Ion exchange reaction of silver and sodium β''-alumina in molten mercury salts
Single and polycrystalline samples of Ag and Na β''-alumina were treated in molten HgCl"2 and HgI"2 and then examined by energy dispersive X-ray analysis. A measurable exchange of Hg^2^+ ions for the mobile ions in the β'' lattice was obtained only from the single cryst...
Ausführliche Beschreibung
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| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1989 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Solid State Ionics - Amsterdam : Elsevier, 34(1989), 1-2, Seite 53-59 |
| Übergeordnetes Werk: |
volume:34 ; year:1989 ; number:1-2 ; pages:53-59 |
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| 520 | |a Single and polycrystalline samples of Ag and Na β''-alumina were treated in molten HgCl"2 and HgI"2 and then examined by energy dispersive X-ray analysis. A measurable exchange of Hg^2^+ ions for the mobile ions in the β'' lattice was obtained only from the single crystal Ag β''-alumina samples. Treating these crystals in HgI"2 gave the largest fraction of ion exchange. Our results indicate that the mercury exchange is limited by unfavorable thermodynamics. Estimates of the equilibrium distribution of Hg^2^+ and Ag^+ cations in the crystal and molten salt suggest that multiple exchange treatments with a large excess of the mercury salt are necessary to approach complete Hg^2^+ ion exchange by this technique. | ||
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(DE-627)NLEJ179128353 (DE-599)GBVNLZ179128353 DE-627 ger DE-627 rakwb eng Ion exchange reaction of silver and sodium β''-alumina in molten mercury salts 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Single and polycrystalline samples of Ag and Na β''-alumina were treated in molten HgCl"2 and HgI"2 and then examined by energy dispersive X-ray analysis. A measurable exchange of Hg^2^+ ions for the mobile ions in the β'' lattice was obtained only from the single crystal Ag β''-alumina samples. Treating these crystals in HgI"2 gave the largest fraction of ion exchange. Our results indicate that the mercury exchange is limited by unfavorable thermodynamics. Estimates of the equilibrium distribution of Hg^2^+ and Ag^+ cations in the crystal and molten salt suggest that multiple exchange treatments with a large excess of the mercury salt are necessary to approach complete Hg^2^+ ion exchange by this technique. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dudney, N.J. oth Bates, J.B. oth in Solid State Ionics Amsterdam : Elsevier 34(1989), 1-2, Seite 53-59 (DE-627)NLEJ177061618 (DE-600)1500750-9 0167-2738 nnns volume:34 year:1989 number:1-2 pages:53-59 http://linkinghub.elsevier.com/retrieve/pii/0167-2738(89)90430-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 34 1989 1-2 53-59 |
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(DE-627)NLEJ179128353 (DE-599)GBVNLZ179128353 DE-627 ger DE-627 rakwb eng Ion exchange reaction of silver and sodium β''-alumina in molten mercury salts 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Single and polycrystalline samples of Ag and Na β''-alumina were treated in molten HgCl"2 and HgI"2 and then examined by energy dispersive X-ray analysis. A measurable exchange of Hg^2^+ ions for the mobile ions in the β'' lattice was obtained only from the single crystal Ag β''-alumina samples. Treating these crystals in HgI"2 gave the largest fraction of ion exchange. Our results indicate that the mercury exchange is limited by unfavorable thermodynamics. Estimates of the equilibrium distribution of Hg^2^+ and Ag^+ cations in the crystal and molten salt suggest that multiple exchange treatments with a large excess of the mercury salt are necessary to approach complete Hg^2^+ ion exchange by this technique. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dudney, N.J. oth Bates, J.B. oth in Solid State Ionics Amsterdam : Elsevier 34(1989), 1-2, Seite 53-59 (DE-627)NLEJ177061618 (DE-600)1500750-9 0167-2738 nnns volume:34 year:1989 number:1-2 pages:53-59 http://linkinghub.elsevier.com/retrieve/pii/0167-2738(89)90430-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 34 1989 1-2 53-59 |
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(DE-627)NLEJ179128353 (DE-599)GBVNLZ179128353 DE-627 ger DE-627 rakwb eng Ion exchange reaction of silver and sodium β''-alumina in molten mercury salts 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Single and polycrystalline samples of Ag and Na β''-alumina were treated in molten HgCl"2 and HgI"2 and then examined by energy dispersive X-ray analysis. A measurable exchange of Hg^2^+ ions for the mobile ions in the β'' lattice was obtained only from the single crystal Ag β''-alumina samples. Treating these crystals in HgI"2 gave the largest fraction of ion exchange. Our results indicate that the mercury exchange is limited by unfavorable thermodynamics. Estimates of the equilibrium distribution of Hg^2^+ and Ag^+ cations in the crystal and molten salt suggest that multiple exchange treatments with a large excess of the mercury salt are necessary to approach complete Hg^2^+ ion exchange by this technique. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dudney, N.J. oth Bates, J.B. oth in Solid State Ionics Amsterdam : Elsevier 34(1989), 1-2, Seite 53-59 (DE-627)NLEJ177061618 (DE-600)1500750-9 0167-2738 nnns volume:34 year:1989 number:1-2 pages:53-59 http://linkinghub.elsevier.com/retrieve/pii/0167-2738(89)90430-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 34 1989 1-2 53-59 |
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(DE-627)NLEJ179128353 (DE-599)GBVNLZ179128353 DE-627 ger DE-627 rakwb eng Ion exchange reaction of silver and sodium β''-alumina in molten mercury salts 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Single and polycrystalline samples of Ag and Na β''-alumina were treated in molten HgCl"2 and HgI"2 and then examined by energy dispersive X-ray analysis. A measurable exchange of Hg^2^+ ions for the mobile ions in the β'' lattice was obtained only from the single crystal Ag β''-alumina samples. Treating these crystals in HgI"2 gave the largest fraction of ion exchange. Our results indicate that the mercury exchange is limited by unfavorable thermodynamics. Estimates of the equilibrium distribution of Hg^2^+ and Ag^+ cations in the crystal and molten salt suggest that multiple exchange treatments with a large excess of the mercury salt are necessary to approach complete Hg^2^+ ion exchange by this technique. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dudney, N.J. oth Bates, J.B. oth in Solid State Ionics Amsterdam : Elsevier 34(1989), 1-2, Seite 53-59 (DE-627)NLEJ177061618 (DE-600)1500750-9 0167-2738 nnns volume:34 year:1989 number:1-2 pages:53-59 http://linkinghub.elsevier.com/retrieve/pii/0167-2738(89)90430-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 34 1989 1-2 53-59 |
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(DE-627)NLEJ179128353 (DE-599)GBVNLZ179128353 DE-627 ger DE-627 rakwb eng Ion exchange reaction of silver and sodium β''-alumina in molten mercury salts 1989 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Single and polycrystalline samples of Ag and Na β''-alumina were treated in molten HgCl"2 and HgI"2 and then examined by energy dispersive X-ray analysis. A measurable exchange of Hg^2^+ ions for the mobile ions in the β'' lattice was obtained only from the single crystal Ag β''-alumina samples. Treating these crystals in HgI"2 gave the largest fraction of ion exchange. Our results indicate that the mercury exchange is limited by unfavorable thermodynamics. Estimates of the equilibrium distribution of Hg^2^+ and Ag^+ cations in the crystal and molten salt suggest that multiple exchange treatments with a large excess of the mercury salt are necessary to approach complete Hg^2^+ ion exchange by this technique. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Dudney, N.J. oth Bates, J.B. oth in Solid State Ionics Amsterdam : Elsevier 34(1989), 1-2, Seite 53-59 (DE-627)NLEJ177061618 (DE-600)1500750-9 0167-2738 nnns volume:34 year:1989 number:1-2 pages:53-59 http://linkinghub.elsevier.com/retrieve/pii/0167-2738(89)90430-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 34 1989 1-2 53-59 |
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ion exchange reaction of silver and sodium β''-alumina in molten mercury salts |
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Ion exchange reaction of silver and sodium β''-alumina in molten mercury salts |
| abstract |
Single and polycrystalline samples of Ag and Na β''-alumina were treated in molten HgCl"2 and HgI"2 and then examined by energy dispersive X-ray analysis. A measurable exchange of Hg^2^+ ions for the mobile ions in the β'' lattice was obtained only from the single crystal Ag β''-alumina samples. Treating these crystals in HgI"2 gave the largest fraction of ion exchange. Our results indicate that the mercury exchange is limited by unfavorable thermodynamics. Estimates of the equilibrium distribution of Hg^2^+ and Ag^+ cations in the crystal and molten salt suggest that multiple exchange treatments with a large excess of the mercury salt are necessary to approach complete Hg^2^+ ion exchange by this technique. |
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Single and polycrystalline samples of Ag and Na β''-alumina were treated in molten HgCl"2 and HgI"2 and then examined by energy dispersive X-ray analysis. A measurable exchange of Hg^2^+ ions for the mobile ions in the β'' lattice was obtained only from the single crystal Ag β''-alumina samples. Treating these crystals in HgI"2 gave the largest fraction of ion exchange. Our results indicate that the mercury exchange is limited by unfavorable thermodynamics. Estimates of the equilibrium distribution of Hg^2^+ and Ag^+ cations in the crystal and molten salt suggest that multiple exchange treatments with a large excess of the mercury salt are necessary to approach complete Hg^2^+ ion exchange by this technique. |
| abstract_unstemmed |
Single and polycrystalline samples of Ag and Na β''-alumina were treated in molten HgCl"2 and HgI"2 and then examined by energy dispersive X-ray analysis. A measurable exchange of Hg^2^+ ions for the mobile ions in the β'' lattice was obtained only from the single crystal Ag β''-alumina samples. Treating these crystals in HgI"2 gave the largest fraction of ion exchange. Our results indicate that the mercury exchange is limited by unfavorable thermodynamics. Estimates of the equilibrium distribution of Hg^2^+ and Ag^+ cations in the crystal and molten salt suggest that multiple exchange treatments with a large excess of the mercury salt are necessary to approach complete Hg^2^+ ion exchange by this technique. |
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