Electrochemistry of metalloflavin complexes in dimethylformamide
Electrochemical studies of a series of stable metalloflavin complexes in nonaqueous media are reported and compared to analogous work in water. While the effects of the nonaqueous media are not consistent, one general result is that both the flavin and metal ion reduction potentials are shifted nega...
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E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1983 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Inorganica Chimica Acta - Amsterdam : Elsevier, 78(1983), Seite 153-160 |
| Übergeordnetes Werk: |
volume:78 ; year:1983 ; pages:153-160 |
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| 520 | |a Electrochemical studies of a series of stable metalloflavin complexes in nonaqueous media are reported and compared to analogous work in water. While the effects of the nonaqueous media are not consistent, one general result is that both the flavin and metal ion reduction potentials are shifted negatively relative to their values in water. Coordination of Ru(II) at the N-5 site resolves the 1e-reduction processes of the flavin and strongly decreases the potential for addition of the second electron. The most striking result relative to studies performed in aqueous solution is the much larger separation of the two flavin reduction potentials. Results are discussed in light of their biological and catalytic significance. | ||
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(DE-627)NLEJ174869924 (DE-599)GBVNLZ174869924 DE-627 ger DE-627 rakwb eng Electrochemistry of metalloflavin complexes in dimethylformamide 1983 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Electrochemical studies of a series of stable metalloflavin complexes in nonaqueous media are reported and compared to analogous work in water. While the effects of the nonaqueous media are not consistent, one general result is that both the flavin and metal ion reduction potentials are shifted negatively relative to their values in water. Coordination of Ru(II) at the N-5 site resolves the 1e-reduction processes of the flavin and strongly decreases the potential for addition of the second electron. The most striking result relative to studies performed in aqueous solution is the much larger separation of the two flavin reduction potentials. Results are discussed in light of their biological and catalytic significance. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dowling, M.G. oth Clarke, M.J. oth in Inorganica Chimica Acta Amsterdam : Elsevier 78(1983), Seite 153-160 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:78 year:1983 pages:153-160 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)86507-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 78 1983 153-160 |
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(DE-627)NLEJ174869924 (DE-599)GBVNLZ174869924 DE-627 ger DE-627 rakwb eng Electrochemistry of metalloflavin complexes in dimethylformamide 1983 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Electrochemical studies of a series of stable metalloflavin complexes in nonaqueous media are reported and compared to analogous work in water. While the effects of the nonaqueous media are not consistent, one general result is that both the flavin and metal ion reduction potentials are shifted negatively relative to their values in water. Coordination of Ru(II) at the N-5 site resolves the 1e-reduction processes of the flavin and strongly decreases the potential for addition of the second electron. The most striking result relative to studies performed in aqueous solution is the much larger separation of the two flavin reduction potentials. Results are discussed in light of their biological and catalytic significance. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dowling, M.G. oth Clarke, M.J. oth in Inorganica Chimica Acta Amsterdam : Elsevier 78(1983), Seite 153-160 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:78 year:1983 pages:153-160 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)86507-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 78 1983 153-160 |
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(DE-627)NLEJ174869924 (DE-599)GBVNLZ174869924 DE-627 ger DE-627 rakwb eng Electrochemistry of metalloflavin complexes in dimethylformamide 1983 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Electrochemical studies of a series of stable metalloflavin complexes in nonaqueous media are reported and compared to analogous work in water. While the effects of the nonaqueous media are not consistent, one general result is that both the flavin and metal ion reduction potentials are shifted negatively relative to their values in water. Coordination of Ru(II) at the N-5 site resolves the 1e-reduction processes of the flavin and strongly decreases the potential for addition of the second electron. The most striking result relative to studies performed in aqueous solution is the much larger separation of the two flavin reduction potentials. Results are discussed in light of their biological and catalytic significance. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dowling, M.G. oth Clarke, M.J. oth in Inorganica Chimica Acta Amsterdam : Elsevier 78(1983), Seite 153-160 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:78 year:1983 pages:153-160 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)86507-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 78 1983 153-160 |
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(DE-627)NLEJ174869924 (DE-599)GBVNLZ174869924 DE-627 ger DE-627 rakwb eng Electrochemistry of metalloflavin complexes in dimethylformamide 1983 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Electrochemical studies of a series of stable metalloflavin complexes in nonaqueous media are reported and compared to analogous work in water. While the effects of the nonaqueous media are not consistent, one general result is that both the flavin and metal ion reduction potentials are shifted negatively relative to their values in water. Coordination of Ru(II) at the N-5 site resolves the 1e-reduction processes of the flavin and strongly decreases the potential for addition of the second electron. The most striking result relative to studies performed in aqueous solution is the much larger separation of the two flavin reduction potentials. Results are discussed in light of their biological and catalytic significance. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dowling, M.G. oth Clarke, M.J. oth in Inorganica Chimica Acta Amsterdam : Elsevier 78(1983), Seite 153-160 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:78 year:1983 pages:153-160 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)86507-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 78 1983 153-160 |
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(DE-627)NLEJ174869924 (DE-599)GBVNLZ174869924 DE-627 ger DE-627 rakwb eng Electrochemistry of metalloflavin complexes in dimethylformamide 1983 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Electrochemical studies of a series of stable metalloflavin complexes in nonaqueous media are reported and compared to analogous work in water. While the effects of the nonaqueous media are not consistent, one general result is that both the flavin and metal ion reduction potentials are shifted negatively relative to their values in water. Coordination of Ru(II) at the N-5 site resolves the 1e-reduction processes of the flavin and strongly decreases the potential for addition of the second electron. The most striking result relative to studies performed in aqueous solution is the much larger separation of the two flavin reduction potentials. Results are discussed in light of their biological and catalytic significance. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dowling, M.G. oth Clarke, M.J. oth in Inorganica Chimica Acta Amsterdam : Elsevier 78(1983), Seite 153-160 (DE-627)NLEJ174799519 (DE-600)1484441-2 0020-1693 nnns volume:78 year:1983 pages:153-160 http://linkinghub.elsevier.com/retrieve/pii/S0020-1693(00)86507-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 78 1983 153-160 |
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Electrochemistry of metalloflavin complexes in dimethylformamide |
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Electrochemical studies of a series of stable metalloflavin complexes in nonaqueous media are reported and compared to analogous work in water. While the effects of the nonaqueous media are not consistent, one general result is that both the flavin and metal ion reduction potentials are shifted negatively relative to their values in water. Coordination of Ru(II) at the N-5 site resolves the 1e-reduction processes of the flavin and strongly decreases the potential for addition of the second electron. The most striking result relative to studies performed in aqueous solution is the much larger separation of the two flavin reduction potentials. Results are discussed in light of their biological and catalytic significance. |
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Electrochemical studies of a series of stable metalloflavin complexes in nonaqueous media are reported and compared to analogous work in water. While the effects of the nonaqueous media are not consistent, one general result is that both the flavin and metal ion reduction potentials are shifted negatively relative to their values in water. Coordination of Ru(II) at the N-5 site resolves the 1e-reduction processes of the flavin and strongly decreases the potential for addition of the second electron. The most striking result relative to studies performed in aqueous solution is the much larger separation of the two flavin reduction potentials. Results are discussed in light of their biological and catalytic significance. |
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Electrochemical studies of a series of stable metalloflavin complexes in nonaqueous media are reported and compared to analogous work in water. While the effects of the nonaqueous media are not consistent, one general result is that both the flavin and metal ion reduction potentials are shifted negatively relative to their values in water. Coordination of Ru(II) at the N-5 site resolves the 1e-reduction processes of the flavin and strongly decreases the potential for addition of the second electron. The most striking result relative to studies performed in aqueous solution is the much larger separation of the two flavin reduction potentials. Results are discussed in light of their biological and catalytic significance. |
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