Oxidation reactions in triterpenes under chemical ionization conditionsCDRI Communication No. 3706.
From a collisional activation spectral study it has been found that certain triterpene alcohols with an ursane or oleanane skeleton undergo oxidation to the corresponding ketones under chemical ionization (NH3) conditions giving rise to abundant [M + NH4 — 2]+ ions. Mass-analysed ion kinetic energy...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1986 |
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| Umfang: |
1 Ill. ; 3 Tab. 5 |
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| Reproduktion: |
Wiley InterScience Backfile Collection 1832-2000 |
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| Übergeordnetes Werk: |
in: Biological Mass Spectrometry - Chichester : Wiley Subscription Services, Inc., A Wiley Company, 21(1986) vom: März, Seite 131-135 |
| Übergeordnetes Werk: |
volume:21 ; year:1986 ; month:03 ; pages:131-135 ; extent:5 |
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| 520 | |a From a collisional activation spectral study it has been found that certain triterpene alcohols with an ursane or oleanane skeleton undergo oxidation to the corresponding ketones under chemical ionization (NH3) conditions giving rise to abundant [M + NH4 — 2]+ ions. Mass-analysed ion kinetic energy and B2/E scan results indicate that both [M + NH4]+ and [M + N2H7 — 2]+ ions contribute to the formation of the [M + NH4 — 2]+ ion. | ||
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(DE-627)NLEJ159274087 DE-627 ger DE-627 rakwb eng Oxidation reactions in triterpenes under chemical ionization conditionsCDRI Communication No. 3706. 1986 1 Ill. 3 Tab. 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier From a collisional activation spectral study it has been found that certain triterpene alcohols with an ursane or oleanane skeleton undergo oxidation to the corresponding ketones under chemical ionization (NH3) conditions giving rise to abundant [M + NH4 — 2]+ ions. Mass-analysed ion kinetic energy and B2/E scan results indicate that both [M + NH4]+ and [M + N2H7 — 2]+ ions contribute to the formation of the [M + NH4 — 2]+ ion. Wiley InterScience Backfile Collection 1832-2000 Madhusudanan, K. P. oth Singh, Chandan oth Fraisse, D. oth in Biological Mass Spectrometry Chichester : Wiley Subscription Services, Inc., A Wiley Company 21(1986) vom: März, Seite 131-135 (DE-627)NLEJ159070465 (DE-600)2197367-2 0306-042X nnns volume:21 year:1986 month:03 pages:131-135 extent:5 http://dx.doi.org/10.1002/oms.1210210307 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 21 1986 3 131-135 5 |
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(DE-627)NLEJ159274087 DE-627 ger DE-627 rakwb eng Oxidation reactions in triterpenes under chemical ionization conditionsCDRI Communication No. 3706. 1986 1 Ill. 3 Tab. 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier From a collisional activation spectral study it has been found that certain triterpene alcohols with an ursane or oleanane skeleton undergo oxidation to the corresponding ketones under chemical ionization (NH3) conditions giving rise to abundant [M + NH4 — 2]+ ions. Mass-analysed ion kinetic energy and B2/E scan results indicate that both [M + NH4]+ and [M + N2H7 — 2]+ ions contribute to the formation of the [M + NH4 — 2]+ ion. Wiley InterScience Backfile Collection 1832-2000 Madhusudanan, K. P. oth Singh, Chandan oth Fraisse, D. oth in Biological Mass Spectrometry Chichester : Wiley Subscription Services, Inc., A Wiley Company 21(1986) vom: März, Seite 131-135 (DE-627)NLEJ159070465 (DE-600)2197367-2 0306-042X nnns volume:21 year:1986 month:03 pages:131-135 extent:5 http://dx.doi.org/10.1002/oms.1210210307 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 21 1986 3 131-135 5 |
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(DE-627)NLEJ159274087 DE-627 ger DE-627 rakwb eng Oxidation reactions in triterpenes under chemical ionization conditionsCDRI Communication No. 3706. 1986 1 Ill. 3 Tab. 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier From a collisional activation spectral study it has been found that certain triterpene alcohols with an ursane or oleanane skeleton undergo oxidation to the corresponding ketones under chemical ionization (NH3) conditions giving rise to abundant [M + NH4 — 2]+ ions. Mass-analysed ion kinetic energy and B2/E scan results indicate that both [M + NH4]+ and [M + N2H7 — 2]+ ions contribute to the formation of the [M + NH4 — 2]+ ion. Wiley InterScience Backfile Collection 1832-2000 Madhusudanan, K. P. oth Singh, Chandan oth Fraisse, D. oth in Biological Mass Spectrometry Chichester : Wiley Subscription Services, Inc., A Wiley Company 21(1986) vom: März, Seite 131-135 (DE-627)NLEJ159070465 (DE-600)2197367-2 0306-042X nnns volume:21 year:1986 month:03 pages:131-135 extent:5 http://dx.doi.org/10.1002/oms.1210210307 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 21 1986 3 131-135 5 |
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(DE-627)NLEJ159274087 DE-627 ger DE-627 rakwb eng Oxidation reactions in triterpenes under chemical ionization conditionsCDRI Communication No. 3706. 1986 1 Ill. 3 Tab. 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier From a collisional activation spectral study it has been found that certain triterpene alcohols with an ursane or oleanane skeleton undergo oxidation to the corresponding ketones under chemical ionization (NH3) conditions giving rise to abundant [M + NH4 — 2]+ ions. Mass-analysed ion kinetic energy and B2/E scan results indicate that both [M + NH4]+ and [M + N2H7 — 2]+ ions contribute to the formation of the [M + NH4 — 2]+ ion. Wiley InterScience Backfile Collection 1832-2000 Madhusudanan, K. P. oth Singh, Chandan oth Fraisse, D. oth in Biological Mass Spectrometry Chichester : Wiley Subscription Services, Inc., A Wiley Company 21(1986) vom: März, Seite 131-135 (DE-627)NLEJ159070465 (DE-600)2197367-2 0306-042X nnns volume:21 year:1986 month:03 pages:131-135 extent:5 http://dx.doi.org/10.1002/oms.1210210307 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 21 1986 3 131-135 5 |
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(DE-627)NLEJ159274087 DE-627 ger DE-627 rakwb eng Oxidation reactions in triterpenes under chemical ionization conditionsCDRI Communication No. 3706. 1986 1 Ill. 3 Tab. 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier From a collisional activation spectral study it has been found that certain triterpene alcohols with an ursane or oleanane skeleton undergo oxidation to the corresponding ketones under chemical ionization (NH3) conditions giving rise to abundant [M + NH4 — 2]+ ions. Mass-analysed ion kinetic energy and B2/E scan results indicate that both [M + NH4]+ and [M + N2H7 — 2]+ ions contribute to the formation of the [M + NH4 — 2]+ ion. Wiley InterScience Backfile Collection 1832-2000 Madhusudanan, K. P. oth Singh, Chandan oth Fraisse, D. oth in Biological Mass Spectrometry Chichester : Wiley Subscription Services, Inc., A Wiley Company 21(1986) vom: März, Seite 131-135 (DE-627)NLEJ159070465 (DE-600)2197367-2 0306-042X nnns volume:21 year:1986 month:03 pages:131-135 extent:5 http://dx.doi.org/10.1002/oms.1210210307 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 21 1986 3 131-135 5 |
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oxidation reactions in triterpenes under chemical ionization conditionscdri communication no. 3706 |
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Oxidation reactions in triterpenes under chemical ionization conditionsCDRI Communication No. 3706. |
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From a collisional activation spectral study it has been found that certain triterpene alcohols with an ursane or oleanane skeleton undergo oxidation to the corresponding ketones under chemical ionization (NH3) conditions giving rise to abundant [M + NH4 — 2]+ ions. Mass-analysed ion kinetic energy and B2/E scan results indicate that both [M + NH4]+ and [M + N2H7 — 2]+ ions contribute to the formation of the [M + NH4 — 2]+ ion. |
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From a collisional activation spectral study it has been found that certain triterpene alcohols with an ursane or oleanane skeleton undergo oxidation to the corresponding ketones under chemical ionization (NH3) conditions giving rise to abundant [M + NH4 — 2]+ ions. Mass-analysed ion kinetic energy and B2/E scan results indicate that both [M + NH4]+ and [M + N2H7 — 2]+ ions contribute to the formation of the [M + NH4 — 2]+ ion. |
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From a collisional activation spectral study it has been found that certain triterpene alcohols with an ursane or oleanane skeleton undergo oxidation to the corresponding ketones under chemical ionization (NH3) conditions giving rise to abundant [M + NH4 — 2]+ ions. Mass-analysed ion kinetic energy and B2/E scan results indicate that both [M + NH4]+ and [M + N2H7 — 2]+ ions contribute to the formation of the [M + NH4 — 2]+ ion. |
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