Catalytic determination of copper in blood plasma using flow-injection biamperometry
A method for the determination of copper based on the catalytic effect of Cu(II) on the oxidation of thiosulphate by Fe(II) is described. Fe(II) formed in this reaction in the presence of an excess of Fe(III) allows the use of amperometric detection with two polarized platinum wire elecrodes. At a p...
Ausführliche Beschreibung
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| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1993 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Analytica Chimica Acta - Amsterdam : Elsevier, 281(1993), 2, Seite 299-304 |
| Übergeordnetes Werk: |
volume:281 ; year:1993 ; number:2 ; pages:299-304 |
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| 520 | |a A method for the determination of copper based on the catalytic effect of Cu(II) on the oxidation of thiosulphate by Fe(II) is described. Fe(II) formed in this reaction in the presence of an excess of Fe(III) allows the use of amperometric detection with two polarized platinum wire elecrodes. At a polarizing voltage voltage of 80 mV a linear dependence of current intensity on Cu(II) concentration is obtained in the range of Cu(II) concentrations present in blood plasma. In determinations with a sampling rate of 70 h^-^1 a satisfactory agreement was obtained between the results of flow-injection analysis with biamperometric detection and flame atomic absorption spectrometry. | ||
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(DE-627)NLEJ173543731 (DE-599)GBVNLZ173543731 DE-627 ger DE-627 rakwb eng Catalytic determination of copper in blood plasma using flow-injection biamperometry 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A method for the determination of copper based on the catalytic effect of Cu(II) on the oxidation of thiosulphate by Fe(II) is described. Fe(II) formed in this reaction in the presence of an excess of Fe(III) allows the use of amperometric detection with two polarized platinum wire elecrodes. At a polarizing voltage voltage of 80 mV a linear dependence of current intensity on Cu(II) concentration is obtained in the range of Cu(II) concentrations present in blood plasma. In determinations with a sampling rate of 70 h^-^1 a satisfactory agreement was obtained between the results of flow-injection analysis with biamperometric detection and flame atomic absorption spectrometry. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Michalowski, J. oth Trojanowicz, M. oth in Analytica Chimica Acta Amsterdam : Elsevier 281(1993), 2, Seite 299-304 (DE-627)NLEJ173450067 (DE-600)1483436-4 0003-2670 nnns volume:281 year:1993 number:2 pages:299-304 http://linkinghub.elsevier.com/retrieve/pii/0003-2670(93)85185-M GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 281 1993 2 299-304 |
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(DE-627)NLEJ173543731 (DE-599)GBVNLZ173543731 DE-627 ger DE-627 rakwb eng Catalytic determination of copper in blood plasma using flow-injection biamperometry 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A method for the determination of copper based on the catalytic effect of Cu(II) on the oxidation of thiosulphate by Fe(II) is described. Fe(II) formed in this reaction in the presence of an excess of Fe(III) allows the use of amperometric detection with two polarized platinum wire elecrodes. At a polarizing voltage voltage of 80 mV a linear dependence of current intensity on Cu(II) concentration is obtained in the range of Cu(II) concentrations present in blood plasma. In determinations with a sampling rate of 70 h^-^1 a satisfactory agreement was obtained between the results of flow-injection analysis with biamperometric detection and flame atomic absorption spectrometry. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Michalowski, J. oth Trojanowicz, M. oth in Analytica Chimica Acta Amsterdam : Elsevier 281(1993), 2, Seite 299-304 (DE-627)NLEJ173450067 (DE-600)1483436-4 0003-2670 nnns volume:281 year:1993 number:2 pages:299-304 http://linkinghub.elsevier.com/retrieve/pii/0003-2670(93)85185-M GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 281 1993 2 299-304 |
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(DE-627)NLEJ173543731 (DE-599)GBVNLZ173543731 DE-627 ger DE-627 rakwb eng Catalytic determination of copper in blood plasma using flow-injection biamperometry 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A method for the determination of copper based on the catalytic effect of Cu(II) on the oxidation of thiosulphate by Fe(II) is described. Fe(II) formed in this reaction in the presence of an excess of Fe(III) allows the use of amperometric detection with two polarized platinum wire elecrodes. At a polarizing voltage voltage of 80 mV a linear dependence of current intensity on Cu(II) concentration is obtained in the range of Cu(II) concentrations present in blood plasma. In determinations with a sampling rate of 70 h^-^1 a satisfactory agreement was obtained between the results of flow-injection analysis with biamperometric detection and flame atomic absorption spectrometry. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Michalowski, J. oth Trojanowicz, M. oth in Analytica Chimica Acta Amsterdam : Elsevier 281(1993), 2, Seite 299-304 (DE-627)NLEJ173450067 (DE-600)1483436-4 0003-2670 nnns volume:281 year:1993 number:2 pages:299-304 http://linkinghub.elsevier.com/retrieve/pii/0003-2670(93)85185-M GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 281 1993 2 299-304 |
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(DE-627)NLEJ173543731 (DE-599)GBVNLZ173543731 DE-627 ger DE-627 rakwb eng Catalytic determination of copper in blood plasma using flow-injection biamperometry 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A method for the determination of copper based on the catalytic effect of Cu(II) on the oxidation of thiosulphate by Fe(II) is described. Fe(II) formed in this reaction in the presence of an excess of Fe(III) allows the use of amperometric detection with two polarized platinum wire elecrodes. At a polarizing voltage voltage of 80 mV a linear dependence of current intensity on Cu(II) concentration is obtained in the range of Cu(II) concentrations present in blood plasma. In determinations with a sampling rate of 70 h^-^1 a satisfactory agreement was obtained between the results of flow-injection analysis with biamperometric detection and flame atomic absorption spectrometry. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Michalowski, J. oth Trojanowicz, M. oth in Analytica Chimica Acta Amsterdam : Elsevier 281(1993), 2, Seite 299-304 (DE-627)NLEJ173450067 (DE-600)1483436-4 0003-2670 nnns volume:281 year:1993 number:2 pages:299-304 http://linkinghub.elsevier.com/retrieve/pii/0003-2670(93)85185-M GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 281 1993 2 299-304 |
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(DE-627)NLEJ173543731 (DE-599)GBVNLZ173543731 DE-627 ger DE-627 rakwb eng Catalytic determination of copper in blood plasma using flow-injection biamperometry 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A method for the determination of copper based on the catalytic effect of Cu(II) on the oxidation of thiosulphate by Fe(II) is described. Fe(II) formed in this reaction in the presence of an excess of Fe(III) allows the use of amperometric detection with two polarized platinum wire elecrodes. At a polarizing voltage voltage of 80 mV a linear dependence of current intensity on Cu(II) concentration is obtained in the range of Cu(II) concentrations present in blood plasma. In determinations with a sampling rate of 70 h^-^1 a satisfactory agreement was obtained between the results of flow-injection analysis with biamperometric detection and flame atomic absorption spectrometry. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Michalowski, J. oth Trojanowicz, M. oth in Analytica Chimica Acta Amsterdam : Elsevier 281(1993), 2, Seite 299-304 (DE-627)NLEJ173450067 (DE-600)1483436-4 0003-2670 nnns volume:281 year:1993 number:2 pages:299-304 http://linkinghub.elsevier.com/retrieve/pii/0003-2670(93)85185-M GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 281 1993 2 299-304 |
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Catalytic determination of copper in blood plasma using flow-injection biamperometry |
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A method for the determination of copper based on the catalytic effect of Cu(II) on the oxidation of thiosulphate by Fe(II) is described. Fe(II) formed in this reaction in the presence of an excess of Fe(III) allows the use of amperometric detection with two polarized platinum wire elecrodes. At a polarizing voltage voltage of 80 mV a linear dependence of current intensity on Cu(II) concentration is obtained in the range of Cu(II) concentrations present in blood plasma. In determinations with a sampling rate of 70 h^-^1 a satisfactory agreement was obtained between the results of flow-injection analysis with biamperometric detection and flame atomic absorption spectrometry. |
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A method for the determination of copper based on the catalytic effect of Cu(II) on the oxidation of thiosulphate by Fe(II) is described. Fe(II) formed in this reaction in the presence of an excess of Fe(III) allows the use of amperometric detection with two polarized platinum wire elecrodes. At a polarizing voltage voltage of 80 mV a linear dependence of current intensity on Cu(II) concentration is obtained in the range of Cu(II) concentrations present in blood plasma. In determinations with a sampling rate of 70 h^-^1 a satisfactory agreement was obtained between the results of flow-injection analysis with biamperometric detection and flame atomic absorption spectrometry. |
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A method for the determination of copper based on the catalytic effect of Cu(II) on the oxidation of thiosulphate by Fe(II) is described. Fe(II) formed in this reaction in the presence of an excess of Fe(III) allows the use of amperometric detection with two polarized platinum wire elecrodes. At a polarizing voltage voltage of 80 mV a linear dependence of current intensity on Cu(II) concentration is obtained in the range of Cu(II) concentrations present in blood plasma. In determinations with a sampling rate of 70 h^-^1 a satisfactory agreement was obtained between the results of flow-injection analysis with biamperometric detection and flame atomic absorption spectrometry. |
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