Synthesis and characterization of 1,6,11-triazacyclopentadecane and its zinc(II) complex
A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(I...
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1991 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Inorganica Chimica Acta - Amsterdam : Elsevier, 184(1991), 2, Seite 197-201 |
| Übergeordnetes Werk: |
volume:184 ; year:1991 ; number:2 ; pages:197-201 |
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| 520 | |a A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(II) and Cu(II) ions. The ^1H and ^1^3C NMR spectra indicated that the zinc complex is stable in N,N-dimethylformamide and formulated as [Zn(tacpd)Cl]"2[ZnCl"4] in which [Zn(tacpd)Cl]^+ assumes a tetrahedral structure formed by the chloride ion and three nitrogens of tacpd. | ||
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(DE-627)NLEJ174865988 (DE-599)GBVNLZ174865988 DE-627 ger DE-627 rakwb eng Synthesis and characterization of 1,6,11-triazacyclopentadecane and its zinc(II) complex 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(II) and Cu(II) ions. The ^1H and ^1^3C NMR spectra indicated that the zinc complex is stable in N,N-dimethylformamide and formulated as [Zn(tacpd)Cl]"2[ZnCl"4] in which [Zn(tacpd)Cl]^+ assumes a tetrahedral structure formed by the chloride ion and three nitrogens of tacpd. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Ida, K. oth Okawa, H. oth Sakiyama, H. oth Kodera, M. oth Kida, S. oth Murase, I. oth in Inorganica Chimica Acta Amsterdam : Elsevier 184(1991), 2, Seite 197-201 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:184 year:1991 number:2 pages:197-201 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)85071-9 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 184 1991 2 197-201 |
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(DE-627)NLEJ174865988 (DE-599)GBVNLZ174865988 DE-627 ger DE-627 rakwb eng Synthesis and characterization of 1,6,11-triazacyclopentadecane and its zinc(II) complex 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(II) and Cu(II) ions. The ^1H and ^1^3C NMR spectra indicated that the zinc complex is stable in N,N-dimethylformamide and formulated as [Zn(tacpd)Cl]"2[ZnCl"4] in which [Zn(tacpd)Cl]^+ assumes a tetrahedral structure formed by the chloride ion and three nitrogens of tacpd. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Ida, K. oth Okawa, H. oth Sakiyama, H. oth Kodera, M. oth Kida, S. oth Murase, I. oth in Inorganica Chimica Acta Amsterdam : Elsevier 184(1991), 2, Seite 197-201 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:184 year:1991 number:2 pages:197-201 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)85071-9 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 184 1991 2 197-201 |
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(DE-627)NLEJ174865988 (DE-599)GBVNLZ174865988 DE-627 ger DE-627 rakwb eng Synthesis and characterization of 1,6,11-triazacyclopentadecane and its zinc(II) complex 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(II) and Cu(II) ions. The ^1H and ^1^3C NMR spectra indicated that the zinc complex is stable in N,N-dimethylformamide and formulated as [Zn(tacpd)Cl]"2[ZnCl"4] in which [Zn(tacpd)Cl]^+ assumes a tetrahedral structure formed by the chloride ion and three nitrogens of tacpd. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Ida, K. oth Okawa, H. oth Sakiyama, H. oth Kodera, M. oth Kida, S. oth Murase, I. oth in Inorganica Chimica Acta Amsterdam : Elsevier 184(1991), 2, Seite 197-201 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:184 year:1991 number:2 pages:197-201 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)85071-9 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 184 1991 2 197-201 |
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(DE-627)NLEJ174865988 (DE-599)GBVNLZ174865988 DE-627 ger DE-627 rakwb eng Synthesis and characterization of 1,6,11-triazacyclopentadecane and its zinc(II) complex 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(II) and Cu(II) ions. The ^1H and ^1^3C NMR spectra indicated that the zinc complex is stable in N,N-dimethylformamide and formulated as [Zn(tacpd)Cl]"2[ZnCl"4] in which [Zn(tacpd)Cl]^+ assumes a tetrahedral structure formed by the chloride ion and three nitrogens of tacpd. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Ida, K. oth Okawa, H. oth Sakiyama, H. oth Kodera, M. oth Kida, S. oth Murase, I. oth in Inorganica Chimica Acta Amsterdam : Elsevier 184(1991), 2, Seite 197-201 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:184 year:1991 number:2 pages:197-201 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)85071-9 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 184 1991 2 197-201 |
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(DE-627)NLEJ174865988 (DE-599)GBVNLZ174865988 DE-627 ger DE-627 rakwb eng Synthesis and characterization of 1,6,11-triazacyclopentadecane and its zinc(II) complex 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(II) and Cu(II) ions. The ^1H and ^1^3C NMR spectra indicated that the zinc complex is stable in N,N-dimethylformamide and formulated as [Zn(tacpd)Cl]"2[ZnCl"4] in which [Zn(tacpd)Cl]^+ assumes a tetrahedral structure formed by the chloride ion and three nitrogens of tacpd. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Ida, K. oth Okawa, H. oth Sakiyama, H. oth Kodera, M. oth Kida, S. oth Murase, I. oth in Inorganica Chimica Acta Amsterdam : Elsevier 184(1991), 2, Seite 197-201 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:184 year:1991 number:2 pages:197-201 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)85071-9 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 184 1991 2 197-201 |
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Synthesis and characterization of 1,6,11-triazacyclopentadecane and its zinc(II) complex |
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A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(II) and Cu(II) ions. The ^1H and ^1^3C NMR spectra indicated that the zinc complex is stable in N,N-dimethylformamide and formulated as [Zn(tacpd)Cl]"2[ZnCl"4] in which [Zn(tacpd)Cl]^+ assumes a tetrahedral structure formed by the chloride ion and three nitrogens of tacpd. |
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A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(II) and Cu(II) ions. The ^1H and ^1^3C NMR spectra indicated that the zinc complex is stable in N,N-dimethylformamide and formulated as [Zn(tacpd)Cl]"2[ZnCl"4] in which [Zn(tacpd)Cl]^+ assumes a tetrahedral structure formed by the chloride ion and three nitrogens of tacpd. |
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A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(II) and Cu(II) ions. The ^1H and ^1^3C NMR spectra indicated that the zinc complex is stable in N,N-dimethylformamide and formulated as [Zn(tacpd)Cl]"2[ZnCl"4] in which [Zn(tacpd)Cl]^+ assumes a tetrahedral structure formed by the chloride ion and three nitrogens of tacpd. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ174865988</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20210705223928.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070505s1991 xx |||||o 00| ||eng c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ174865988</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVNLZ174865988</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Synthesis and characterization of 1,6,11-triazacyclopentadecane and its zinc(II) complex</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1991</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">A new triazamacrocycle, 1,6,11-triazacyclopentadecane (tacpd), has been synthesized and its complexation behaviors toward nickel(II), copper(II) and zinc(II) ions have been examined. tacpd formed a Zn(II) complex of the composition Zn"3(tacpd)"2Cl"6 but no discrete complexes with Ni(II) and Cu(II) ions. The ^1H and ^1^3C NMR spectra indicated that the zinc complex is stable in N,N-dimethylformamide and formulated as [Zn(tacpd)Cl]"2[ZnCl"4] in which [Zn(tacpd)Cl]^+ assumes a tetrahedral structure formed by the chloride ion and three nitrogens of tacpd.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Elsevier Journal Backfiles on ScienceDirect 1907 - 2002</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Ida, K.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Okawa, H.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sakiyama, H.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kodera, M.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kida, S.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Murase, I.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Inorganica Chimica Acta</subfield><subfield code="d">Amsterdam : Elsevier</subfield><subfield code="g">184(1991), 2, Seite 197-201</subfield><subfield code="w">(DE-627)NLEJ174799519</subfield><subfield code="w">(DE-600)1484441-2</subfield><subfield code="x">0020-1693</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:184</subfield><subfield code="g">year:1991</subfield><subfield code="g">number:2</subfield><subfield code="g">pages:197-201</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)85071-9</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_H</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-SDJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">184</subfield><subfield code="j">1991</subfield><subfield code="e">2</subfield><subfield code="h">197-201</subfield></datafield></record></collection>
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