Evaluation of stability constants of complexes based on irreversible polarograpihc waves with variable electrode mechanism - Part II. The Ni^2^+-C"2O"4^2^- system
The polarographic reduction of Ni(II)-oxalate complexes proceeds through the electrode reaction of aquo-ion and of the NiC"2O"4 complex with the rate constants k"0^0=1.63 x 10^-^3s^-^1, k"1^0=4.15 x 10^-^4s^-^1 (at potential 0.982 V vs. SCE as reference potential). The Ni(C"...
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Gespeichert in:
| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1981 |
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| Reproduktion: |
Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 |
|---|---|
| Übergeordnetes Werk: |
in: Journal of Electroanalytical Chemistry - Amsterdam : Elsevier, 130(1981), Seite 141-151 |
| Übergeordnetes Werk: |
volume:130 ; year:1981 ; pages:141-151 |
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| 245 | 1 | 0 | |a Evaluation of stability constants of complexes based on irreversible polarograpihc waves with variable electrode mechanism - Part II. The Ni^2^+-C"2O"4^2^- system |
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| 520 | |a The polarographic reduction of Ni(II)-oxalate complexes proceeds through the electrode reaction of aquo-ion and of the NiC"2O"4 complex with the rate constants k"0^0=1.63 x 10^-^3s^-^1, k"1^0=4.15 x 10^-^4s^-^1 (at potential 0.982 V vs. SCE as reference potential). The Ni(C"2O"4)"2^2^- complex was found to be non-labile, and thus responsible for considerable lowering of the limiting current. Stability constants of complexes logsβ"1 = 4.255 and logβ"2 = 7.544 were calculated from polarographic data. | ||
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(DE-627)NLEJ188189416 (DE-599)GBVNLZ188189416 DE-627 ger DE-627 rakwb eng Evaluation of stability constants of complexes based on irreversible polarograpihc waves with variable electrode mechanism - Part II. The Ni^2^+-C"2O"4^2^- system 1981 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The polarographic reduction of Ni(II)-oxalate complexes proceeds through the electrode reaction of aquo-ion and of the NiC"2O"4 complex with the rate constants k"0^0=1.63 x 10^-^3s^-^1, k"1^0=4.15 x 10^-^4s^-^1 (at potential 0.982 V vs. SCE as reference potential). The Ni(C"2O"4)"2^2^- complex was found to be non-labile, and thus responsible for considerable lowering of the limiting current. Stability constants of complexes logsβ"1 = 4.255 and logβ"2 = 7.544 were calculated from polarographic data. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Urbanska, J. oth Biernat, J. oth in Journal of Electroanalytical Chemistry Amsterdam : Elsevier 130(1981), Seite 141-151 (DE-627)NLEJ188047972 (DE-600)1491150-4 0368-1874 nnns volume:130 year:1981 pages:141-151 http://linkinghub.elsevier.com/retrieve/pii/0368-1874(81)87431-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 130 1981 141-151 |
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(DE-627)NLEJ188189416 (DE-599)GBVNLZ188189416 DE-627 ger DE-627 rakwb eng Evaluation of stability constants of complexes based on irreversible polarograpihc waves with variable electrode mechanism - Part II. The Ni^2^+-C"2O"4^2^- system 1981 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The polarographic reduction of Ni(II)-oxalate complexes proceeds through the electrode reaction of aquo-ion and of the NiC"2O"4 complex with the rate constants k"0^0=1.63 x 10^-^3s^-^1, k"1^0=4.15 x 10^-^4s^-^1 (at potential 0.982 V vs. SCE as reference potential). The Ni(C"2O"4)"2^2^- complex was found to be non-labile, and thus responsible for considerable lowering of the limiting current. Stability constants of complexes logsβ"1 = 4.255 and logβ"2 = 7.544 were calculated from polarographic data. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Urbanska, J. oth Biernat, J. oth in Journal of Electroanalytical Chemistry Amsterdam : Elsevier 130(1981), Seite 141-151 (DE-627)NLEJ188047972 (DE-600)1491150-4 0368-1874 nnns volume:130 year:1981 pages:141-151 http://linkinghub.elsevier.com/retrieve/pii/0368-1874(81)87431-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 130 1981 141-151 |
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(DE-627)NLEJ188189416 (DE-599)GBVNLZ188189416 DE-627 ger DE-627 rakwb eng Evaluation of stability constants of complexes based on irreversible polarograpihc waves with variable electrode mechanism - Part II. The Ni^2^+-C"2O"4^2^- system 1981 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The polarographic reduction of Ni(II)-oxalate complexes proceeds through the electrode reaction of aquo-ion and of the NiC"2O"4 complex with the rate constants k"0^0=1.63 x 10^-^3s^-^1, k"1^0=4.15 x 10^-^4s^-^1 (at potential 0.982 V vs. SCE as reference potential). The Ni(C"2O"4)"2^2^- complex was found to be non-labile, and thus responsible for considerable lowering of the limiting current. Stability constants of complexes logsβ"1 = 4.255 and logβ"2 = 7.544 were calculated from polarographic data. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Urbanska, J. oth Biernat, J. oth in Journal of Electroanalytical Chemistry Amsterdam : Elsevier 130(1981), Seite 141-151 (DE-627)NLEJ188047972 (DE-600)1491150-4 0368-1874 nnns volume:130 year:1981 pages:141-151 http://linkinghub.elsevier.com/retrieve/pii/0368-1874(81)87431-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 130 1981 141-151 |
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(DE-627)NLEJ188189416 (DE-599)GBVNLZ188189416 DE-627 ger DE-627 rakwb eng Evaluation of stability constants of complexes based on irreversible polarograpihc waves with variable electrode mechanism - Part II. The Ni^2^+-C"2O"4^2^- system 1981 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The polarographic reduction of Ni(II)-oxalate complexes proceeds through the electrode reaction of aquo-ion and of the NiC"2O"4 complex with the rate constants k"0^0=1.63 x 10^-^3s^-^1, k"1^0=4.15 x 10^-^4s^-^1 (at potential 0.982 V vs. SCE as reference potential). The Ni(C"2O"4)"2^2^- complex was found to be non-labile, and thus responsible for considerable lowering of the limiting current. Stability constants of complexes logsβ"1 = 4.255 and logβ"2 = 7.544 were calculated from polarographic data. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Urbanska, J. oth Biernat, J. oth in Journal of Electroanalytical Chemistry Amsterdam : Elsevier 130(1981), Seite 141-151 (DE-627)NLEJ188047972 (DE-600)1491150-4 0368-1874 nnns volume:130 year:1981 pages:141-151 http://linkinghub.elsevier.com/retrieve/pii/0368-1874(81)87431-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 130 1981 141-151 |
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(DE-627)NLEJ188189416 (DE-599)GBVNLZ188189416 DE-627 ger DE-627 rakwb eng Evaluation of stability constants of complexes based on irreversible polarograpihc waves with variable electrode mechanism - Part II. The Ni^2^+-C"2O"4^2^- system 1981 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier The polarographic reduction of Ni(II)-oxalate complexes proceeds through the electrode reaction of aquo-ion and of the NiC"2O"4 complex with the rate constants k"0^0=1.63 x 10^-^3s^-^1, k"1^0=4.15 x 10^-^4s^-^1 (at potential 0.982 V vs. SCE as reference potential). The Ni(C"2O"4)"2^2^- complex was found to be non-labile, and thus responsible for considerable lowering of the limiting current. Stability constants of complexes logsβ"1 = 4.255 and logβ"2 = 7.544 were calculated from polarographic data. Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 Urbanska, J. oth Biernat, J. oth in Journal of Electroanalytical Chemistry Amsterdam : Elsevier 130(1981), Seite 141-151 (DE-627)NLEJ188047972 (DE-600)1491150-4 0368-1874 nnns volume:130 year:1981 pages:141-151 http://linkinghub.elsevier.com/retrieve/pii/0368-1874(81)87431-X GBV_USEFLAG_H ZDB-1-SDJ GBV_NL_ARTICLE AR 130 1981 141-151 |
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evaluation of stability constants of complexes based on irreversible polarograpihc waves with variable electrode mechanism - part ii. the ni^2^+-c"2o"4^2^- system |
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Evaluation of stability constants of complexes based on irreversible polarograpihc waves with variable electrode mechanism - Part II. The Ni^2^+-C"2O"4^2^- system |
| abstract |
The polarographic reduction of Ni(II)-oxalate complexes proceeds through the electrode reaction of aquo-ion and of the NiC"2O"4 complex with the rate constants k"0^0=1.63 x 10^-^3s^-^1, k"1^0=4.15 x 10^-^4s^-^1 (at potential 0.982 V vs. SCE as reference potential). The Ni(C"2O"4)"2^2^- complex was found to be non-labile, and thus responsible for considerable lowering of the limiting current. Stability constants of complexes logsβ"1 = 4.255 and logβ"2 = 7.544 were calculated from polarographic data. |
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The polarographic reduction of Ni(II)-oxalate complexes proceeds through the electrode reaction of aquo-ion and of the NiC"2O"4 complex with the rate constants k"0^0=1.63 x 10^-^3s^-^1, k"1^0=4.15 x 10^-^4s^-^1 (at potential 0.982 V vs. SCE as reference potential). The Ni(C"2O"4)"2^2^- complex was found to be non-labile, and thus responsible for considerable lowering of the limiting current. Stability constants of complexes logsβ"1 = 4.255 and logβ"2 = 7.544 were calculated from polarographic data. |
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The polarographic reduction of Ni(II)-oxalate complexes proceeds through the electrode reaction of aquo-ion and of the NiC"2O"4 complex with the rate constants k"0^0=1.63 x 10^-^3s^-^1, k"1^0=4.15 x 10^-^4s^-^1 (at potential 0.982 V vs. SCE as reference potential). The Ni(C"2O"4)"2^2^- complex was found to be non-labile, and thus responsible for considerable lowering of the limiting current. Stability constants of complexes logsβ"1 = 4.255 and logβ"2 = 7.544 were calculated from polarographic data. |
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