Synthesis and crystal structure of potassium tetranitrato palladate(II)
K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. Th...
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E-Artikel |
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Englisch |
| Erschienen: |
1986 |
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Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Inorganica Chimica Acta - Amsterdam : Elsevier, 114(1986), 1, Seite 71-74 |
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volume:114 ; year:1986 ; number:1 ; pages:71-74 |
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| 520 | |a K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. The structure contains discrete complexes of [Pd(NO"3)"4]^2^- with pseudosymmetry C4. Pd coordinates four oxygens from different unidentate nitrato groups. The average Pd-O distance is 2.000(7) Å. The coordination around Pd is distorted square-planar, with Pd situated 0.139 A above the plane through the four coordinated oxygens. Similar to [Pt(NO"3)"4]^2^-, but in contrast with [Au(NO"3)"4]^-, all four nitrato ligands are situated on the same side of the coordination plane forming a basket-like structure. This is probably due to interactions between the non-coordinated oxygens of the nitrato ligands and suitably located potassium ions. Comparison with the structure of cis-[Pd- (NO"3)"2(DMSO)"2] indicates strong ground-state trans- influence of dimethyl sulfoxide in palladium complexes. | ||
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(DE-627)NLEJ174819196 (DE-599)GBVNLZ174819196 DE-627 ger DE-627 rakwb eng Synthesis and crystal structure of potassium tetranitrato palladate(II) 1986 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. The structure contains discrete complexes of [Pd(NO"3)"4]^2^- with pseudosymmetry C4. Pd coordinates four oxygens from different unidentate nitrato groups. The average Pd-O distance is 2.000(7) Å. The coordination around Pd is distorted square-planar, with Pd situated 0.139 A above the plane through the four coordinated oxygens. Similar to [Pt(NO"3)"4]^2^-, but in contrast with [Au(NO"3)"4]^-, all four nitrato ligands are situated on the same side of the coordination plane forming a basket-like structure. This is probably due to interactions between the non-coordinated oxygens of the nitrato ligands and suitably located potassium ions. Comparison with the structure of cis-[Pd- (NO"3)"2(DMSO)"2] indicates strong ground-state trans- influence of dimethyl sulfoxide in palladium complexes. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Elding, L.I. oth Noren, B. oth Oskarsson, Å. oth in Inorganica Chimica Acta Amsterdam : Elsevier 114(1986), 1, Seite 71-74 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:114 year:1986 number:1 pages:71-74 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)84591-0 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 114 1986 1 71-74 |
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(DE-627)NLEJ174819196 (DE-599)GBVNLZ174819196 DE-627 ger DE-627 rakwb eng Synthesis and crystal structure of potassium tetranitrato palladate(II) 1986 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. The structure contains discrete complexes of [Pd(NO"3)"4]^2^- with pseudosymmetry C4. Pd coordinates four oxygens from different unidentate nitrato groups. The average Pd-O distance is 2.000(7) Å. The coordination around Pd is distorted square-planar, with Pd situated 0.139 A above the plane through the four coordinated oxygens. Similar to [Pt(NO"3)"4]^2^-, but in contrast with [Au(NO"3)"4]^-, all four nitrato ligands are situated on the same side of the coordination plane forming a basket-like structure. This is probably due to interactions between the non-coordinated oxygens of the nitrato ligands and suitably located potassium ions. Comparison with the structure of cis-[Pd- (NO"3)"2(DMSO)"2] indicates strong ground-state trans- influence of dimethyl sulfoxide in palladium complexes. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Elding, L.I. oth Noren, B. oth Oskarsson, Å. oth in Inorganica Chimica Acta Amsterdam : Elsevier 114(1986), 1, Seite 71-74 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:114 year:1986 number:1 pages:71-74 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)84591-0 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 114 1986 1 71-74 |
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(DE-627)NLEJ174819196 (DE-599)GBVNLZ174819196 DE-627 ger DE-627 rakwb eng Synthesis and crystal structure of potassium tetranitrato palladate(II) 1986 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. The structure contains discrete complexes of [Pd(NO"3)"4]^2^- with pseudosymmetry C4. Pd coordinates four oxygens from different unidentate nitrato groups. The average Pd-O distance is 2.000(7) Å. The coordination around Pd is distorted square-planar, with Pd situated 0.139 A above the plane through the four coordinated oxygens. Similar to [Pt(NO"3)"4]^2^-, but in contrast with [Au(NO"3)"4]^-, all four nitrato ligands are situated on the same side of the coordination plane forming a basket-like structure. This is probably due to interactions between the non-coordinated oxygens of the nitrato ligands and suitably located potassium ions. Comparison with the structure of cis-[Pd- (NO"3)"2(DMSO)"2] indicates strong ground-state trans- influence of dimethyl sulfoxide in palladium complexes. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Elding, L.I. oth Noren, B. oth Oskarsson, Å. oth in Inorganica Chimica Acta Amsterdam : Elsevier 114(1986), 1, Seite 71-74 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:114 year:1986 number:1 pages:71-74 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)84591-0 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 114 1986 1 71-74 |
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(DE-627)NLEJ174819196 (DE-599)GBVNLZ174819196 DE-627 ger DE-627 rakwb eng Synthesis and crystal structure of potassium tetranitrato palladate(II) 1986 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. The structure contains discrete complexes of [Pd(NO"3)"4]^2^- with pseudosymmetry C4. Pd coordinates four oxygens from different unidentate nitrato groups. The average Pd-O distance is 2.000(7) Å. The coordination around Pd is distorted square-planar, with Pd situated 0.139 A above the plane through the four coordinated oxygens. Similar to [Pt(NO"3)"4]^2^-, but in contrast with [Au(NO"3)"4]^-, all four nitrato ligands are situated on the same side of the coordination plane forming a basket-like structure. This is probably due to interactions between the non-coordinated oxygens of the nitrato ligands and suitably located potassium ions. Comparison with the structure of cis-[Pd- (NO"3)"2(DMSO)"2] indicates strong ground-state trans- influence of dimethyl sulfoxide in palladium complexes. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Elding, L.I. oth Noren, B. oth Oskarsson, Å. oth in Inorganica Chimica Acta Amsterdam : Elsevier 114(1986), 1, Seite 71-74 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:114 year:1986 number:1 pages:71-74 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)84591-0 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 114 1986 1 71-74 |
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(DE-627)NLEJ174819196 (DE-599)GBVNLZ174819196 DE-627 ger DE-627 rakwb eng Synthesis and crystal structure of potassium tetranitrato palladate(II) 1986 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. The structure contains discrete complexes of [Pd(NO"3)"4]^2^- with pseudosymmetry C4. Pd coordinates four oxygens from different unidentate nitrato groups. The average Pd-O distance is 2.000(7) Å. The coordination around Pd is distorted square-planar, with Pd situated 0.139 A above the plane through the four coordinated oxygens. Similar to [Pt(NO"3)"4]^2^-, but in contrast with [Au(NO"3)"4]^-, all four nitrato ligands are situated on the same side of the coordination plane forming a basket-like structure. This is probably due to interactions between the non-coordinated oxygens of the nitrato ligands and suitably located potassium ions. Comparison with the structure of cis-[Pd- (NO"3)"2(DMSO)"2] indicates strong ground-state trans- influence of dimethyl sulfoxide in palladium complexes. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Elding, L.I. oth Noren, B. oth Oskarsson, Å. oth in Inorganica Chimica Acta Amsterdam : Elsevier 114(1986), 1, Seite 71-74 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:114 year:1986 number:1 pages:71-74 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)84591-0 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 114 1986 1 71-74 |
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Synthesis and crystal structure of potassium tetranitrato palladate(II) |
| abstract |
K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. The structure contains discrete complexes of [Pd(NO"3)"4]^2^- with pseudosymmetry C4. Pd coordinates four oxygens from different unidentate nitrato groups. The average Pd-O distance is 2.000(7) Å. The coordination around Pd is distorted square-planar, with Pd situated 0.139 A above the plane through the four coordinated oxygens. Similar to [Pt(NO"3)"4]^2^-, but in contrast with [Au(NO"3)"4]^-, all four nitrato ligands are situated on the same side of the coordination plane forming a basket-like structure. This is probably due to interactions between the non-coordinated oxygens of the nitrato ligands and suitably located potassium ions. Comparison with the structure of cis-[Pd- (NO"3)"2(DMSO)"2] indicates strong ground-state trans- influence of dimethyl sulfoxide in palladium complexes. |
| abstractGer |
K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. The structure contains discrete complexes of [Pd(NO"3)"4]^2^- with pseudosymmetry C4. Pd coordinates four oxygens from different unidentate nitrato groups. The average Pd-O distance is 2.000(7) Å. The coordination around Pd is distorted square-planar, with Pd situated 0.139 A above the plane through the four coordinated oxygens. Similar to [Pt(NO"3)"4]^2^-, but in contrast with [Au(NO"3)"4]^-, all four nitrato ligands are situated on the same side of the coordination plane forming a basket-like structure. This is probably due to interactions between the non-coordinated oxygens of the nitrato ligands and suitably located potassium ions. Comparison with the structure of cis-[Pd- (NO"3)"2(DMSO)"2] indicates strong ground-state trans- influence of dimethyl sulfoxide in palladium complexes. |
| abstract_unstemmed |
K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. The structure contains discrete complexes of [Pd(NO"3)"4]^2^- with pseudosymmetry C4. Pd coordinates four oxygens from different unidentate nitrato groups. The average Pd-O distance is 2.000(7) Å. The coordination around Pd is distorted square-planar, with Pd situated 0.139 A above the plane through the four coordinated oxygens. Similar to [Pt(NO"3)"4]^2^-, but in contrast with [Au(NO"3)"4]^-, all four nitrato ligands are situated on the same side of the coordination plane forming a basket-like structure. This is probably due to interactions between the non-coordinated oxygens of the nitrato ligands and suitably located potassium ions. Comparison with the structure of cis-[Pd- (NO"3)"2(DMSO)"2] indicates strong ground-state trans- influence of dimethyl sulfoxide in palladium complexes. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ174819196</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20210705223206.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070505s1986 xx |||||o 00| ||eng c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ174819196</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVNLZ174819196</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis and crystal structure of potassium tetranitrato palladate(II)</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1986</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">K"2 [Pd(NO"3)"4] has been prepared and its crystal structure determined by use of a CAD-4 diffractometer with monochromatic Mo Kα radiation. The space group is P2"1/c with Z = 4; a= 7.940(2); b = 15.469(4); c = 9.453(2) Å; β = 91.10(3)^o. The refinement converged to R = 0.023. The structure contains discrete complexes of [Pd(NO"3)"4]^2^- with pseudosymmetry C4. Pd coordinates four oxygens from different unidentate nitrato groups. The average Pd-O distance is 2.000(7) Å. The coordination around Pd is distorted square-planar, with Pd situated 0.139 A above the plane through the four coordinated oxygens. Similar to [Pt(NO"3)"4]^2^-, but in contrast with [Au(NO"3)"4]^-, all four nitrato ligands are situated on the same side of the coordination plane forming a basket-like structure. This is probably due to interactions between the non-coordinated oxygens of the nitrato ligands and suitably located potassium ions. Comparison with the structure of cis-[Pd- (NO"3)"2(DMSO)"2] indicates strong ground-state trans- influence of dimethyl sulfoxide in palladium complexes.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Elsevier Journal Backfiles on ScienceDirect 1907 - 2002</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Elding, L.I.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Noren, B.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Oskarsson, Å.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Inorganica Chimica Acta</subfield><subfield code="d">Amsterdam : Elsevier</subfield><subfield code="g">114(1986), 1, Seite 71-74</subfield><subfield code="w">(DE-627)NLEJ174799519</subfield><subfield code="w">(DE-600)1484441-2</subfield><subfield code="x">0020-1693</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:114</subfield><subfield code="g">year:1986</subfield><subfield code="g">number:1</subfield><subfield code="g">pages:71-74</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)84591-0</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_H</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-SDJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">114</subfield><subfield code="j">1986</subfield><subfield code="e">1</subfield><subfield code="h">71-74</subfield></datafield></record></collection>
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