Synthese par aldolisation dirigee des 2-desoxy-2-C-methylene-D-erythro- ET -D-threo-pentoses
Branched-chain sugars with a CH"2-2 group were obtained by aldol condensation at 70^o between 1.1-diethoxy-2-lithio-2-propene and 2,3-O-isopropylidene-D- glyceraldehyde. Depending on the experimental procedure, hydrolysis in acidic medium of the products, precursors of C-2 branched-chain pentos...
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E-Artikel |
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Englisch |
| Erschienen: |
1980 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Carbohydrate Research - Amsterdam : Elsevier, 83(1980), 1, Seite 51-62 |
| Übergeordnetes Werk: |
volume:83 ; year:1980 ; number:1 ; pages:51-62 |
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| 520 | |a Branched-chain sugars with a CH"2-2 group were obtained by aldol condensation at 70^o between 1.1-diethoxy-2-lithio-2-propene and 2,3-O-isopropylidene-D- glyceraldehyde. Depending on the experimental procedure, hydrolysis in acidic medium of the products, precursors of C-2 branched-chain pentoses, led to methyl 2-deoxy-2-C-methylene-β-D-erythro- and -α-D-threo-pentopyranosides, 2,4-disubstituted furans, or unsaturated aldehydes transformed into the corresponding α methylenelactones. | ||
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(DE-627)NLEJ175466505 (DE-599)GBVNLZ175466505 DE-627 ger DE-627 rakwb eng Synthese par aldolisation dirigee des 2-desoxy-2-C-methylene-D-erythro- ET -D-threo-pentoses 1980 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Branched-chain sugars with a CH"2-2 group were obtained by aldol condensation at 70^o between 1.1-diethoxy-2-lithio-2-propene and 2,3-O-isopropylidene-D- glyceraldehyde. Depending on the experimental procedure, hydrolysis in acidic medium of the products, precursors of C-2 branched-chain pentoses, led to methyl 2-deoxy-2-C-methylene-β-D-erythro- and -α-D-threo-pentopyranosides, 2,4-disubstituted furans, or unsaturated aldehydes transformed into the corresponding α methylenelactones. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Depezay, J.-C. oth Le Merrer, Y. oth in Carbohydrate Research Amsterdam : Elsevier 83(1980), 1, Seite 51-62 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:83 year:1980 number:1 pages:51-62 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)85363-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 83 1980 1 51-62 |
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(DE-627)NLEJ175466505 (DE-599)GBVNLZ175466505 DE-627 ger DE-627 rakwb eng Synthese par aldolisation dirigee des 2-desoxy-2-C-methylene-D-erythro- ET -D-threo-pentoses 1980 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Branched-chain sugars with a CH"2-2 group were obtained by aldol condensation at 70^o between 1.1-diethoxy-2-lithio-2-propene and 2,3-O-isopropylidene-D- glyceraldehyde. Depending on the experimental procedure, hydrolysis in acidic medium of the products, precursors of C-2 branched-chain pentoses, led to methyl 2-deoxy-2-C-methylene-β-D-erythro- and -α-D-threo-pentopyranosides, 2,4-disubstituted furans, or unsaturated aldehydes transformed into the corresponding α methylenelactones. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Depezay, J.-C. oth Le Merrer, Y. oth in Carbohydrate Research Amsterdam : Elsevier 83(1980), 1, Seite 51-62 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:83 year:1980 number:1 pages:51-62 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)85363-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 83 1980 1 51-62 |
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(DE-627)NLEJ175466505 (DE-599)GBVNLZ175466505 DE-627 ger DE-627 rakwb eng Synthese par aldolisation dirigee des 2-desoxy-2-C-methylene-D-erythro- ET -D-threo-pentoses 1980 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Branched-chain sugars with a CH"2-2 group were obtained by aldol condensation at 70^o between 1.1-diethoxy-2-lithio-2-propene and 2,3-O-isopropylidene-D- glyceraldehyde. Depending on the experimental procedure, hydrolysis in acidic medium of the products, precursors of C-2 branched-chain pentoses, led to methyl 2-deoxy-2-C-methylene-β-D-erythro- and -α-D-threo-pentopyranosides, 2,4-disubstituted furans, or unsaturated aldehydes transformed into the corresponding α methylenelactones. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Depezay, J.-C. oth Le Merrer, Y. oth in Carbohydrate Research Amsterdam : Elsevier 83(1980), 1, Seite 51-62 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:83 year:1980 number:1 pages:51-62 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)85363-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 83 1980 1 51-62 |
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(DE-627)NLEJ175466505 (DE-599)GBVNLZ175466505 DE-627 ger DE-627 rakwb eng Synthese par aldolisation dirigee des 2-desoxy-2-C-methylene-D-erythro- ET -D-threo-pentoses 1980 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Branched-chain sugars with a CH"2-2 group were obtained by aldol condensation at 70^o between 1.1-diethoxy-2-lithio-2-propene and 2,3-O-isopropylidene-D- glyceraldehyde. Depending on the experimental procedure, hydrolysis in acidic medium of the products, precursors of C-2 branched-chain pentoses, led to methyl 2-deoxy-2-C-methylene-β-D-erythro- and -α-D-threo-pentopyranosides, 2,4-disubstituted furans, or unsaturated aldehydes transformed into the corresponding α methylenelactones. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Depezay, J.-C. oth Le Merrer, Y. oth in Carbohydrate Research Amsterdam : Elsevier 83(1980), 1, Seite 51-62 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:83 year:1980 number:1 pages:51-62 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)85363-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 83 1980 1 51-62 |
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(DE-627)NLEJ175466505 (DE-599)GBVNLZ175466505 DE-627 ger DE-627 rakwb eng Synthese par aldolisation dirigee des 2-desoxy-2-C-methylene-D-erythro- ET -D-threo-pentoses 1980 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Branched-chain sugars with a CH"2-2 group were obtained by aldol condensation at 70^o between 1.1-diethoxy-2-lithio-2-propene and 2,3-O-isopropylidene-D- glyceraldehyde. Depending on the experimental procedure, hydrolysis in acidic medium of the products, precursors of C-2 branched-chain pentoses, led to methyl 2-deoxy-2-C-methylene-β-D-erythro- and -α-D-threo-pentopyranosides, 2,4-disubstituted furans, or unsaturated aldehydes transformed into the corresponding α methylenelactones. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Depezay, J.-C. oth Le Merrer, Y. oth in Carbohydrate Research Amsterdam : Elsevier 83(1980), 1, Seite 51-62 (DE-627)NLEJ175413258 (DE-600)1496822-8 0008-6215 nnns volume:83 year:1980 number:1 pages:51-62 http://linkinghub.elsevier.com/retrieve/pii/S0008-6215(00)85363-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 83 1980 1 51-62 |
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Synthese par aldolisation dirigee des 2-desoxy-2-C-methylene-D-erythro- ET -D-threo-pentoses |
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Branched-chain sugars with a CH"2-2 group were obtained by aldol condensation at 70^o between 1.1-diethoxy-2-lithio-2-propene and 2,3-O-isopropylidene-D- glyceraldehyde. Depending on the experimental procedure, hydrolysis in acidic medium of the products, precursors of C-2 branched-chain pentoses, led to methyl 2-deoxy-2-C-methylene-β-D-erythro- and -α-D-threo-pentopyranosides, 2,4-disubstituted furans, or unsaturated aldehydes transformed into the corresponding α methylenelactones. |
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Branched-chain sugars with a CH"2-2 group were obtained by aldol condensation at 70^o between 1.1-diethoxy-2-lithio-2-propene and 2,3-O-isopropylidene-D- glyceraldehyde. Depending on the experimental procedure, hydrolysis in acidic medium of the products, precursors of C-2 branched-chain pentoses, led to methyl 2-deoxy-2-C-methylene-β-D-erythro- and -α-D-threo-pentopyranosides, 2,4-disubstituted furans, or unsaturated aldehydes transformed into the corresponding α methylenelactones. |
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Branched-chain sugars with a CH"2-2 group were obtained by aldol condensation at 70^o between 1.1-diethoxy-2-lithio-2-propene and 2,3-O-isopropylidene-D- glyceraldehyde. Depending on the experimental procedure, hydrolysis in acidic medium of the products, precursors of C-2 branched-chain pentoses, led to methyl 2-deoxy-2-C-methylene-β-D-erythro- and -α-D-threo-pentopyranosides, 2,4-disubstituted furans, or unsaturated aldehydes transformed into the corresponding α methylenelactones. |
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