The origin of hyperfine structure in excited electronic states of NO"2
The analysis of measured hyperfine splittings in the ^2B"2 <- X^2A"1 spectrum of NO"2 shows that the major cause of the observed hfs splittings in the excited ^2B"2 state is vibronic coupling between a single level of the ^2B"2 state and many high lying vibrational levels...
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E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1985 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Chemical Physics Letters - Amsterdam : Elsevier, 114(1985), 2, Seite 125-132 |
| Übergeordnetes Werk: |
volume:114 ; year:1985 ; number:2 ; pages:125-132 |
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| 245 | 1 | 4 | |a The origin of hyperfine structure in excited electronic states of NO"2 |
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| 520 | |a The analysis of measured hyperfine splittings in the ^2B"2 <- X^2A"1 spectrum of NO"2 shows that the major cause of the observed hfs splittings in the excited ^2B"2 state is vibronic coupling between a single level of the ^2B"2 state and many high lying vibrational levels of the X^2A"1 ground state. Only a minor part of the hfs splitting may be due to spin polarization of the core. These results agree with the simple MO picture of NO"2 which predicts no Fermi interaction type hfs in the pure ^2B"2 state. | ||
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(DE-627)NLEJ17365200X (DE-599)GBVNLZ17365200X DE-627 ger DE-627 rakwb eng The origin of hyperfine structure in excited electronic states of NO"2 1985 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The analysis of measured hyperfine splittings in the ^2B"2 <- X^2A"1 spectrum of NO"2 shows that the major cause of the observed hfs splittings in the excited ^2B"2 state is vibronic coupling between a single level of the ^2B"2 state and many high lying vibrational levels of the X^2A"1 ground state. Only a minor part of the hfs splitting may be due to spin polarization of the core. These results agree with the simple MO picture of NO"2 which predicts no Fermi interaction type hfs in the pure ^2B"2 state. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Vedder, H.J. oth Persch, G. oth Foth, H.-J. oth in Chemical Physics Letters Amsterdam : Elsevier 114(1985), 2, Seite 125-132 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:114 year:1985 number:2 pages:125-132 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(85)85071-5 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 114 1985 2 125-132 |
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(DE-627)NLEJ17365200X (DE-599)GBVNLZ17365200X DE-627 ger DE-627 rakwb eng The origin of hyperfine structure in excited electronic states of NO"2 1985 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The analysis of measured hyperfine splittings in the ^2B"2 <- X^2A"1 spectrum of NO"2 shows that the major cause of the observed hfs splittings in the excited ^2B"2 state is vibronic coupling between a single level of the ^2B"2 state and many high lying vibrational levels of the X^2A"1 ground state. Only a minor part of the hfs splitting may be due to spin polarization of the core. These results agree with the simple MO picture of NO"2 which predicts no Fermi interaction type hfs in the pure ^2B"2 state. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Vedder, H.J. oth Persch, G. oth Foth, H.-J. oth in Chemical Physics Letters Amsterdam : Elsevier 114(1985), 2, Seite 125-132 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:114 year:1985 number:2 pages:125-132 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(85)85071-5 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 114 1985 2 125-132 |
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(DE-627)NLEJ17365200X (DE-599)GBVNLZ17365200X DE-627 ger DE-627 rakwb eng The origin of hyperfine structure in excited electronic states of NO"2 1985 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The analysis of measured hyperfine splittings in the ^2B"2 <- X^2A"1 spectrum of NO"2 shows that the major cause of the observed hfs splittings in the excited ^2B"2 state is vibronic coupling between a single level of the ^2B"2 state and many high lying vibrational levels of the X^2A"1 ground state. Only a minor part of the hfs splitting may be due to spin polarization of the core. These results agree with the simple MO picture of NO"2 which predicts no Fermi interaction type hfs in the pure ^2B"2 state. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Vedder, H.J. oth Persch, G. oth Foth, H.-J. oth in Chemical Physics Letters Amsterdam : Elsevier 114(1985), 2, Seite 125-132 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:114 year:1985 number:2 pages:125-132 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(85)85071-5 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 114 1985 2 125-132 |
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(DE-627)NLEJ17365200X (DE-599)GBVNLZ17365200X DE-627 ger DE-627 rakwb eng The origin of hyperfine structure in excited electronic states of NO"2 1985 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The analysis of measured hyperfine splittings in the ^2B"2 <- X^2A"1 spectrum of NO"2 shows that the major cause of the observed hfs splittings in the excited ^2B"2 state is vibronic coupling between a single level of the ^2B"2 state and many high lying vibrational levels of the X^2A"1 ground state. Only a minor part of the hfs splitting may be due to spin polarization of the core. These results agree with the simple MO picture of NO"2 which predicts no Fermi interaction type hfs in the pure ^2B"2 state. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Vedder, H.J. oth Persch, G. oth Foth, H.-J. oth in Chemical Physics Letters Amsterdam : Elsevier 114(1985), 2, Seite 125-132 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:114 year:1985 number:2 pages:125-132 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(85)85071-5 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 114 1985 2 125-132 |
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(DE-627)NLEJ17365200X (DE-599)GBVNLZ17365200X DE-627 ger DE-627 rakwb eng The origin of hyperfine structure in excited electronic states of NO"2 1985 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The analysis of measured hyperfine splittings in the ^2B"2 <- X^2A"1 spectrum of NO"2 shows that the major cause of the observed hfs splittings in the excited ^2B"2 state is vibronic coupling between a single level of the ^2B"2 state and many high lying vibrational levels of the X^2A"1 ground state. Only a minor part of the hfs splitting may be due to spin polarization of the core. These results agree with the simple MO picture of NO"2 which predicts no Fermi interaction type hfs in the pure ^2B"2 state. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Vedder, H.J. oth Persch, G. oth Foth, H.-J. oth in Chemical Physics Letters Amsterdam : Elsevier 114(1985), 2, Seite 125-132 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:114 year:1985 number:2 pages:125-132 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(85)85071-5 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 114 1985 2 125-132 |
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origin of hyperfine structure in excited electronic states of no"2 |
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The origin of hyperfine structure in excited electronic states of NO"2 |
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The analysis of measured hyperfine splittings in the ^2B"2 <- X^2A"1 spectrum of NO"2 shows that the major cause of the observed hfs splittings in the excited ^2B"2 state is vibronic coupling between a single level of the ^2B"2 state and many high lying vibrational levels of the X^2A"1 ground state. Only a minor part of the hfs splitting may be due to spin polarization of the core. These results agree with the simple MO picture of NO"2 which predicts no Fermi interaction type hfs in the pure ^2B"2 state. |
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The analysis of measured hyperfine splittings in the ^2B"2 <- X^2A"1 spectrum of NO"2 shows that the major cause of the observed hfs splittings in the excited ^2B"2 state is vibronic coupling between a single level of the ^2B"2 state and many high lying vibrational levels of the X^2A"1 ground state. Only a minor part of the hfs splitting may be due to spin polarization of the core. These results agree with the simple MO picture of NO"2 which predicts no Fermi interaction type hfs in the pure ^2B"2 state. |
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The analysis of measured hyperfine splittings in the ^2B"2 <- X^2A"1 spectrum of NO"2 shows that the major cause of the observed hfs splittings in the excited ^2B"2 state is vibronic coupling between a single level of the ^2B"2 state and many high lying vibrational levels of the X^2A"1 ground state. Only a minor part of the hfs splitting may be due to spin polarization of the core. These results agree with the simple MO picture of NO"2 which predicts no Fermi interaction type hfs in the pure ^2B"2 state. |
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