Kinetics of addition of acetic acid to epichlorohydrin in the presence of DMF or DMSO
The kinetics of reaction between acetic acid and epichlorohydrin carried out in the presence of DMF or DMSO was studied. In addition, the conductivity of the reaction mixture was measured. The conductivity was found to increase considerably as the reaction proceeded. This was explained in terms of t...
Ausführliche Beschreibung
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E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
1995 |
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Umfang: |
4 Ill. ; 4 Tab. 5 |
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Reproduktion: |
Wiley InterScience Backfile Collection 1832-2000 |
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Übergeordnetes Werk: |
in: Journal of Chemical Technology AND Biotechnology - Chichester : Wiley, 63(1995) vom: Apr., Seite 379-383 |
Übergeordnetes Werk: |
volume:63 ; year:1995 ; month:04 ; pages:379-383 ; extent:5 |
Links: |
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NLEJ159412749 |
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520 | |a The kinetics of reaction between acetic acid and epichlorohydrin carried out in the presence of DMF or DMSO was studied. In addition, the conductivity of the reaction mixture was measured. The conductivity was found to increase considerably as the reaction proceeded. This was explained in terms of the formation of new effective forms of catalysts: the ammonium salt (in case of DMF) or sulphonium salt (for DMSO). A reaction scheme has been proposed, taking into account the active catalyst forms. The set of kinetic equations describing the reaction has been developed and the appropriate rate constants evaluated. | ||
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700 | 1 | |a Svets, Valery F. |4 oth | |
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(DE-627)NLEJ159412749 DE-627 ger DE-627 rakwb eng Kinetics of addition of acetic acid to epichlorohydrin in the presence of DMF or DMSO 1995 4 Ill. 4 Tab. 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The kinetics of reaction between acetic acid and epichlorohydrin carried out in the presence of DMF or DMSO was studied. In addition, the conductivity of the reaction mixture was measured. The conductivity was found to increase considerably as the reaction proceeded. This was explained in terms of the formation of new effective forms of catalysts: the ammonium salt (in case of DMF) or sulphonium salt (for DMSO). A reaction scheme has been proposed, taking into account the active catalyst forms. The set of kinetic equations describing the reaction has been developed and the appropriate rate constants evaluated. Wiley InterScience Backfile Collection 1832-2000 Bukowska, Agnieszka oth Guskov, Andrei K. oth Makarov, Mikhail G. oth Rokaszewski, Edward oth Svets, Valery F. oth in Journal of Chemical Technology AND Biotechnology Chichester : Wiley 63(1995) vom: Apr., Seite 379-383 (DE-627)NLEJ159070589 (DE-600)1479465-2 0268-2575 nnns volume:63 year:1995 month:04 pages:379-383 extent:5 http://dx.doi.org/10.1002/jctb.280630412 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 63 1995 4 379-383 5 |
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(DE-627)NLEJ159412749 DE-627 ger DE-627 rakwb eng Kinetics of addition of acetic acid to epichlorohydrin in the presence of DMF or DMSO 1995 4 Ill. 4 Tab. 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The kinetics of reaction between acetic acid and epichlorohydrin carried out in the presence of DMF or DMSO was studied. In addition, the conductivity of the reaction mixture was measured. The conductivity was found to increase considerably as the reaction proceeded. This was explained in terms of the formation of new effective forms of catalysts: the ammonium salt (in case of DMF) or sulphonium salt (for DMSO). A reaction scheme has been proposed, taking into account the active catalyst forms. The set of kinetic equations describing the reaction has been developed and the appropriate rate constants evaluated. Wiley InterScience Backfile Collection 1832-2000 Bukowska, Agnieszka oth Guskov, Andrei K. oth Makarov, Mikhail G. oth Rokaszewski, Edward oth Svets, Valery F. oth in Journal of Chemical Technology AND Biotechnology Chichester : Wiley 63(1995) vom: Apr., Seite 379-383 (DE-627)NLEJ159070589 (DE-600)1479465-2 0268-2575 nnns volume:63 year:1995 month:04 pages:379-383 extent:5 http://dx.doi.org/10.1002/jctb.280630412 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 63 1995 4 379-383 5 |
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(DE-627)NLEJ159412749 DE-627 ger DE-627 rakwb eng Kinetics of addition of acetic acid to epichlorohydrin in the presence of DMF or DMSO 1995 4 Ill. 4 Tab. 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The kinetics of reaction between acetic acid and epichlorohydrin carried out in the presence of DMF or DMSO was studied. In addition, the conductivity of the reaction mixture was measured. The conductivity was found to increase considerably as the reaction proceeded. This was explained in terms of the formation of new effective forms of catalysts: the ammonium salt (in case of DMF) or sulphonium salt (for DMSO). A reaction scheme has been proposed, taking into account the active catalyst forms. The set of kinetic equations describing the reaction has been developed and the appropriate rate constants evaluated. Wiley InterScience Backfile Collection 1832-2000 Bukowska, Agnieszka oth Guskov, Andrei K. oth Makarov, Mikhail G. oth Rokaszewski, Edward oth Svets, Valery F. oth in Journal of Chemical Technology AND Biotechnology Chichester : Wiley 63(1995) vom: Apr., Seite 379-383 (DE-627)NLEJ159070589 (DE-600)1479465-2 0268-2575 nnns volume:63 year:1995 month:04 pages:379-383 extent:5 http://dx.doi.org/10.1002/jctb.280630412 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 63 1995 4 379-383 5 |
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(DE-627)NLEJ159412749 DE-627 ger DE-627 rakwb eng Kinetics of addition of acetic acid to epichlorohydrin in the presence of DMF or DMSO 1995 4 Ill. 4 Tab. 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The kinetics of reaction between acetic acid and epichlorohydrin carried out in the presence of DMF or DMSO was studied. In addition, the conductivity of the reaction mixture was measured. The conductivity was found to increase considerably as the reaction proceeded. This was explained in terms of the formation of new effective forms of catalysts: the ammonium salt (in case of DMF) or sulphonium salt (for DMSO). A reaction scheme has been proposed, taking into account the active catalyst forms. The set of kinetic equations describing the reaction has been developed and the appropriate rate constants evaluated. Wiley InterScience Backfile Collection 1832-2000 Bukowska, Agnieszka oth Guskov, Andrei K. oth Makarov, Mikhail G. oth Rokaszewski, Edward oth Svets, Valery F. oth in Journal of Chemical Technology AND Biotechnology Chichester : Wiley 63(1995) vom: Apr., Seite 379-383 (DE-627)NLEJ159070589 (DE-600)1479465-2 0268-2575 nnns volume:63 year:1995 month:04 pages:379-383 extent:5 http://dx.doi.org/10.1002/jctb.280630412 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 63 1995 4 379-383 5 |
allfieldsSound |
(DE-627)NLEJ159412749 DE-627 ger DE-627 rakwb eng Kinetics of addition of acetic acid to epichlorohydrin in the presence of DMF or DMSO 1995 4 Ill. 4 Tab. 5 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The kinetics of reaction between acetic acid and epichlorohydrin carried out in the presence of DMF or DMSO was studied. In addition, the conductivity of the reaction mixture was measured. The conductivity was found to increase considerably as the reaction proceeded. This was explained in terms of the formation of new effective forms of catalysts: the ammonium salt (in case of DMF) or sulphonium salt (for DMSO). A reaction scheme has been proposed, taking into account the active catalyst forms. The set of kinetic equations describing the reaction has been developed and the appropriate rate constants evaluated. Wiley InterScience Backfile Collection 1832-2000 Bukowska, Agnieszka oth Guskov, Andrei K. oth Makarov, Mikhail G. oth Rokaszewski, Edward oth Svets, Valery F. oth in Journal of Chemical Technology AND Biotechnology Chichester : Wiley 63(1995) vom: Apr., Seite 379-383 (DE-627)NLEJ159070589 (DE-600)1479465-2 0268-2575 nnns volume:63 year:1995 month:04 pages:379-383 extent:5 http://dx.doi.org/10.1002/jctb.280630412 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 63 1995 4 379-383 5 |
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kinetics of addition of acetic acid to epichlorohydrin in the presence of dmf or dmso |
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Kinetics of addition of acetic acid to epichlorohydrin in the presence of DMF or DMSO |
abstract |
The kinetics of reaction between acetic acid and epichlorohydrin carried out in the presence of DMF or DMSO was studied. In addition, the conductivity of the reaction mixture was measured. The conductivity was found to increase considerably as the reaction proceeded. This was explained in terms of the formation of new effective forms of catalysts: the ammonium salt (in case of DMF) or sulphonium salt (for DMSO). A reaction scheme has been proposed, taking into account the active catalyst forms. The set of kinetic equations describing the reaction has been developed and the appropriate rate constants evaluated. |
abstractGer |
The kinetics of reaction between acetic acid and epichlorohydrin carried out in the presence of DMF or DMSO was studied. In addition, the conductivity of the reaction mixture was measured. The conductivity was found to increase considerably as the reaction proceeded. This was explained in terms of the formation of new effective forms of catalysts: the ammonium salt (in case of DMF) or sulphonium salt (for DMSO). A reaction scheme has been proposed, taking into account the active catalyst forms. The set of kinetic equations describing the reaction has been developed and the appropriate rate constants evaluated. |
abstract_unstemmed |
The kinetics of reaction between acetic acid and epichlorohydrin carried out in the presence of DMF or DMSO was studied. In addition, the conductivity of the reaction mixture was measured. The conductivity was found to increase considerably as the reaction proceeded. This was explained in terms of the formation of new effective forms of catalysts: the ammonium salt (in case of DMF) or sulphonium salt (for DMSO). A reaction scheme has been proposed, taking into account the active catalyst forms. The set of kinetic equations describing the reaction has been developed and the appropriate rate constants evaluated. |
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Kinetics of addition of acetic acid to epichlorohydrin in the presence of DMF or DMSO |
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