Raman measurements of the mobile cation vibrations in Na, K, Ag and Li β''-alumina
Polarized Raman measurements have been made for single crystals of Na, K, Ag and Li β''-alumina. For each material, the modes due principally to the mobile cations have been identified. The number and symmetry of the observed modes can best be explained by considering the local ordering of...
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| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1983 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Solid State Ionics - Amsterdam : Elsevier, 9-10(1983), Seite 207-214 |
| Übergeordnetes Werk: |
volume:9-10 ; year:1983 ; pages:207-214 |
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| 245 | 1 | 0 | |a Raman measurements of the mobile cation vibrations in Na, K, Ag and Li β''-alumina |
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| 520 | |a Polarized Raman measurements have been made for single crystals of Na, K, Ag and Li β''-alumina. For each material, the modes due principally to the mobile cations have been identified. The number and symmetry of the observed modes can best be explained by considering the local ordering of the cations as a two-dimensional superlattice. Raman spectra for a number of Na β''-alumina samples with different growth temperatures, compositions, and degrees of hydration were carefully compared. Several of the observed differences in the Raman intensities can be attributed to the effects of either composition or short-range superlattice ordering. A Raman mode which is a likely candidate for the attempt mode for diffusion has been identified for the Na, K and Ag crystals. | ||
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(DE-627)NLEJ179038869 (DE-599)GBVNLZ179038869 DE-627 ger DE-627 rakwb eng Raman measurements of the mobile cation vibrations in Na, K, Ag and Li β''-alumina 1983 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Polarized Raman measurements have been made for single crystals of Na, K, Ag and Li β''-alumina. For each material, the modes due principally to the mobile cations have been identified. The number and symmetry of the observed modes can best be explained by considering the local ordering of the cations as a two-dimensional superlattice. Raman spectra for a number of Na β''-alumina samples with different growth temperatures, compositions, and degrees of hydration were carefully compared. Several of the observed differences in the Raman intensities can be attributed to the effects of either composition or short-range superlattice ordering. A Raman mode which is a likely candidate for the attempt mode for diffusion has been identified for the Na, K and Ag crystals. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dudney, N.J. oth Bates, J.B. oth Brundage, W.E. oth in Solid State Ionics Amsterdam : Elsevier 9-10(1983), Seite 207-214 (DE-627)NLEJ177061618 (DE-600)1500750-9 0167-2738 nnns volume:9-10 year:1983 pages:207-214 http://linkinghub.elsevier.com/retrieve/pii/0167-2738(83)90235-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 9-10 1983 207-214 |
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(DE-627)NLEJ179038869 (DE-599)GBVNLZ179038869 DE-627 ger DE-627 rakwb eng Raman measurements of the mobile cation vibrations in Na, K, Ag and Li β''-alumina 1983 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Polarized Raman measurements have been made for single crystals of Na, K, Ag and Li β''-alumina. For each material, the modes due principally to the mobile cations have been identified. The number and symmetry of the observed modes can best be explained by considering the local ordering of the cations as a two-dimensional superlattice. Raman spectra for a number of Na β''-alumina samples with different growth temperatures, compositions, and degrees of hydration were carefully compared. Several of the observed differences in the Raman intensities can be attributed to the effects of either composition or short-range superlattice ordering. A Raman mode which is a likely candidate for the attempt mode for diffusion has been identified for the Na, K and Ag crystals. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dudney, N.J. oth Bates, J.B. oth Brundage, W.E. oth in Solid State Ionics Amsterdam : Elsevier 9-10(1983), Seite 207-214 (DE-627)NLEJ177061618 (DE-600)1500750-9 0167-2738 nnns volume:9-10 year:1983 pages:207-214 http://linkinghub.elsevier.com/retrieve/pii/0167-2738(83)90235-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 9-10 1983 207-214 |
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(DE-627)NLEJ179038869 (DE-599)GBVNLZ179038869 DE-627 ger DE-627 rakwb eng Raman measurements of the mobile cation vibrations in Na, K, Ag and Li β''-alumina 1983 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Polarized Raman measurements have been made for single crystals of Na, K, Ag and Li β''-alumina. For each material, the modes due principally to the mobile cations have been identified. The number and symmetry of the observed modes can best be explained by considering the local ordering of the cations as a two-dimensional superlattice. Raman spectra for a number of Na β''-alumina samples with different growth temperatures, compositions, and degrees of hydration were carefully compared. Several of the observed differences in the Raman intensities can be attributed to the effects of either composition or short-range superlattice ordering. A Raman mode which is a likely candidate for the attempt mode for diffusion has been identified for the Na, K and Ag crystals. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dudney, N.J. oth Bates, J.B. oth Brundage, W.E. oth in Solid State Ionics Amsterdam : Elsevier 9-10(1983), Seite 207-214 (DE-627)NLEJ177061618 (DE-600)1500750-9 0167-2738 nnns volume:9-10 year:1983 pages:207-214 http://linkinghub.elsevier.com/retrieve/pii/0167-2738(83)90235-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 9-10 1983 207-214 |
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(DE-627)NLEJ179038869 (DE-599)GBVNLZ179038869 DE-627 ger DE-627 rakwb eng Raman measurements of the mobile cation vibrations in Na, K, Ag and Li β''-alumina 1983 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Polarized Raman measurements have been made for single crystals of Na, K, Ag and Li β''-alumina. For each material, the modes due principally to the mobile cations have been identified. The number and symmetry of the observed modes can best be explained by considering the local ordering of the cations as a two-dimensional superlattice. Raman spectra for a number of Na β''-alumina samples with different growth temperatures, compositions, and degrees of hydration were carefully compared. Several of the observed differences in the Raman intensities can be attributed to the effects of either composition or short-range superlattice ordering. A Raman mode which is a likely candidate for the attempt mode for diffusion has been identified for the Na, K and Ag crystals. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dudney, N.J. oth Bates, J.B. oth Brundage, W.E. oth in Solid State Ionics Amsterdam : Elsevier 9-10(1983), Seite 207-214 (DE-627)NLEJ177061618 (DE-600)1500750-9 0167-2738 nnns volume:9-10 year:1983 pages:207-214 http://linkinghub.elsevier.com/retrieve/pii/0167-2738(83)90235-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 9-10 1983 207-214 |
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(DE-627)NLEJ179038869 (DE-599)GBVNLZ179038869 DE-627 ger DE-627 rakwb eng Raman measurements of the mobile cation vibrations in Na, K, Ag and Li β''-alumina 1983 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Polarized Raman measurements have been made for single crystals of Na, K, Ag and Li β''-alumina. For each material, the modes due principally to the mobile cations have been identified. The number and symmetry of the observed modes can best be explained by considering the local ordering of the cations as a two-dimensional superlattice. Raman spectra for a number of Na β''-alumina samples with different growth temperatures, compositions, and degrees of hydration were carefully compared. Several of the observed differences in the Raman intensities can be attributed to the effects of either composition or short-range superlattice ordering. A Raman mode which is a likely candidate for the attempt mode for diffusion has been identified for the Na, K and Ag crystals. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dudney, N.J. oth Bates, J.B. oth Brundage, W.E. oth in Solid State Ionics Amsterdam : Elsevier 9-10(1983), Seite 207-214 (DE-627)NLEJ177061618 (DE-600)1500750-9 0167-2738 nnns volume:9-10 year:1983 pages:207-214 http://linkinghub.elsevier.com/retrieve/pii/0167-2738(83)90235-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 9-10 1983 207-214 |
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raman measurements of the mobile cation vibrations in na, k, ag and li β''-alumina |
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Raman measurements of the mobile cation vibrations in Na, K, Ag and Li β''-alumina |
| abstract |
Polarized Raman measurements have been made for single crystals of Na, K, Ag and Li β''-alumina. For each material, the modes due principally to the mobile cations have been identified. The number and symmetry of the observed modes can best be explained by considering the local ordering of the cations as a two-dimensional superlattice. Raman spectra for a number of Na β''-alumina samples with different growth temperatures, compositions, and degrees of hydration were carefully compared. Several of the observed differences in the Raman intensities can be attributed to the effects of either composition or short-range superlattice ordering. A Raman mode which is a likely candidate for the attempt mode for diffusion has been identified for the Na, K and Ag crystals. |
| abstractGer |
Polarized Raman measurements have been made for single crystals of Na, K, Ag and Li β''-alumina. For each material, the modes due principally to the mobile cations have been identified. The number and symmetry of the observed modes can best be explained by considering the local ordering of the cations as a two-dimensional superlattice. Raman spectra for a number of Na β''-alumina samples with different growth temperatures, compositions, and degrees of hydration were carefully compared. Several of the observed differences in the Raman intensities can be attributed to the effects of either composition or short-range superlattice ordering. A Raman mode which is a likely candidate for the attempt mode for diffusion has been identified for the Na, K and Ag crystals. |
| abstract_unstemmed |
Polarized Raman measurements have been made for single crystals of Na, K, Ag and Li β''-alumina. For each material, the modes due principally to the mobile cations have been identified. The number and symmetry of the observed modes can best be explained by considering the local ordering of the cations as a two-dimensional superlattice. Raman spectra for a number of Na β''-alumina samples with different growth temperatures, compositions, and degrees of hydration were carefully compared. Several of the observed differences in the Raman intensities can be attributed to the effects of either composition or short-range superlattice ordering. A Raman mode which is a likely candidate for the attempt mode for diffusion has been identified for the Na, K and Ag crystals. |
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Raman measurements of the mobile cation vibrations in Na, K, Ag and Li β''-alumina |
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