Thermal degradation of 3-deoxy-D-erythro-hexosulose
3-Deoxy-D-erythro-hexosulose is less stable than normal carbohydrates and polymerizes within the range 100-200^o. The polymerization is accompanied by dehydration, fission, and rearrangement reactions which produce water, furan derivatives, carbonyl compounds of low molecular weight, saccharinic aci...
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E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1975 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Carbohydrate Research - Amsterdam : Elsevier, 40(1975), 2, Seite 263-274 |
| Übergeordnetes Werk: |
volume:40 ; year:1975 ; number:2 ; pages:263-274 |
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| 520 | |a 3-Deoxy-D-erythro-hexosulose is less stable than normal carbohydrates and polymerizes within the range 100-200^o. The polymerization is accompanied by dehydration, fission, and rearrangement reactions which produce water, furan derivatives, carbonyl compounds of low molecular weight, saccharinic acid, carbon dioxide, and carbon monoxide. Heating at higher temperatures results in charring of the polymeric material and further dehydration, fission, and disproportionation reactions which provide a variety of secondary pyrolysis products. The dehydration reactions are catalyzed by the addition of zinc chloride, and the fission reactions by the addition of sodium carbonate. | ||
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(DE-627)NLEJ17543381X (DE-599)GBVNLZ17543381X DE-627 ger DE-627 rakwb eng Thermal degradation of 3-deoxy-D-erythro-hexosulose 1975 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier 3-Deoxy-D-erythro-hexosulose is less stable than normal carbohydrates and polymerizes within the range 100-200^o. The polymerization is accompanied by dehydration, fission, and rearrangement reactions which produce water, furan derivatives, carbonyl compounds of low molecular weight, saccharinic acid, carbon dioxide, and carbon monoxide. Heating at higher temperatures results in charring of the polymeric material and further dehydration, fission, and disproportionation reactions which provide a variety of secondary pyrolysis products. The dehydration reactions are catalyzed by the addition of zinc chloride, and the fission reactions by the addition of sodium carbonate. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Shafizadeh, F. oth Yuan-Zong, L. oth in Carbohydrate Research Amsterdam : Elsevier 40(1975), 2, Seite 263-274 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:40 year:1975 number:2 pages:263-274 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)82608-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 40 1975 2 263-274 |
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(DE-627)NLEJ17543381X (DE-599)GBVNLZ17543381X DE-627 ger DE-627 rakwb eng Thermal degradation of 3-deoxy-D-erythro-hexosulose 1975 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier 3-Deoxy-D-erythro-hexosulose is less stable than normal carbohydrates and polymerizes within the range 100-200^o. The polymerization is accompanied by dehydration, fission, and rearrangement reactions which produce water, furan derivatives, carbonyl compounds of low molecular weight, saccharinic acid, carbon dioxide, and carbon monoxide. Heating at higher temperatures results in charring of the polymeric material and further dehydration, fission, and disproportionation reactions which provide a variety of secondary pyrolysis products. The dehydration reactions are catalyzed by the addition of zinc chloride, and the fission reactions by the addition of sodium carbonate. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Shafizadeh, F. oth Yuan-Zong, L. oth in Carbohydrate Research Amsterdam : Elsevier 40(1975), 2, Seite 263-274 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:40 year:1975 number:2 pages:263-274 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)82608-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 40 1975 2 263-274 |
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(DE-627)NLEJ17543381X (DE-599)GBVNLZ17543381X DE-627 ger DE-627 rakwb eng Thermal degradation of 3-deoxy-D-erythro-hexosulose 1975 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier 3-Deoxy-D-erythro-hexosulose is less stable than normal carbohydrates and polymerizes within the range 100-200^o. The polymerization is accompanied by dehydration, fission, and rearrangement reactions which produce water, furan derivatives, carbonyl compounds of low molecular weight, saccharinic acid, carbon dioxide, and carbon monoxide. Heating at higher temperatures results in charring of the polymeric material and further dehydration, fission, and disproportionation reactions which provide a variety of secondary pyrolysis products. The dehydration reactions are catalyzed by the addition of zinc chloride, and the fission reactions by the addition of sodium carbonate. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Shafizadeh, F. oth Yuan-Zong, L. oth in Carbohydrate Research Amsterdam : Elsevier 40(1975), 2, Seite 263-274 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:40 year:1975 number:2 pages:263-274 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)82608-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 40 1975 2 263-274 |
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(DE-627)NLEJ17543381X (DE-599)GBVNLZ17543381X DE-627 ger DE-627 rakwb eng Thermal degradation of 3-deoxy-D-erythro-hexosulose 1975 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier 3-Deoxy-D-erythro-hexosulose is less stable than normal carbohydrates and polymerizes within the range 100-200^o. The polymerization is accompanied by dehydration, fission, and rearrangement reactions which produce water, furan derivatives, carbonyl compounds of low molecular weight, saccharinic acid, carbon dioxide, and carbon monoxide. Heating at higher temperatures results in charring of the polymeric material and further dehydration, fission, and disproportionation reactions which provide a variety of secondary pyrolysis products. The dehydration reactions are catalyzed by the addition of zinc chloride, and the fission reactions by the addition of sodium carbonate. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Shafizadeh, F. oth Yuan-Zong, L. oth in Carbohydrate Research Amsterdam : Elsevier 40(1975), 2, Seite 263-274 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:40 year:1975 number:2 pages:263-274 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)82608-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 40 1975 2 263-274 |
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Thermal degradation of 3-deoxy-D-erythro-hexosulose |
| abstract |
3-Deoxy-D-erythro-hexosulose is less stable than normal carbohydrates and polymerizes within the range 100-200^o. The polymerization is accompanied by dehydration, fission, and rearrangement reactions which produce water, furan derivatives, carbonyl compounds of low molecular weight, saccharinic acid, carbon dioxide, and carbon monoxide. Heating at higher temperatures results in charring of the polymeric material and further dehydration, fission, and disproportionation reactions which provide a variety of secondary pyrolysis products. The dehydration reactions are catalyzed by the addition of zinc chloride, and the fission reactions by the addition of sodium carbonate. |
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3-Deoxy-D-erythro-hexosulose is less stable than normal carbohydrates and polymerizes within the range 100-200^o. The polymerization is accompanied by dehydration, fission, and rearrangement reactions which produce water, furan derivatives, carbonyl compounds of low molecular weight, saccharinic acid, carbon dioxide, and carbon monoxide. Heating at higher temperatures results in charring of the polymeric material and further dehydration, fission, and disproportionation reactions which provide a variety of secondary pyrolysis products. The dehydration reactions are catalyzed by the addition of zinc chloride, and the fission reactions by the addition of sodium carbonate. |
| abstract_unstemmed |
3-Deoxy-D-erythro-hexosulose is less stable than normal carbohydrates and polymerizes within the range 100-200^o. The polymerization is accompanied by dehydration, fission, and rearrangement reactions which produce water, furan derivatives, carbonyl compounds of low molecular weight, saccharinic acid, carbon dioxide, and carbon monoxide. Heating at higher temperatures results in charring of the polymeric material and further dehydration, fission, and disproportionation reactions which provide a variety of secondary pyrolysis products. The dehydration reactions are catalyzed by the addition of zinc chloride, and the fission reactions by the addition of sodium carbonate. |
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