calcium lignosulphonate (CLS) to disperse calcite on fluorite surface. The test results show that SHMP and CLS alone cannot effectively remove the cover, but the combination of the two can achieve good dispersion effect. In addition, Zeta potential shows that SHMP can significantly enhance the electrical properties of mineral surface, while CLS has a negligible effect on it. The contact Angle test proved that CLS adsorbed on the surface of mineral enhanced the hydrophilicity and hydration force of mineral. E-DLVO theoretical calculation further proves that CLS can not only enhance the hydration force between minerals, but also generate steric hindrance effect. When the distance between minerals is less than 1.8 nm, the steric hindrance force is greater than the repulsion force of hydration, and the steric hindrance force plays a dominant role. Fluorite Calcite Cover Calcium lignosulphonate E-DLVO Kuang, Jingzhong verfasserin aut Zhang, Shaoyan verfasserin aut Huang, Zheyu verfasserin aut Enthalten in Separation and purification technology Amsterdam [u.a.] : Elsevier Science, 1997 336 Online-Ressource (DE-627)320620123 (DE-600)2022535-0 (DE-576)259485349 nnns volume:336 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.11 Mechanische Verfahrenstechnik VZ 58.13 Thermische Verfahrenstechnik VZ AR 336 |
spelling |
10.1016/j.seppur.2023.126172 doi (DE-627)ELV067106935 (ELSEVIER)S1383-5866(23)03080-0 DE-627 ger DE-627 rda eng 540 VZ 58.11 bkl 58.13 bkl Guo, Shihai verfasserin aut Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The separation of fluorite and calcite during flotation is challenging due to the complex interfacial forces that cause capping of fine-grained calcite on coarse-grained fluorite. In this paper, the micro flotation test, Zeta potential test, contact Angle test, scanning electron microscope and E-DLVO theoretical calculation were used to investigate the combination of sodium hexametaphosphate (SHMP) and calcium lignosulphonate (CLS) to disperse calcite on fluorite surface. The test results show that SHMP and CLS alone cannot effectively remove the cover, but the combination of the two can achieve good dispersion effect. In addition, Zeta potential shows that SHMP can significantly enhance the electrical properties of mineral surface, while CLS has a negligible effect on it. The contact Angle test proved that CLS adsorbed on the surface of mineral enhanced the hydrophilicity and hydration force of mineral. E-DLVO theoretical calculation further proves that CLS can not only enhance the hydration force between minerals, but also generate steric hindrance effect. When the distance between minerals is less than 1.8 nm, the steric hindrance force is greater than the repulsion force of hydration, and the steric hindrance force plays a dominant role. Fluorite Calcite Cover Calcium lignosulphonate E-DLVO Kuang, Jingzhong verfasserin aut Zhang, Shaoyan verfasserin aut Huang, Zheyu verfasserin aut Enthalten in Separation and purification technology Amsterdam [u.a.] : Elsevier Science, 1997 336 Online-Ressource (DE-627)320620123 (DE-600)2022535-0 (DE-576)259485349 nnns volume:336 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.11 Mechanische Verfahrenstechnik VZ 58.13 Thermische Verfahrenstechnik VZ AR 336 |
allfields_unstemmed |
10.1016/j.seppur.2023.126172 doi (DE-627)ELV067106935 (ELSEVIER)S1383-5866(23)03080-0 DE-627 ger DE-627 rda eng 540 VZ 58.11 bkl 58.13 bkl Guo, Shihai verfasserin aut Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The separation of fluorite and calcite during flotation is challenging due to the complex interfacial forces that cause capping of fine-grained calcite on coarse-grained fluorite. In this paper, the micro flotation test, Zeta potential test, contact Angle test, scanning electron microscope and E-DLVO theoretical calculation were used to investigate the combination of sodium hexametaphosphate (SHMP) and calcium lignosulphonate (CLS) to disperse calcite on fluorite surface. The test results show that SHMP and CLS alone cannot effectively remove the cover, but the combination of the two can achieve good dispersion effect. In addition, Zeta potential shows that SHMP can significantly enhance the electrical properties of mineral surface, while CLS has a negligible effect on it. The contact Angle test proved that CLS adsorbed on the surface of mineral enhanced the hydrophilicity and hydration force of mineral. E-DLVO theoretical calculation further proves that CLS can not only enhance the hydration force between minerals, but also generate steric hindrance effect. When the distance between minerals is less than 1.8 nm, the steric hindrance force is greater than the repulsion force of hydration, and the steric hindrance force plays a dominant role. Fluorite Calcite Cover Calcium lignosulphonate E-DLVO Kuang, Jingzhong verfasserin aut Zhang, Shaoyan verfasserin aut Huang, Zheyu verfasserin aut Enthalten in Separation and purification technology Amsterdam [u.a.] : Elsevier Science, 1997 336 Online-Ressource (DE-627)320620123 (DE-600)2022535-0 (DE-576)259485349 nnns volume:336 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.11 Mechanische Verfahrenstechnik VZ 58.13 Thermische Verfahrenstechnik VZ AR 336 |
allfieldsGer |
10.1016/j.seppur.2023.126172 doi (DE-627)ELV067106935 (ELSEVIER)S1383-5866(23)03080-0 DE-627 ger DE-627 rda eng 540 VZ 58.11 bkl 58.13 bkl Guo, Shihai verfasserin aut Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The separation of fluorite and calcite during flotation is challenging due to the complex interfacial forces that cause capping of fine-grained calcite on coarse-grained fluorite. In this paper, the micro flotation test, Zeta potential test, contact Angle test, scanning electron microscope and E-DLVO theoretical calculation were used to investigate the combination of sodium hexametaphosphate (SHMP) and calcium lignosulphonate (CLS) to disperse calcite on fluorite surface. The test results show that SHMP and CLS alone cannot effectively remove the cover, but the combination of the two can achieve good dispersion effect. In addition, Zeta potential shows that SHMP can significantly enhance the electrical properties of mineral surface, while CLS has a negligible effect on it. The contact Angle test proved that CLS adsorbed on the surface of mineral enhanced the hydrophilicity and hydration force of mineral. E-DLVO theoretical calculation further proves that CLS can not only enhance the hydration force between minerals, but also generate steric hindrance effect. When the distance between minerals is less than 1.8 nm, the steric hindrance force is greater than the repulsion force of hydration, and the steric hindrance force plays a dominant role. Fluorite Calcite Cover Calcium lignosulphonate E-DLVO Kuang, Jingzhong verfasserin aut Zhang, Shaoyan verfasserin aut Huang, Zheyu verfasserin aut Enthalten in Separation and purification technology Amsterdam [u.a.] : Elsevier Science, 1997 336 Online-Ressource (DE-627)320620123 (DE-600)2022535-0 (DE-576)259485349 nnns volume:336 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.11 Mechanische Verfahrenstechnik VZ 58.13 Thermische Verfahrenstechnik VZ AR 336 |
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10.1016/j.seppur.2023.126172 doi (DE-627)ELV067106935 (ELSEVIER)S1383-5866(23)03080-0 DE-627 ger DE-627 rda eng 540 VZ 58.11 bkl 58.13 bkl Guo, Shihai verfasserin aut Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite 2023 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The separation of fluorite and calcite during flotation is challenging due to the complex interfacial forces that cause capping of fine-grained calcite on coarse-grained fluorite. In this paper, the micro flotation test, Zeta potential test, contact Angle test, scanning electron microscope and E-DLVO theoretical calculation were used to investigate the combination of sodium hexametaphosphate (SHMP) and calcium lignosulphonate (CLS) to disperse calcite on fluorite surface. The test results show that SHMP and CLS alone cannot effectively remove the cover, but the combination of the two can achieve good dispersion effect. In addition, Zeta potential shows that SHMP can significantly enhance the electrical properties of mineral surface, while CLS has a negligible effect on it. The contact Angle test proved that CLS adsorbed on the surface of mineral enhanced the hydrophilicity and hydration force of mineral. E-DLVO theoretical calculation further proves that CLS can not only enhance the hydration force between minerals, but also generate steric hindrance effect. When the distance between minerals is less than 1.8 nm, the steric hindrance force is greater than the repulsion force of hydration, and the steric hindrance force plays a dominant role. Fluorite Calcite Cover Calcium lignosulphonate E-DLVO Kuang, Jingzhong verfasserin aut Zhang, Shaoyan verfasserin aut Huang, Zheyu verfasserin aut Enthalten in Separation and purification technology Amsterdam [u.a.] : Elsevier Science, 1997 336 Online-Ressource (DE-627)320620123 (DE-600)2022535-0 (DE-576)259485349 nnns volume:336 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OLC-PHA GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_101 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4325 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 58.11 Mechanische Verfahrenstechnik VZ 58.13 Thermische Verfahrenstechnik VZ AR 336 |
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540 VZ 58.11 bkl 58.13 bkl Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite Fluorite Calcite Cover Calcium lignosulphonate E-DLVO |
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Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite |
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Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite |
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Guo, Shihai |
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Guo, Shihai Kuang, Jingzhong Zhang, Shaoyan Huang, Zheyu |
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10.1016/j.seppur.2023.126172 |
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540 |
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effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite |
title_auth |
Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite |
abstract |
The separation of fluorite and calcite during flotation is challenging due to the complex interfacial forces that cause capping of fine-grained calcite on coarse-grained fluorite. In this paper, the micro flotation test, Zeta potential test, contact Angle test, scanning electron microscope and E-DLVO theoretical calculation were used to investigate the combination of sodium hexametaphosphate (SHMP) and calcium lignosulphonate (CLS) to disperse calcite on fluorite surface. The test results show that SHMP and CLS alone cannot effectively remove the cover, but the combination of the two can achieve good dispersion effect. In addition, Zeta potential shows that SHMP can significantly enhance the electrical properties of mineral surface, while CLS has a negligible effect on it. The contact Angle test proved that CLS adsorbed on the surface of mineral enhanced the hydrophilicity and hydration force of mineral. E-DLVO theoretical calculation further proves that CLS can not only enhance the hydration force between minerals, but also generate steric hindrance effect. When the distance between minerals is less than 1.8 nm, the steric hindrance force is greater than the repulsion force of hydration, and the steric hindrance force plays a dominant role. |
abstractGer |
The separation of fluorite and calcite during flotation is challenging due to the complex interfacial forces that cause capping of fine-grained calcite on coarse-grained fluorite. In this paper, the micro flotation test, Zeta potential test, contact Angle test, scanning electron microscope and E-DLVO theoretical calculation were used to investigate the combination of sodium hexametaphosphate (SHMP) and calcium lignosulphonate (CLS) to disperse calcite on fluorite surface. The test results show that SHMP and CLS alone cannot effectively remove the cover, but the combination of the two can achieve good dispersion effect. In addition, Zeta potential shows that SHMP can significantly enhance the electrical properties of mineral surface, while CLS has a negligible effect on it. The contact Angle test proved that CLS adsorbed on the surface of mineral enhanced the hydrophilicity and hydration force of mineral. E-DLVO theoretical calculation further proves that CLS can not only enhance the hydration force between minerals, but also generate steric hindrance effect. When the distance between minerals is less than 1.8 nm, the steric hindrance force is greater than the repulsion force of hydration, and the steric hindrance force plays a dominant role. |
abstract_unstemmed |
The separation of fluorite and calcite during flotation is challenging due to the complex interfacial forces that cause capping of fine-grained calcite on coarse-grained fluorite. In this paper, the micro flotation test, Zeta potential test, contact Angle test, scanning electron microscope and E-DLVO theoretical calculation were used to investigate the combination of sodium hexametaphosphate (SHMP) and calcium lignosulphonate (CLS) to disperse calcite on fluorite surface. The test results show that SHMP and CLS alone cannot effectively remove the cover, but the combination of the two can achieve good dispersion effect. In addition, Zeta potential shows that SHMP can significantly enhance the electrical properties of mineral surface, while CLS has a negligible effect on it. The contact Angle test proved that CLS adsorbed on the surface of mineral enhanced the hydrophilicity and hydration force of mineral. E-DLVO theoretical calculation further proves that CLS can not only enhance the hydration force between minerals, but also generate steric hindrance effect. When the distance between minerals is less than 1.8 nm, the steric hindrance force is greater than the repulsion force of hydration, and the steric hindrance force plays a dominant role. |
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title_short |
Effect of calcium lignosulfonate on the interaction forces between fine calcite and fluorite |
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