Jahn-Teller Distortions and Cation Distribution in Cu(II)-Me(II) [Me = Mg, Co] Hydroxide Nitrate Solid Solutions-A Spectroscopic and Structural Study
Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it...
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1994 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Journal of Solid State Chemistry - Amsterdam : Elsevier, 108(1994), 1, Seite 37-45 |
| Übergeordnetes Werk: |
volume:108 ; year:1994 ; number:1 ; pages:37-45 |
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| 245 | 1 | 0 | |a Jahn-Teller Distortions and Cation Distribution in Cu(II)-Me(II) [Me = Mg, Co] Hydroxide Nitrate Solid Solutions-A Spectroscopic and Structural Study |
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| 520 | |a Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it provides a larger Jahn-Teller distortion than the Me (OH)"5(ONO"2) site (2). The magnetic exchange coupling between the Cu^2^+ polyhedra is rather large and of antiferromagnetic nature. The electronic and elastic interactions underlying the observed cooperative Jahn-Teller order pattern are analyzed. | ||
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(DE-627)NLEJ185540198 (DE-599)GBVNLZ185540198 DE-627 ger DE-627 rakwb eng Jahn-Teller Distortions and Cation Distribution in Cu(II)-Me(II) [Me = Mg, Co] Hydroxide Nitrate Solid Solutions-A Spectroscopic and Structural Study 1994 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it provides a larger Jahn-Teller distortion than the Me (OH)"5(ONO"2) site (2). The magnetic exchange coupling between the Cu^2^+ polyhedra is rather large and of antiferromagnetic nature. The electronic and elastic interactions underlying the observed cooperative Jahn-Teller order pattern are analyzed. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Atanasov, M. oth Zotov, N. oth Friebel, C. oth Petrov, K. oth Reinen, D. oth in Journal of Solid State Chemistry Amsterdam : Elsevier 108(1994), 1, Seite 37-45 (DE-627)NLEJ176864113 (DE-600)1469806-7 0022-4596 nnns volume:108 year:1994 number:1 pages:37-45 http://dx.doi.org/10.1006/jssc.1994.1006 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 108 1994 1 37-45 |
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(DE-627)NLEJ185540198 (DE-599)GBVNLZ185540198 DE-627 ger DE-627 rakwb eng Jahn-Teller Distortions and Cation Distribution in Cu(II)-Me(II) [Me = Mg, Co] Hydroxide Nitrate Solid Solutions-A Spectroscopic and Structural Study 1994 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it provides a larger Jahn-Teller distortion than the Me (OH)"5(ONO"2) site (2). The magnetic exchange coupling between the Cu^2^+ polyhedra is rather large and of antiferromagnetic nature. The electronic and elastic interactions underlying the observed cooperative Jahn-Teller order pattern are analyzed. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Atanasov, M. oth Zotov, N. oth Friebel, C. oth Petrov, K. oth Reinen, D. oth in Journal of Solid State Chemistry Amsterdam : Elsevier 108(1994), 1, Seite 37-45 (DE-627)NLEJ176864113 (DE-600)1469806-7 0022-4596 nnns volume:108 year:1994 number:1 pages:37-45 http://dx.doi.org/10.1006/jssc.1994.1006 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 108 1994 1 37-45 |
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(DE-627)NLEJ185540198 (DE-599)GBVNLZ185540198 DE-627 ger DE-627 rakwb eng Jahn-Teller Distortions and Cation Distribution in Cu(II)-Me(II) [Me = Mg, Co] Hydroxide Nitrate Solid Solutions-A Spectroscopic and Structural Study 1994 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it provides a larger Jahn-Teller distortion than the Me (OH)"5(ONO"2) site (2). The magnetic exchange coupling between the Cu^2^+ polyhedra is rather large and of antiferromagnetic nature. The electronic and elastic interactions underlying the observed cooperative Jahn-Teller order pattern are analyzed. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Atanasov, M. oth Zotov, N. oth Friebel, C. oth Petrov, K. oth Reinen, D. oth in Journal of Solid State Chemistry Amsterdam : Elsevier 108(1994), 1, Seite 37-45 (DE-627)NLEJ176864113 (DE-600)1469806-7 0022-4596 nnns volume:108 year:1994 number:1 pages:37-45 http://dx.doi.org/10.1006/jssc.1994.1006 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 108 1994 1 37-45 |
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(DE-627)NLEJ185540198 (DE-599)GBVNLZ185540198 DE-627 ger DE-627 rakwb eng Jahn-Teller Distortions and Cation Distribution in Cu(II)-Me(II) [Me = Mg, Co] Hydroxide Nitrate Solid Solutions-A Spectroscopic and Structural Study 1994 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it provides a larger Jahn-Teller distortion than the Me (OH)"5(ONO"2) site (2). The magnetic exchange coupling between the Cu^2^+ polyhedra is rather large and of antiferromagnetic nature. The electronic and elastic interactions underlying the observed cooperative Jahn-Teller order pattern are analyzed. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Atanasov, M. oth Zotov, N. oth Friebel, C. oth Petrov, K. oth Reinen, D. oth in Journal of Solid State Chemistry Amsterdam : Elsevier 108(1994), 1, Seite 37-45 (DE-627)NLEJ176864113 (DE-600)1469806-7 0022-4596 nnns volume:108 year:1994 number:1 pages:37-45 http://dx.doi.org/10.1006/jssc.1994.1006 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 108 1994 1 37-45 |
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(DE-627)NLEJ185540198 (DE-599)GBVNLZ185540198 DE-627 ger DE-627 rakwb eng Jahn-Teller Distortions and Cation Distribution in Cu(II)-Me(II) [Me = Mg, Co] Hydroxide Nitrate Solid Solutions-A Spectroscopic and Structural Study 1994 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it provides a larger Jahn-Teller distortion than the Me (OH)"5(ONO"2) site (2). The magnetic exchange coupling between the Cu^2^+ polyhedra is rather large and of antiferromagnetic nature. The electronic and elastic interactions underlying the observed cooperative Jahn-Teller order pattern are analyzed. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Atanasov, M. oth Zotov, N. oth Friebel, C. oth Petrov, K. oth Reinen, D. oth in Journal of Solid State Chemistry Amsterdam : Elsevier 108(1994), 1, Seite 37-45 (DE-627)NLEJ176864113 (DE-600)1469806-7 0022-4596 nnns volume:108 year:1994 number:1 pages:37-45 http://dx.doi.org/10.1006/jssc.1994.1006 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 108 1994 1 37-45 |
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Jahn-Teller Distortions and Cation Distribution in Cu(II)-Me(II) [Me = Mg, Co] Hydroxide Nitrate Solid Solutions-A Spectroscopic and Structural Study |
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jahn-teller distortions and cation distribution in cu(ii)-me(ii) [me = mg, co] hydroxide nitrate solid solutions-a spectroscopic and structural study |
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Jahn-Teller Distortions and Cation Distribution in Cu(II)-Me(II) [Me = Mg, Co] Hydroxide Nitrate Solid Solutions-A Spectroscopic and Structural Study |
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Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it provides a larger Jahn-Teller distortion than the Me (OH)"5(ONO"2) site (2). The magnetic exchange coupling between the Cu^2^+ polyhedra is rather large and of antiferromagnetic nature. The electronic and elastic interactions underlying the observed cooperative Jahn-Teller order pattern are analyzed. |
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Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it provides a larger Jahn-Teller distortion than the Me (OH)"5(ONO"2) site (2). The magnetic exchange coupling between the Cu^2^+ polyhedra is rather large and of antiferromagnetic nature. The electronic and elastic interactions underlying the observed cooperative Jahn-Teller order pattern are analyzed. |
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Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it provides a larger Jahn-Teller distortion than the Me (OH)"5(ONO"2) site (2). The magnetic exchange coupling between the Cu^2^+ polyhedra is rather large and of antiferromagnetic nature. The electronic and elastic interactions underlying the observed cooperative Jahn-Teller order pattern are analyzed. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ185540198</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230506181813.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070506s1994 xx |||||o 00| ||eng c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ185540198</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVNLZ185540198</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Jahn-Teller Distortions and Cation Distribution in Cu(II)-Me(II) [Me = Mg, Co] Hydroxide Nitrate Solid Solutions-A Spectroscopic and Structural Study</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1994</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Mixed crystals Me"2"-"xCu"x(OH)"3NO"3 (Me: Co^2^+, Mg^2^+) were investigated by spectroscopic (EPR, ligand field), structural, and magnetic methods. For 0 < x < 1 the Me(OH)"4(ONO"2)"2 site (1) is occupied with great preference by Cu^2^+, because it provides a larger Jahn-Teller distortion than the Me (OH)"5(ONO"2) site (2). The magnetic exchange coupling between the Cu^2^+ polyhedra is rather large and of antiferromagnetic nature. The electronic and elastic interactions underlying the observed cooperative Jahn-Teller order pattern are analyzed.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Elsevier Journal Backfiles on ScienceDirect 1907 - 2002</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Atanasov, M.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zotov, N.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Friebel, C.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Petrov, K.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Reinen, D.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Journal of Solid State Chemistry</subfield><subfield code="d">Amsterdam : Elsevier</subfield><subfield code="g">108(1994), 1, Seite 37-45</subfield><subfield code="w">(DE-627)NLEJ176864113</subfield><subfield code="w">(DE-600)1469806-7</subfield><subfield code="x">0022-4596</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:108</subfield><subfield code="g">year:1994</subfield><subfield code="g">number:1</subfield><subfield code="g">pages:37-45</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://dx.doi.org/10.1006/jssc.1994.1006</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_H</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-SDJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">108</subfield><subfield code="j">1994</subfield><subfield code="e">1</subfield><subfield code="h">37-45</subfield></datafield></record></collection>
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