Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles
The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on th...
Ausführliche Beschreibung
Autor*in: |
Kocik, Emma M. [verfasserIn] Kim, Abigail [verfasserIn] Aiken, Miranda L. [verfasserIn] Smith, Lauren [verfasserIn] Kim, Christopher S. [verfasserIn] |
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2024 |
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Schlagwörter: |
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Übergeordnetes Werk: |
Enthalten in: Applied geochemistry - Amsterdam [u.a.] : Elsevier Science, 1986, 162 |
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Übergeordnetes Werk: |
volume:162 |
DOI / URN: |
10.1016/j.apgeochem.2024.105929 |
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Katalog-ID: |
ELV067167322 |
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245 | 1 | 0 | |a Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles |
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520 | |a The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on the adsorption and retention of Cu(II) and Zn(II) to synthetic iron oxyhydroxide nanoparticles (NPs) and their aggregates. Batch uptake experiments with monodisperse NPs and NPs aggregated by changes in pH, ionic strength, and temperature were conducted over sulfate concentrations ranging from 0 to 0.30 M. The introduction of 0.03 M sulfate significantly increased the initial adsorption and retention of Zn(II) and Cu(II) compared to sulfate-free conditions; with increasing sulfate >0.03 M, Zn(II) retention continuously increased, while Cu(II) retention was considerably more variable but increased slightly. NP aggregation, when induced by pH and ionic strength, was positively correlated with metal ion retention, while aggregation temperature was negatively correlated with both adsorption and retention. Aqueous geochemical modeling indicated that Zn(II) readily complexes with sulfate to form ZnSO4 (aq), but that stable aqueous CuSO4 species are uncommon. EXAFS spectroscopic analysis suggests structural incorporation of Zn(II) and Zn(II)-sulfate ternary surface complexation, while Cu(II) primarily forms inner-sphere bidentate surface complexes. Collectively, the effects of sulfate in both reducing surface charge repulsion, initiating ternary surface complexation, and enabling structural incorporation aid to enhance both metal adsorption and retention to iron oxyhydroxide NPs and their aggregates. | ||
650 | 4 | |a Iron oxyhydroxides | |
650 | 4 | |a Copper | |
650 | 4 | |a Zinc | |
650 | 4 | |a Sulfate | |
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650 | 4 | |a nanoparticles | |
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700 | 1 | |a Aiken, Miranda L. |e verfasserin |4 aut | |
700 | 1 | |a Smith, Lauren |e verfasserin |4 aut | |
700 | 1 | |a Kim, Christopher S. |e verfasserin |0 (orcid)0000-0001-5211-880X |4 aut | |
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10.1016/j.apgeochem.2024.105929 doi (DE-627)ELV067167322 (ELSEVIER)S0883-2927(24)00034-9 DE-627 ger DE-627 rda eng 550 VZ 38.32 bkl Kocik, Emma M. verfasserin aut Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles 2024 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on the adsorption and retention of Cu(II) and Zn(II) to synthetic iron oxyhydroxide nanoparticles (NPs) and their aggregates. Batch uptake experiments with monodisperse NPs and NPs aggregated by changes in pH, ionic strength, and temperature were conducted over sulfate concentrations ranging from 0 to 0.30 M. The introduction of 0.03 M sulfate significantly increased the initial adsorption and retention of Zn(II) and Cu(II) compared to sulfate-free conditions; with increasing sulfate >0.03 M, Zn(II) retention continuously increased, while Cu(II) retention was considerably more variable but increased slightly. NP aggregation, when induced by pH and ionic strength, was positively correlated with metal ion retention, while aggregation temperature was negatively correlated with both adsorption and retention. Aqueous geochemical modeling indicated that Zn(II) readily complexes with sulfate to form ZnSO4 (aq), but that stable aqueous CuSO4 species are uncommon. EXAFS spectroscopic analysis suggests structural incorporation of Zn(II) and Zn(II)-sulfate ternary surface complexation, while Cu(II) primarily forms inner-sphere bidentate surface complexes. Collectively, the effects of sulfate in both reducing surface charge repulsion, initiating ternary surface complexation, and enabling structural incorporation aid to enhance both metal adsorption and retention to iron oxyhydroxide NPs and their aggregates. Iron oxyhydroxides Copper Zinc Sulfate EXAFS nanoparticles Kim, Abigail verfasserin aut Aiken, Miranda L. verfasserin aut Smith, Lauren verfasserin aut Kim, Christopher S. verfasserin (orcid)0000-0001-5211-880X aut Enthalten in Applied geochemistry Amsterdam [u.a.] : Elsevier Science, 1986 162 Online-Ressource (DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X nnns volume:162 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.32 Geochemie VZ AR 162 |
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10.1016/j.apgeochem.2024.105929 doi (DE-627)ELV067167322 (ELSEVIER)S0883-2927(24)00034-9 DE-627 ger DE-627 rda eng 550 VZ 38.32 bkl Kocik, Emma M. verfasserin aut Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles 2024 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on the adsorption and retention of Cu(II) and Zn(II) to synthetic iron oxyhydroxide nanoparticles (NPs) and their aggregates. Batch uptake experiments with monodisperse NPs and NPs aggregated by changes in pH, ionic strength, and temperature were conducted over sulfate concentrations ranging from 0 to 0.30 M. The introduction of 0.03 M sulfate significantly increased the initial adsorption and retention of Zn(II) and Cu(II) compared to sulfate-free conditions; with increasing sulfate >0.03 M, Zn(II) retention continuously increased, while Cu(II) retention was considerably more variable but increased slightly. NP aggregation, when induced by pH and ionic strength, was positively correlated with metal ion retention, while aggregation temperature was negatively correlated with both adsorption and retention. Aqueous geochemical modeling indicated that Zn(II) readily complexes with sulfate to form ZnSO4 (aq), but that stable aqueous CuSO4 species are uncommon. EXAFS spectroscopic analysis suggests structural incorporation of Zn(II) and Zn(II)-sulfate ternary surface complexation, while Cu(II) primarily forms inner-sphere bidentate surface complexes. Collectively, the effects of sulfate in both reducing surface charge repulsion, initiating ternary surface complexation, and enabling structural incorporation aid to enhance both metal adsorption and retention to iron oxyhydroxide NPs and their aggregates. Iron oxyhydroxides Copper Zinc Sulfate EXAFS nanoparticles Kim, Abigail verfasserin aut Aiken, Miranda L. verfasserin aut Smith, Lauren verfasserin aut Kim, Christopher S. verfasserin (orcid)0000-0001-5211-880X aut Enthalten in Applied geochemistry Amsterdam [u.a.] : Elsevier Science, 1986 162 Online-Ressource (DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X nnns volume:162 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.32 Geochemie VZ AR 162 |
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10.1016/j.apgeochem.2024.105929 doi (DE-627)ELV067167322 (ELSEVIER)S0883-2927(24)00034-9 DE-627 ger DE-627 rda eng 550 VZ 38.32 bkl Kocik, Emma M. verfasserin aut Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles 2024 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on the adsorption and retention of Cu(II) and Zn(II) to synthetic iron oxyhydroxide nanoparticles (NPs) and their aggregates. Batch uptake experiments with monodisperse NPs and NPs aggregated by changes in pH, ionic strength, and temperature were conducted over sulfate concentrations ranging from 0 to 0.30 M. The introduction of 0.03 M sulfate significantly increased the initial adsorption and retention of Zn(II) and Cu(II) compared to sulfate-free conditions; with increasing sulfate >0.03 M, Zn(II) retention continuously increased, while Cu(II) retention was considerably more variable but increased slightly. NP aggregation, when induced by pH and ionic strength, was positively correlated with metal ion retention, while aggregation temperature was negatively correlated with both adsorption and retention. Aqueous geochemical modeling indicated that Zn(II) readily complexes with sulfate to form ZnSO4 (aq), but that stable aqueous CuSO4 species are uncommon. EXAFS spectroscopic analysis suggests structural incorporation of Zn(II) and Zn(II)-sulfate ternary surface complexation, while Cu(II) primarily forms inner-sphere bidentate surface complexes. Collectively, the effects of sulfate in both reducing surface charge repulsion, initiating ternary surface complexation, and enabling structural incorporation aid to enhance both metal adsorption and retention to iron oxyhydroxide NPs and their aggregates. Iron oxyhydroxides Copper Zinc Sulfate EXAFS nanoparticles Kim, Abigail verfasserin aut Aiken, Miranda L. verfasserin aut Smith, Lauren verfasserin aut Kim, Christopher S. verfasserin (orcid)0000-0001-5211-880X aut Enthalten in Applied geochemistry Amsterdam [u.a.] : Elsevier Science, 1986 162 Online-Ressource (DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X nnns volume:162 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.32 Geochemie VZ AR 162 |
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10.1016/j.apgeochem.2024.105929 doi (DE-627)ELV067167322 (ELSEVIER)S0883-2927(24)00034-9 DE-627 ger DE-627 rda eng 550 VZ 38.32 bkl Kocik, Emma M. verfasserin aut Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles 2024 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on the adsorption and retention of Cu(II) and Zn(II) to synthetic iron oxyhydroxide nanoparticles (NPs) and their aggregates. Batch uptake experiments with monodisperse NPs and NPs aggregated by changes in pH, ionic strength, and temperature were conducted over sulfate concentrations ranging from 0 to 0.30 M. The introduction of 0.03 M sulfate significantly increased the initial adsorption and retention of Zn(II) and Cu(II) compared to sulfate-free conditions; with increasing sulfate >0.03 M, Zn(II) retention continuously increased, while Cu(II) retention was considerably more variable but increased slightly. NP aggregation, when induced by pH and ionic strength, was positively correlated with metal ion retention, while aggregation temperature was negatively correlated with both adsorption and retention. Aqueous geochemical modeling indicated that Zn(II) readily complexes with sulfate to form ZnSO4 (aq), but that stable aqueous CuSO4 species are uncommon. EXAFS spectroscopic analysis suggests structural incorporation of Zn(II) and Zn(II)-sulfate ternary surface complexation, while Cu(II) primarily forms inner-sphere bidentate surface complexes. Collectively, the effects of sulfate in both reducing surface charge repulsion, initiating ternary surface complexation, and enabling structural incorporation aid to enhance both metal adsorption and retention to iron oxyhydroxide NPs and their aggregates. Iron oxyhydroxides Copper Zinc Sulfate EXAFS nanoparticles Kim, Abigail verfasserin aut Aiken, Miranda L. verfasserin aut Smith, Lauren verfasserin aut Kim, Christopher S. verfasserin (orcid)0000-0001-5211-880X aut Enthalten in Applied geochemistry Amsterdam [u.a.] : Elsevier Science, 1986 162 Online-Ressource (DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X nnns volume:162 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.32 Geochemie VZ AR 162 |
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10.1016/j.apgeochem.2024.105929 doi (DE-627)ELV067167322 (ELSEVIER)S0883-2927(24)00034-9 DE-627 ger DE-627 rda eng 550 VZ 38.32 bkl Kocik, Emma M. verfasserin aut Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles 2024 nicht spezifiziert zzz rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on the adsorption and retention of Cu(II) and Zn(II) to synthetic iron oxyhydroxide nanoparticles (NPs) and their aggregates. Batch uptake experiments with monodisperse NPs and NPs aggregated by changes in pH, ionic strength, and temperature were conducted over sulfate concentrations ranging from 0 to 0.30 M. The introduction of 0.03 M sulfate significantly increased the initial adsorption and retention of Zn(II) and Cu(II) compared to sulfate-free conditions; with increasing sulfate >0.03 M, Zn(II) retention continuously increased, while Cu(II) retention was considerably more variable but increased slightly. NP aggregation, when induced by pH and ionic strength, was positively correlated with metal ion retention, while aggregation temperature was negatively correlated with both adsorption and retention. Aqueous geochemical modeling indicated that Zn(II) readily complexes with sulfate to form ZnSO4 (aq), but that stable aqueous CuSO4 species are uncommon. EXAFS spectroscopic analysis suggests structural incorporation of Zn(II) and Zn(II)-sulfate ternary surface complexation, while Cu(II) primarily forms inner-sphere bidentate surface complexes. Collectively, the effects of sulfate in both reducing surface charge repulsion, initiating ternary surface complexation, and enabling structural incorporation aid to enhance both metal adsorption and retention to iron oxyhydroxide NPs and their aggregates. Iron oxyhydroxides Copper Zinc Sulfate EXAFS nanoparticles Kim, Abigail verfasserin aut Aiken, Miranda L. verfasserin aut Smith, Lauren verfasserin aut Kim, Christopher S. verfasserin (orcid)0000-0001-5211-880X aut Enthalten in Applied geochemistry Amsterdam [u.a.] : Elsevier Science, 1986 162 Online-Ressource (DE-627)306648091 (DE-600)1499242-5 (DE-576)08198426X nnns volume:162 GBV_USEFLAG_U GBV_ELV SYSFLAG_U SSG-OPC-GGO GBV_ILN_20 GBV_ILN_22 GBV_ILN_23 GBV_ILN_24 GBV_ILN_31 GBV_ILN_32 GBV_ILN_40 GBV_ILN_60 GBV_ILN_62 GBV_ILN_65 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_74 GBV_ILN_90 GBV_ILN_95 GBV_ILN_100 GBV_ILN_105 GBV_ILN_110 GBV_ILN_150 GBV_ILN_151 GBV_ILN_187 GBV_ILN_213 GBV_ILN_224 GBV_ILN_230 GBV_ILN_370 GBV_ILN_602 GBV_ILN_702 GBV_ILN_2001 GBV_ILN_2003 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2009 GBV_ILN_2010 GBV_ILN_2011 GBV_ILN_2014 GBV_ILN_2015 GBV_ILN_2020 GBV_ILN_2021 GBV_ILN_2025 GBV_ILN_2026 GBV_ILN_2027 GBV_ILN_2034 GBV_ILN_2044 GBV_ILN_2048 GBV_ILN_2049 GBV_ILN_2050 GBV_ILN_2055 GBV_ILN_2056 GBV_ILN_2059 GBV_ILN_2061 GBV_ILN_2064 GBV_ILN_2106 GBV_ILN_2110 GBV_ILN_2111 GBV_ILN_2112 GBV_ILN_2122 GBV_ILN_2129 GBV_ILN_2143 GBV_ILN_2152 GBV_ILN_2153 GBV_ILN_2190 GBV_ILN_2232 GBV_ILN_2336 GBV_ILN_2470 GBV_ILN_2507 GBV_ILN_4035 GBV_ILN_4037 GBV_ILN_4112 GBV_ILN_4125 GBV_ILN_4242 GBV_ILN_4249 GBV_ILN_4251 GBV_ILN_4305 GBV_ILN_4306 GBV_ILN_4307 GBV_ILN_4313 GBV_ILN_4322 GBV_ILN_4323 GBV_ILN_4324 GBV_ILN_4326 GBV_ILN_4333 GBV_ILN_4334 GBV_ILN_4338 GBV_ILN_4393 GBV_ILN_4700 38.32 Geochemie VZ AR 162 |
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Kocik, Emma M. ddc 550 bkl 38.32 misc Iron oxyhydroxides misc Copper misc Zinc misc Sulfate misc EXAFS misc nanoparticles Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles |
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550 VZ 38.32 bkl Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles Iron oxyhydroxides Copper Zinc Sulfate EXAFS nanoparticles |
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ddc 550 bkl 38.32 misc Iron oxyhydroxides misc Copper misc Zinc misc Sulfate misc EXAFS misc nanoparticles |
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Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles |
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(DE-627)ELV067167322 (ELSEVIER)S0883-2927(24)00034-9 |
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Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles |
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Kocik, Emma M. |
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Applied geochemistry |
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Kocik, Emma M. Kim, Abigail Aiken, Miranda L. Smith, Lauren Kim, Christopher S. |
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sulfate enhances the adsorption and retention of cu(ii) and zn(ii) to dispersed and aggregated iron oxyhydroxide nanoparticles |
title_auth |
Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles |
abstract |
The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on the adsorption and retention of Cu(II) and Zn(II) to synthetic iron oxyhydroxide nanoparticles (NPs) and their aggregates. Batch uptake experiments with monodisperse NPs and NPs aggregated by changes in pH, ionic strength, and temperature were conducted over sulfate concentrations ranging from 0 to 0.30 M. The introduction of 0.03 M sulfate significantly increased the initial adsorption and retention of Zn(II) and Cu(II) compared to sulfate-free conditions; with increasing sulfate >0.03 M, Zn(II) retention continuously increased, while Cu(II) retention was considerably more variable but increased slightly. NP aggregation, when induced by pH and ionic strength, was positively correlated with metal ion retention, while aggregation temperature was negatively correlated with both adsorption and retention. Aqueous geochemical modeling indicated that Zn(II) readily complexes with sulfate to form ZnSO4 (aq), but that stable aqueous CuSO4 species are uncommon. EXAFS spectroscopic analysis suggests structural incorporation of Zn(II) and Zn(II)-sulfate ternary surface complexation, while Cu(II) primarily forms inner-sphere bidentate surface complexes. Collectively, the effects of sulfate in both reducing surface charge repulsion, initiating ternary surface complexation, and enabling structural incorporation aid to enhance both metal adsorption and retention to iron oxyhydroxide NPs and their aggregates. |
abstractGer |
The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on the adsorption and retention of Cu(II) and Zn(II) to synthetic iron oxyhydroxide nanoparticles (NPs) and their aggregates. Batch uptake experiments with monodisperse NPs and NPs aggregated by changes in pH, ionic strength, and temperature were conducted over sulfate concentrations ranging from 0 to 0.30 M. The introduction of 0.03 M sulfate significantly increased the initial adsorption and retention of Zn(II) and Cu(II) compared to sulfate-free conditions; with increasing sulfate >0.03 M, Zn(II) retention continuously increased, while Cu(II) retention was considerably more variable but increased slightly. NP aggregation, when induced by pH and ionic strength, was positively correlated with metal ion retention, while aggregation temperature was negatively correlated with both adsorption and retention. Aqueous geochemical modeling indicated that Zn(II) readily complexes with sulfate to form ZnSO4 (aq), but that stable aqueous CuSO4 species are uncommon. EXAFS spectroscopic analysis suggests structural incorporation of Zn(II) and Zn(II)-sulfate ternary surface complexation, while Cu(II) primarily forms inner-sphere bidentate surface complexes. Collectively, the effects of sulfate in both reducing surface charge repulsion, initiating ternary surface complexation, and enabling structural incorporation aid to enhance both metal adsorption and retention to iron oxyhydroxide NPs and their aggregates. |
abstract_unstemmed |
The adsorption and retention of metal ions to nanoscale iron (hydr)oxides in aqueous systems is significantly influenced by prevailing environmental conditions. We examined the influence of sulfate, the second most common anion in seawater that is present in many other natural aquatic systems, on the adsorption and retention of Cu(II) and Zn(II) to synthetic iron oxyhydroxide nanoparticles (NPs) and their aggregates. Batch uptake experiments with monodisperse NPs and NPs aggregated by changes in pH, ionic strength, and temperature were conducted over sulfate concentrations ranging from 0 to 0.30 M. The introduction of 0.03 M sulfate significantly increased the initial adsorption and retention of Zn(II) and Cu(II) compared to sulfate-free conditions; with increasing sulfate >0.03 M, Zn(II) retention continuously increased, while Cu(II) retention was considerably more variable but increased slightly. NP aggregation, when induced by pH and ionic strength, was positively correlated with metal ion retention, while aggregation temperature was negatively correlated with both adsorption and retention. Aqueous geochemical modeling indicated that Zn(II) readily complexes with sulfate to form ZnSO4 (aq), but that stable aqueous CuSO4 species are uncommon. EXAFS spectroscopic analysis suggests structural incorporation of Zn(II) and Zn(II)-sulfate ternary surface complexation, while Cu(II) primarily forms inner-sphere bidentate surface complexes. Collectively, the effects of sulfate in both reducing surface charge repulsion, initiating ternary surface complexation, and enabling structural incorporation aid to enhance both metal adsorption and retention to iron oxyhydroxide NPs and their aggregates. |
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title_short |
Sulfate enhances the adsorption and retention of Cu(II) and Zn(II) to dispersed and aggregated iron oxyhydroxide nanoparticles |
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