Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents
Treatment of [Mo(CO)"6] in tetrahydrofuran, with 1,1'-dilithioferrocene in light petroleum, followed by (CF"3CO)"2O and tmeda (Me"2NCH"2CH"2NMe"2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo"2Fe(μ-σ, σ',:η^5-CC"5H&qu...
Ausführliche Beschreibung
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| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1989 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Polyhedron - Amsterdam : Elsevier, 8(1989), 18, Seite 2265-2270 |
| Übergeordnetes Werk: |
volume:8 ; year:1989 ; number:18 ; pages:2265-2270 |
| Links: |
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NLEJ17519212X |
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| 245 | 1 | 0 | |a Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents |
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| 520 | |a Treatment of [Mo(CO)"6] in tetrahydrofuran, with 1,1'-dilithioferrocene in light petroleum, followed by (CF"3CO)"2O and tmeda (Me"2NCH"2CH"2NMe"2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo"2Fe(μ-σ, σ',:η^5-CC"5H"4)"2(O"2CCF"3)"2 (CO)"4(tmeda)"2]. The latter with K[HB(pz)"3] [HB(pz)"3 = hydrotris(pyrazol-1-yl)borate] in CH"2Cl"2 gives [Mo"2Fe(μ-σ,σ':gh^5 -CC"5H"4)"2(CO)"4{HB(pz)"3}"2], which with [Pt(cod)"2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo"2FePt(μ-σ,σ',δ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}"2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand. | ||
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(DE-627)NLEJ17519212X (DE-599)GBVNLZ17519212X DE-627 ger DE-627 rakwb eng Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Treatment of [Mo(CO)"6] in tetrahydrofuran, with 1,1'-dilithioferrocene in light petroleum, followed by (CF"3CO)"2O and tmeda (Me"2NCH"2CH"2NMe"2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo"2Fe(μ-σ, σ',:η^5-CC"5H"4)"2(O"2CCF"3)"2 (CO)"4(tmeda)"2]. The latter with K[HB(pz)"3] [HB(pz)"3 = hydrotris(pyrazol-1-yl)borate] in CH"2Cl"2 gives [Mo"2Fe(μ-σ,σ':gh^5 -CC"5H"4)"2(CO)"4{HB(pz)"3}"2], which with [Pt(cod)"2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo"2FePt(μ-σ,σ',δ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}"2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Davies, S.J. oth Hill, A.F. oth Pilotti, M.U. oth A. Stone, F.G. oth in Polyhedron Amsterdam : Elsevier 8(1989), 18, Seite 2265-2270 (DE-627)NLEJ175173621 (DE-600)2000326-2 0277-5387 nnns volume:8 year:1989 number:18 pages:2265-2270 http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)81253-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 8 1989 18 2265-2270 |
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(DE-627)NLEJ17519212X (DE-599)GBVNLZ17519212X DE-627 ger DE-627 rakwb eng Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Treatment of [Mo(CO)"6] in tetrahydrofuran, with 1,1'-dilithioferrocene in light petroleum, followed by (CF"3CO)"2O and tmeda (Me"2NCH"2CH"2NMe"2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo"2Fe(μ-σ, σ',:η^5-CC"5H"4)"2(O"2CCF"3)"2 (CO)"4(tmeda)"2]. The latter with K[HB(pz)"3] [HB(pz)"3 = hydrotris(pyrazol-1-yl)borate] in CH"2Cl"2 gives [Mo"2Fe(μ-σ,σ':gh^5 -CC"5H"4)"2(CO)"4{HB(pz)"3}"2], which with [Pt(cod)"2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo"2FePt(μ-σ,σ',δ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}"2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Davies, S.J. oth Hill, A.F. oth Pilotti, M.U. oth A. Stone, F.G. oth in Polyhedron Amsterdam : Elsevier 8(1989), 18, Seite 2265-2270 (DE-627)NLEJ175173621 (DE-600)2000326-2 0277-5387 nnns volume:8 year:1989 number:18 pages:2265-2270 http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)81253-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 8 1989 18 2265-2270 |
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(DE-627)NLEJ17519212X (DE-599)GBVNLZ17519212X DE-627 ger DE-627 rakwb eng Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Treatment of [Mo(CO)"6] in tetrahydrofuran, with 1,1'-dilithioferrocene in light petroleum, followed by (CF"3CO)"2O and tmeda (Me"2NCH"2CH"2NMe"2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo"2Fe(μ-σ, σ',:η^5-CC"5H"4)"2(O"2CCF"3)"2 (CO)"4(tmeda)"2]. The latter with K[HB(pz)"3] [HB(pz)"3 = hydrotris(pyrazol-1-yl)borate] in CH"2Cl"2 gives [Mo"2Fe(μ-σ,σ':gh^5 -CC"5H"4)"2(CO)"4{HB(pz)"3}"2], which with [Pt(cod)"2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo"2FePt(μ-σ,σ',δ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}"2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Davies, S.J. oth Hill, A.F. oth Pilotti, M.U. oth A. Stone, F.G. oth in Polyhedron Amsterdam : Elsevier 8(1989), 18, Seite 2265-2270 (DE-627)NLEJ175173621 (DE-600)2000326-2 0277-5387 nnns volume:8 year:1989 number:18 pages:2265-2270 http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)81253-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 8 1989 18 2265-2270 |
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(DE-627)NLEJ17519212X (DE-599)GBVNLZ17519212X DE-627 ger DE-627 rakwb eng Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Treatment of [Mo(CO)"6] in tetrahydrofuran, with 1,1'-dilithioferrocene in light petroleum, followed by (CF"3CO)"2O and tmeda (Me"2NCH"2CH"2NMe"2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo"2Fe(μ-σ, σ',:η^5-CC"5H"4)"2(O"2CCF"3)"2 (CO)"4(tmeda)"2]. The latter with K[HB(pz)"3] [HB(pz)"3 = hydrotris(pyrazol-1-yl)borate] in CH"2Cl"2 gives [Mo"2Fe(μ-σ,σ':gh^5 -CC"5H"4)"2(CO)"4{HB(pz)"3}"2], which with [Pt(cod)"2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo"2FePt(μ-σ,σ',δ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}"2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Davies, S.J. oth Hill, A.F. oth Pilotti, M.U. oth A. Stone, F.G. oth in Polyhedron Amsterdam : Elsevier 8(1989), 18, Seite 2265-2270 (DE-627)NLEJ175173621 (DE-600)2000326-2 0277-5387 nnns volume:8 year:1989 number:18 pages:2265-2270 http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)81253-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 8 1989 18 2265-2270 |
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(DE-627)NLEJ17519212X (DE-599)GBVNLZ17519212X DE-627 ger DE-627 rakwb eng Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Treatment of [Mo(CO)"6] in tetrahydrofuran, with 1,1'-dilithioferrocene in light petroleum, followed by (CF"3CO)"2O and tmeda (Me"2NCH"2CH"2NMe"2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo"2Fe(μ-σ, σ',:η^5-CC"5H"4)"2(O"2CCF"3)"2 (CO)"4(tmeda)"2]. The latter with K[HB(pz)"3] [HB(pz)"3 = hydrotris(pyrazol-1-yl)borate] in CH"2Cl"2 gives [Mo"2Fe(μ-σ,σ':gh^5 -CC"5H"4)"2(CO)"4{HB(pz)"3}"2], which with [Pt(cod)"2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo"2FePt(μ-σ,σ',δ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}"2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Davies, S.J. oth Hill, A.F. oth Pilotti, M.U. oth A. Stone, F.G. oth in Polyhedron Amsterdam : Elsevier 8(1989), 18, Seite 2265-2270 (DE-627)NLEJ175173621 (DE-600)2000326-2 0277-5387 nnns volume:8 year:1989 number:18 pages:2265-2270 http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)81253-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 8 1989 18 2265-2270 |
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Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents |
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Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents |
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Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents |
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Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents |
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synthesis and crystal structure of [mo"2fept(μ-σ,σ',σ'':η^5-cc"5h"4)"2(co)"4{hb(pz)"3}2][hb(pz)"3 = hydrotris(pyrazol-1-yl)borate]; a complex derived from a 1,1'-ferrocene derivative with cmo(co)"2{hb(pz)"3} substituents |
| title_auth |
Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents |
| abstract |
Treatment of [Mo(CO)"6] in tetrahydrofuran, with 1,1'-dilithioferrocene in light petroleum, followed by (CF"3CO)"2O and tmeda (Me"2NCH"2CH"2NMe"2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo"2Fe(μ-σ, σ',:η^5-CC"5H"4)"2(O"2CCF"3)"2 (CO)"4(tmeda)"2]. The latter with K[HB(pz)"3] [HB(pz)"3 = hydrotris(pyrazol-1-yl)borate] in CH"2Cl"2 gives [Mo"2Fe(μ-σ,σ':gh^5 -CC"5H"4)"2(CO)"4{HB(pz)"3}"2], which with [Pt(cod)"2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo"2FePt(μ-σ,σ',δ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}"2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand. |
| abstractGer |
Treatment of [Mo(CO)"6] in tetrahydrofuran, with 1,1'-dilithioferrocene in light petroleum, followed by (CF"3CO)"2O and tmeda (Me"2NCH"2CH"2NMe"2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo"2Fe(μ-σ, σ',:η^5-CC"5H"4)"2(O"2CCF"3)"2 (CO)"4(tmeda)"2]. The latter with K[HB(pz)"3] [HB(pz)"3 = hydrotris(pyrazol-1-yl)borate] in CH"2Cl"2 gives [Mo"2Fe(μ-σ,σ':gh^5 -CC"5H"4)"2(CO)"4{HB(pz)"3}"2], which with [Pt(cod)"2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo"2FePt(μ-σ,σ',δ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}"2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand. |
| abstract_unstemmed |
Treatment of [Mo(CO)"6] in tetrahydrofuran, with 1,1'-dilithioferrocene in light petroleum, followed by (CF"3CO)"2O and tmeda (Me"2NCH"2CH"2NMe"2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo"2Fe(μ-σ, σ',:η^5-CC"5H"4)"2(O"2CCF"3)"2 (CO)"4(tmeda)"2]. The latter with K[HB(pz)"3] [HB(pz)"3 = hydrotris(pyrazol-1-yl)borate] in CH"2Cl"2 gives [Mo"2Fe(μ-σ,σ':gh^5 -CC"5H"4)"2(CO)"4{HB(pz)"3}"2], which with [Pt(cod)"2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo"2FePt(μ-σ,σ',δ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}"2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand. |
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18 |
| title_short |
Synthesis and crystal structure of [Mo"2FePt(μ-σ,σ',σ'':η^5-CC"5H"4)"2(CO)"4{HB(pz)"3}2][HB(pz)"3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1'-ferrocene derivative with CMo(CO)"2{HB(pz)"3} substituents |
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| author2 |
Davies, S.J. Hill, A.F. Pilotti, M.U. A. Stone, F.G. |
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Davies, S.J. Hill, A.F. Pilotti, M.U. A. Stone, F.G. |
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2024-07-06T03:24:08.198Z |
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7.399884 |