Metabolism of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane in the rabbit
The neutral urinary excretion products of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane from the rabbit, dosed orally, were investigated. Column chromatography yielded five crystalline metabolites which were identified by GLC and spectroscopic measurements. Three of these substances were hydroxylated...
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| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1976 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
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| Übergeordnetes Werk: |
in: Steroids - Amsterdam : Elsevier, 27(1976), 5, Seite 581-593 |
| Übergeordnetes Werk: |
volume:27 ; year:1976 ; number:5 ; pages:581-593 |
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| 520 | |a The neutral urinary excretion products of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane from the rabbit, dosed orally, were investigated. Column chromatography yielded five crystalline metabolites which were identified by GLC and spectroscopic measurements. Three of these substances were hydroxylated in the 4α-position and one in the 6a-position with the cyclopropane ring intact. The fifth substance, 17β-hydroxy-3β-methyl-5α-androstan-2-one, can be derived from initial hydroxylation of the cyclopropane ring at C-2 followed by ring opening. The dosed substance and triol material was shown to be present by GLC and m.s. measurements. GLC determinations show that hydroxylation has occurred at C-4C-6>C-2. | ||
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(DE-627)NLEJ187872686 (DE-599)GBVNLZ187872686 DE-627 ger DE-627 rakwb eng Metabolism of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane in the rabbit 1976 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The neutral urinary excretion products of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane from the rabbit, dosed orally, were investigated. Column chromatography yielded five crystalline metabolites which were identified by GLC and spectroscopic measurements. Three of these substances were hydroxylated in the 4α-position and one in the 6a-position with the cyclopropane ring intact. The fifth substance, 17β-hydroxy-3β-methyl-5α-androstan-2-one, can be derived from initial hydroxylation of the cyclopropane ring at C-2 followed by ring opening. The dosed substance and triol material was shown to be present by GLC and m.s. measurements. GLC determinations show that hydroxylation has occurred at C-4C-6>C-2. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Templeton, J.F. oth Kim, R.-s.S. oth in Steroids Amsterdam : Elsevier 27(1976), 5, Seite 581-593 (DE-627)NLEJ17701184X (DE-600)1498762-4 0039-128X nnns volume:27 year:1976 number:5 pages:581-593 http://dx.doi.org/10.1016/S0039-128X(76)90064-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 27 1976 5 581-593 |
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(DE-627)NLEJ187872686 (DE-599)GBVNLZ187872686 DE-627 ger DE-627 rakwb eng Metabolism of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane in the rabbit 1976 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The neutral urinary excretion products of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane from the rabbit, dosed orally, were investigated. Column chromatography yielded five crystalline metabolites which were identified by GLC and spectroscopic measurements. Three of these substances were hydroxylated in the 4α-position and one in the 6a-position with the cyclopropane ring intact. The fifth substance, 17β-hydroxy-3β-methyl-5α-androstan-2-one, can be derived from initial hydroxylation of the cyclopropane ring at C-2 followed by ring opening. The dosed substance and triol material was shown to be present by GLC and m.s. measurements. GLC determinations show that hydroxylation has occurred at C-4C-6>C-2. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Templeton, J.F. oth Kim, R.-s.S. oth in Steroids Amsterdam : Elsevier 27(1976), 5, Seite 581-593 (DE-627)NLEJ17701184X (DE-600)1498762-4 0039-128X nnns volume:27 year:1976 number:5 pages:581-593 http://dx.doi.org/10.1016/S0039-128X(76)90064-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 27 1976 5 581-593 |
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(DE-627)NLEJ187872686 (DE-599)GBVNLZ187872686 DE-627 ger DE-627 rakwb eng Metabolism of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane in the rabbit 1976 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The neutral urinary excretion products of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane from the rabbit, dosed orally, were investigated. Column chromatography yielded five crystalline metabolites which were identified by GLC and spectroscopic measurements. Three of these substances were hydroxylated in the 4α-position and one in the 6a-position with the cyclopropane ring intact. The fifth substance, 17β-hydroxy-3β-methyl-5α-androstan-2-one, can be derived from initial hydroxylation of the cyclopropane ring at C-2 followed by ring opening. The dosed substance and triol material was shown to be present by GLC and m.s. measurements. GLC determinations show that hydroxylation has occurred at C-4C-6>C-2. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Templeton, J.F. oth Kim, R.-s.S. oth in Steroids Amsterdam : Elsevier 27(1976), 5, Seite 581-593 (DE-627)NLEJ17701184X (DE-600)1498762-4 0039-128X nnns volume:27 year:1976 number:5 pages:581-593 http://dx.doi.org/10.1016/S0039-128X(76)90064-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 27 1976 5 581-593 |
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(DE-627)NLEJ187872686 (DE-599)GBVNLZ187872686 DE-627 ger DE-627 rakwb eng Metabolism of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane in the rabbit 1976 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The neutral urinary excretion products of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane from the rabbit, dosed orally, were investigated. Column chromatography yielded five crystalline metabolites which were identified by GLC and spectroscopic measurements. Three of these substances were hydroxylated in the 4α-position and one in the 6a-position with the cyclopropane ring intact. The fifth substance, 17β-hydroxy-3β-methyl-5α-androstan-2-one, can be derived from initial hydroxylation of the cyclopropane ring at C-2 followed by ring opening. The dosed substance and triol material was shown to be present by GLC and m.s. measurements. GLC determinations show that hydroxylation has occurred at C-4C-6>C-2. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Templeton, J.F. oth Kim, R.-s.S. oth in Steroids Amsterdam : Elsevier 27(1976), 5, Seite 581-593 (DE-627)NLEJ17701184X (DE-600)1498762-4 0039-128X nnns volume:27 year:1976 number:5 pages:581-593 http://dx.doi.org/10.1016/S0039-128X(76)90064-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 27 1976 5 581-593 |
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(DE-627)NLEJ187872686 (DE-599)GBVNLZ187872686 DE-627 ger DE-627 rakwb eng Metabolism of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane in the rabbit 1976 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The neutral urinary excretion products of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane from the rabbit, dosed orally, were investigated. Column chromatography yielded five crystalline metabolites which were identified by GLC and spectroscopic measurements. Three of these substances were hydroxylated in the 4α-position and one in the 6a-position with the cyclopropane ring intact. The fifth substance, 17β-hydroxy-3β-methyl-5α-androstan-2-one, can be derived from initial hydroxylation of the cyclopropane ring at C-2 followed by ring opening. The dosed substance and triol material was shown to be present by GLC and m.s. measurements. GLC determinations show that hydroxylation has occurred at C-4C-6>C-2. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Templeton, J.F. oth Kim, R.-s.S. oth in Steroids Amsterdam : Elsevier 27(1976), 5, Seite 581-593 (DE-627)NLEJ17701184X (DE-600)1498762-4 0039-128X nnns volume:27 year:1976 number:5 pages:581-593 http://dx.doi.org/10.1016/S0039-128X(76)90064-7 GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 27 1976 5 581-593 |
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metabolism of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane in the rabbit |
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Metabolism of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane in the rabbit |
| abstract |
The neutral urinary excretion products of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane from the rabbit, dosed orally, were investigated. Column chromatography yielded five crystalline metabolites which were identified by GLC and spectroscopic measurements. Three of these substances were hydroxylated in the 4α-position and one in the 6a-position with the cyclopropane ring intact. The fifth substance, 17β-hydroxy-3β-methyl-5α-androstan-2-one, can be derived from initial hydroxylation of the cyclopropane ring at C-2 followed by ring opening. The dosed substance and triol material was shown to be present by GLC and m.s. measurements. GLC determinations show that hydroxylation has occurred at C-4C-6>C-2. |
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The neutral urinary excretion products of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane from the rabbit, dosed orally, were investigated. Column chromatography yielded five crystalline metabolites which were identified by GLC and spectroscopic measurements. Three of these substances were hydroxylated in the 4α-position and one in the 6a-position with the cyclopropane ring intact. The fifth substance, 17β-hydroxy-3β-methyl-5α-androstan-2-one, can be derived from initial hydroxylation of the cyclopropane ring at C-2 followed by ring opening. The dosed substance and triol material was shown to be present by GLC and m.s. measurements. GLC determinations show that hydroxylation has occurred at C-4C-6>C-2. |
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The neutral urinary excretion products of 17β-hydroxy-2α,3α-cyclopropano-5α-androstane from the rabbit, dosed orally, were investigated. Column chromatography yielded five crystalline metabolites which were identified by GLC and spectroscopic measurements. Three of these substances were hydroxylated in the 4α-position and one in the 6a-position with the cyclopropane ring intact. The fifth substance, 17β-hydroxy-3β-methyl-5α-androstan-2-one, can be derived from initial hydroxylation of the cyclopropane ring at C-2 followed by ring opening. The dosed substance and triol material was shown to be present by GLC and m.s. measurements. GLC determinations show that hydroxylation has occurred at C-4C-6>C-2. |
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