Comparative study of the reduction kinetics of magnetites and derived ammonia synthesis catalysts
A study of the reduction behaviour of both natural and synthetic magnetite, as ammonia synthesis catalyst precursors, as well as of the synthesized catalysts, was performed by differential thermal analysis and thermogravimetric analysis in hydrogen under nonisothermal conditions. The presence of pro...
Ausführliche Beschreibung
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Englisch |
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1990 |
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Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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Übergeordnetes Werk: |
in: Thermochimica Acta - Amsterdam : Elsevier, 173(1990), Seite 71-79 |
Übergeordnetes Werk: |
volume:173 ; year:1990 ; pages:71-79 |
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520 | |a A study of the reduction behaviour of both natural and synthetic magnetite, as ammonia synthesis catalyst precursors, as well as of the synthesized catalysts, was performed by differential thermal analysis and thermogravimetric analysis in hydrogen under nonisothermal conditions. The presence of promoters in the synthesized catalysts caused shifting of the temperatures of the beginning and end of the reduction toward higher values relative to those of the starting magnetites. The close values of the activation energy of the reduction (E) indicated the existence of the same mechanism of reduction of the catalysts and the precursors. Wustite was not detected by the applied Mossbauer spectroscopic measurements. | ||
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700 | 1 | |a Klisurski, D.G. |4 oth | |
700 | 1 | |a Petranovic, N.A. |4 oth | |
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(DE-627)NLEJ174670621 (DE-599)GBVNLZ174670621 DE-627 ger DE-627 rakwb eng Comparative study of the reduction kinetics of magnetites and derived ammonia synthesis catalysts 1990 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A study of the reduction behaviour of both natural and synthetic magnetite, as ammonia synthesis catalyst precursors, as well as of the synthesized catalysts, was performed by differential thermal analysis and thermogravimetric analysis in hydrogen under nonisothermal conditions. The presence of promoters in the synthesized catalysts caused shifting of the temperatures of the beginning and end of the reduction toward higher values relative to those of the starting magnetites. The close values of the activation energy of the reduction (E) indicated the existence of the same mechanism of reduction of the catalysts and the precursors. Wustite was not detected by the applied Mossbauer spectroscopic measurements. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Bogdanov, S.S. oth Aleksic, B.D. oth Mitov, I.G. oth Klisurski, D.G. oth Petranovic, N.A. oth in Thermochimica Acta Amsterdam : Elsevier 173(1990), Seite 71-79 (DE-627)NLEJ174595298 (DE-600)1500974-9 0040-6031 nnns volume:173 year:1990 pages:71-79 http://linkinghub.elsevier.com/retrieve/pii/0040-6031(90)80591-L GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 173 1990 71-79 |
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(DE-627)NLEJ174670621 (DE-599)GBVNLZ174670621 DE-627 ger DE-627 rakwb eng Comparative study of the reduction kinetics of magnetites and derived ammonia synthesis catalysts 1990 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A study of the reduction behaviour of both natural and synthetic magnetite, as ammonia synthesis catalyst precursors, as well as of the synthesized catalysts, was performed by differential thermal analysis and thermogravimetric analysis in hydrogen under nonisothermal conditions. The presence of promoters in the synthesized catalysts caused shifting of the temperatures of the beginning and end of the reduction toward higher values relative to those of the starting magnetites. The close values of the activation energy of the reduction (E) indicated the existence of the same mechanism of reduction of the catalysts and the precursors. Wustite was not detected by the applied Mossbauer spectroscopic measurements. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Bogdanov, S.S. oth Aleksic, B.D. oth Mitov, I.G. oth Klisurski, D.G. oth Petranovic, N.A. oth in Thermochimica Acta Amsterdam : Elsevier 173(1990), Seite 71-79 (DE-627)NLEJ174595298 (DE-600)1500974-9 0040-6031 nnns volume:173 year:1990 pages:71-79 http://linkinghub.elsevier.com/retrieve/pii/0040-6031(90)80591-L GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 173 1990 71-79 |
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(DE-627)NLEJ174670621 (DE-599)GBVNLZ174670621 DE-627 ger DE-627 rakwb eng Comparative study of the reduction kinetics of magnetites and derived ammonia synthesis catalysts 1990 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A study of the reduction behaviour of both natural and synthetic magnetite, as ammonia synthesis catalyst precursors, as well as of the synthesized catalysts, was performed by differential thermal analysis and thermogravimetric analysis in hydrogen under nonisothermal conditions. The presence of promoters in the synthesized catalysts caused shifting of the temperatures of the beginning and end of the reduction toward higher values relative to those of the starting magnetites. The close values of the activation energy of the reduction (E) indicated the existence of the same mechanism of reduction of the catalysts and the precursors. Wustite was not detected by the applied Mossbauer spectroscopic measurements. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Bogdanov, S.S. oth Aleksic, B.D. oth Mitov, I.G. oth Klisurski, D.G. oth Petranovic, N.A. oth in Thermochimica Acta Amsterdam : Elsevier 173(1990), Seite 71-79 (DE-627)NLEJ174595298 (DE-600)1500974-9 0040-6031 nnns volume:173 year:1990 pages:71-79 http://linkinghub.elsevier.com/retrieve/pii/0040-6031(90)80591-L GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 173 1990 71-79 |
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(DE-627)NLEJ174670621 (DE-599)GBVNLZ174670621 DE-627 ger DE-627 rakwb eng Comparative study of the reduction kinetics of magnetites and derived ammonia synthesis catalysts 1990 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A study of the reduction behaviour of both natural and synthetic magnetite, as ammonia synthesis catalyst precursors, as well as of the synthesized catalysts, was performed by differential thermal analysis and thermogravimetric analysis in hydrogen under nonisothermal conditions. The presence of promoters in the synthesized catalysts caused shifting of the temperatures of the beginning and end of the reduction toward higher values relative to those of the starting magnetites. The close values of the activation energy of the reduction (E) indicated the existence of the same mechanism of reduction of the catalysts and the precursors. Wustite was not detected by the applied Mossbauer spectroscopic measurements. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Bogdanov, S.S. oth Aleksic, B.D. oth Mitov, I.G. oth Klisurski, D.G. oth Petranovic, N.A. oth in Thermochimica Acta Amsterdam : Elsevier 173(1990), Seite 71-79 (DE-627)NLEJ174595298 (DE-600)1500974-9 0040-6031 nnns volume:173 year:1990 pages:71-79 http://linkinghub.elsevier.com/retrieve/pii/0040-6031(90)80591-L GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 173 1990 71-79 |
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(DE-627)NLEJ174670621 (DE-599)GBVNLZ174670621 DE-627 ger DE-627 rakwb eng Comparative study of the reduction kinetics of magnetites and derived ammonia synthesis catalysts 1990 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A study of the reduction behaviour of both natural and synthetic magnetite, as ammonia synthesis catalyst precursors, as well as of the synthesized catalysts, was performed by differential thermal analysis and thermogravimetric analysis in hydrogen under nonisothermal conditions. The presence of promoters in the synthesized catalysts caused shifting of the temperatures of the beginning and end of the reduction toward higher values relative to those of the starting magnetites. The close values of the activation energy of the reduction (E) indicated the existence of the same mechanism of reduction of the catalysts and the precursors. Wustite was not detected by the applied Mossbauer spectroscopic measurements. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Bogdanov, S.S. oth Aleksic, B.D. oth Mitov, I.G. oth Klisurski, D.G. oth Petranovic, N.A. oth in Thermochimica Acta Amsterdam : Elsevier 173(1990), Seite 71-79 (DE-627)NLEJ174595298 (DE-600)1500974-9 0040-6031 nnns volume:173 year:1990 pages:71-79 http://linkinghub.elsevier.com/retrieve/pii/0040-6031(90)80591-L GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 173 1990 71-79 |
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comparative study of the reduction kinetics of magnetites and derived ammonia synthesis catalysts |
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Comparative study of the reduction kinetics of magnetites and derived ammonia synthesis catalysts |
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A study of the reduction behaviour of both natural and synthetic magnetite, as ammonia synthesis catalyst precursors, as well as of the synthesized catalysts, was performed by differential thermal analysis and thermogravimetric analysis in hydrogen under nonisothermal conditions. The presence of promoters in the synthesized catalysts caused shifting of the temperatures of the beginning and end of the reduction toward higher values relative to those of the starting magnetites. The close values of the activation energy of the reduction (E) indicated the existence of the same mechanism of reduction of the catalysts and the precursors. Wustite was not detected by the applied Mossbauer spectroscopic measurements. |
abstractGer |
A study of the reduction behaviour of both natural and synthetic magnetite, as ammonia synthesis catalyst precursors, as well as of the synthesized catalysts, was performed by differential thermal analysis and thermogravimetric analysis in hydrogen under nonisothermal conditions. The presence of promoters in the synthesized catalysts caused shifting of the temperatures of the beginning and end of the reduction toward higher values relative to those of the starting magnetites. The close values of the activation energy of the reduction (E) indicated the existence of the same mechanism of reduction of the catalysts and the precursors. Wustite was not detected by the applied Mossbauer spectroscopic measurements. |
abstract_unstemmed |
A study of the reduction behaviour of both natural and synthetic magnetite, as ammonia synthesis catalyst precursors, as well as of the synthesized catalysts, was performed by differential thermal analysis and thermogravimetric analysis in hydrogen under nonisothermal conditions. The presence of promoters in the synthesized catalysts caused shifting of the temperatures of the beginning and end of the reduction toward higher values relative to those of the starting magnetites. The close values of the activation energy of the reduction (E) indicated the existence of the same mechanism of reduction of the catalysts and the precursors. Wustite was not detected by the applied Mossbauer spectroscopic measurements. |
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Comparative study of the reduction kinetics of magnetites and derived ammonia synthesis catalysts |
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