Radiation studies of aryl glycosides - Part VI. Radicals derived from Phenyl β-d-glucopyranosides
Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after i...
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1973 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Carbohydrate Research - Amsterdam : Elsevier, 31(1973), 2, Seite 199-209 |
| Übergeordnetes Werk: |
volume:31 ; year:1973 ; number:2 ; pages:199-209 |
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| 520 | |a Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after irradiation of the compounds in the solid state and in frozen, aqueous solutions. Cyclohexadienyl radicals are the more stable during thermal annealing and are present in 2-3 times greater yield than the sugar radicals. p-Hydroxy- and methoxy-phenyl β-d-glucopyranosides yield phenoxy radicals, which can be transformed into substituted cyclohexadienyl radicals by thermal annealing. Hydrogen abstraction and inter- and intra-molecular hydrogen-transfer are the most likely processes leading to the radicals which have been identified. | ||
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(DE-627)NLEJ175464286 (DE-599)GBVNLZ175464286 DE-627 ger DE-627 rakwb eng Radiation studies of aryl glycosides - Part VI. Radicals derived from Phenyl β-d-glucopyranosides 1973 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after irradiation of the compounds in the solid state and in frozen, aqueous solutions. Cyclohexadienyl radicals are the more stable during thermal annealing and are present in 2-3 times greater yield than the sugar radicals. p-Hydroxy- and methoxy-phenyl β-d-glucopyranosides yield phenoxy radicals, which can be transformed into substituted cyclohexadienyl radicals by thermal annealing. Hydrogen abstraction and inter- and intra-molecular hydrogen-transfer are the most likely processes leading to the radicals which have been identified. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Baugh, P.J. oth Kershaw, K. oth Phillips, G.O. oth Webber, M.G. oth in Carbohydrate Research Amsterdam : Elsevier 31(1973), 2, Seite 199-209 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:31 year:1973 number:2 pages:199-209 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)86185-6 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 31 1973 2 199-209 |
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(DE-627)NLEJ175464286 (DE-599)GBVNLZ175464286 DE-627 ger DE-627 rakwb eng Radiation studies of aryl glycosides - Part VI. Radicals derived from Phenyl β-d-glucopyranosides 1973 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after irradiation of the compounds in the solid state and in frozen, aqueous solutions. Cyclohexadienyl radicals are the more stable during thermal annealing and are present in 2-3 times greater yield than the sugar radicals. p-Hydroxy- and methoxy-phenyl β-d-glucopyranosides yield phenoxy radicals, which can be transformed into substituted cyclohexadienyl radicals by thermal annealing. Hydrogen abstraction and inter- and intra-molecular hydrogen-transfer are the most likely processes leading to the radicals which have been identified. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Baugh, P.J. oth Kershaw, K. oth Phillips, G.O. oth Webber, M.G. oth in Carbohydrate Research Amsterdam : Elsevier 31(1973), 2, Seite 199-209 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:31 year:1973 number:2 pages:199-209 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)86185-6 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 31 1973 2 199-209 |
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(DE-627)NLEJ175464286 (DE-599)GBVNLZ175464286 DE-627 ger DE-627 rakwb eng Radiation studies of aryl glycosides - Part VI. Radicals derived from Phenyl β-d-glucopyranosides 1973 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after irradiation of the compounds in the solid state and in frozen, aqueous solutions. Cyclohexadienyl radicals are the more stable during thermal annealing and are present in 2-3 times greater yield than the sugar radicals. p-Hydroxy- and methoxy-phenyl β-d-glucopyranosides yield phenoxy radicals, which can be transformed into substituted cyclohexadienyl radicals by thermal annealing. Hydrogen abstraction and inter- and intra-molecular hydrogen-transfer are the most likely processes leading to the radicals which have been identified. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Baugh, P.J. oth Kershaw, K. oth Phillips, G.O. oth Webber, M.G. oth in Carbohydrate Research Amsterdam : Elsevier 31(1973), 2, Seite 199-209 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:31 year:1973 number:2 pages:199-209 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)86185-6 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 31 1973 2 199-209 |
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(DE-627)NLEJ175464286 (DE-599)GBVNLZ175464286 DE-627 ger DE-627 rakwb eng Radiation studies of aryl glycosides - Part VI. Radicals derived from Phenyl β-d-glucopyranosides 1973 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after irradiation of the compounds in the solid state and in frozen, aqueous solutions. Cyclohexadienyl radicals are the more stable during thermal annealing and are present in 2-3 times greater yield than the sugar radicals. p-Hydroxy- and methoxy-phenyl β-d-glucopyranosides yield phenoxy radicals, which can be transformed into substituted cyclohexadienyl radicals by thermal annealing. Hydrogen abstraction and inter- and intra-molecular hydrogen-transfer are the most likely processes leading to the radicals which have been identified. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Baugh, P.J. oth Kershaw, K. oth Phillips, G.O. oth Webber, M.G. oth in Carbohydrate Research Amsterdam : Elsevier 31(1973), 2, Seite 199-209 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:31 year:1973 number:2 pages:199-209 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)86185-6 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 31 1973 2 199-209 |
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(DE-627)NLEJ175464286 (DE-599)GBVNLZ175464286 DE-627 ger DE-627 rakwb eng Radiation studies of aryl glycosides - Part VI. Radicals derived from Phenyl β-d-glucopyranosides 1973 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after irradiation of the compounds in the solid state and in frozen, aqueous solutions. Cyclohexadienyl radicals are the more stable during thermal annealing and are present in 2-3 times greater yield than the sugar radicals. p-Hydroxy- and methoxy-phenyl β-d-glucopyranosides yield phenoxy radicals, which can be transformed into substituted cyclohexadienyl radicals by thermal annealing. Hydrogen abstraction and inter- and intra-molecular hydrogen-transfer are the most likely processes leading to the radicals which have been identified. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Baugh, P.J. oth Kershaw, K. oth Phillips, G.O. oth Webber, M.G. oth in Carbohydrate Research Amsterdam : Elsevier 31(1973), 2, Seite 199-209 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:31 year:1973 number:2 pages:199-209 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)86185-6 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 31 1973 2 199-209 |
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Radiation studies of aryl glycosides - Part VI. Radicals derived from Phenyl β-d-glucopyranosides |
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Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after irradiation of the compounds in the solid state and in frozen, aqueous solutions. Cyclohexadienyl radicals are the more stable during thermal annealing and are present in 2-3 times greater yield than the sugar radicals. p-Hydroxy- and methoxy-phenyl β-d-glucopyranosides yield phenoxy radicals, which can be transformed into substituted cyclohexadienyl radicals by thermal annealing. Hydrogen abstraction and inter- and intra-molecular hydrogen-transfer are the most likely processes leading to the radicals which have been identified. |
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Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after irradiation of the compounds in the solid state and in frozen, aqueous solutions. Cyclohexadienyl radicals are the more stable during thermal annealing and are present in 2-3 times greater yield than the sugar radicals. p-Hydroxy- and methoxy-phenyl β-d-glucopyranosides yield phenoxy radicals, which can be transformed into substituted cyclohexadienyl radicals by thermal annealing. Hydrogen abstraction and inter- and intra-molecular hydrogen-transfer are the most likely processes leading to the radicals which have been identified. |
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Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after irradiation of the compounds in the solid state and in frozen, aqueous solutions. Cyclohexadienyl radicals are the more stable during thermal annealing and are present in 2-3 times greater yield than the sugar radicals. p-Hydroxy- and methoxy-phenyl β-d-glucopyranosides yield phenoxy radicals, which can be transformed into substituted cyclohexadienyl radicals by thermal annealing. Hydrogen abstraction and inter- and intra-molecular hydrogen-transfer are the most likely processes leading to the radicals which have been identified. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ175464286</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20210706000740.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070505s1973 xx |||||o 00| ||eng c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ175464286</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVNLZ175464286</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Radiation studies of aryl glycosides - Part VI. Radicals derived from Phenyl β-d-glucopyranosides</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1973</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Radicals formed by γ-irradiation of o-, m-, and p-substituted-phenyl β-d-glucopyranosides have been studied in the polycrystalline state, in glassy methanol, and in frozen, aqueous solution. Substituted cyclohexadienyl radicals and radicals derived from the d-glucopyranosyl group are evident after irradiation of the compounds in the solid state and in frozen, aqueous solutions. Cyclohexadienyl radicals are the more stable during thermal annealing and are present in 2-3 times greater yield than the sugar radicals. p-Hydroxy- and methoxy-phenyl β-d-glucopyranosides yield phenoxy radicals, which can be transformed into substituted cyclohexadienyl radicals by thermal annealing. Hydrogen abstraction and inter- and intra-molecular hydrogen-transfer are the most likely processes leading to the radicals which have been identified.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Elsevier Journal Backfiles on ScienceDirect 1907 - 2002</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Baugh, P.J.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kershaw, K.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Phillips, G.O.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Webber, M.G.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Carbohydrate Research</subfield><subfield code="d">Amsterdam : Elsevier</subfield><subfield code="g">31(1973), 2, Seite 199-209</subfield><subfield code="w">(DE-627)NLEJ175413258</subfield><subfield code="w">(DE-600)1496822-8</subfield><subfield code="x">0008-6215</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:31</subfield><subfield code="g">year:1973</subfield><subfield code="g">number:2</subfield><subfield code="g">pages:199-209</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)86185-6</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_H</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-SDJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">31</subfield><subfield code="j">1973</subfield><subfield code="e">2</subfield><subfield code="h">199-209</subfield></datafield></record></collection>
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