Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η^5-C"5Me"5)Ir(CO)"2 and the effect on CH activation
Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3...
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1993 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Chemical Physics Letters - Amsterdam : Elsevier, 206(1993), 1-4, Seite 175-180 |
| Übergeordnetes Werk: |
volume:206 ; year:1993 ; number:1-4 ; pages:175-180 |
| Links: |
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| 520 | |a Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3)"3C). At 200 K, the equilibrium between Cp*Ip(CO)"2 and the hydrogen-bonded complex, Cp*Ir(CO)"2...HOR"F, is frozen out and can be disturbed photochemically, because Cp*Ir(CO)"2 is more efficient than Cp*Ir(CO)"2...HOR"F for CH activation of polyethylene. | ||
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(DE-627)NLEJ173885276 (DE-599)GBVNLZ173885276 DE-627 ger DE-627 rakwb eng Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η^5-C"5Me"5)Ir(CO)"2 and the effect on CH activation 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3)"3C). At 200 K, the equilibrium between Cp*Ip(CO)"2 and the hydrogen-bonded complex, Cp*Ir(CO)"2...HOR"F, is frozen out and can be disturbed photochemically, because Cp*Ir(CO)"2 is more efficient than Cp*Ir(CO)"2...HOR"F for CH activation of polyethylene. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cooper, A.I. oth Kazarian, S.G. oth Poliakoff, M. oth in Chemical Physics Letters Amsterdam : Elsevier 206(1993), 1-4, Seite 175-180 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:206 year:1993 number:1-4 pages:175-180 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85537-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 206 1993 1-4 175-180 |
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(DE-627)NLEJ173885276 (DE-599)GBVNLZ173885276 DE-627 ger DE-627 rakwb eng Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η^5-C"5Me"5)Ir(CO)"2 and the effect on CH activation 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3)"3C). At 200 K, the equilibrium between Cp*Ip(CO)"2 and the hydrogen-bonded complex, Cp*Ir(CO)"2...HOR"F, is frozen out and can be disturbed photochemically, because Cp*Ir(CO)"2 is more efficient than Cp*Ir(CO)"2...HOR"F for CH activation of polyethylene. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cooper, A.I. oth Kazarian, S.G. oth Poliakoff, M. oth in Chemical Physics Letters Amsterdam : Elsevier 206(1993), 1-4, Seite 175-180 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:206 year:1993 number:1-4 pages:175-180 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85537-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 206 1993 1-4 175-180 |
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(DE-627)NLEJ173885276 (DE-599)GBVNLZ173885276 DE-627 ger DE-627 rakwb eng Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η^5-C"5Me"5)Ir(CO)"2 and the effect on CH activation 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3)"3C). At 200 K, the equilibrium between Cp*Ip(CO)"2 and the hydrogen-bonded complex, Cp*Ir(CO)"2...HOR"F, is frozen out and can be disturbed photochemically, because Cp*Ir(CO)"2 is more efficient than Cp*Ir(CO)"2...HOR"F for CH activation of polyethylene. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cooper, A.I. oth Kazarian, S.G. oth Poliakoff, M. oth in Chemical Physics Letters Amsterdam : Elsevier 206(1993), 1-4, Seite 175-180 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:206 year:1993 number:1-4 pages:175-180 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85537-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 206 1993 1-4 175-180 |
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(DE-627)NLEJ173885276 (DE-599)GBVNLZ173885276 DE-627 ger DE-627 rakwb eng Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η^5-C"5Me"5)Ir(CO)"2 and the effect on CH activation 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3)"3C). At 200 K, the equilibrium between Cp*Ip(CO)"2 and the hydrogen-bonded complex, Cp*Ir(CO)"2...HOR"F, is frozen out and can be disturbed photochemically, because Cp*Ir(CO)"2 is more efficient than Cp*Ir(CO)"2...HOR"F for CH activation of polyethylene. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cooper, A.I. oth Kazarian, S.G. oth Poliakoff, M. oth in Chemical Physics Letters Amsterdam : Elsevier 206(1993), 1-4, Seite 175-180 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:206 year:1993 number:1-4 pages:175-180 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85537-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 206 1993 1-4 175-180 |
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(DE-627)NLEJ173885276 (DE-599)GBVNLZ173885276 DE-627 ger DE-627 rakwb eng Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η^5-C"5Me"5)Ir(CO)"2 and the effect on CH activation 1993 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3)"3C). At 200 K, the equilibrium between Cp*Ip(CO)"2 and the hydrogen-bonded complex, Cp*Ir(CO)"2...HOR"F, is frozen out and can be disturbed photochemically, because Cp*Ir(CO)"2 is more efficient than Cp*Ir(CO)"2...HOR"F for CH activation of polyethylene. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cooper, A.I. oth Kazarian, S.G. oth Poliakoff, M. oth in Chemical Physics Letters Amsterdam : Elsevier 206(1993), 1-4, Seite 175-180 (DE-627)NLEJ17363009X (DE-600)1466293-0 0009-2614 nnns volume:206 year:1993 number:1-4 pages:175-180 http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85537-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 206 1993 1-4 175-180 |
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supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η^5-c"5me"5)ir(co)"2 and the effect on ch activation |
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Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η^5-C"5Me"5)Ir(CO)"2 and the effect on CH activation |
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Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3)"3C). At 200 K, the equilibrium between Cp*Ip(CO)"2 and the hydrogen-bonded complex, Cp*Ir(CO)"2...HOR"F, is frozen out and can be disturbed photochemically, because Cp*Ir(CO)"2 is more efficient than Cp*Ir(CO)"2...HOR"F for CH activation of polyethylene. |
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Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3)"3C). At 200 K, the equilibrium between Cp*Ip(CO)"2 and the hydrogen-bonded complex, Cp*Ir(CO)"2...HOR"F, is frozen out and can be disturbed photochemically, because Cp*Ir(CO)"2 is more efficient than Cp*Ir(CO)"2...HOR"F for CH activation of polyethylene. |
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Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3)"3C). At 200 K, the equilibrium between Cp*Ip(CO)"2 and the hydrogen-bonded complex, Cp*Ir(CO)"2...HOR"F, is frozen out and can be disturbed photochemically, because Cp*Ir(CO)"2 is more efficient than Cp*Ir(CO)"2...HOR"F for CH activation of polyethylene. |
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Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η^5-C"5Me"5)Ir(CO)"2 and the effect on CH activation |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ173885276</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230505185541.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070505s1993 xx |||||o 00| ||eng c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ173885276</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVNLZ173885276</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η^5-C"5Me"5)Ir(CO)"2 and the effect on CH activation</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1993</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Polyethylene (PE) film is used as a matrix for studying temperature-dependent equilibria by IR spectroscopy; the film is impregnated with Cp*Ir(CO)"2 (Cp*=η^5-C"5Me"5) using supercritical CO"2 and subsequently saturated with HOR"F (R"F=(CF"3)"2CH or (CF"3)"3C). At 200 K, the equilibrium between Cp*Ip(CO)"2 and the hydrogen-bonded complex, Cp*Ir(CO)"2...HOR"F, is frozen out and can be disturbed photochemically, because Cp*Ir(CO)"2 is more efficient than Cp*Ir(CO)"2...HOR"F for CH activation of polyethylene.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Elsevier Journal Backfiles on ScienceDirect 1907 - 2002</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cooper, A.I.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kazarian, S.G.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Poliakoff, M.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Chemical Physics Letters</subfield><subfield code="d">Amsterdam : Elsevier</subfield><subfield code="g">206(1993), 1-4, Seite 175-180</subfield><subfield code="w">(DE-627)NLEJ17363009X</subfield><subfield code="w">(DE-600)1466293-0</subfield><subfield code="x">0009-2614</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:206</subfield><subfield code="g">year:1993</subfield><subfield code="g">number:1-4</subfield><subfield code="g">pages:175-180</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://linkinghub.elsevier.com/retrieve/pii/0009-2614(93)85537-X</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_H</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-SDJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">206</subfield><subfield code="j">1993</subfield><subfield code="e">1-4</subfield><subfield code="h">175-180</subfield></datafield></record></collection>
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