Macromolecular compounds
Summary 1. A method has been developed for the determination of the thernal stability and decomposition kinetics for organic carboxylic acids. 2. The decarboxylation temperatures have been determined for oxalic, malonic, succinic, glutaric, adipic, suberic, azelaic, and sebacic acids. 3. It has been...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1952 |
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| Umfang: |
7 |
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| Reproduktion: |
Springer Online Journal Archives 1860-2002 |
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| Übergeordnetes Werk: |
in: Russian chemical bulletin - 1952, 1(1952) vom: März, Seite 509-515 |
| Übergeordnetes Werk: |
volume:1 ; year:1952 ; month:03 ; pages:509-515 ; extent:7 |
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NLEJ19198728X |
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| 520 | |a Summary 1. A method has been developed for the determination of the thernal stability and decomposition kinetics for organic carboxylic acids. 2. The decarboxylation temperatures have been determined for oxalic, malonic, succinic, glutaric, adipic, suberic, azelaic, and sebacic acids. 3. It has been found that dicarboxylic acids having an odd number of carbon atoms decompose at lower temperatures than acids having an even number of carbon atoms. 4. It has been shown that the thermal stability of the acid increases as we proceed from the lower t the higher members of the homologous series of dicarboxylic acids. 5. It has been shown that decarboxylation of dicarboxylic acids must play a considerable inhibiting role in the course of the polycondensation of these acids with bifunctional substances. | ||
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| 700 | 1 | |a Korshak, V. V. |4 oth | |
| 700 | 1 | |a Rogozhin, S. V. |4 oth | |
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(DE-627)NLEJ19198728X DE-627 ger DE-627 rakwb eng Macromolecular compounds 1952 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Summary 1. A method has been developed for the determination of the thernal stability and decomposition kinetics for organic carboxylic acids. 2. The decarboxylation temperatures have been determined for oxalic, malonic, succinic, glutaric, adipic, suberic, azelaic, and sebacic acids. 3. It has been found that dicarboxylic acids having an odd number of carbon atoms decompose at lower temperatures than acids having an even number of carbon atoms. 4. It has been shown that the thermal stability of the acid increases as we proceed from the lower t the higher members of the homologous series of dicarboxylic acids. 5. It has been shown that decarboxylation of dicarboxylic acids must play a considerable inhibiting role in the course of the polycondensation of these acids with bifunctional substances. Springer Online Journal Archives 1860-2002 Korshak, V. V. oth Rogozhin, S. V. oth in Russian chemical bulletin 1952 1(1952) vom: März, Seite 509-515 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:1 year:1952 month:03 pages:509-515 extent:7 http://dx.doi.org/10.1007/BF01172006 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 1 1952 3 509-515 7 |
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(DE-627)NLEJ19198728X DE-627 ger DE-627 rakwb eng Macromolecular compounds 1952 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Summary 1. A method has been developed for the determination of the thernal stability and decomposition kinetics for organic carboxylic acids. 2. The decarboxylation temperatures have been determined for oxalic, malonic, succinic, glutaric, adipic, suberic, azelaic, and sebacic acids. 3. It has been found that dicarboxylic acids having an odd number of carbon atoms decompose at lower temperatures than acids having an even number of carbon atoms. 4. It has been shown that the thermal stability of the acid increases as we proceed from the lower t the higher members of the homologous series of dicarboxylic acids. 5. It has been shown that decarboxylation of dicarboxylic acids must play a considerable inhibiting role in the course of the polycondensation of these acids with bifunctional substances. Springer Online Journal Archives 1860-2002 Korshak, V. V. oth Rogozhin, S. V. oth in Russian chemical bulletin 1952 1(1952) vom: März, Seite 509-515 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:1 year:1952 month:03 pages:509-515 extent:7 http://dx.doi.org/10.1007/BF01172006 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 1 1952 3 509-515 7 |
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(DE-627)NLEJ19198728X DE-627 ger DE-627 rakwb eng Macromolecular compounds 1952 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Summary 1. A method has been developed for the determination of the thernal stability and decomposition kinetics for organic carboxylic acids. 2. The decarboxylation temperatures have been determined for oxalic, malonic, succinic, glutaric, adipic, suberic, azelaic, and sebacic acids. 3. It has been found that dicarboxylic acids having an odd number of carbon atoms decompose at lower temperatures than acids having an even number of carbon atoms. 4. It has been shown that the thermal stability of the acid increases as we proceed from the lower t the higher members of the homologous series of dicarboxylic acids. 5. It has been shown that decarboxylation of dicarboxylic acids must play a considerable inhibiting role in the course of the polycondensation of these acids with bifunctional substances. Springer Online Journal Archives 1860-2002 Korshak, V. V. oth Rogozhin, S. V. oth in Russian chemical bulletin 1952 1(1952) vom: März, Seite 509-515 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:1 year:1952 month:03 pages:509-515 extent:7 http://dx.doi.org/10.1007/BF01172006 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 1 1952 3 509-515 7 |
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(DE-627)NLEJ19198728X DE-627 ger DE-627 rakwb eng Macromolecular compounds 1952 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Summary 1. A method has been developed for the determination of the thernal stability and decomposition kinetics for organic carboxylic acids. 2. The decarboxylation temperatures have been determined for oxalic, malonic, succinic, glutaric, adipic, suberic, azelaic, and sebacic acids. 3. It has been found that dicarboxylic acids having an odd number of carbon atoms decompose at lower temperatures than acids having an even number of carbon atoms. 4. It has been shown that the thermal stability of the acid increases as we proceed from the lower t the higher members of the homologous series of dicarboxylic acids. 5. It has been shown that decarboxylation of dicarboxylic acids must play a considerable inhibiting role in the course of the polycondensation of these acids with bifunctional substances. Springer Online Journal Archives 1860-2002 Korshak, V. V. oth Rogozhin, S. V. oth in Russian chemical bulletin 1952 1(1952) vom: März, Seite 509-515 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:1 year:1952 month:03 pages:509-515 extent:7 http://dx.doi.org/10.1007/BF01172006 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 1 1952 3 509-515 7 |
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(DE-627)NLEJ19198728X DE-627 ger DE-627 rakwb eng Macromolecular compounds 1952 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Summary 1. A method has been developed for the determination of the thernal stability and decomposition kinetics for organic carboxylic acids. 2. The decarboxylation temperatures have been determined for oxalic, malonic, succinic, glutaric, adipic, suberic, azelaic, and sebacic acids. 3. It has been found that dicarboxylic acids having an odd number of carbon atoms decompose at lower temperatures than acids having an even number of carbon atoms. 4. It has been shown that the thermal stability of the acid increases as we proceed from the lower t the higher members of the homologous series of dicarboxylic acids. 5. It has been shown that decarboxylation of dicarboxylic acids must play a considerable inhibiting role in the course of the polycondensation of these acids with bifunctional substances. Springer Online Journal Archives 1860-2002 Korshak, V. V. oth Rogozhin, S. V. oth in Russian chemical bulletin 1952 1(1952) vom: März, Seite 509-515 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:1 year:1952 month:03 pages:509-515 extent:7 http://dx.doi.org/10.1007/BF01172006 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 1 1952 3 509-515 7 |
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Summary 1. A method has been developed for the determination of the thernal stability and decomposition kinetics for organic carboxylic acids. 2. The decarboxylation temperatures have been determined for oxalic, malonic, succinic, glutaric, adipic, suberic, azelaic, and sebacic acids. 3. It has been found that dicarboxylic acids having an odd number of carbon atoms decompose at lower temperatures than acids having an even number of carbon atoms. 4. It has been shown that the thermal stability of the acid increases as we proceed from the lower t the higher members of the homologous series of dicarboxylic acids. 5. It has been shown that decarboxylation of dicarboxylic acids must play a considerable inhibiting role in the course of the polycondensation of these acids with bifunctional substances. |
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Summary 1. A method has been developed for the determination of the thernal stability and decomposition kinetics for organic carboxylic acids. 2. The decarboxylation temperatures have been determined for oxalic, malonic, succinic, glutaric, adipic, suberic, azelaic, and sebacic acids. 3. It has been found that dicarboxylic acids having an odd number of carbon atoms decompose at lower temperatures than acids having an even number of carbon atoms. 4. It has been shown that the thermal stability of the acid increases as we proceed from the lower t the higher members of the homologous series of dicarboxylic acids. 5. It has been shown that decarboxylation of dicarboxylic acids must play a considerable inhibiting role in the course of the polycondensation of these acids with bifunctional substances. |
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Summary 1. A method has been developed for the determination of the thernal stability and decomposition kinetics for organic carboxylic acids. 2. The decarboxylation temperatures have been determined for oxalic, malonic, succinic, glutaric, adipic, suberic, azelaic, and sebacic acids. 3. It has been found that dicarboxylic acids having an odd number of carbon atoms decompose at lower temperatures than acids having an even number of carbon atoms. 4. It has been shown that the thermal stability of the acid increases as we proceed from the lower t the higher members of the homologous series of dicarboxylic acids. 5. It has been shown that decarboxylation of dicarboxylic acids must play a considerable inhibiting role in the course of the polycondensation of these acids with bifunctional substances. |
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