High-pressure reactions in polyethylene films, a new development in matrix isolation. The photochemical reaction of Fe (CO)"5 with N"2 and the thermal reaction of Fe (CO)"4 (N"2) with H"2
A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N"2 or H"2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical r...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1993 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Chemical Physics Letters - Amsterdam : Elsevier, 212(1993), 6, Seite 611-616 |
| Übergeordnetes Werk: |
volume:212 ; year:1993 ; number:6 ; pages:611-616 |
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NLEJ173879063 |
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| 245 | 1 | 0 | |a High-pressure reactions in polyethylene films, a new development in matrix isolation. The photochemical reaction of Fe (CO)"5 with N"2 and the thermal reaction of Fe (CO)"4 (N"2) with H"2 |
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| 520 | |a A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N"2 or H"2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical reactions of Fe(CO)"5 in polyethylene film (PE) with N"2 and H"2 at 190 K to form Fe (CO)"4(N"2) and Fe (CO)"4H"2 respectively. IR spectra suggest that the N"2 group may occupy an equatorial rather than an axial position. Once formed, Fe (CO)"4(N"2) is shown to react thermally with H"2 at ~ 210 K to yield the dihydride compound, Fe (CO)"4H"2. | ||
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(DE-627)NLEJ173879063 (DE-599)GBVNLZ173879063 DE-627 ger DE-627 rakwb eng High-pressure reactions in polyethylene films, a new development in matrix isolation. The photochemical reaction of Fe (CO)"5 with N"2 and the thermal reaction of Fe (CO)"4 (N"2) with H"2 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N"2 or H"2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical reactions of Fe(CO)"5 in polyethylene film (PE) with N"2 and H"2 at 190 K to form Fe (CO)"4(N"2) and Fe (CO)"4H"2 respectively. IR spectra suggest that the N"2 group may occupy an equatorial rather than an axial position. Once formed, Fe (CO)"4(N"2) is shown to react thermally with H"2 at ~ 210 K to yield the dihydride compound, Fe (CO)"4H"2. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cooper, A.I. oth Poliakoff, M. oth in Chemical Physics Letters Amsterdam : Elsevier 212(1993), 6, Seite 611-616 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:212 year:1993 number:6 pages:611-616 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85493-8 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 212 1993 6 611-616 |
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(DE-627)NLEJ173879063 (DE-599)GBVNLZ173879063 DE-627 ger DE-627 rakwb eng High-pressure reactions in polyethylene films, a new development in matrix isolation. The photochemical reaction of Fe (CO)"5 with N"2 and the thermal reaction of Fe (CO)"4 (N"2) with H"2 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N"2 or H"2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical reactions of Fe(CO)"5 in polyethylene film (PE) with N"2 and H"2 at 190 K to form Fe (CO)"4(N"2) and Fe (CO)"4H"2 respectively. IR spectra suggest that the N"2 group may occupy an equatorial rather than an axial position. Once formed, Fe (CO)"4(N"2) is shown to react thermally with H"2 at ~ 210 K to yield the dihydride compound, Fe (CO)"4H"2. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cooper, A.I. oth Poliakoff, M. oth in Chemical Physics Letters Amsterdam : Elsevier 212(1993), 6, Seite 611-616 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:212 year:1993 number:6 pages:611-616 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85493-8 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 212 1993 6 611-616 |
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(DE-627)NLEJ173879063 (DE-599)GBVNLZ173879063 DE-627 ger DE-627 rakwb eng High-pressure reactions in polyethylene films, a new development in matrix isolation. The photochemical reaction of Fe (CO)"5 with N"2 and the thermal reaction of Fe (CO)"4 (N"2) with H"2 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N"2 or H"2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical reactions of Fe(CO)"5 in polyethylene film (PE) with N"2 and H"2 at 190 K to form Fe (CO)"4(N"2) and Fe (CO)"4H"2 respectively. IR spectra suggest that the N"2 group may occupy an equatorial rather than an axial position. Once formed, Fe (CO)"4(N"2) is shown to react thermally with H"2 at ~ 210 K to yield the dihydride compound, Fe (CO)"4H"2. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cooper, A.I. oth Poliakoff, M. oth in Chemical Physics Letters Amsterdam : Elsevier 212(1993), 6, Seite 611-616 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:212 year:1993 number:6 pages:611-616 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85493-8 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 212 1993 6 611-616 |
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(DE-627)NLEJ173879063 (DE-599)GBVNLZ173879063 DE-627 ger DE-627 rakwb eng High-pressure reactions in polyethylene films, a new development in matrix isolation. The photochemical reaction of Fe (CO)"5 with N"2 and the thermal reaction of Fe (CO)"4 (N"2) with H"2 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N"2 or H"2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical reactions of Fe(CO)"5 in polyethylene film (PE) with N"2 and H"2 at 190 K to form Fe (CO)"4(N"2) and Fe (CO)"4H"2 respectively. IR spectra suggest that the N"2 group may occupy an equatorial rather than an axial position. Once formed, Fe (CO)"4(N"2) is shown to react thermally with H"2 at ~ 210 K to yield the dihydride compound, Fe (CO)"4H"2. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cooper, A.I. oth Poliakoff, M. oth in Chemical Physics Letters Amsterdam : Elsevier 212(1993), 6, Seite 611-616 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:212 year:1993 number:6 pages:611-616 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85493-8 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 212 1993 6 611-616 |
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(DE-627)NLEJ173879063 (DE-599)GBVNLZ173879063 DE-627 ger DE-627 rakwb eng High-pressure reactions in polyethylene films, a new development in matrix isolation. The photochemical reaction of Fe (CO)"5 with N"2 and the thermal reaction of Fe (CO)"4 (N"2) with H"2 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N"2 or H"2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical reactions of Fe(CO)"5 in polyethylene film (PE) with N"2 and H"2 at 190 K to form Fe (CO)"4(N"2) and Fe (CO)"4H"2 respectively. IR spectra suggest that the N"2 group may occupy an equatorial rather than an axial position. Once formed, Fe (CO)"4(N"2) is shown to react thermally with H"2 at ~ 210 K to yield the dihydride compound, Fe (CO)"4H"2. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cooper, A.I. oth Poliakoff, M. oth in Chemical Physics Letters Amsterdam : Elsevier 212(1993), 6, Seite 611-616 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:212 year:1993 number:6 pages:611-616 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85493-8 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 212 1993 6 611-616 |
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high-pressure reactions in polyethylene films, a new development in matrix isolation. the photochemical reaction of fe (co)"5 with n"2 and the thermal reaction of fe (co)"4 (n"2) with h"2 |
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High-pressure reactions in polyethylene films, a new development in matrix isolation. The photochemical reaction of Fe (CO)"5 with N"2 and the thermal reaction of Fe (CO)"4 (N"2) with H"2 |
| abstract |
A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N"2 or H"2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical reactions of Fe(CO)"5 in polyethylene film (PE) with N"2 and H"2 at 190 K to form Fe (CO)"4(N"2) and Fe (CO)"4H"2 respectively. IR spectra suggest that the N"2 group may occupy an equatorial rather than an axial position. Once formed, Fe (CO)"4(N"2) is shown to react thermally with H"2 at ~ 210 K to yield the dihydride compound, Fe (CO)"4H"2. |
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A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N"2 or H"2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical reactions of Fe(CO)"5 in polyethylene film (PE) with N"2 and H"2 at 190 K to form Fe (CO)"4(N"2) and Fe (CO)"4H"2 respectively. IR spectra suggest that the N"2 group may occupy an equatorial rather than an axial position. Once formed, Fe (CO)"4(N"2) is shown to react thermally with H"2 at ~ 210 K to yield the dihydride compound, Fe (CO)"4H"2. |
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A new miniature high-pressure cell has been developed for the spectroscopic study of reactions between organometallic compounds impregnated into polymer films and gases such as N"2 or H"2 at any temperature between ambient and 20 K. The use of the cell is illustrated by the photochemical reactions of Fe(CO)"5 in polyethylene film (PE) with N"2 and H"2 at 190 K to form Fe (CO)"4(N"2) and Fe (CO)"4H"2 respectively. IR spectra suggest that the N"2 group may occupy an equatorial rather than an axial position. Once formed, Fe (CO)"4(N"2) is shown to react thermally with H"2 at ~ 210 K to yield the dihydride compound, Fe (CO)"4H"2. |
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