Recations of cationic (η^6-chloroarene) complexes of iron and ruthenium with some O-silyl and C-silyl compounds
The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side cha...
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E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1991 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Journal of Organometallic Chemistry - Amsterdam : Elsevier, 409(1991), 3, Seite 385-409 |
| Übergeordnetes Werk: |
volume:409 ; year:1991 ; number:3 ; pages:385-409 |
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| 520 | |a The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side chain has been introduced similarly using ethyl trimethylsilylacetate. The resulting (η^5-chlorocyclohexadienyl)(η^5-cyclopentadienyl) adducts derived from the ruthenium salts are more stable than their iron analogues. Treatment of the neutral ruthenium adducts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gives moderate yields of the [η^6-(substituted chloroarene)(η^5-Cp)]Ru^+PF^-"6 salt, together with the decomplexed substituted chloroarene. | ||
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(DE-627)NLEJ175135800 (DE-599)GBVNLZ175135800 DE-627 ger DE-627 rakwb eng Recations of cationic (η^6-chloroarene) complexes of iron and ruthenium with some O-silyl and C-silyl compounds 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side chain has been introduced similarly using ethyl trimethylsilylacetate. The resulting (η^5-chlorocyclohexadienyl)(η^5-cyclopentadienyl) adducts derived from the ruthenium salts are more stable than their iron analogues. Treatment of the neutral ruthenium adducts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gives moderate yields of the [η^6-(substituted chloroarene)(η^5-Cp)]Ru^+PF^-"6 salt, together with the decomplexed substituted chloroarene. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cambie, R.C. oth Coulson, S.A. oth Mackay, L.G. oth Janssen, S.J. oth Rutledge, P.S. oth Woodgate, P.D. oth in Journal of Organometallic Chemistry Amsterdam : Elsevier 409(1991), 3, Seite 385-409 (DE-627)NLEJ174930496 (DE-600)1491530-3 0022-328X nnns volume:409 year:1991 number:3 pages:385-409 http://linkinghub.elsevier.com/retrieve/pii/0022-328X(91)80025-F GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 409 1991 3 385-409 |
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(DE-627)NLEJ175135800 (DE-599)GBVNLZ175135800 DE-627 ger DE-627 rakwb eng Recations of cationic (η^6-chloroarene) complexes of iron and ruthenium with some O-silyl and C-silyl compounds 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side chain has been introduced similarly using ethyl trimethylsilylacetate. The resulting (η^5-chlorocyclohexadienyl)(η^5-cyclopentadienyl) adducts derived from the ruthenium salts are more stable than their iron analogues. Treatment of the neutral ruthenium adducts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gives moderate yields of the [η^6-(substituted chloroarene)(η^5-Cp)]Ru^+PF^-"6 salt, together with the decomplexed substituted chloroarene. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cambie, R.C. oth Coulson, S.A. oth Mackay, L.G. oth Janssen, S.J. oth Rutledge, P.S. oth Woodgate, P.D. oth in Journal of Organometallic Chemistry Amsterdam : Elsevier 409(1991), 3, Seite 385-409 (DE-627)NLEJ174930496 (DE-600)1491530-3 0022-328X nnns volume:409 year:1991 number:3 pages:385-409 http://linkinghub.elsevier.com/retrieve/pii/0022-328X(91)80025-F GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 409 1991 3 385-409 |
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(DE-627)NLEJ175135800 (DE-599)GBVNLZ175135800 DE-627 ger DE-627 rakwb eng Recations of cationic (η^6-chloroarene) complexes of iron and ruthenium with some O-silyl and C-silyl compounds 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side chain has been introduced similarly using ethyl trimethylsilylacetate. The resulting (η^5-chlorocyclohexadienyl)(η^5-cyclopentadienyl) adducts derived from the ruthenium salts are more stable than their iron analogues. Treatment of the neutral ruthenium adducts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gives moderate yields of the [η^6-(substituted chloroarene)(η^5-Cp)]Ru^+PF^-"6 salt, together with the decomplexed substituted chloroarene. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cambie, R.C. oth Coulson, S.A. oth Mackay, L.G. oth Janssen, S.J. oth Rutledge, P.S. oth Woodgate, P.D. oth in Journal of Organometallic Chemistry Amsterdam : Elsevier 409(1991), 3, Seite 385-409 (DE-627)NLEJ174930496 (DE-600)1491530-3 0022-328X nnns volume:409 year:1991 number:3 pages:385-409 http://linkinghub.elsevier.com/retrieve/pii/0022-328X(91)80025-F GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 409 1991 3 385-409 |
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(DE-627)NLEJ175135800 (DE-599)GBVNLZ175135800 DE-627 ger DE-627 rakwb eng Recations of cationic (η^6-chloroarene) complexes of iron and ruthenium with some O-silyl and C-silyl compounds 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side chain has been introduced similarly using ethyl trimethylsilylacetate. The resulting (η^5-chlorocyclohexadienyl)(η^5-cyclopentadienyl) adducts derived from the ruthenium salts are more stable than their iron analogues. Treatment of the neutral ruthenium adducts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gives moderate yields of the [η^6-(substituted chloroarene)(η^5-Cp)]Ru^+PF^-"6 salt, together with the decomplexed substituted chloroarene. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cambie, R.C. oth Coulson, S.A. oth Mackay, L.G. oth Janssen, S.J. oth Rutledge, P.S. oth Woodgate, P.D. oth in Journal of Organometallic Chemistry Amsterdam : Elsevier 409(1991), 3, Seite 385-409 (DE-627)NLEJ174930496 (DE-600)1491530-3 0022-328X nnns volume:409 year:1991 number:3 pages:385-409 http://linkinghub.elsevier.com/retrieve/pii/0022-328X(91)80025-F GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 409 1991 3 385-409 |
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(DE-627)NLEJ175135800 (DE-599)GBVNLZ175135800 DE-627 ger DE-627 rakwb eng Recations of cationic (η^6-chloroarene) complexes of iron and ruthenium with some O-silyl and C-silyl compounds 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side chain has been introduced similarly using ethyl trimethylsilylacetate. The resulting (η^5-chlorocyclohexadienyl)(η^5-cyclopentadienyl) adducts derived from the ruthenium salts are more stable than their iron analogues. Treatment of the neutral ruthenium adducts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gives moderate yields of the [η^6-(substituted chloroarene)(η^5-Cp)]Ru^+PF^-"6 salt, together with the decomplexed substituted chloroarene. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Cambie, R.C. oth Coulson, S.A. oth Mackay, L.G. oth Janssen, S.J. oth Rutledge, P.S. oth Woodgate, P.D. oth in Journal of Organometallic Chemistry Amsterdam : Elsevier 409(1991), 3, Seite 385-409 (DE-627)NLEJ174930496 (DE-600)1491530-3 0022-328X nnns volume:409 year:1991 number:3 pages:385-409 http://linkinghub.elsevier.com/retrieve/pii/0022-328X(91)80025-F GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 409 1991 3 385-409 |
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Recations of cationic (η^6-chloroarene) complexes of iron and ruthenium with some O-silyl and C-silyl compounds |
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The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side chain has been introduced similarly using ethyl trimethylsilylacetate. The resulting (η^5-chlorocyclohexadienyl)(η^5-cyclopentadienyl) adducts derived from the ruthenium salts are more stable than their iron analogues. Treatment of the neutral ruthenium adducts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gives moderate yields of the [η^6-(substituted chloroarene)(η^5-Cp)]Ru^+PF^-"6 salt, together with the decomplexed substituted chloroarene. |
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The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side chain has been introduced similarly using ethyl trimethylsilylacetate. The resulting (η^5-chlorocyclohexadienyl)(η^5-cyclopentadienyl) adducts derived from the ruthenium salts are more stable than their iron analogues. Treatment of the neutral ruthenium adducts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gives moderate yields of the [η^6-(substituted chloroarene)(η^5-Cp)]Ru^+PF^-"6 salt, together with the decomplexed substituted chloroarene. |
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The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side chain has been introduced similarly using ethyl trimethylsilylacetate. The resulting (η^5-chlorocyclohexadienyl)(η^5-cyclopentadienyl) adducts derived from the ruthenium salts are more stable than their iron analogues. Treatment of the neutral ruthenium adducts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gives moderate yields of the [η^6-(substituted chloroarene)(η^5-Cp)]Ru^+PF^-"6 salt, together with the decomplexed substituted chloroarene. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ175135800</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230506101632.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070505s1991 xx |||||o 00| ||eng c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ175135800</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVNLZ175135800</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Recations of cationic (η^6-chloroarene) complexes of iron and ruthenium with some O-silyl and C-silyl compounds</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1991</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The introduction of an alkylcarbonyl side chain into the aromatic ring of some chloro-substituted benzenes has been achieved under mild conditions by the Yanovsky-type reaction of (η^6chloroarene)(η^5-cyclopentadienyl) cationic complexes of iron or ruthenium with silyl enol ethers. An ester side chain has been introduced similarly using ethyl trimethylsilylacetate. The resulting (η^5-chlorocyclohexadienyl)(η^5-cyclopentadienyl) adducts derived from the ruthenium salts are more stable than their iron analogues. Treatment of the neutral ruthenium adducts with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gives moderate yields of the [η^6-(substituted chloroarene)(η^5-Cp)]Ru^+PF^-"6 salt, together with the decomplexed substituted chloroarene.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Elsevier Journal Backfiles on ScienceDirect 1907 - 2002</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cambie, R.C.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Coulson, S.A.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mackay, L.G.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Janssen, S.J.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Rutledge, P.S.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Woodgate, P.D.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Journal of Organometallic Chemistry</subfield><subfield code="d">Amsterdam : Elsevier</subfield><subfield code="g">409(1991), 3, Seite 385-409</subfield><subfield code="w">(DE-627)NLEJ174930496</subfield><subfield code="w">(DE-600)1491530-3</subfield><subfield code="x">0022-328X</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:409</subfield><subfield code="g">year:1991</subfield><subfield code="g">number:3</subfield><subfield code="g">pages:385-409</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://linkinghub.elsevier.com/retrieve/pii/0022-328X(91)80025-F</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_H</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-SDJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">409</subfield><subfield code="j">1991</subfield><subfield code="e">3</subfield><subfield code="h">385-409</subfield></datafield></record></collection>
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