Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides
The Z:E ratios for the trifluoroethanolysis at 25^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values.
Gespeichert in:
| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1992 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Tetrahedron Letters - Amsterdam : Elsevier, 33(1992), 23, Seite 3335-3338 |
| Übergeordnetes Werk: |
volume:33 ; year:1992 ; number:23 ; pages:3335-3338 |
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| 245 | 1 | 0 | |a Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides |
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| 520 | |a The Z:E ratios for the trifluoroethanolysis at 25^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values. | ||
| 520 | |a The Z:E rate ratios for the trifluoroethanolysis at 25 ^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively. | ||
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(DE-627)NLEJ176328602 (DE-599)GBVNLZ176328602 DE-627 ger DE-627 rakwb eng Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides 1992 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The Z:E ratios for the trifluoroethanolysis at 25^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values. The Z:E rate ratios for the trifluoroethanolysis at 25 ^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Takeuchi, K. oth Ohga, Y. oth Munakata, M. oth Kitagawa, T. oth Kinoshita, T. oth in Tetrahedron Letters Amsterdam : Elsevier 33(1992), 23, Seite 3335-3338 (DE-627)NLEJ175981779 (DE-600)2007074-3 0040-4039 nnns volume:33 year:1992 number:23 pages:3335-3338 http://linkinghub.elsevier.com/retrieve/pii/S0040-4039(00)92082-3 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 33 1992 23 3335-3338 |
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(DE-627)NLEJ176328602 (DE-599)GBVNLZ176328602 DE-627 ger DE-627 rakwb eng Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides 1992 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The Z:E ratios for the trifluoroethanolysis at 25^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values. The Z:E rate ratios for the trifluoroethanolysis at 25 ^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Takeuchi, K. oth Ohga, Y. oth Munakata, M. oth Kitagawa, T. oth Kinoshita, T. oth in Tetrahedron Letters Amsterdam : Elsevier 33(1992), 23, Seite 3335-3338 (DE-627)NLEJ175981779 (DE-600)2007074-3 0040-4039 nnns volume:33 year:1992 number:23 pages:3335-3338 http://linkinghub.elsevier.com/retrieve/pii/S0040-4039(00)92082-3 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 33 1992 23 3335-3338 |
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(DE-627)NLEJ176328602 (DE-599)GBVNLZ176328602 DE-627 ger DE-627 rakwb eng Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides 1992 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The Z:E ratios for the trifluoroethanolysis at 25^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values. The Z:E rate ratios for the trifluoroethanolysis at 25 ^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Takeuchi, K. oth Ohga, Y. oth Munakata, M. oth Kitagawa, T. oth Kinoshita, T. oth in Tetrahedron Letters Amsterdam : Elsevier 33(1992), 23, Seite 3335-3338 (DE-627)NLEJ175981779 (DE-600)2007074-3 0040-4039 nnns volume:33 year:1992 number:23 pages:3335-3338 http://linkinghub.elsevier.com/retrieve/pii/S0040-4039(00)92082-3 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 33 1992 23 3335-3338 |
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(DE-627)NLEJ176328602 (DE-599)GBVNLZ176328602 DE-627 ger DE-627 rakwb eng Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides 1992 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The Z:E ratios for the trifluoroethanolysis at 25^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values. The Z:E rate ratios for the trifluoroethanolysis at 25 ^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Takeuchi, K. oth Ohga, Y. oth Munakata, M. oth Kitagawa, T. oth Kinoshita, T. oth in Tetrahedron Letters Amsterdam : Elsevier 33(1992), 23, Seite 3335-3338 (DE-627)NLEJ175981779 (DE-600)2007074-3 0040-4039 nnns volume:33 year:1992 number:23 pages:3335-3338 http://linkinghub.elsevier.com/retrieve/pii/S0040-4039(00)92082-3 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 33 1992 23 3335-3338 |
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(DE-627)NLEJ176328602 (DE-599)GBVNLZ176328602 DE-627 ger DE-627 rakwb eng Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides 1992 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The Z:E ratios for the trifluoroethanolysis at 25^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values. The Z:E rate ratios for the trifluoroethanolysis at 25 ^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Takeuchi, K. oth Ohga, Y. oth Munakata, M. oth Kitagawa, T. oth Kinoshita, T. oth in Tetrahedron Letters Amsterdam : Elsevier 33(1992), 23, Seite 3335-3338 (DE-627)NLEJ175981779 (DE-600)2007074-3 0040-4039 nnns volume:33 year:1992 number:23 pages:3335-3338 http://linkinghub.elsevier.com/retrieve/pii/S0040-4039(00)92082-3 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 33 1992 23 3335-3338 |
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Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides |
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quantitative treatment of rate enhancement due to f-strain in the solvolysis of z-2-ethylidene-1-adamantyl mesylate and halides |
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Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides |
| abstract |
The Z:E ratios for the trifluoroethanolysis at 25^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values. The Z:E rate ratios for the trifluoroethanolysis at 25 ^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively. |
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The Z:E ratios for the trifluoroethanolysis at 25^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values. The Z:E rate ratios for the trifluoroethanolysis at 25 ^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively. |
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The Z:E ratios for the trifluoroethanolysis at 25^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively, whose logarithms are linearly correlated with MM2 steric energies and Hansch's Es values. The Z:E rate ratios for the trifluoroethanolysis at 25 ^oC of the title mesylate, chloride, bromide, and iodide are 126, 1020, 2230, and 9680, respectively. |
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Quantitative treatment of rate enhancement due to f-strain in the solvolysis of Z-2-ethylidene-1-adamantyl mesylate and halides |
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