UV-excited resonance Raman spectra of methyl orange and its complex with cetyltrimethylammonium bromide
Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1983 |
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| Umfang: |
4 Ill. 4 |
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| Reproduktion: |
Wiley InterScience Backfile Collection 1832-2000 |
|---|---|
| Übergeordnetes Werk: |
in: Journal of Raman Spectroscopy - Chichester [u.a.] : Wiley, 14(1983) vom: Feb., Seite 126-129 |
| Übergeordnetes Werk: |
volume:14 ; year:1983 ; month:02 ; pages:126-129 ; extent:4 |
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NLEJ159158001 |
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| 520 | |a Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as the absence, of the surfactant, the UV-excited resonance Raman spectrum of each isotope of methyl orange is appreciably different from the corresponding spectrum excited with the Ar+ 488.0 nm line. The UV-excited spectrum of the pure aqueous solution of the dye is attributed to the non-hydrated monomeric species of the dye anion responsible for the absorption band around 420 nm. The spectral pattern between 1500 and 1300 cm-1 of the mixed solution of the dye and the surfactant changes in two steps on increase of the surfactant concentration in accordance with the change of the absorption spectrum in the UV-visible region due to the formation of micelles. The UV-excited resonance Raman spectra of a cidic solutions of the isotopic methyl orange zwitterions were also meaured. By combining the data relating to the effect of pH and the concentration of the surfactant, the N—N stretching frequency in the Raman spectrum was shown to be correlated closely with the π-π* transition frequency in the absorption spectrum. | ||
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| 700 | 1 | |a Harada, Issei |4 oth | |
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(DE-627)NLEJ159158001 DE-627 ger DE-627 rakwb eng UV-excited resonance Raman spectra of methyl orange and its complex with cetyltrimethylammonium bromide 1983 4 Ill. 4 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as the absence, of the surfactant, the UV-excited resonance Raman spectrum of each isotope of methyl orange is appreciably different from the corresponding spectrum excited with the Ar+ 488.0 nm line. The UV-excited spectrum of the pure aqueous solution of the dye is attributed to the non-hydrated monomeric species of the dye anion responsible for the absorption band around 420 nm. The spectral pattern between 1500 and 1300 cm-1 of the mixed solution of the dye and the surfactant changes in two steps on increase of the surfactant concentration in accordance with the change of the absorption spectrum in the UV-visible region due to the formation of micelles. The UV-excited resonance Raman spectra of a cidic solutions of the isotopic methyl orange zwitterions were also meaured. By combining the data relating to the effect of pH and the concentration of the surfactant, the N—N stretching frequency in the Raman spectrum was shown to be correlated closely with the π-π* transition frequency in the absorption spectrum. Wiley InterScience Backfile Collection 1832-2000 Lee, Hohi oth Machida, Katsunosuke oth Kuwae, Akio oth Harada, Issei oth in Journal of Raman Spectroscopy Chichester [u.a.] : Wiley 14(1983) vom: Feb., Seite 126-129 (DE-627)NLEJ159070473 (DE-600)1481008-6 0377-0486 nnns volume:14 year:1983 month:02 pages:126-129 extent:4 http://dx.doi.org/10.1002/jrs.1250140213 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 14 1983 2 126-129 4 |
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(DE-627)NLEJ159158001 DE-627 ger DE-627 rakwb eng UV-excited resonance Raman spectra of methyl orange and its complex with cetyltrimethylammonium bromide 1983 4 Ill. 4 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as the absence, of the surfactant, the UV-excited resonance Raman spectrum of each isotope of methyl orange is appreciably different from the corresponding spectrum excited with the Ar+ 488.0 nm line. The UV-excited spectrum of the pure aqueous solution of the dye is attributed to the non-hydrated monomeric species of the dye anion responsible for the absorption band around 420 nm. The spectral pattern between 1500 and 1300 cm-1 of the mixed solution of the dye and the surfactant changes in two steps on increase of the surfactant concentration in accordance with the change of the absorption spectrum in the UV-visible region due to the formation of micelles. The UV-excited resonance Raman spectra of a cidic solutions of the isotopic methyl orange zwitterions were also meaured. By combining the data relating to the effect of pH and the concentration of the surfactant, the N—N stretching frequency in the Raman spectrum was shown to be correlated closely with the π-π* transition frequency in the absorption spectrum. Wiley InterScience Backfile Collection 1832-2000 Lee, Hohi oth Machida, Katsunosuke oth Kuwae, Akio oth Harada, Issei oth in Journal of Raman Spectroscopy Chichester [u.a.] : Wiley 14(1983) vom: Feb., Seite 126-129 (DE-627)NLEJ159070473 (DE-600)1481008-6 0377-0486 nnns volume:14 year:1983 month:02 pages:126-129 extent:4 http://dx.doi.org/10.1002/jrs.1250140213 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 14 1983 2 126-129 4 |
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(DE-627)NLEJ159158001 DE-627 ger DE-627 rakwb eng UV-excited resonance Raman spectra of methyl orange and its complex with cetyltrimethylammonium bromide 1983 4 Ill. 4 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as the absence, of the surfactant, the UV-excited resonance Raman spectrum of each isotope of methyl orange is appreciably different from the corresponding spectrum excited with the Ar+ 488.0 nm line. The UV-excited spectrum of the pure aqueous solution of the dye is attributed to the non-hydrated monomeric species of the dye anion responsible for the absorption band around 420 nm. The spectral pattern between 1500 and 1300 cm-1 of the mixed solution of the dye and the surfactant changes in two steps on increase of the surfactant concentration in accordance with the change of the absorption spectrum in the UV-visible region due to the formation of micelles. The UV-excited resonance Raman spectra of a cidic solutions of the isotopic methyl orange zwitterions were also meaured. By combining the data relating to the effect of pH and the concentration of the surfactant, the N—N stretching frequency in the Raman spectrum was shown to be correlated closely with the π-π* transition frequency in the absorption spectrum. Wiley InterScience Backfile Collection 1832-2000 Lee, Hohi oth Machida, Katsunosuke oth Kuwae, Akio oth Harada, Issei oth in Journal of Raman Spectroscopy Chichester [u.a.] : Wiley 14(1983) vom: Feb., Seite 126-129 (DE-627)NLEJ159070473 (DE-600)1481008-6 0377-0486 nnns volume:14 year:1983 month:02 pages:126-129 extent:4 http://dx.doi.org/10.1002/jrs.1250140213 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 14 1983 2 126-129 4 |
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(DE-627)NLEJ159158001 DE-627 ger DE-627 rakwb eng UV-excited resonance Raman spectra of methyl orange and its complex with cetyltrimethylammonium bromide 1983 4 Ill. 4 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as the absence, of the surfactant, the UV-excited resonance Raman spectrum of each isotope of methyl orange is appreciably different from the corresponding spectrum excited with the Ar+ 488.0 nm line. The UV-excited spectrum of the pure aqueous solution of the dye is attributed to the non-hydrated monomeric species of the dye anion responsible for the absorption band around 420 nm. The spectral pattern between 1500 and 1300 cm-1 of the mixed solution of the dye and the surfactant changes in two steps on increase of the surfactant concentration in accordance with the change of the absorption spectrum in the UV-visible region due to the formation of micelles. The UV-excited resonance Raman spectra of a cidic solutions of the isotopic methyl orange zwitterions were also meaured. By combining the data relating to the effect of pH and the concentration of the surfactant, the N—N stretching frequency in the Raman spectrum was shown to be correlated closely with the π-π* transition frequency in the absorption spectrum. Wiley InterScience Backfile Collection 1832-2000 Lee, Hohi oth Machida, Katsunosuke oth Kuwae, Akio oth Harada, Issei oth in Journal of Raman Spectroscopy Chichester [u.a.] : Wiley 14(1983) vom: Feb., Seite 126-129 (DE-627)NLEJ159070473 (DE-600)1481008-6 0377-0486 nnns volume:14 year:1983 month:02 pages:126-129 extent:4 http://dx.doi.org/10.1002/jrs.1250140213 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 14 1983 2 126-129 4 |
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(DE-627)NLEJ159158001 DE-627 ger DE-627 rakwb eng UV-excited resonance Raman spectra of methyl orange and its complex with cetyltrimethylammonium bromide 1983 4 Ill. 4 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as the absence, of the surfactant, the UV-excited resonance Raman spectrum of each isotope of methyl orange is appreciably different from the corresponding spectrum excited with the Ar+ 488.0 nm line. The UV-excited spectrum of the pure aqueous solution of the dye is attributed to the non-hydrated monomeric species of the dye anion responsible for the absorption band around 420 nm. The spectral pattern between 1500 and 1300 cm-1 of the mixed solution of the dye and the surfactant changes in two steps on increase of the surfactant concentration in accordance with the change of the absorption spectrum in the UV-visible region due to the formation of micelles. The UV-excited resonance Raman spectra of a cidic solutions of the isotopic methyl orange zwitterions were also meaured. By combining the data relating to the effect of pH and the concentration of the surfactant, the N—N stretching frequency in the Raman spectrum was shown to be correlated closely with the π-π* transition frequency in the absorption spectrum. Wiley InterScience Backfile Collection 1832-2000 Lee, Hohi oth Machida, Katsunosuke oth Kuwae, Akio oth Harada, Issei oth in Journal of Raman Spectroscopy Chichester [u.a.] : Wiley 14(1983) vom: Feb., Seite 126-129 (DE-627)NLEJ159070473 (DE-600)1481008-6 0377-0486 nnns volume:14 year:1983 month:02 pages:126-129 extent:4 http://dx.doi.org/10.1002/jrs.1250140213 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 14 1983 2 126-129 4 |
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uv-excited resonance raman spectra of methyl orange and its complex with cetyltrimethylammonium bromide |
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UV-excited resonance Raman spectra of methyl orange and its complex with cetyltrimethylammonium bromide |
| abstract |
Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as the absence, of the surfactant, the UV-excited resonance Raman spectrum of each isotope of methyl orange is appreciably different from the corresponding spectrum excited with the Ar+ 488.0 nm line. The UV-excited spectrum of the pure aqueous solution of the dye is attributed to the non-hydrated monomeric species of the dye anion responsible for the absorption band around 420 nm. The spectral pattern between 1500 and 1300 cm-1 of the mixed solution of the dye and the surfactant changes in two steps on increase of the surfactant concentration in accordance with the change of the absorption spectrum in the UV-visible region due to the formation of micelles. The UV-excited resonance Raman spectra of a cidic solutions of the isotopic methyl orange zwitterions were also meaured. By combining the data relating to the effect of pH and the concentration of the surfactant, the N—N stretching frequency in the Raman spectrum was shown to be correlated closely with the π-π* transition frequency in the absorption spectrum. |
| abstractGer |
Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as the absence, of the surfactant, the UV-excited resonance Raman spectrum of each isotope of methyl orange is appreciably different from the corresponding spectrum excited with the Ar+ 488.0 nm line. The UV-excited spectrum of the pure aqueous solution of the dye is attributed to the non-hydrated monomeric species of the dye anion responsible for the absorption band around 420 nm. The spectral pattern between 1500 and 1300 cm-1 of the mixed solution of the dye and the surfactant changes in two steps on increase of the surfactant concentration in accordance with the change of the absorption spectrum in the UV-visible region due to the formation of micelles. The UV-excited resonance Raman spectra of a cidic solutions of the isotopic methyl orange zwitterions were also meaured. By combining the data relating to the effect of pH and the concentration of the surfactant, the N—N stretching frequency in the Raman spectrum was shown to be correlated closely with the π-π* transition frequency in the absorption spectrum. |
| abstract_unstemmed |
Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as the absence, of the surfactant, the UV-excited resonance Raman spectrum of each isotope of methyl orange is appreciably different from the corresponding spectrum excited with the Ar+ 488.0 nm line. The UV-excited spectrum of the pure aqueous solution of the dye is attributed to the non-hydrated monomeric species of the dye anion responsible for the absorption band around 420 nm. The spectral pattern between 1500 and 1300 cm-1 of the mixed solution of the dye and the surfactant changes in two steps on increase of the surfactant concentration in accordance with the change of the absorption spectrum in the UV-visible region due to the formation of micelles. The UV-excited resonance Raman spectra of a cidic solutions of the isotopic methyl orange zwitterions were also meaured. By combining the data relating to the effect of pH and the concentration of the surfactant, the N—N stretching frequency in the Raman spectrum was shown to be correlated closely with the π-π* transition frequency in the absorption spectrum. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ159158001</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20210707001119.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070201s1983 xx |||||o 00| ||eng c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ159158001</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">UV-excited resonance Raman spectra of methyl orange and its complex with cetyltrimethylammonium bromide</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1983</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="b">4 Ill.</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">4</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Resonance Raman spectra of methyl organge and its ring-deuterated and 15N-azo derivatives were measured with the excitation line at 350.7 nm of a Kr+ laser, and the spectral changes on the complex formation between the dye and cetyltrimethylammonium bromide were studied. In the presence, as well as the absence, of the surfactant, the UV-excited resonance Raman spectrum of each isotope of methyl orange is appreciably different from the corresponding spectrum excited with the Ar+ 488.0 nm line. The UV-excited spectrum of the pure aqueous solution of the dye is attributed to the non-hydrated monomeric species of the dye anion responsible for the absorption band around 420 nm. The spectral pattern between 1500 and 1300 cm-1 of the mixed solution of the dye and the surfactant changes in two steps on increase of the surfactant concentration in accordance with the change of the absorption spectrum in the UV-visible region due to the formation of micelles. The UV-excited resonance Raman spectra of a cidic solutions of the isotopic methyl orange zwitterions were also meaured. By combining the data relating to the effect of pH and the concentration of the surfactant, the N—N stretching frequency in the Raman spectrum was shown to be correlated closely with the π-π* transition frequency in the absorption spectrum.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Wiley InterScience Backfile Collection 1832-2000</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lee, Hohi</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Machida, Katsunosuke</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kuwae, Akio</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Harada, Issei</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Journal of Raman Spectroscopy</subfield><subfield code="d">Chichester [u.a.] : Wiley</subfield><subfield code="g">14(1983) vom: Feb., Seite 126-129</subfield><subfield code="w">(DE-627)NLEJ159070473</subfield><subfield code="w">(DE-600)1481008-6</subfield><subfield code="x">0377-0486</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:14</subfield><subfield code="g">year:1983</subfield><subfield code="g">month:02</subfield><subfield code="g">pages:126-129</subfield><subfield code="g">extent:4</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://dx.doi.org/10.1002/jrs.1250140213</subfield><subfield code="q">text/html</subfield><subfield code="z">Deutschlandweit zugänglich</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-WIS</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">14</subfield><subfield code="j">1983</subfield><subfield code="c">2</subfield><subfield code="h">126-129</subfield><subfield code="g">4</subfield></datafield></record></collection>
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7.3990326 |