Syntheses of enantiomerically pure 9(S)- and 9(R)-hete from D-mannitol. Use of a malic dialdehyde equivalent.
Starting from D-mannitol, the total syntheses of methyl 9(S)- and 9(R)-hydroxy 5(Z), 7(E), 11(Z) eicosatetraenoate are described by two different ways. One route uses a diepoxide opening by an acetylide while the second one involved the transformation of a diepoxide into an equivalent of malic aldeh...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1989 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Tetrahedron - Amsterdam : Elsevier, 45(1989), 23, Seite 7317-7328 |
| Übergeordnetes Werk: |
volume:45 ; year:1989 ; number:23 ; pages:7317-7328 |
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| 520 | |a Starting from D-mannitol, the total syntheses of methyl 9(S)- and 9(R)-hydroxy 5(Z), 7(E), 11(Z) eicosatetraenoate are described by two different ways. One route uses a diepoxide opening by an acetylide while the second one involved the transformation of a diepoxide into an equivalent of malic aldehyde, an important intermediate in the synthesis of other oxidation products of arachidonic acid. Both methods are available for the synthesis of each enantiomer. | ||
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(DE-627)NLEJ175927235 (DE-599)GBVNLZ175927235 DE-627 ger DE-627 rakwb eng Syntheses of enantiomerically pure 9(S)- and 9(R)-hete from D-mannitol. Use of a malic dialdehyde equivalent. 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Starting from D-mannitol, the total syntheses of methyl 9(S)- and 9(R)-hydroxy 5(Z), 7(E), 11(Z) eicosatetraenoate are described by two different ways. One route uses a diepoxide opening by an acetylide while the second one involved the transformation of a diepoxide into an equivalent of malic aldehyde, an important intermediate in the synthesis of other oxidation products of arachidonic acid. Both methods are available for the synthesis of each enantiomer. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Saniere, M. oth Merrer, Y.L. oth Barbe, B. oth Koscielniak, T. oth Depezay, J.C. oth in Tetrahedron Amsterdam : Elsevier 45(1989), 23, Seite 7317-7328 (DE-627)NLEJ175783357 (DE-600)2007072-X 0040-4020 nnns volume:45 year:1989 number:23 pages:7317-7328 http://linkinghub.elsevier.com/retrieve/pii/S0040-4020(01)89193-6 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 45 1989 23 7317-7328 |
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(DE-627)NLEJ175927235 (DE-599)GBVNLZ175927235 DE-627 ger DE-627 rakwb eng Syntheses of enantiomerically pure 9(S)- and 9(R)-hete from D-mannitol. Use of a malic dialdehyde equivalent. 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Starting from D-mannitol, the total syntheses of methyl 9(S)- and 9(R)-hydroxy 5(Z), 7(E), 11(Z) eicosatetraenoate are described by two different ways. One route uses a diepoxide opening by an acetylide while the second one involved the transformation of a diepoxide into an equivalent of malic aldehyde, an important intermediate in the synthesis of other oxidation products of arachidonic acid. Both methods are available for the synthesis of each enantiomer. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Saniere, M. oth Merrer, Y.L. oth Barbe, B. oth Koscielniak, T. oth Depezay, J.C. oth in Tetrahedron Amsterdam : Elsevier 45(1989), 23, Seite 7317-7328 (DE-627)NLEJ175783357 (DE-600)2007072-X 0040-4020 nnns volume:45 year:1989 number:23 pages:7317-7328 http://linkinghub.elsevier.com/retrieve/pii/S0040-4020(01)89193-6 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 45 1989 23 7317-7328 |
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(DE-627)NLEJ175927235 (DE-599)GBVNLZ175927235 DE-627 ger DE-627 rakwb eng Syntheses of enantiomerically pure 9(S)- and 9(R)-hete from D-mannitol. Use of a malic dialdehyde equivalent. 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Starting from D-mannitol, the total syntheses of methyl 9(S)- and 9(R)-hydroxy 5(Z), 7(E), 11(Z) eicosatetraenoate are described by two different ways. One route uses a diepoxide opening by an acetylide while the second one involved the transformation of a diepoxide into an equivalent of malic aldehyde, an important intermediate in the synthesis of other oxidation products of arachidonic acid. Both methods are available for the synthesis of each enantiomer. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Saniere, M. oth Merrer, Y.L. oth Barbe, B. oth Koscielniak, T. oth Depezay, J.C. oth in Tetrahedron Amsterdam : Elsevier 45(1989), 23, Seite 7317-7328 (DE-627)NLEJ175783357 (DE-600)2007072-X 0040-4020 nnns volume:45 year:1989 number:23 pages:7317-7328 http://linkinghub.elsevier.com/retrieve/pii/S0040-4020(01)89193-6 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 45 1989 23 7317-7328 |
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(DE-627)NLEJ175927235 (DE-599)GBVNLZ175927235 DE-627 ger DE-627 rakwb eng Syntheses of enantiomerically pure 9(S)- and 9(R)-hete from D-mannitol. Use of a malic dialdehyde equivalent. 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Starting from D-mannitol, the total syntheses of methyl 9(S)- and 9(R)-hydroxy 5(Z), 7(E), 11(Z) eicosatetraenoate are described by two different ways. One route uses a diepoxide opening by an acetylide while the second one involved the transformation of a diepoxide into an equivalent of malic aldehyde, an important intermediate in the synthesis of other oxidation products of arachidonic acid. Both methods are available for the synthesis of each enantiomer. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Saniere, M. oth Merrer, Y.L. oth Barbe, B. oth Koscielniak, T. oth Depezay, J.C. oth in Tetrahedron Amsterdam : Elsevier 45(1989), 23, Seite 7317-7328 (DE-627)NLEJ175783357 (DE-600)2007072-X 0040-4020 nnns volume:45 year:1989 number:23 pages:7317-7328 http://linkinghub.elsevier.com/retrieve/pii/S0040-4020(01)89193-6 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 45 1989 23 7317-7328 |
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(DE-627)NLEJ175927235 (DE-599)GBVNLZ175927235 DE-627 ger DE-627 rakwb eng Syntheses of enantiomerically pure 9(S)- and 9(R)-hete from D-mannitol. Use of a malic dialdehyde equivalent. 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Starting from D-mannitol, the total syntheses of methyl 9(S)- and 9(R)-hydroxy 5(Z), 7(E), 11(Z) eicosatetraenoate are described by two different ways. One route uses a diepoxide opening by an acetylide while the second one involved the transformation of a diepoxide into an equivalent of malic aldehyde, an important intermediate in the synthesis of other oxidation products of arachidonic acid. Both methods are available for the synthesis of each enantiomer. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Saniere, M. oth Merrer, Y.L. oth Barbe, B. oth Koscielniak, T. oth Depezay, J.C. oth in Tetrahedron Amsterdam : Elsevier 45(1989), 23, Seite 7317-7328 (DE-627)NLEJ175783357 (DE-600)2007072-X 0040-4020 nnns volume:45 year:1989 number:23 pages:7317-7328 http://linkinghub.elsevier.com/retrieve/pii/S0040-4020(01)89193-6 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 45 1989 23 7317-7328 |
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syntheses of enantiomerically pure 9(s)- and 9(r)-hete from d-mannitol. use of a malic dialdehyde equivalent |
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Syntheses of enantiomerically pure 9(S)- and 9(R)-hete from D-mannitol. Use of a malic dialdehyde equivalent. |
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Starting from D-mannitol, the total syntheses of methyl 9(S)- and 9(R)-hydroxy 5(Z), 7(E), 11(Z) eicosatetraenoate are described by two different ways. One route uses a diepoxide opening by an acetylide while the second one involved the transformation of a diepoxide into an equivalent of malic aldehyde, an important intermediate in the synthesis of other oxidation products of arachidonic acid. Both methods are available for the synthesis of each enantiomer. |
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Starting from D-mannitol, the total syntheses of methyl 9(S)- and 9(R)-hydroxy 5(Z), 7(E), 11(Z) eicosatetraenoate are described by two different ways. One route uses a diepoxide opening by an acetylide while the second one involved the transformation of a diepoxide into an equivalent of malic aldehyde, an important intermediate in the synthesis of other oxidation products of arachidonic acid. Both methods are available for the synthesis of each enantiomer. |
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Starting from D-mannitol, the total syntheses of methyl 9(S)- and 9(R)-hydroxy 5(Z), 7(E), 11(Z) eicosatetraenoate are described by two different ways. One route uses a diepoxide opening by an acetylide while the second one involved the transformation of a diepoxide into an equivalent of malic aldehyde, an important intermediate in the synthesis of other oxidation products of arachidonic acid. Both methods are available for the synthesis of each enantiomer. |
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Syntheses of enantiomerically pure 9(S)- and 9(R)-hete from D-mannitol. Use of a malic dialdehyde equivalent. |
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