Sub-Doppler laser spectroscopy of NO"2 in the λ = 592.5-nm region
High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1981 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Journal of Molecular Spectroscopy - Amsterdam : Elsevier, 88(1981), 1, Seite 109-125 |
| Übergeordnetes Werk: |
volume:88 ; year:1981 ; number:1 ; pages:109-125 |
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NLEJ182935701 |
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| 245 | 1 | 0 | |a Sub-Doppler laser spectroscopy of NO"2 in the λ = 592.5-nm region |
| 264 | 1 | |c 1981 | |
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| 520 | |a High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO"2 lines were measured with a ''Lambdameter'' of the Michelson-type with an absolute accuracy of 10^-^3 cm^-^1. The analysis of a K"-"1 = 0 subband showed strong anomalies of the spin splittings in the upper ^2B"2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the ^2B"2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results. | ||
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(DE-627)NLEJ182935701 (DE-599)GBVNLZ182935701 DE-627 ger DE-627 rakwb eng Sub-Doppler laser spectroscopy of NO"2 in the λ = 592.5-nm region 1981 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO"2 lines were measured with a ''Lambdameter'' of the Michelson-type with an absolute accuracy of 10^-^3 cm^-^1. The analysis of a K"-"1 = 0 subband showed strong anomalies of the spin splittings in the upper ^2B"2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the ^2B"2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Foth, H.J. oth Vedder, H.J. oth Demtroder, W. oth in Journal of Molecular Spectroscopy Amsterdam : Elsevier 88(1981), 1, Seite 109-125 (DE-627)NLEJ177259469 (DE-600)1469771-3 0022-2852 nnns volume:88 year:1981 number:1 pages:109-125 http://dx.doi.org/10.1016/0022-2852(81)90358-1 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 88 1981 1 109-125 |
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(DE-627)NLEJ182935701 (DE-599)GBVNLZ182935701 DE-627 ger DE-627 rakwb eng Sub-Doppler laser spectroscopy of NO"2 in the λ = 592.5-nm region 1981 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO"2 lines were measured with a ''Lambdameter'' of the Michelson-type with an absolute accuracy of 10^-^3 cm^-^1. The analysis of a K"-"1 = 0 subband showed strong anomalies of the spin splittings in the upper ^2B"2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the ^2B"2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Foth, H.J. oth Vedder, H.J. oth Demtroder, W. oth in Journal of Molecular Spectroscopy Amsterdam : Elsevier 88(1981), 1, Seite 109-125 (DE-627)NLEJ177259469 (DE-600)1469771-3 0022-2852 nnns volume:88 year:1981 number:1 pages:109-125 http://dx.doi.org/10.1016/0022-2852(81)90358-1 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 88 1981 1 109-125 |
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(DE-627)NLEJ182935701 (DE-599)GBVNLZ182935701 DE-627 ger DE-627 rakwb eng Sub-Doppler laser spectroscopy of NO"2 in the λ = 592.5-nm region 1981 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO"2 lines were measured with a ''Lambdameter'' of the Michelson-type with an absolute accuracy of 10^-^3 cm^-^1. The analysis of a K"-"1 = 0 subband showed strong anomalies of the spin splittings in the upper ^2B"2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the ^2B"2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Foth, H.J. oth Vedder, H.J. oth Demtroder, W. oth in Journal of Molecular Spectroscopy Amsterdam : Elsevier 88(1981), 1, Seite 109-125 (DE-627)NLEJ177259469 (DE-600)1469771-3 0022-2852 nnns volume:88 year:1981 number:1 pages:109-125 http://dx.doi.org/10.1016/0022-2852(81)90358-1 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 88 1981 1 109-125 |
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(DE-627)NLEJ182935701 (DE-599)GBVNLZ182935701 DE-627 ger DE-627 rakwb eng Sub-Doppler laser spectroscopy of NO"2 in the λ = 592.5-nm region 1981 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO"2 lines were measured with a ''Lambdameter'' of the Michelson-type with an absolute accuracy of 10^-^3 cm^-^1. The analysis of a K"-"1 = 0 subband showed strong anomalies of the spin splittings in the upper ^2B"2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the ^2B"2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Foth, H.J. oth Vedder, H.J. oth Demtroder, W. oth in Journal of Molecular Spectroscopy Amsterdam : Elsevier 88(1981), 1, Seite 109-125 (DE-627)NLEJ177259469 (DE-600)1469771-3 0022-2852 nnns volume:88 year:1981 number:1 pages:109-125 http://dx.doi.org/10.1016/0022-2852(81)90358-1 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 88 1981 1 109-125 |
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(DE-627)NLEJ182935701 (DE-599)GBVNLZ182935701 DE-627 ger DE-627 rakwb eng Sub-Doppler laser spectroscopy of NO"2 in the λ = 592.5-nm region 1981 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO"2 lines were measured with a ''Lambdameter'' of the Michelson-type with an absolute accuracy of 10^-^3 cm^-^1. The analysis of a K"-"1 = 0 subband showed strong anomalies of the spin splittings in the upper ^2B"2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the ^2B"2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Foth, H.J. oth Vedder, H.J. oth Demtroder, W. oth in Journal of Molecular Spectroscopy Amsterdam : Elsevier 88(1981), 1, Seite 109-125 (DE-627)NLEJ177259469 (DE-600)1469771-3 0022-2852 nnns volume:88 year:1981 number:1 pages:109-125 http://dx.doi.org/10.1016/0022-2852(81)90358-1 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 88 1981 1 109-125 |
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sub-doppler laser spectroscopy of no"2 in the λ = 592.5-nm region |
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Sub-Doppler laser spectroscopy of NO"2 in the λ = 592.5-nm region |
| abstract |
High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO"2 lines were measured with a ''Lambdameter'' of the Michelson-type with an absolute accuracy of 10^-^3 cm^-^1. The analysis of a K"-"1 = 0 subband showed strong anomalies of the spin splittings in the upper ^2B"2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the ^2B"2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results. |
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High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO"2 lines were measured with a ''Lambdameter'' of the Michelson-type with an absolute accuracy of 10^-^3 cm^-^1. The analysis of a K"-"1 = 0 subband showed strong anomalies of the spin splittings in the upper ^2B"2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the ^2B"2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results. |
| abstract_unstemmed |
High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO"2 lines were measured with a ''Lambdameter'' of the Michelson-type with an absolute accuracy of 10^-^3 cm^-^1. The analysis of a K"-"1 = 0 subband showed strong anomalies of the spin splittings in the upper ^2B"2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the ^2B"2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ182935701</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20210706190945.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070505s1981 xx |||||o 00| ||eng c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ182935701</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVNLZ182935701</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Sub-Doppler laser spectroscopy of NO"2 in the λ = 592.5-nm region</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1981</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">High-resolution excitation spectra of some NO"2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO"2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO"2 lines were measured with a ''Lambdameter'' of the Michelson-type with an absolute accuracy of 10^-^3 cm^-^1. The analysis of a K"-"1 = 0 subband showed strong anomalies of the spin splittings in the upper ^2B"2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the ^2B"2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Elsevier Journal Backfiles on ScienceDirect 1907 - 2002</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Foth, H.J.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Vedder, H.J.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Demtroder, W.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Journal of Molecular Spectroscopy</subfield><subfield code="d">Amsterdam : Elsevier</subfield><subfield code="g">88(1981), 1, Seite 109-125</subfield><subfield code="w">(DE-627)NLEJ177259469</subfield><subfield code="w">(DE-600)1469771-3</subfield><subfield code="x">0022-2852</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:88</subfield><subfield code="g">year:1981</subfield><subfield code="g">number:1</subfield><subfield code="g">pages:109-125</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://dx.doi.org/10.1016/0022-2852(81)90358-1</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_H</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-SDJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">88</subfield><subfield code="j">1981</subfield><subfield code="e">1</subfield><subfield code="h">109-125</subfield></datafield></record></collection>
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