Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies
Elucidation of the products and kinetics of thermolysis of the series of compounds, CP(CO)"nM-CH(CH"3)C"6H"5 (n = 2, M Fe, Ru; n = 3, M Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH^ (kcal/mol) for the homolytic bond d...
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| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1992 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Journal of Organometallic Chemistry - Amsterdam : Elsevier, 428(1992), 1-2, Seite C8-C11 |
| Übergeordnetes Werk: |
volume:428 ; year:1992 ; number:1-2 ; pages:C8-C11 |
| Links: |
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NLEJ175114722 |
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| 245 | 1 | 0 | |a Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies |
| 264 | 1 | |c 1992 | |
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| 520 | |a Elucidation of the products and kinetics of thermolysis of the series of compounds, CP(CO)"nM-CH(CH"3)C"6H"5 (n = 2, M Fe, Ru; n = 3, M Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH^ (kcal/mol) for the homolytic bond dissociation reactions, Cp(CO)"nM-CH(CH"3)C"6H"5 -> Cp(CO)"nM. + .CH(CH"3)C"6H"5: Fe, 29.6; Ru, 34.6; Mo, 26.6; W, 30.6. The corresponding M-CH(CH"3)C"6H"5 bond dissociation energies were deduced to be 28, 33, 25 and 29 kcal/mol, respectively. | ||
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| 700 | 1 | |a Halpern, J. |4 oth | |
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(DE-627)NLEJ175114722 (DE-599)GBVNLZ175114722 DE-627 ger DE-627 rakwb eng Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies 1992 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Elucidation of the products and kinetics of thermolysis of the series of compounds, CP(CO)"nM-CH(CH"3)C"6H"5 (n = 2, M Fe, Ru; n = 3, M Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH^ (kcal/mol) for the homolytic bond dissociation reactions, Cp(CO)"nM-CH(CH"3)C"6H"5 -> Cp(CO)"nM. + .CH(CH"3)C"6H"5: Fe, 29.6; Ru, 34.6; Mo, 26.6; W, 30.6. The corresponding M-CH(CH"3)C"6H"5 bond dissociation energies were deduced to be 28, 33, 25 and 29 kcal/mol, respectively. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Mancuso, C. oth Halpern, J. oth in Journal of Organometallic Chemistry Amsterdam : Elsevier 428(1992), 1-2, Seite C8-C11 (DE-627)NLEJ174930496 (DE-600)1491530-3 0022-328X nnns volume:428 year:1992 number:1-2 pages:C8-C11 http://linkinghub.elsevier.com/retrieve/pii/0022-328X(92)83242-A GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 428 1992 1-2 C8-C11 |
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(DE-627)NLEJ175114722 (DE-599)GBVNLZ175114722 DE-627 ger DE-627 rakwb eng Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies 1992 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Elucidation of the products and kinetics of thermolysis of the series of compounds, CP(CO)"nM-CH(CH"3)C"6H"5 (n = 2, M Fe, Ru; n = 3, M Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH^ (kcal/mol) for the homolytic bond dissociation reactions, Cp(CO)"nM-CH(CH"3)C"6H"5 -> Cp(CO)"nM. + .CH(CH"3)C"6H"5: Fe, 29.6; Ru, 34.6; Mo, 26.6; W, 30.6. The corresponding M-CH(CH"3)C"6H"5 bond dissociation energies were deduced to be 28, 33, 25 and 29 kcal/mol, respectively. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Mancuso, C. oth Halpern, J. oth in Journal of Organometallic Chemistry Amsterdam : Elsevier 428(1992), 1-2, Seite C8-C11 (DE-627)NLEJ174930496 (DE-600)1491530-3 0022-328X nnns volume:428 year:1992 number:1-2 pages:C8-C11 http://linkinghub.elsevier.com/retrieve/pii/0022-328X(92)83242-A GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 428 1992 1-2 C8-C11 |
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(DE-627)NLEJ175114722 (DE-599)GBVNLZ175114722 DE-627 ger DE-627 rakwb eng Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies 1992 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Elucidation of the products and kinetics of thermolysis of the series of compounds, CP(CO)"nM-CH(CH"3)C"6H"5 (n = 2, M Fe, Ru; n = 3, M Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH^ (kcal/mol) for the homolytic bond dissociation reactions, Cp(CO)"nM-CH(CH"3)C"6H"5 -> Cp(CO)"nM. + .CH(CH"3)C"6H"5: Fe, 29.6; Ru, 34.6; Mo, 26.6; W, 30.6. The corresponding M-CH(CH"3)C"6H"5 bond dissociation energies were deduced to be 28, 33, 25 and 29 kcal/mol, respectively. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Mancuso, C. oth Halpern, J. oth in Journal of Organometallic Chemistry Amsterdam : Elsevier 428(1992), 1-2, Seite C8-C11 (DE-627)NLEJ174930496 (DE-600)1491530-3 0022-328X nnns volume:428 year:1992 number:1-2 pages:C8-C11 http://linkinghub.elsevier.com/retrieve/pii/0022-328X(92)83242-A GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 428 1992 1-2 C8-C11 |
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(DE-627)NLEJ175114722 (DE-599)GBVNLZ175114722 DE-627 ger DE-627 rakwb eng Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies 1992 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Elucidation of the products and kinetics of thermolysis of the series of compounds, CP(CO)"nM-CH(CH"3)C"6H"5 (n = 2, M Fe, Ru; n = 3, M Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH^ (kcal/mol) for the homolytic bond dissociation reactions, Cp(CO)"nM-CH(CH"3)C"6H"5 -> Cp(CO)"nM. + .CH(CH"3)C"6H"5: Fe, 29.6; Ru, 34.6; Mo, 26.6; W, 30.6. The corresponding M-CH(CH"3)C"6H"5 bond dissociation energies were deduced to be 28, 33, 25 and 29 kcal/mol, respectively. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Mancuso, C. oth Halpern, J. oth in Journal of Organometallic Chemistry Amsterdam : Elsevier 428(1992), 1-2, Seite C8-C11 (DE-627)NLEJ174930496 (DE-600)1491530-3 0022-328X nnns volume:428 year:1992 number:1-2 pages:C8-C11 http://linkinghub.elsevier.com/retrieve/pii/0022-328X(92)83242-A GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 428 1992 1-2 C8-C11 |
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(DE-627)NLEJ175114722 (DE-599)GBVNLZ175114722 DE-627 ger DE-627 rakwb eng Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies 1992 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Elucidation of the products and kinetics of thermolysis of the series of compounds, CP(CO)"nM-CH(CH"3)C"6H"5 (n = 2, M Fe, Ru; n = 3, M Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH^ (kcal/mol) for the homolytic bond dissociation reactions, Cp(CO)"nM-CH(CH"3)C"6H"5 -> Cp(CO)"nM. + .CH(CH"3)C"6H"5: Fe, 29.6; Ru, 34.6; Mo, 26.6; W, 30.6. The corresponding M-CH(CH"3)C"6H"5 bond dissociation energies were deduced to be 28, 33, 25 and 29 kcal/mol, respectively. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Mancuso, C. oth Halpern, J. oth in Journal of Organometallic Chemistry Amsterdam : Elsevier 428(1992), 1-2, Seite C8-C11 (DE-627)NLEJ174930496 (DE-600)1491530-3 0022-328X nnns volume:428 year:1992 number:1-2 pages:C8-C11 http://linkinghub.elsevier.com/retrieve/pii/0022-328X(92)83242-A GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 428 1992 1-2 C8-C11 |
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Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies |
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Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies |
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Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies |
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thermolysis of cp(co)"nm-ch(ch"3)c"6h"5 (n =2, m fe, ru; n = 3, m mo, w). some vertical trends in transition metalalkyl bond dissociation energies |
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Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies |
| abstract |
Elucidation of the products and kinetics of thermolysis of the series of compounds, CP(CO)"nM-CH(CH"3)C"6H"5 (n = 2, M Fe, Ru; n = 3, M Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH^ (kcal/mol) for the homolytic bond dissociation reactions, Cp(CO)"nM-CH(CH"3)C"6H"5 -> Cp(CO)"nM. + .CH(CH"3)C"6H"5: Fe, 29.6; Ru, 34.6; Mo, 26.6; W, 30.6. The corresponding M-CH(CH"3)C"6H"5 bond dissociation energies were deduced to be 28, 33, 25 and 29 kcal/mol, respectively. |
| abstractGer |
Elucidation of the products and kinetics of thermolysis of the series of compounds, CP(CO)"nM-CH(CH"3)C"6H"5 (n = 2, M Fe, Ru; n = 3, M Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH^ (kcal/mol) for the homolytic bond dissociation reactions, Cp(CO)"nM-CH(CH"3)C"6H"5 -> Cp(CO)"nM. + .CH(CH"3)C"6H"5: Fe, 29.6; Ru, 34.6; Mo, 26.6; W, 30.6. The corresponding M-CH(CH"3)C"6H"5 bond dissociation energies were deduced to be 28, 33, 25 and 29 kcal/mol, respectively. |
| abstract_unstemmed |
Elucidation of the products and kinetics of thermolysis of the series of compounds, CP(CO)"nM-CH(CH"3)C"6H"5 (n = 2, M Fe, Ru; n = 3, M Mo, W), in benzene, in the absence and presence of free radical traps, yielded the following values of ΔH^ (kcal/mol) for the homolytic bond dissociation reactions, Cp(CO)"nM-CH(CH"3)C"6H"5 -> Cp(CO)"nM. + .CH(CH"3)C"6H"5: Fe, 29.6; Ru, 34.6; Mo, 26.6; W, 30.6. The corresponding M-CH(CH"3)C"6H"5 bond dissociation energies were deduced to be 28, 33, 25 and 29 kcal/mol, respectively. |
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1-2 |
| title_short |
Thermolysis of Cp(CO)"nM-CH(CH"3)C"6H"5 (n =2, M Fe, Ru; n = 3, M Mo, W). Some vertical trends in transition metalalkyl bond dissociation energies |
| url |
http://linkinghub.elsevier.com/retrieve/pii/0022-328X(92)83242-A |
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true |
| author2 |
Mancuso, C. Halpern, J. |
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Mancuso, C. Halpern, J. |
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NLEJ174930496 |
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z |
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oth oth |
| up_date |
2024-07-06T03:08:34.710Z |
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1803797465357352960 |
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7.3988037 |