Aglycone fragmentation accompanies β-glucosidase catalyzed hydrolysis of salicortin, a naturally-occurring phenol glycoside
Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates.
Gespeichert in:
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E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1990 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Tetrahedron Letters - Amsterdam : Elsevier, 31(1990), 32, Seite 4537-4538 |
| Übergeordnetes Werk: |
volume:31 ; year:1990 ; number:32 ; pages:4537-4538 |
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| 520 | |a Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates. | ||
| 520 | |a The aglycone of salicortin (1) undergoes an unusual fragmentation/recombination reaction to produce 2 via a proposed ortho-quinone methide pathway. | ||
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(DE-627)NLEJ176309896 (DE-599)GBVNLZ176309896 DE-627 ger DE-627 rakwb eng Aglycone fragmentation accompanies β-glucosidase catalyzed hydrolysis of salicortin, a naturally-occurring phenol glycoside 1990 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates. The aglycone of salicortin (1) undergoes an unusual fragmentation/recombination reaction to produce 2 via a proposed ortho-quinone methide pathway. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Clausen, T.P. oth Koller, J.W. oth Reichardt, P.B. oth in Tetrahedron Letters Amsterdam : Elsevier 31(1990), 32, Seite 4537-4538 (DE-627)NLEJ175981779 (DE-600)2007074-3 0040-4039 nnns volume:31 year:1990 number:32 pages:4537-4538 http://linkinghub.elsevier.com/retrieve/pii/S0040-4039(00)97668-8 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 31 1990 32 4537-4538 |
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(DE-627)NLEJ176309896 (DE-599)GBVNLZ176309896 DE-627 ger DE-627 rakwb eng Aglycone fragmentation accompanies β-glucosidase catalyzed hydrolysis of salicortin, a naturally-occurring phenol glycoside 1990 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates. The aglycone of salicortin (1) undergoes an unusual fragmentation/recombination reaction to produce 2 via a proposed ortho-quinone methide pathway. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Clausen, T.P. oth Koller, J.W. oth Reichardt, P.B. oth in Tetrahedron Letters Amsterdam : Elsevier 31(1990), 32, Seite 4537-4538 (DE-627)NLEJ175981779 (DE-600)2007074-3 0040-4039 nnns volume:31 year:1990 number:32 pages:4537-4538 http://linkinghub.elsevier.com/retrieve/pii/S0040-4039(00)97668-8 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 31 1990 32 4537-4538 |
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(DE-627)NLEJ176309896 (DE-599)GBVNLZ176309896 DE-627 ger DE-627 rakwb eng Aglycone fragmentation accompanies β-glucosidase catalyzed hydrolysis of salicortin, a naturally-occurring phenol glycoside 1990 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates. The aglycone of salicortin (1) undergoes an unusual fragmentation/recombination reaction to produce 2 via a proposed ortho-quinone methide pathway. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Clausen, T.P. oth Koller, J.W. oth Reichardt, P.B. oth in Tetrahedron Letters Amsterdam : Elsevier 31(1990), 32, Seite 4537-4538 (DE-627)NLEJ175981779 (DE-600)2007074-3 0040-4039 nnns volume:31 year:1990 number:32 pages:4537-4538 http://linkinghub.elsevier.com/retrieve/pii/S0040-4039(00)97668-8 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 31 1990 32 4537-4538 |
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(DE-627)NLEJ176309896 (DE-599)GBVNLZ176309896 DE-627 ger DE-627 rakwb eng Aglycone fragmentation accompanies β-glucosidase catalyzed hydrolysis of salicortin, a naturally-occurring phenol glycoside 1990 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates. The aglycone of salicortin (1) undergoes an unusual fragmentation/recombination reaction to produce 2 via a proposed ortho-quinone methide pathway. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Clausen, T.P. oth Koller, J.W. oth Reichardt, P.B. oth in Tetrahedron Letters Amsterdam : Elsevier 31(1990), 32, Seite 4537-4538 (DE-627)NLEJ175981779 (DE-600)2007074-3 0040-4039 nnns volume:31 year:1990 number:32 pages:4537-4538 http://linkinghub.elsevier.com/retrieve/pii/S0040-4039(00)97668-8 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 31 1990 32 4537-4538 |
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(DE-627)NLEJ176309896 (DE-599)GBVNLZ176309896 DE-627 ger DE-627 rakwb eng Aglycone fragmentation accompanies β-glucosidase catalyzed hydrolysis of salicortin, a naturally-occurring phenol glycoside 1990 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates. The aglycone of salicortin (1) undergoes an unusual fragmentation/recombination reaction to produce 2 via a proposed ortho-quinone methide pathway. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Clausen, T.P. oth Koller, J.W. oth Reichardt, P.B. oth in Tetrahedron Letters Amsterdam : Elsevier 31(1990), 32, Seite 4537-4538 (DE-627)NLEJ175981779 (DE-600)2007074-3 0040-4039 nnns volume:31 year:1990 number:32 pages:4537-4538 http://linkinghub.elsevier.com/retrieve/pii/S0040-4039(00)97668-8 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 31 1990 32 4537-4538 |
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aglycone fragmentation accompanies β-glucosidase catalyzed hydrolysis of salicortin, a naturally-occurring phenol glycoside |
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Aglycone fragmentation accompanies β-glucosidase catalyzed hydrolysis of salicortin, a naturally-occurring phenol glycoside |
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Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates. The aglycone of salicortin (1) undergoes an unusual fragmentation/recombination reaction to produce 2 via a proposed ortho-quinone methide pathway. |
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Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates. The aglycone of salicortin (1) undergoes an unusual fragmentation/recombination reaction to produce 2 via a proposed ortho-quinone methide pathway. |
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Salicortin (1a), upon enzyme-mediated glycosidic hydrolysis, undergoes an unusual and rapid fragmentation-recombination reaction leading to 2 via postulated ortho-quinone methide (3) and enol (4) intermediates. The aglycone of salicortin (1) undergoes an unusual fragmentation/recombination reaction to produce 2 via a proposed ortho-quinone methide pathway. |
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Aglycone fragmentation accompanies β-glucosidase catalyzed hydrolysis of salicortin, a naturally-occurring phenol glycoside |
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