Absorption of sulfonic acids on nylon in ethylene glycol
The absorption isotherms of methanesulfonic acid, ethanedisulfonic acid, and R-acid on nylon fiber were determined in water and ethylene glycol at 80°C. The saturation values of the sulfonic acids on the nylon fiber were determined by extrapolation of a reciprocal plot of the absorption isotherms. I...
Ausführliche Beschreibung
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E-Artikel |
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Sprache: |
Englisch |
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1974 |
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Umfang: |
2 Ill. ; 1 Tab. 6 |
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Reproduktion: |
Wiley InterScience Backfile Collection 1832-2000 |
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Übergeordnetes Werk: |
in: Journal of Applied Polymer Science - New York, NY [u.a.] : Wiley, 18(1974) vom: Aug., Seite 2465-2470 |
Übergeordnetes Werk: |
volume:18 ; year:1974 ; month:08 ; pages:2465-2470 ; extent:6 |
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520 | |a The absorption isotherms of methanesulfonic acid, ethanedisulfonic acid, and R-acid on nylon fiber were determined in water and ethylene glycol at 80°C. The saturation values of the sulfonic acids on the nylon fiber were determined by extrapolation of a reciprocal plot of the absorption isotherms. In water, the saturation values of the three acids were near the amino group content of the fiber. In ethylene glycol, the saturation values of the dibasic acids, ethanedisulfonic acid and R-acid, were much larger than the stoichiometric quantity corresponding to the amino group content of the nylon fiber, approximately twice, though the saturation value of the monobasic acid, methanesulfonic acid, was near the amino group content. A dyeing model of nylon with polybasic dyes was proposed, in order to explain how a polybasic dye can physically saturate fixed sites. | ||
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(DE-627)NLEJ163619336 DE-627 ger DE-627 rakwb eng Absorption of sulfonic acids on nylon in ethylene glycol 1974 2 Ill. 1 Tab. 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The absorption isotherms of methanesulfonic acid, ethanedisulfonic acid, and R-acid on nylon fiber were determined in water and ethylene glycol at 80°C. The saturation values of the sulfonic acids on the nylon fiber were determined by extrapolation of a reciprocal plot of the absorption isotherms. In water, the saturation values of the three acids were near the amino group content of the fiber. In ethylene glycol, the saturation values of the dibasic acids, ethanedisulfonic acid and R-acid, were much larger than the stoichiometric quantity corresponding to the amino group content of the nylon fiber, approximately twice, though the saturation value of the monobasic acid, methanesulfonic acid, was near the amino group content. A dyeing model of nylon with polybasic dyes was proposed, in order to explain how a polybasic dye can physically saturate fixed sites. Wiley InterScience Backfile Collection 1832-2000 Nango, Mamoru oth Katayama, Akira oth Kuroki, Nobuhiko oth in Journal of Applied Polymer Science New York, NY [u.a.] : Wiley 18(1974) vom: Aug., Seite 2465-2470 (DE-627)NLEJ159071461 (DE-600)1491105-x 0021-8995 nnns volume:18 year:1974 month:08 pages:2465-2470 extent:6 http://dx.doi.org/10.1002/app.1974.070180824 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 18 1974 8 2465-2470 6 |
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(DE-627)NLEJ163619336 DE-627 ger DE-627 rakwb eng Absorption of sulfonic acids on nylon in ethylene glycol 1974 2 Ill. 1 Tab. 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The absorption isotherms of methanesulfonic acid, ethanedisulfonic acid, and R-acid on nylon fiber were determined in water and ethylene glycol at 80°C. The saturation values of the sulfonic acids on the nylon fiber were determined by extrapolation of a reciprocal plot of the absorption isotherms. In water, the saturation values of the three acids were near the amino group content of the fiber. In ethylene glycol, the saturation values of the dibasic acids, ethanedisulfonic acid and R-acid, were much larger than the stoichiometric quantity corresponding to the amino group content of the nylon fiber, approximately twice, though the saturation value of the monobasic acid, methanesulfonic acid, was near the amino group content. A dyeing model of nylon with polybasic dyes was proposed, in order to explain how a polybasic dye can physically saturate fixed sites. Wiley InterScience Backfile Collection 1832-2000 Nango, Mamoru oth Katayama, Akira oth Kuroki, Nobuhiko oth in Journal of Applied Polymer Science New York, NY [u.a.] : Wiley 18(1974) vom: Aug., Seite 2465-2470 (DE-627)NLEJ159071461 (DE-600)1491105-x 0021-8995 nnns volume:18 year:1974 month:08 pages:2465-2470 extent:6 http://dx.doi.org/10.1002/app.1974.070180824 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 18 1974 8 2465-2470 6 |
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(DE-627)NLEJ163619336 DE-627 ger DE-627 rakwb eng Absorption of sulfonic acids on nylon in ethylene glycol 1974 2 Ill. 1 Tab. 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The absorption isotherms of methanesulfonic acid, ethanedisulfonic acid, and R-acid on nylon fiber were determined in water and ethylene glycol at 80°C. The saturation values of the sulfonic acids on the nylon fiber were determined by extrapolation of a reciprocal plot of the absorption isotherms. In water, the saturation values of the three acids were near the amino group content of the fiber. In ethylene glycol, the saturation values of the dibasic acids, ethanedisulfonic acid and R-acid, were much larger than the stoichiometric quantity corresponding to the amino group content of the nylon fiber, approximately twice, though the saturation value of the monobasic acid, methanesulfonic acid, was near the amino group content. A dyeing model of nylon with polybasic dyes was proposed, in order to explain how a polybasic dye can physically saturate fixed sites. Wiley InterScience Backfile Collection 1832-2000 Nango, Mamoru oth Katayama, Akira oth Kuroki, Nobuhiko oth in Journal of Applied Polymer Science New York, NY [u.a.] : Wiley 18(1974) vom: Aug., Seite 2465-2470 (DE-627)NLEJ159071461 (DE-600)1491105-x 0021-8995 nnns volume:18 year:1974 month:08 pages:2465-2470 extent:6 http://dx.doi.org/10.1002/app.1974.070180824 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 18 1974 8 2465-2470 6 |
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(DE-627)NLEJ163619336 DE-627 ger DE-627 rakwb eng Absorption of sulfonic acids on nylon in ethylene glycol 1974 2 Ill. 1 Tab. 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The absorption isotherms of methanesulfonic acid, ethanedisulfonic acid, and R-acid on nylon fiber were determined in water and ethylene glycol at 80°C. The saturation values of the sulfonic acids on the nylon fiber were determined by extrapolation of a reciprocal plot of the absorption isotherms. In water, the saturation values of the three acids were near the amino group content of the fiber. In ethylene glycol, the saturation values of the dibasic acids, ethanedisulfonic acid and R-acid, were much larger than the stoichiometric quantity corresponding to the amino group content of the nylon fiber, approximately twice, though the saturation value of the monobasic acid, methanesulfonic acid, was near the amino group content. A dyeing model of nylon with polybasic dyes was proposed, in order to explain how a polybasic dye can physically saturate fixed sites. Wiley InterScience Backfile Collection 1832-2000 Nango, Mamoru oth Katayama, Akira oth Kuroki, Nobuhiko oth in Journal of Applied Polymer Science New York, NY [u.a.] : Wiley 18(1974) vom: Aug., Seite 2465-2470 (DE-627)NLEJ159071461 (DE-600)1491105-x 0021-8995 nnns volume:18 year:1974 month:08 pages:2465-2470 extent:6 http://dx.doi.org/10.1002/app.1974.070180824 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 18 1974 8 2465-2470 6 |
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(DE-627)NLEJ163619336 DE-627 ger DE-627 rakwb eng Absorption of sulfonic acids on nylon in ethylene glycol 1974 2 Ill. 1 Tab. 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The absorption isotherms of methanesulfonic acid, ethanedisulfonic acid, and R-acid on nylon fiber were determined in water and ethylene glycol at 80°C. The saturation values of the sulfonic acids on the nylon fiber were determined by extrapolation of a reciprocal plot of the absorption isotherms. In water, the saturation values of the three acids were near the amino group content of the fiber. In ethylene glycol, the saturation values of the dibasic acids, ethanedisulfonic acid and R-acid, were much larger than the stoichiometric quantity corresponding to the amino group content of the nylon fiber, approximately twice, though the saturation value of the monobasic acid, methanesulfonic acid, was near the amino group content. A dyeing model of nylon with polybasic dyes was proposed, in order to explain how a polybasic dye can physically saturate fixed sites. Wiley InterScience Backfile Collection 1832-2000 Nango, Mamoru oth Katayama, Akira oth Kuroki, Nobuhiko oth in Journal of Applied Polymer Science New York, NY [u.a.] : Wiley 18(1974) vom: Aug., Seite 2465-2470 (DE-627)NLEJ159071461 (DE-600)1491105-x 0021-8995 nnns volume:18 year:1974 month:08 pages:2465-2470 extent:6 http://dx.doi.org/10.1002/app.1974.070180824 text/html Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-WIS GBV_NL_ARTICLE AR 18 1974 8 2465-2470 6 |
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absorption of sulfonic acids on nylon in ethylene glycol |
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Absorption of sulfonic acids on nylon in ethylene glycol |
abstract |
The absorption isotherms of methanesulfonic acid, ethanedisulfonic acid, and R-acid on nylon fiber were determined in water and ethylene glycol at 80°C. The saturation values of the sulfonic acids on the nylon fiber were determined by extrapolation of a reciprocal plot of the absorption isotherms. In water, the saturation values of the three acids were near the amino group content of the fiber. In ethylene glycol, the saturation values of the dibasic acids, ethanedisulfonic acid and R-acid, were much larger than the stoichiometric quantity corresponding to the amino group content of the nylon fiber, approximately twice, though the saturation value of the monobasic acid, methanesulfonic acid, was near the amino group content. A dyeing model of nylon with polybasic dyes was proposed, in order to explain how a polybasic dye can physically saturate fixed sites. |
abstractGer |
The absorption isotherms of methanesulfonic acid, ethanedisulfonic acid, and R-acid on nylon fiber were determined in water and ethylene glycol at 80°C. The saturation values of the sulfonic acids on the nylon fiber were determined by extrapolation of a reciprocal plot of the absorption isotherms. In water, the saturation values of the three acids were near the amino group content of the fiber. In ethylene glycol, the saturation values of the dibasic acids, ethanedisulfonic acid and R-acid, were much larger than the stoichiometric quantity corresponding to the amino group content of the nylon fiber, approximately twice, though the saturation value of the monobasic acid, methanesulfonic acid, was near the amino group content. A dyeing model of nylon with polybasic dyes was proposed, in order to explain how a polybasic dye can physically saturate fixed sites. |
abstract_unstemmed |
The absorption isotherms of methanesulfonic acid, ethanedisulfonic acid, and R-acid on nylon fiber were determined in water and ethylene glycol at 80°C. The saturation values of the sulfonic acids on the nylon fiber were determined by extrapolation of a reciprocal plot of the absorption isotherms. In water, the saturation values of the three acids were near the amino group content of the fiber. In ethylene glycol, the saturation values of the dibasic acids, ethanedisulfonic acid and R-acid, were much larger than the stoichiometric quantity corresponding to the amino group content of the nylon fiber, approximately twice, though the saturation value of the monobasic acid, methanesulfonic acid, was near the amino group content. A dyeing model of nylon with polybasic dyes was proposed, in order to explain how a polybasic dye can physically saturate fixed sites. |
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