Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday.

Replacement of SMe2 at the pseudo-alkylidyne μ-carbon atom of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)SMe2}]SO3CF3 by PR2H (PR2 = PEt2, PCyH, PPhH) results in the formation of the phosphonium salts [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PHR2}]SO3CF3 which upon deprotonation with NEt3 yield the corresponding neutral complexes...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Busetto, Luigi Carlucci, Lucia Zanotti, Valerio Albano, Vincenzo G. Monari, Magda

Format:	E-Artikel
Sprache:	Deutsch

Erschienen:	1992

Umfang:	1 Ill. ; 1 Tab. 3

Reproduktion:	Wiley InterScience Backfile Collection 1832-2000
Übergeordnetes Werk:	in: Berichte der deutschen chemischen Gesellschaft - Weinheim : Wiley-VCH, 125(1992) vom: Mai, Seite 1125-1127
Übergeordnetes Werk:	volume:125 ; year:1992 ; month:05 ; pages:1125-1127 ; extent:3

Links:	Link aufrufen

Katalog-ID:	NLEJ161562779

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matchkey_str	article:03659496:1992----::yteioteoepopaolyieeopeef2pc2ocp2rptpcppadoeuasrcuefhptdrvtvddctdorf
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allfields	(DE-627)NLEJ161562779 DE-627 ger DE-627 rakwb ger Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday. 1992 1 Ill. 1 Tab. 3 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Replacement of SMe2 at the pseudo-alkylidyne μ-carbon atom of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)SMe2}]SO3CF3 by PR2H (PR2 = PEt2, PCyH, PPhH) results in the formation of the phosphonium salts [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PHR2}]SO3CF3 which upon deprotonation with NEt3 yield the corresponding neutral complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}]. These μ-(phosphanoalkylidene) complexes have been characterized on the basis of IR, 31P{1H}-, 1H-, and 13C{1H}-NMR spectra and by the X-ray molecular structure of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PEt2}]. Wiley InterScience Backfile Collection 1832-2000 Busetto, Luigi oth Carlucci, Lucia oth Zanotti, Valerio oth Albano, Vincenzo G. oth Monari, Magda oth in Berichte der deutschen chemischen Gesellschaft Weinheim : Wiley-VCH 125(1992) vom: Mai, Seite 1125-1127 (DE-627)NLEJ159071097 0365-9496 nnns volume:125 year:1992 month:05 pages:1125-1127 extent:3 http://dx.doi.org/10.1002/cber.19921250523 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 125 1992 5 1125-1127 3
spelling	(DE-627)NLEJ161562779 DE-627 ger DE-627 rakwb ger Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday. 1992 1 Ill. 1 Tab. 3 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Replacement of SMe2 at the pseudo-alkylidyne μ-carbon atom of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)SMe2}]SO3CF3 by PR2H (PR2 = PEt2, PCyH, PPhH) results in the formation of the phosphonium salts [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PHR2}]SO3CF3 which upon deprotonation with NEt3 yield the corresponding neutral complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}]. These μ-(phosphanoalkylidene) complexes have been characterized on the basis of IR, 31P{1H}-, 1H-, and 13C{1H}-NMR spectra and by the X-ray molecular structure of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PEt2}]. Wiley InterScience Backfile Collection 1832-2000 Busetto, Luigi oth Carlucci, Lucia oth Zanotti, Valerio oth Albano, Vincenzo G. oth Monari, Magda oth in Berichte der deutschen chemischen Gesellschaft Weinheim : Wiley-VCH 125(1992) vom: Mai, Seite 1125-1127 (DE-627)NLEJ159071097 0365-9496 nnns volume:125 year:1992 month:05 pages:1125-1127 extent:3 http://dx.doi.org/10.1002/cber.19921250523 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 125 1992 5 1125-1127 3
allfields_unstemmed	(DE-627)NLEJ161562779 DE-627 ger DE-627 rakwb ger Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday. 1992 1 Ill. 1 Tab. 3 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Replacement of SMe2 at the pseudo-alkylidyne μ-carbon atom of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)SMe2}]SO3CF3 by PR2H (PR2 = PEt2, PCyH, PPhH) results in the formation of the phosphonium salts [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PHR2}]SO3CF3 which upon deprotonation with NEt3 yield the corresponding neutral complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}]. These μ-(phosphanoalkylidene) complexes have been characterized on the basis of IR, 31P{1H}-, 1H-, and 13C{1H}-NMR spectra and by the X-ray molecular structure of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PEt2}]. Wiley InterScience Backfile Collection 1832-2000 Busetto, Luigi oth Carlucci, Lucia oth Zanotti, Valerio oth Albano, Vincenzo G. oth Monari, Magda oth in Berichte der deutschen chemischen Gesellschaft Weinheim : Wiley-VCH 125(1992) vom: Mai, Seite 1125-1127 (DE-627)NLEJ159071097 0365-9496 nnns volume:125 year:1992 month:05 pages:1125-1127 extent:3 http://dx.doi.org/10.1002/cber.19921250523 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 125 1992 5 1125-1127 3
allfieldsGer	(DE-627)NLEJ161562779 DE-627 ger DE-627 rakwb ger Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday. 1992 1 Ill. 1 Tab. 3 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Replacement of SMe2 at the pseudo-alkylidyne μ-carbon atom of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)SMe2}]SO3CF3 by PR2H (PR2 = PEt2, PCyH, PPhH) results in the formation of the phosphonium salts [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PHR2}]SO3CF3 which upon deprotonation with NEt3 yield the corresponding neutral complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}]. These μ-(phosphanoalkylidene) complexes have been characterized on the basis of IR, 31P{1H}-, 1H-, and 13C{1H}-NMR spectra and by the X-ray molecular structure of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PEt2}]. Wiley InterScience Backfile Collection 1832-2000 Busetto, Luigi oth Carlucci, Lucia oth Zanotti, Valerio oth Albano, Vincenzo G. oth Monari, Magda oth in Berichte der deutschen chemischen Gesellschaft Weinheim : Wiley-VCH 125(1992) vom: Mai, Seite 1125-1127 (DE-627)NLEJ159071097 0365-9496 nnns volume:125 year:1992 month:05 pages:1125-1127 extent:3 http://dx.doi.org/10.1002/cber.19921250523 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 125 1992 5 1125-1127 3
allfieldsSound	(DE-627)NLEJ161562779 DE-627 ger DE-627 rakwb ger Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday. 1992 1 Ill. 1 Tab. 3 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Replacement of SMe2 at the pseudo-alkylidyne μ-carbon atom of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)SMe2}]SO3CF3 by PR2H (PR2 = PEt2, PCyH, PPhH) results in the formation of the phosphonium salts [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PHR2}]SO3CF3 which upon deprotonation with NEt3 yield the corresponding neutral complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}]. These μ-(phosphanoalkylidene) complexes have been characterized on the basis of IR, 31P{1H}-, 1H-, and 13C{1H}-NMR spectra and by the X-ray molecular structure of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PEt2}]. Wiley InterScience Backfile Collection 1832-2000 Busetto, Luigi oth Carlucci, Lucia oth Zanotti, Valerio oth Albano, Vincenzo G. oth Monari, Magda oth in Berichte der deutschen chemischen Gesellschaft Weinheim : Wiley-VCH 125(1992) vom: Mai, Seite 1125-1127 (DE-627)NLEJ159071097 0365-9496 nnns volume:125 year:1992 month:05 pages:1125-1127 extent:3 http://dx.doi.org/10.1002/cber.19921250523 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 125 1992 5 1125-1127 3
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topic_title	Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday
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title	Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday.
spellingShingle	Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday.
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title_full	Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday
journal	Berichte der deutschen chemischen Gesellschaft
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title_sort	synthesis of the novel μ-(phosphanoalkylidene) complexes [fe2cp2(co)2(μ-co){μ-c(cn)pr2}] (pr2 = pet2, phcy, phph) and molecular structure of the pet2 derivativededicated to professor wolfgang beck on the occasion of his 60th birthday
title_auth	Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday.
abstract	Replacement of SMe2 at the pseudo-alkylidyne μ-carbon atom of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)SMe2}]SO3CF3 by PR2H (PR2 = PEt2, PCyH, PPhH) results in the formation of the phosphonium salts [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PHR2}]SO3CF3 which upon deprotonation with NEt3 yield the corresponding neutral complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}]. These μ-(phosphanoalkylidene) complexes have been characterized on the basis of IR, 31P{1H}-, 1H-, and 13C{1H}-NMR spectra and by the X-ray molecular structure of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PEt2}].
abstractGer	Replacement of SMe2 at the pseudo-alkylidyne μ-carbon atom of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)SMe2}]SO3CF3 by PR2H (PR2 = PEt2, PCyH, PPhH) results in the formation of the phosphonium salts [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PHR2}]SO3CF3 which upon deprotonation with NEt3 yield the corresponding neutral complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}]. These μ-(phosphanoalkylidene) complexes have been characterized on the basis of IR, 31P{1H}-, 1H-, and 13C{1H}-NMR spectra and by the X-ray molecular structure of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PEt2}].
abstract_unstemmed	Replacement of SMe2 at the pseudo-alkylidyne μ-carbon atom of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)SMe2}]SO3CF3 by PR2H (PR2 = PEt2, PCyH, PPhH) results in the formation of the phosphonium salts [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PHR2}]SO3CF3 which upon deprotonation with NEt3 yield the corresponding neutral complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}]. These μ-(phosphanoalkylidene) complexes have been characterized on the basis of IR, 31P{1H}-, 1H-, and 13C{1H}-NMR spectra and by the X-ray molecular structure of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PEt2}].
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title_short	Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday.
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up_date	2024-07-06T03:43:46.004Z
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fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ161562779</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230506164600.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070201s1992 xx \|\|\|\|\|o 00\| \|\|ger c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ161562779</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">ger</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday.</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1992</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="b">1 Ill.</subfield><subfield code="b">1 Tab.</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">3</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Replacement of SMe2 at the pseudo-alkylidyne μ-carbon atom of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)SMe2}]SO3CF3 by PR2H (PR2 = PEt2, PCyH, PPhH) results in the formation of the phosphonium salts [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PHR2}]SO3CF3 which upon deprotonation with NEt3 yield the corresponding neutral complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}]. These μ-(phosphanoalkylidene) complexes have been characterized on the basis of IR, 31P{1H}-, 1H-, and 13C{1H}-NMR spectra and by the X-ray molecular structure of [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PEt2}].</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Wiley InterScience Backfile Collection 1832-2000</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Busetto, Luigi</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Carlucci, Lucia</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zanotti, Valerio</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Albano, Vincenzo G.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Monari, Magda</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Berichte der deutschen chemischen Gesellschaft</subfield><subfield code="d">Weinheim : Wiley-VCH</subfield><subfield code="g">125(1992) vom: Mai, Seite 1125-1127</subfield><subfield code="w">(DE-627)NLEJ159071097</subfield><subfield code="x">0365-9496</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:125</subfield><subfield code="g">year:1992</subfield><subfield code="g">month:05</subfield><subfield code="g">pages:1125-1127</subfield><subfield code="g">extent:3</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://dx.doi.org/10.1002/cber.19921250523</subfield><subfield code="q">text/html</subfield><subfield code="z">Deutschlandweit zugänglich</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-WIS</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">125</subfield><subfield code="j">1992</subfield><subfield code="c">5</subfield><subfield code="h">1125-1127</subfield><subfield code="g">3</subfield></datafield></record></collection>
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Synthesis of the Novel μ-(Phosphanoalkylidene) Complexes [Fe2Cp2(CO)2(μ-CO){μ-C(CN)PR2}] (PR2 = PEt2, PHCy, PHPh) and Molecular Structure of the PEt2 DerivativeDedicated to Professor Wolfgang Beck on the occasion of his 60th birthday.

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