Microwave spectrum, dipole moment and structure of 1,1-difluorocyclohexane
From the analysis of the microwave rotational spectrum of 1,1-difluorocyclohexane in the frequency region 8-40 GHz the rotational constants (A = 3191.781, B = 1759.768, C = 1512.293 MHz), the centrifugal distortion coefficients (D"J = 124 x 10^-^4, D"J"K = 2.92 x 10^-^4, D"K = -8...
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| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1974 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Chemical Physics Letters - Amsterdam : Elsevier, 24(1974), 3, Seite 357-360 |
| Übergeordnetes Werk: |
volume:24 ; year:1974 ; number:3 ; pages:357-360 |
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NLEJ173799868 |
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| 245 | 1 | 0 | |a Microwave spectrum, dipole moment and structure of 1,1-difluorocyclohexane |
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| 520 | |a From the analysis of the microwave rotational spectrum of 1,1-difluorocyclohexane in the frequency region 8-40 GHz the rotational constants (A = 3191.781, B = 1759.768, C = 1512.293 MHz), the centrifugal distortion coefficients (D"J = 124 x 10^-^4, D"J"K = 2.92 x 10^-^4, D"K = -8.20 x 10^-^3) and the dipole moment and its components (μ = 2.556, μ"a = 2.415, μ"b = 0, μ"c = 0.837 debye) have been derived. Assuming that the CC and CH distances are the same as those of propane and that the ring structure in the chair form is symmetrical, the following structural parameters are obtained: CCC = 111.95^o, FCF = 108.68^o, C-F = 1.356 Å. | ||
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(DE-627)NLEJ173799868 (DE-599)GBVNLZ173799868 DE-627 ger DE-627 rakwb eng Microwave spectrum, dipole moment and structure of 1,1-difluorocyclohexane 1974 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier From the analysis of the microwave rotational spectrum of 1,1-difluorocyclohexane in the frequency region 8-40 GHz the rotational constants (A = 3191.781, B = 1759.768, C = 1512.293 MHz), the centrifugal distortion coefficients (D"J = 124 x 10^-^4, D"J"K = 2.92 x 10^-^4, D"K = -8.20 x 10^-^3) and the dipole moment and its components (μ = 2.556, μ"a = 2.415, μ"b = 0, μ"c = 0.837 debye) have been derived. Assuming that the CC and CH distances are the same as those of propane and that the ring structure in the chair form is symmetrical, the following structural parameters are obtained: CCC = 111.95^o, FCF = 108.68^o, C-F = 1.356 Å. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Damiani, D. oth Ferretti, L. oth in Chemical Physics Letters Amsterdam : Elsevier 24(1974), 3, Seite 357-360 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:24 year:1974 number:3 pages:357-360 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(74)85277-2 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 24 1974 3 357-360 |
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(DE-627)NLEJ173799868 (DE-599)GBVNLZ173799868 DE-627 ger DE-627 rakwb eng Microwave spectrum, dipole moment and structure of 1,1-difluorocyclohexane 1974 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier From the analysis of the microwave rotational spectrum of 1,1-difluorocyclohexane in the frequency region 8-40 GHz the rotational constants (A = 3191.781, B = 1759.768, C = 1512.293 MHz), the centrifugal distortion coefficients (D"J = 124 x 10^-^4, D"J"K = 2.92 x 10^-^4, D"K = -8.20 x 10^-^3) and the dipole moment and its components (μ = 2.556, μ"a = 2.415, μ"b = 0, μ"c = 0.837 debye) have been derived. Assuming that the CC and CH distances are the same as those of propane and that the ring structure in the chair form is symmetrical, the following structural parameters are obtained: CCC = 111.95^o, FCF = 108.68^o, C-F = 1.356 Å. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Damiani, D. oth Ferretti, L. oth in Chemical Physics Letters Amsterdam : Elsevier 24(1974), 3, Seite 357-360 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:24 year:1974 number:3 pages:357-360 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(74)85277-2 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 24 1974 3 357-360 |
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(DE-627)NLEJ173799868 (DE-599)GBVNLZ173799868 DE-627 ger DE-627 rakwb eng Microwave spectrum, dipole moment and structure of 1,1-difluorocyclohexane 1974 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier From the analysis of the microwave rotational spectrum of 1,1-difluorocyclohexane in the frequency region 8-40 GHz the rotational constants (A = 3191.781, B = 1759.768, C = 1512.293 MHz), the centrifugal distortion coefficients (D"J = 124 x 10^-^4, D"J"K = 2.92 x 10^-^4, D"K = -8.20 x 10^-^3) and the dipole moment and its components (μ = 2.556, μ"a = 2.415, μ"b = 0, μ"c = 0.837 debye) have been derived. Assuming that the CC and CH distances are the same as those of propane and that the ring structure in the chair form is symmetrical, the following structural parameters are obtained: CCC = 111.95^o, FCF = 108.68^o, C-F = 1.356 Å. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Damiani, D. oth Ferretti, L. oth in Chemical Physics Letters Amsterdam : Elsevier 24(1974), 3, Seite 357-360 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:24 year:1974 number:3 pages:357-360 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(74)85277-2 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 24 1974 3 357-360 |
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(DE-627)NLEJ173799868 (DE-599)GBVNLZ173799868 DE-627 ger DE-627 rakwb eng Microwave spectrum, dipole moment and structure of 1,1-difluorocyclohexane 1974 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier From the analysis of the microwave rotational spectrum of 1,1-difluorocyclohexane in the frequency region 8-40 GHz the rotational constants (A = 3191.781, B = 1759.768, C = 1512.293 MHz), the centrifugal distortion coefficients (D"J = 124 x 10^-^4, D"J"K = 2.92 x 10^-^4, D"K = -8.20 x 10^-^3) and the dipole moment and its components (μ = 2.556, μ"a = 2.415, μ"b = 0, μ"c = 0.837 debye) have been derived. Assuming that the CC and CH distances are the same as those of propane and that the ring structure in the chair form is symmetrical, the following structural parameters are obtained: CCC = 111.95^o, FCF = 108.68^o, C-F = 1.356 Å. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Damiani, D. oth Ferretti, L. oth in Chemical Physics Letters Amsterdam : Elsevier 24(1974), 3, Seite 357-360 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:24 year:1974 number:3 pages:357-360 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(74)85277-2 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 24 1974 3 357-360 |
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(DE-627)NLEJ173799868 (DE-599)GBVNLZ173799868 DE-627 ger DE-627 rakwb eng Microwave spectrum, dipole moment and structure of 1,1-difluorocyclohexane 1974 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier From the analysis of the microwave rotational spectrum of 1,1-difluorocyclohexane in the frequency region 8-40 GHz the rotational constants (A = 3191.781, B = 1759.768, C = 1512.293 MHz), the centrifugal distortion coefficients (D"J = 124 x 10^-^4, D"J"K = 2.92 x 10^-^4, D"K = -8.20 x 10^-^3) and the dipole moment and its components (μ = 2.556, μ"a = 2.415, μ"b = 0, μ"c = 0.837 debye) have been derived. Assuming that the CC and CH distances are the same as those of propane and that the ring structure in the chair form is symmetrical, the following structural parameters are obtained: CCC = 111.95^o, FCF = 108.68^o, C-F = 1.356 Å. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Damiani, D. oth Ferretti, L. oth in Chemical Physics Letters Amsterdam : Elsevier 24(1974), 3, Seite 357-360 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:24 year:1974 number:3 pages:357-360 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(74)85277-2 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 24 1974 3 357-360 |
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microwave spectrum, dipole moment and structure of 1,1-difluorocyclohexane |
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Microwave spectrum, dipole moment and structure of 1,1-difluorocyclohexane |
| abstract |
From the analysis of the microwave rotational spectrum of 1,1-difluorocyclohexane in the frequency region 8-40 GHz the rotational constants (A = 3191.781, B = 1759.768, C = 1512.293 MHz), the centrifugal distortion coefficients (D"J = 124 x 10^-^4, D"J"K = 2.92 x 10^-^4, D"K = -8.20 x 10^-^3) and the dipole moment and its components (μ = 2.556, μ"a = 2.415, μ"b = 0, μ"c = 0.837 debye) have been derived. Assuming that the CC and CH distances are the same as those of propane and that the ring structure in the chair form is symmetrical, the following structural parameters are obtained: CCC = 111.95^o, FCF = 108.68^o, C-F = 1.356 Å. |
| abstractGer |
From the analysis of the microwave rotational spectrum of 1,1-difluorocyclohexane in the frequency region 8-40 GHz the rotational constants (A = 3191.781, B = 1759.768, C = 1512.293 MHz), the centrifugal distortion coefficients (D"J = 124 x 10^-^4, D"J"K = 2.92 x 10^-^4, D"K = -8.20 x 10^-^3) and the dipole moment and its components (μ = 2.556, μ"a = 2.415, μ"b = 0, μ"c = 0.837 debye) have been derived. Assuming that the CC and CH distances are the same as those of propane and that the ring structure in the chair form is symmetrical, the following structural parameters are obtained: CCC = 111.95^o, FCF = 108.68^o, C-F = 1.356 Å. |
| abstract_unstemmed |
From the analysis of the microwave rotational spectrum of 1,1-difluorocyclohexane in the frequency region 8-40 GHz the rotational constants (A = 3191.781, B = 1759.768, C = 1512.293 MHz), the centrifugal distortion coefficients (D"J = 124 x 10^-^4, D"J"K = 2.92 x 10^-^4, D"K = -8.20 x 10^-^3) and the dipole moment and its components (μ = 2.556, μ"a = 2.415, μ"b = 0, μ"c = 0.837 debye) have been derived. Assuming that the CC and CH distances are the same as those of propane and that the ring structure in the chair form is symmetrical, the following structural parameters are obtained: CCC = 111.95^o, FCF = 108.68^o, C-F = 1.356 Å. |
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