Synthesis of poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide), a new biodegradable thermoplastic elastomer
The anionic ring-opening polymerization of L-lactide was initiated by dipotassium-poly-isobutylene-alcoholate telechelic polymer to yield poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide) triblock copolymer, a partially biodegradable thermoplastic elastomer. The pure triblock copolymer was...
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| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1995 |
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| Umfang: |
4 Ill. 6 |
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| Reproduktion: |
Wiley InterScience Backfile Collection 1832-2000 |
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| Übergeordnetes Werk: |
in: Macromolecular Rapid Communications - Weinheim : Wiley-VCH, 16(1995) vom: Dez., Seite 935-940 |
| Übergeordnetes Werk: |
volume:16 ; year:1995 ; month:12 ; pages:935-940 ; extent:6 |
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| 520 | |a The anionic ring-opening polymerization of L-lactide was initiated by dipotassium-poly-isobutylene-alcoholate telechelic polymer to yield poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide) triblock copolymer, a partially biodegradable thermoplastic elastomer. The pure triblock copolymer was obtained by gradient column chromatography on silica gel. The molar mass and molar mass distribution of the block copolymer was ascertained by SEC and quantitative 1H NMR spectroscopy. It showed two glass transitions and microphase separation. | ||
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(DE-627)NLEJ163445923 DE-627 ger DE-627 rakwb eng Synthesis of poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide), a new biodegradable thermoplastic elastomer 1995 4 Ill. 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The anionic ring-opening polymerization of L-lactide was initiated by dipotassium-poly-isobutylene-alcoholate telechelic polymer to yield poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide) triblock copolymer, a partially biodegradable thermoplastic elastomer. The pure triblock copolymer was obtained by gradient column chromatography on silica gel. The molar mass and molar mass distribution of the block copolymer was ascertained by SEC and quantitative 1H NMR spectroscopy. It showed two glass transitions and microphase separation. Wiley InterScience Backfile Collection 1832-2000 Sipos, László oth Zsuga, Miklós oth Deák, György oth in Macromolecular Rapid Communications Weinheim : Wiley-VCH 16(1995) vom: Dez., Seite 935-940 (DE-627)NLEJ159071372 (DE-600)1475027-2 1022-1336 nnns volume:16 year:1995 month:12 pages:935-940 extent:6 http://dx.doi.org/10.1002/marc.1995.030161209 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 16 1995 12 935-940 6 |
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(DE-627)NLEJ163445923 DE-627 ger DE-627 rakwb eng Synthesis of poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide), a new biodegradable thermoplastic elastomer 1995 4 Ill. 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The anionic ring-opening polymerization of L-lactide was initiated by dipotassium-poly-isobutylene-alcoholate telechelic polymer to yield poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide) triblock copolymer, a partially biodegradable thermoplastic elastomer. The pure triblock copolymer was obtained by gradient column chromatography on silica gel. The molar mass and molar mass distribution of the block copolymer was ascertained by SEC and quantitative 1H NMR spectroscopy. It showed two glass transitions and microphase separation. Wiley InterScience Backfile Collection 1832-2000 Sipos, László oth Zsuga, Miklós oth Deák, György oth in Macromolecular Rapid Communications Weinheim : Wiley-VCH 16(1995) vom: Dez., Seite 935-940 (DE-627)NLEJ159071372 (DE-600)1475027-2 1022-1336 nnns volume:16 year:1995 month:12 pages:935-940 extent:6 http://dx.doi.org/10.1002/marc.1995.030161209 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 16 1995 12 935-940 6 |
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(DE-627)NLEJ163445923 DE-627 ger DE-627 rakwb eng Synthesis of poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide), a new biodegradable thermoplastic elastomer 1995 4 Ill. 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The anionic ring-opening polymerization of L-lactide was initiated by dipotassium-poly-isobutylene-alcoholate telechelic polymer to yield poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide) triblock copolymer, a partially biodegradable thermoplastic elastomer. The pure triblock copolymer was obtained by gradient column chromatography on silica gel. The molar mass and molar mass distribution of the block copolymer was ascertained by SEC and quantitative 1H NMR spectroscopy. It showed two glass transitions and microphase separation. Wiley InterScience Backfile Collection 1832-2000 Sipos, László oth Zsuga, Miklós oth Deák, György oth in Macromolecular Rapid Communications Weinheim : Wiley-VCH 16(1995) vom: Dez., Seite 935-940 (DE-627)NLEJ159071372 (DE-600)1475027-2 1022-1336 nnns volume:16 year:1995 month:12 pages:935-940 extent:6 http://dx.doi.org/10.1002/marc.1995.030161209 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 16 1995 12 935-940 6 |
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(DE-627)NLEJ163445923 DE-627 ger DE-627 rakwb eng Synthesis of poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide), a new biodegradable thermoplastic elastomer 1995 4 Ill. 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The anionic ring-opening polymerization of L-lactide was initiated by dipotassium-poly-isobutylene-alcoholate telechelic polymer to yield poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide) triblock copolymer, a partially biodegradable thermoplastic elastomer. The pure triblock copolymer was obtained by gradient column chromatography on silica gel. The molar mass and molar mass distribution of the block copolymer was ascertained by SEC and quantitative 1H NMR spectroscopy. It showed two glass transitions and microphase separation. Wiley InterScience Backfile Collection 1832-2000 Sipos, László oth Zsuga, Miklós oth Deák, György oth in Macromolecular Rapid Communications Weinheim : Wiley-VCH 16(1995) vom: Dez., Seite 935-940 (DE-627)NLEJ159071372 (DE-600)1475027-2 1022-1336 nnns volume:16 year:1995 month:12 pages:935-940 extent:6 http://dx.doi.org/10.1002/marc.1995.030161209 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 16 1995 12 935-940 6 |
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(DE-627)NLEJ163445923 DE-627 ger DE-627 rakwb eng Synthesis of poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide), a new biodegradable thermoplastic elastomer 1995 4 Ill. 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The anionic ring-opening polymerization of L-lactide was initiated by dipotassium-poly-isobutylene-alcoholate telechelic polymer to yield poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide) triblock copolymer, a partially biodegradable thermoplastic elastomer. The pure triblock copolymer was obtained by gradient column chromatography on silica gel. The molar mass and molar mass distribution of the block copolymer was ascertained by SEC and quantitative 1H NMR spectroscopy. It showed two glass transitions and microphase separation. Wiley InterScience Backfile Collection 1832-2000 Sipos, László oth Zsuga, Miklós oth Deák, György oth in Macromolecular Rapid Communications Weinheim : Wiley-VCH 16(1995) vom: Dez., Seite 935-940 (DE-627)NLEJ159071372 (DE-600)1475027-2 1022-1336 nnns volume:16 year:1995 month:12 pages:935-940 extent:6 http://dx.doi.org/10.1002/marc.1995.030161209 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 16 1995 12 935-940 6 |
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synthesis of poly(l-lactide)-block-polyisobutylene-block-poly(l-lactide), a new biodegradable thermoplastic elastomer |
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Synthesis of poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide), a new biodegradable thermoplastic elastomer |
| abstract |
The anionic ring-opening polymerization of L-lactide was initiated by dipotassium-poly-isobutylene-alcoholate telechelic polymer to yield poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide) triblock copolymer, a partially biodegradable thermoplastic elastomer. The pure triblock copolymer was obtained by gradient column chromatography on silica gel. The molar mass and molar mass distribution of the block copolymer was ascertained by SEC and quantitative 1H NMR spectroscopy. It showed two glass transitions and microphase separation. |
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The anionic ring-opening polymerization of L-lactide was initiated by dipotassium-poly-isobutylene-alcoholate telechelic polymer to yield poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide) triblock copolymer, a partially biodegradable thermoplastic elastomer. The pure triblock copolymer was obtained by gradient column chromatography on silica gel. The molar mass and molar mass distribution of the block copolymer was ascertained by SEC and quantitative 1H NMR spectroscopy. It showed two glass transitions and microphase separation. |
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The anionic ring-opening polymerization of L-lactide was initiated by dipotassium-poly-isobutylene-alcoholate telechelic polymer to yield poly(L-lactide)-block-polyisobutylene-block-poly(L-lactide) triblock copolymer, a partially biodegradable thermoplastic elastomer. The pure triblock copolymer was obtained by gradient column chromatography on silica gel. The molar mass and molar mass distribution of the block copolymer was ascertained by SEC and quantitative 1H NMR spectroscopy. It showed two glass transitions and microphase separation. |
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