Qualitative models for the NMR chemical shifts of interstitial atoms in clusters
Qualitative models for the NMR chemical shifts of interstitial atoms in clusters are presented which draw heavily upon our present understanding of cluster bonding. The deshielding of interstitial hydrogen atoms can be understood in terms of secondary paramagnetic fields arising on the transition me...
Ausführliche Beschreibung
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| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1991 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Polyhedron - Amsterdam : Elsevier, 10(1991), 15, Seite 1749-1758 |
| Übergeordnetes Werk: |
volume:10 ; year:1991 ; number:15 ; pages:1749-1758 |
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| 245 | 1 | 0 | |a Qualitative models for the NMR chemical shifts of interstitial atoms in clusters |
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| 520 | |a Qualitative models for the NMR chemical shifts of interstitial atoms in clusters are presented which draw heavily upon our present understanding of cluster bonding. The deshielding of interstitial hydrogen atoms can be understood in terms of secondary paramagnetic fields arising on the transition metal centres, whilst that of interstitial carbon and nitrogen atoms is thought to arise from more local sources. In these models, Stone's Tensor Surface Harmonic theory is used to describe the interaction between the interstitial atoms and the metal cluster framework. Model calculations of the susceptibility tensor for [Ru"6H(CO)"1"8]^- and the electronic structures of [Rh"6C(CO)"1"5]^2^- and [Rh"6N(CO)"1"5]^- support the proposals. | ||
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| 700 | 1 | |a Wales, D.J. |4 oth | |
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(DE-627)NLEJ175198195 (DE-599)GBVNLZ175198195 DE-627 ger DE-627 rakwb eng Qualitative models for the NMR chemical shifts of interstitial atoms in clusters 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Qualitative models for the NMR chemical shifts of interstitial atoms in clusters are presented which draw heavily upon our present understanding of cluster bonding. The deshielding of interstitial hydrogen atoms can be understood in terms of secondary paramagnetic fields arising on the transition metal centres, whilst that of interstitial carbon and nitrogen atoms is thought to arise from more local sources. In these models, Stone's Tensor Surface Harmonic theory is used to describe the interaction between the interstitial atoms and the metal cluster framework. Model calculations of the susceptibility tensor for [Ru"6H(CO)"1"8]^- and the electronic structures of [Rh"6C(CO)"1"5]^2^- and [Rh"6N(CO)"1"5]^- support the proposals. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Duer, M.J. oth Wales, D.J. oth in Polyhedron Amsterdam : Elsevier 10(1991), 15, Seite 1749-1758 (DE-627)NLEJ175173621 (DE-600)2000326-2 0277-5387 nnns volume:10 year:1991 number:15 pages:1749-1758 http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)83795-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 10 1991 15 1749-1758 |
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(DE-627)NLEJ175198195 (DE-599)GBVNLZ175198195 DE-627 ger DE-627 rakwb eng Qualitative models for the NMR chemical shifts of interstitial atoms in clusters 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Qualitative models for the NMR chemical shifts of interstitial atoms in clusters are presented which draw heavily upon our present understanding of cluster bonding. The deshielding of interstitial hydrogen atoms can be understood in terms of secondary paramagnetic fields arising on the transition metal centres, whilst that of interstitial carbon and nitrogen atoms is thought to arise from more local sources. In these models, Stone's Tensor Surface Harmonic theory is used to describe the interaction between the interstitial atoms and the metal cluster framework. Model calculations of the susceptibility tensor for [Ru"6H(CO)"1"8]^- and the electronic structures of [Rh"6C(CO)"1"5]^2^- and [Rh"6N(CO)"1"5]^- support the proposals. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Duer, M.J. oth Wales, D.J. oth in Polyhedron Amsterdam : Elsevier 10(1991), 15, Seite 1749-1758 (DE-627)NLEJ175173621 (DE-600)2000326-2 0277-5387 nnns volume:10 year:1991 number:15 pages:1749-1758 http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)83795-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 10 1991 15 1749-1758 |
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(DE-627)NLEJ175198195 (DE-599)GBVNLZ175198195 DE-627 ger DE-627 rakwb eng Qualitative models for the NMR chemical shifts of interstitial atoms in clusters 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Qualitative models for the NMR chemical shifts of interstitial atoms in clusters are presented which draw heavily upon our present understanding of cluster bonding. The deshielding of interstitial hydrogen atoms can be understood in terms of secondary paramagnetic fields arising on the transition metal centres, whilst that of interstitial carbon and nitrogen atoms is thought to arise from more local sources. In these models, Stone's Tensor Surface Harmonic theory is used to describe the interaction between the interstitial atoms and the metal cluster framework. Model calculations of the susceptibility tensor for [Ru"6H(CO)"1"8]^- and the electronic structures of [Rh"6C(CO)"1"5]^2^- and [Rh"6N(CO)"1"5]^- support the proposals. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Duer, M.J. oth Wales, D.J. oth in Polyhedron Amsterdam : Elsevier 10(1991), 15, Seite 1749-1758 (DE-627)NLEJ175173621 (DE-600)2000326-2 0277-5387 nnns volume:10 year:1991 number:15 pages:1749-1758 http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)83795-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 10 1991 15 1749-1758 |
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(DE-627)NLEJ175198195 (DE-599)GBVNLZ175198195 DE-627 ger DE-627 rakwb eng Qualitative models for the NMR chemical shifts of interstitial atoms in clusters 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Qualitative models for the NMR chemical shifts of interstitial atoms in clusters are presented which draw heavily upon our present understanding of cluster bonding. The deshielding of interstitial hydrogen atoms can be understood in terms of secondary paramagnetic fields arising on the transition metal centres, whilst that of interstitial carbon and nitrogen atoms is thought to arise from more local sources. In these models, Stone's Tensor Surface Harmonic theory is used to describe the interaction between the interstitial atoms and the metal cluster framework. Model calculations of the susceptibility tensor for [Ru"6H(CO)"1"8]^- and the electronic structures of [Rh"6C(CO)"1"5]^2^- and [Rh"6N(CO)"1"5]^- support the proposals. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Duer, M.J. oth Wales, D.J. oth in Polyhedron Amsterdam : Elsevier 10(1991), 15, Seite 1749-1758 (DE-627)NLEJ175173621 (DE-600)2000326-2 0277-5387 nnns volume:10 year:1991 number:15 pages:1749-1758 http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)83795-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 10 1991 15 1749-1758 |
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(DE-627)NLEJ175198195 (DE-599)GBVNLZ175198195 DE-627 ger DE-627 rakwb eng Qualitative models for the NMR chemical shifts of interstitial atoms in clusters 1991 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Qualitative models for the NMR chemical shifts of interstitial atoms in clusters are presented which draw heavily upon our present understanding of cluster bonding. The deshielding of interstitial hydrogen atoms can be understood in terms of secondary paramagnetic fields arising on the transition metal centres, whilst that of interstitial carbon and nitrogen atoms is thought to arise from more local sources. In these models, Stone's Tensor Surface Harmonic theory is used to describe the interaction between the interstitial atoms and the metal cluster framework. Model calculations of the susceptibility tensor for [Ru"6H(CO)"1"8]^- and the electronic structures of [Rh"6C(CO)"1"5]^2^- and [Rh"6N(CO)"1"5]^- support the proposals. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Duer, M.J. oth Wales, D.J. oth in Polyhedron Amsterdam : Elsevier 10(1991), 15, Seite 1749-1758 (DE-627)NLEJ175173621 (DE-600)2000326-2 0277-5387 nnns volume:10 year:1991 number:15 pages:1749-1758 http://linkinghub.elsevier.com/retrieve/pii/S0277-5387(00)83795-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 10 1991 15 1749-1758 |
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qualitative models for the nmr chemical shifts of interstitial atoms in clusters |
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Qualitative models for the NMR chemical shifts of interstitial atoms in clusters |
| abstract |
Qualitative models for the NMR chemical shifts of interstitial atoms in clusters are presented which draw heavily upon our present understanding of cluster bonding. The deshielding of interstitial hydrogen atoms can be understood in terms of secondary paramagnetic fields arising on the transition metal centres, whilst that of interstitial carbon and nitrogen atoms is thought to arise from more local sources. In these models, Stone's Tensor Surface Harmonic theory is used to describe the interaction between the interstitial atoms and the metal cluster framework. Model calculations of the susceptibility tensor for [Ru"6H(CO)"1"8]^- and the electronic structures of [Rh"6C(CO)"1"5]^2^- and [Rh"6N(CO)"1"5]^- support the proposals. |
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Qualitative models for the NMR chemical shifts of interstitial atoms in clusters are presented which draw heavily upon our present understanding of cluster bonding. The deshielding of interstitial hydrogen atoms can be understood in terms of secondary paramagnetic fields arising on the transition metal centres, whilst that of interstitial carbon and nitrogen atoms is thought to arise from more local sources. In these models, Stone's Tensor Surface Harmonic theory is used to describe the interaction between the interstitial atoms and the metal cluster framework. Model calculations of the susceptibility tensor for [Ru"6H(CO)"1"8]^- and the electronic structures of [Rh"6C(CO)"1"5]^2^- and [Rh"6N(CO)"1"5]^- support the proposals. |
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Qualitative models for the NMR chemical shifts of interstitial atoms in clusters are presented which draw heavily upon our present understanding of cluster bonding. The deshielding of interstitial hydrogen atoms can be understood in terms of secondary paramagnetic fields arising on the transition metal centres, whilst that of interstitial carbon and nitrogen atoms is thought to arise from more local sources. In these models, Stone's Tensor Surface Harmonic theory is used to describe the interaction between the interstitial atoms and the metal cluster framework. Model calculations of the susceptibility tensor for [Ru"6H(CO)"1"8]^- and the electronic structures of [Rh"6C(CO)"1"5]^2^- and [Rh"6N(CO)"1"5]^- support the proposals. |
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Qualitative models for the NMR chemical shifts of interstitial atoms in clusters |
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